AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

In this study, the application of freeze-concentration method to treat low-concentration polluted water was demonstrated. The effects of stirring, the temperature in a freezing cabinet and the volume of water involved in the freeze-concentration treatment of pollutants were investigated under laboratory conditions. The removal of pollutant by freeze-concentration treatment was also attempted. Results had shown that the ratio of pollutants removed was about 83% when the experiment was carried out...
Autori: Yingjie Dai, Ying Zhang, Baiyin Liu, Masahiro Teduka, Yongbo Lin, Shunitz Tanakahttp://www.ecozone.ro/reviste.php?RID=25709

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

Marine species (n=36) available in a supermarket of Cluj-Napoca city, Romania were collected and analyzed for the levels of heavy metals (Cr, Cu, Zn, Cd, Pb, Hg) and As, polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and analogous, hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB). The collection included samples from twelve fish groups (sardine, tuna, herring, pangasius, marbled rockcod, hake, shrimp, pink shrimp, lo...
Autori: Adriana Gog, Claudiu Tanaselia, Ioan Ştefan Groza, Marin Senila, Mirela Miclean, Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25863

AbstractTo understand the typical organic pollutant contamination status of the main source water in Yellow River basin, samples werecollected from fifty source water points (including reservoir and river) in Yellow River basin. The samples were analyzed for therepresentative organic pollutants, including benzene homologous, chlorobenzene compounds, organophosphorous pesticides, and nitrobenzene compounds, total of 17 compounds. It was observed that all concentrations of the 17 compounds in the ...
Autori: Jijun Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26155

AbstractThe monitored natural attenuation (MNA) of groundwater contamination is in many cases considered to be a cost-effective andappropriate strategy to manage the remediation of contaminated aquifers. A prerequisite for the public acceptance of such NAremediationapproaches is that the efficiency of the presumed NA-processes should be proven. This proof must be based on anextensive hydrogeological and in-situ characterization of the ongoing aquifer processes. Additional investigations of aquif...
Autori: Achim Möller, Anja Berning, Anne Berghoff, Bernd Mahro, Christoph Wortmann
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26312

AbstractDue to its toxicity, persistence in the environment and specific properties, 1,2-dichlorobenzene (DCB) has been listed as apriority pollutant by the European Agency. In this study, the oxidation with ozone alone as well as in combination withultraviolet irradiation was applied for the degradation of DCB. This article presents the abatements obtained, after the varioustreatments proposed, in the levels of chemical pollution as monitored by chromatographic techniques (GC/ECD, GC/MS andHPLC...
Autori: Bertrand Sancey, Corina Bradu, Grégorio Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26328

Abstract Established applications of emulsion liquid membranes (ELM) refer to refining in hydrocarbons and hydrometallurgical processing, rehabilitation of poisoned patients. In this work we investigated the separation of aromatic compounds of biological interest, more often encountered as intermediates in dyes and drugs industry: aniline, nitrobenzene, ortho and para-toluidine, using emulsion liquid membranes. The experimental results showed that in the case of basic substances separation t...
Autori: Alexandra Raluca Miron
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26650

Abstract The present study explores the potential of Streptococcus epidermis, an indigenous isolate for biotransformation of phenol and phenol derivatives. Different phenolic derivatives such as 4-methylphenol, methylbenzene, 2,4-dichlorophenol, 2,6- dichlorophenol and 4-nitrophenol were attempted for biotransformation study. The results have shown that 4-nitrophenol was best transformed. The effect of degradation parameters like pH and temperature was studied, showing the value of 7.0 as o...
Autori: Bhavana V. Mohite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26705

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract A VOC monitoring was carried out inside and outside a multi-storey car park in order to characterize the emission profile of vehicular traffic source in an indoor environment. BTEX, and in particular toluene, were the most abundant compounds in all monitored sites, with different compositions between indoor parking areas and outdoor sites. The motor vehicle exhaust and gasoline vapor emission in these enclosed parking garages were characterized by diffusion or degradation phenomena ...
Autori: Gianluigi de Gennaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26778

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract A study of a classical BLEVE fireball model associated with a toxic Puff release one was made in order to evaluate the influence of accident conjugate conditions on its consequences in two neighbouring industrial plants. The possible occurrence of the Domino effect is also exemplified for the approached chemical complex including two sensitive neighbouring chemical plants including tubular reactors for catalytic oxidation of butane to maleic anhydride and catalytic hydrogenation of ...
Autori: Hasan Hadi Salman Khwayyir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26880

Abstract Safe operation of highly thermally sensitive industrial reactors is still considered a major issue in chemical engineering practice. The problem becomes even more stringent when highly exothermic reactions are conducted under randomly fluctuating operating variables, and especially when the set-point is located in a close vicinity of the runaway boundaries for increasing the reactor productivity. This study is aiming to derive the runaway boundaries and their associated region of co...
Autori: Constantin Muscalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26884

Abstract Much attention is paid to removing formaldehyde from indoor air to decrease the health risk for urban inhabitants since formaldehyde is a main indoor pollutant causing various symptoms. In this study, formaldehyde removal by the shoots of potted Chlorphytum comosum (spider plant), Epipremnum aureum (golden pothos) and Aloe vera (aloe) was investigated with a dynamic chamber technique. The results indicated that the order of formaldehyde removal capacities for the plant shoots was C....
Autori: Haiping Hou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26908

