Contain all the articles from this issueEditorialEstablishing effluent discharge limits - have we got it right?Yusuf Chisti Full papersSurvey on the treatment of gaseous streams containing volatile organic compoundsOana Penciu, Maria GavrilescuEU environmental policy for industrial pollution control. IPPC DirectiveElena Bobu Environmental monitoring Antonius A.F. KettrupProcess The sonochemical degradationof cyanide ions using atmospheric oxygen as oxidizing agentIoan Iordache, Mircea Teodor Nec...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25171

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

AbstractThe paper presents the research made on the FP7 project „Magnetic Sorting and Ultrasound Sensor Technologies for Productionof High Purity Secondary Polyolefins from Waste” in order to develop a magnetic fluid equipment for sorting of polypropylene(PP) and polyethylene (PE) from polymers mixed waste streams. Because both PP and PE float in water, it is difficult to separateone from the other. The paper presents the principles of inverse magnetic density separation process and the results ...
Autori: Bin Hu, Francesco Di Maio, Guillaume Houzeaux, Liana Baltes, Mircea Tierean, Peter Rem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26028

AbstractThe aim of this work is to study the valorisation of two regenerated low density polyethylene (LDPE) coming from dirty wastesby blending with polypropylene (PP) in presence of compatibilizer. The first step was the determination of the physico-chemicalproperties of the two regenerated samples (density, melt flow index, water absorption, melting temperature and oxidation index)and the mechanical properties (tensile and shore D hardness).The second step was the characterization of the phys...
Autori: Nabila Guerfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26565

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

Nowadays, the polyolefins (polyethylene, polypropylene) are increasingly consumed in large amounts for many applications. This issue causes a concern regarding the environmental impact of the waste materials generated after the first use. Mechanical recycling of polyolefin wastes helps to conserve oil and gas resources and reduce the polymeric waste accumulation in environment. In this paper, the modification of some post-consumer polypropylene (rPP) properties coming from packaging processi...
Autori: Maria Râpă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27493

This paper introduces basic information on the biodegradation of polymers as well as the mechanisms of degradation and factors influencing this process. This paper describes prodegradant additives that induce decomposition of polymers to biodegradable compounds with regard to additives causing oxo-biodegradation. Based on the results of experiments conducted for molded pieces made of polypropylene and extrudates made of low density polyethylene with a d2w prodegradant additive, dependences betwe...
Autori: Tomasz Jachowicz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27519

Irrigation is an increasingly important practice for sustainable agriculture. Water reuse as refined or non-refined wastewater can help agroecosystem productivity. Contaminated water may influence seed germination. Two experiments as laboratory and pot were carried out to assess impact of different levels of laundry detergent and water stress on seed germination and early growth in maize. At the laboratory experiment, seeds were treated with solutions of 0, -0.01, -0.09, -0.6 MPa polyethylene gl...
Autori: Hassan Heidari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27527

Recycling of solid plastic waste composed of post-consumer mixed polyolefines (polypropylene and polyethylene) was carried out by injection moulding of secondary material streams. The materials have been characterized by melt flow index (MFI), tensile, bending and impact measurements, density and differential scanning calorimetry (DSC). The sink-float technique was used to separate the polyethylene fraction, which was then blended into virgin polyethylene at different ratios and processed anew. ...
Autori: Laurens Delva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27646

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

The catalytic hydrogenolysis of glycerol, a by-product of the biodiesel manufacturing process was studied on copper chromite catalysts with different chemical composition. The obtaining of propylene glycol was studied under mild reaction conditions (180- 240oC temperature range, 8 hours reaction time and moderate pressures). These important parameters have significant effects on the glycerol conversion and that is way the actual study was concerned to the obtaining of a superior selectivity t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27892

Proteins from Hermetia illucens (or Black Soldier Fly, BSF) have been employed in this study as possible source for bioplastic formulation. This type of bioplastic can replace the actual materials employed in agriculture, avoiding the critical issues concerning the soil pollution due to conventional plastic end-life. Different plasticizing agents (glycerol and polyethylene glycol) have been tested and the ability to generate a homogenous film, through wet casting, has been evaluated. Characteriz...
Autori: Silvia Barbi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28074

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Autori: Radu Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28139

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162