In the presence of surfactant sodium dodecylbenzene sulfonate (SDBS), the development of main hydrolysis products (soluble carbohydrate and protein) and hydrolytic enzyme activities (amylase and protease) were monitored during microaerobic thermophilic digestion (MATD) of waste activated sludge (WAS). Results showed that the presence of SDBS remarkably increased the solubility of protein and carbohydrate into aqueous phase. The maximal concentration of carbohydrate and protein was 990.39 and...
Autori: Qi Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26958

The removal of toxic heavy metal ions such as lead and zinc from industrial and mining wastewaters has been widely studied because their existence in surface and underground water is responsible for several types of health problems caused to animals and human beings. Also, there are some organic compounds, which must be prevented from reaching in drinking water from various sources of pollution. For these reasons in this paper the experiments were conducted to study the ability of activated ...
Autori: Cristina Ileana Covaliu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27027

The selection of proper compounds to include in perfumes’ formulation is of particular interest for the perfume industry. Essential oils and perfumes are subject to quality control as well as to chemical characterization; therefore, GC/MS-O methodology can be considered a useful tool for research purposes and/or for improving industrial manufacturing processes. In this study, GC/MS-O methodology was applied to a commercial brand perfume and a natural-derived one, both characterized by ...
Autori: Antonella Amenduni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27125

Common issues of the gasification systems relate to filtering apparatus. Dry filtering processes are simple and reliable. However, the filtering material defines the maximum and minimum temperature at which the filter can operate properly. In addition, dry filtration is not effective on light tar compounds (i.e. benzene and toluene) or ammonia compounds. On the other hand, despite being very efficient, wet filters drop the gas temperature below the line of condensation of tar, ammonia and ste...
Autori: Giulio Allesina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27412

Average emission factors of air toxic compounds, emitted from motorcycles in Bangkok, Thailand were analyzed using the IVE (International Vehicle Emission) model. The model was utilized taking into account the actual fleet and characteristics of motorcycles of the study area. Four air toxic compounds (namely benzene, 1,3 butadiene, acetaldehyde and formaldehyde) and their emission rates were calculated under two main pollution abatement scenarios (the improvement of fuel quality and switching of...
Autori: Pantitcha Outapa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27513

This study undertakes to characterize through thermal analysis in dynamic conditions a wide range of building materials used for various types of insulation and presents for the first time a comparative analysis of their thermal stability. To this effect, the dynamic thermal analysis TG/DTG was applied. The results show a degradation resulting in one, two or three stages after a complex mechanism, with different mass loss, depending on the structure and atmosphere in which the thermal decomposit...
Autori: Andreea-Camelia Sprânceană
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27514

A series of column experiments were conducted to study volatile contaminant (benzene) removal and process principles using soil vapor extraction (SVE) under different thermal conditions. Compared with the normal SVE method, two thermal methodssteam injection and electrical resistance heating effectively increased the benzene vapor diffusion and removal rates. The removal efficiency of benzene with the electrical resistance heating method was 96.5%, which was significantly higher than that with t...
Autori: Peng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27534

Organoarsenic compounds are used extensively as swine feed-additives to promote animal growth and control diseases, e.g. roxarsone (4-hydroxy-3-nitrobenzenearsonic acid) and arsanilic acid (4-aminophenylarsonic acid) are usually overused in swine industry in China. As a cost-effective technology for animal manure treatment and reuse, composting is widely used for swine manure treatment. Therefore, the purpose of this study was to investigate changes of arsenic species and fractions during a full...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27683

The bioremediation represents an ongoing challenge, especially in the case of organochlorinated compounds, due to the difficulties in their degradation that causes persistence in the environment. Herein we report a study on the ability of a mixture of microorganisms (MOM) to interact with organochlorinated compounds belonging to different chemical classes, i.e. DDT, PCB, tetrachlorobenzene, and lindane. Experiments in vitro showed the disappearance, partially reversible of these compounds in mix...
Autori: Carla Boga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27784

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

During the 2014-2015 period of environmental air quality research, concentrations of NO2, SO2 and BTEX (benzene, toluene, ethylbenzene and xylenes) and PM10 were measured. In order to evaluate the spatial distribution of pollutants, 5 sampling sites in Anykščiai city (Lithuania) were chosen. Measured values of NO2, SO2, PM10 and benzene were compared with limit values set for these pollutants in ambient air according to 2008/50/EC and 2000/69/EC directives. Toluene, ethylbenzene, ...
Autori: Dainius Paliulis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27926

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

At present, the production of oily sludge is huge, and the micro-emulsion method can effectively separate crude oil and water from the oily sludge by reducing the interfacial tension between oil and cement. In this paper, the micro-emulsion was prepared by using surfactants, such as sodium dodecyl benzene sulfonate (SDBS), cetyltrimethylammonium chloride (CTAB), sodium dodecyl sulfonate (SDS), sodium cetyl sulfate (CAS), and alkylphenol polyoxyethylene ether (OP-10) as the main raw materials. T...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28344