Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractIn India, transportation sector is growing fast and the number of vehicles on Indian roads is increasing at a rate more than 7 percent a year. During the period of 50 years from 1951 to 2001, the number of vehicles has increased from 0.3 million to 43 million i.e. an increase of almost 143 times. This has led to overcrowded roads and noise pollution. The transportation sector is one of the major contributors to noise in urban areas, accounting to as much as 55 percent of total noise on t...
Autori: Arvind Kumar Shukla, Jyoti Bhushan Srivastava, Manoranjan Parida, Sukhvir Singh Jain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25279

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

AbstractThe paper proposes a suitable solution for a one step treatment process of the wastewaters resulted from the textile industry, using a mixture of anatase and modified fly ash. The dyes photo-degradation on TiO2 anatase is well known. The use of fly ash in advanced wastewater treatment, for heavy metal adsorption, represents an environmental friendly process, efficient if the fly ash surface charge is controlled by solubilisation/reprecipitation. The first step in implementing the single ...
Autori: Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25292

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

AbstractSince public concerns about the environmental issues have increased, several universities all over the world have been establishing environmental engineering programs. Environmental engineering programs in Iran at graduate level have been developed since 1990. At the present time, there are ten universities are presenting environmental engineering programs at graduate levels. The environmental engineering education systems of almost all Iran universities are quite traditional. As the env...
Autori: Ahmad Tahershamsi, , Reza Maknoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25324

Abstract        The sorption of metal ions from aqueous solution plays an important role in water pollution control and in recent years there has been considerable interest in the use of low-cost adsorbents. Many researchers have tried to exploit naturally occurring materials as low-cost adsorbents, for removing of heavy metals. In this article the removal performance of various low-cost adsorbents derived from agricultural waste or natural material is evaluate...
Autori: Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25379

AbstractThe technological process of basic chemical organic compounds synthesis is included among the economic activities that can affect the environment quality. The environmental impact of chemical organic synthesis is evaluated using the alternative method of global pollution index that considers the concentric circles graphical methodology proposing a scale of the arithmetic mean values for the evaluation scores of each environmental components (e.g. water resources, gaseous emission, soil a...
Autori: Carmen Zaharia, Ilie Murăraşu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25352

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

AbstractThe use of adhesives for floor covering have been deeply modified for longtime, by formulations of polymer-based products in aqueous dispersion as an alternative to organic solvents. These advances envisaged ways for obtaining nonpolluting products. Developing these adhesives required the parallel development of methods for monitoring and analyzing the emissions over time. This paper shows the results of some research devoted to identify the indoor presence of volatile organic compounds ...
Autori: Irina Ioniţă, Domnica Ciobanu, Monica Tulbure, Iulian Tanţoş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25388

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract This study examined the effect of hexane concentration in the inlet gas stream on the treatment performance of a concentric tube internal loop airlift bioreactor with a 7 L capacity, inoculated with a strain of Pseudomonas aeruginosa. The experiments were conducted employing hexane-contaminated air, in 0.62, 1.26, 2.15 and 4.5 g/m3 concentrations at 29 ¹ 1°C. The 100% hydrocarbon removal was verified when effluents containing 0.62 and 1.26 g/m3 of hexane were employed. Under contin...
Autori: Fernando Jorge Santos Oliveira, Leonardo Vazquez, Francisca Pessoa de Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25437

Abstract Using slag in steel making represents a challenge for road construction industry and decreasing environment interactions also.Steel making slag wit granulations of < 10 mm, which today have not a sure solution, represents the research object. The technological research solutions have aimed reducing CaO free content in these slugs, and reducing slug fraction with granulationof ...
Autori: Florian Zaman, Mirela Gabriela Sohaciu, Ecaterina Matei, Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25439

Abstract The waste recycling done in order to obtain composite products with performant properties and also, with long life cycle is the main purpose for the sustainable development. The present paper describes the way in which, different kind of solid wastes are immobilised in an organic resin as a binder matrix. Composites with different proportion of waste as, rubber/plastic, glass and silica sand have been obtained. The physical-mechanical properties and chemical stability of such organic...
Autori: Ioan Ropota, Emilia Zamfirache, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25450

Abstract Two types of zeolite-modified electrodes, e.g., Ag-doped zeolite-expanded graphite-epoxy (AgZEG) and Cu-doped zeoliteexpanded graphite-epoxy (CuZEG) composite electrodes were tested for the application of the electrochemical determination of 4-aminophenol (4-AP). The electrochemical techniques used for the electrochemical determination of 4-AP were cyclic voltammetry (CV) and chronoamperometry (CA). Some aspects related to the mechanistic behaviour are discussed. The electrochemical ...
Autori: Cornelia Ratiu, Carmen Lazau, Corina Orha, Ioan Grozescu, Aniela Pop, Daniela Sonea, Florica Manea, Georgeta Burtica, Joop Schoonman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25468

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract The paper briefly presents the principle, methodology basics and the research opportunities offered by a modified L-joint test for a complex in-field evaluation of wood behaviour in outdoor above ground exposure, corresponding to the biological use class 3. A comprehensive and detailed examination of the tested samples, looking not only to the biological degradation of wood but also to wood cracking and coating performance (cracking, flaking, exfoliation, adherence), was performed an...
Autori: Maria Cristina Timar, Emanuela Beldean, Mihaela Porojan, Lidia Gurau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25494

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract The purpose of this work is to investigate the secondary Al slag (SAS) relating to its technical and environmental properties and, as consequence, to its compatibility with Portland cement matrix. This study may be a contribution to establish of SAS potential valorization as secondary raw material (SRM) in low strength cement matrix composites, as construction products. DRX mineralogical analyses revealed that SAS includes transition alumina compounds, especial boehmite. The hydrati...
Autori: Maria Gheorghe, Nastasia Panait, Romanita Teodorescu, Maria Roman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25498

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract This work presents a global approach of the impact generated in the environment by rubber processing activity. The objective analyzed as a case study is a company that produces rubber tires for trucks and industrial vehicles. The experimental part includes the determination of quality indicators for each environmental factor (air, water, soil) and the evaluation of environmental impact on these factors. Determination of the environmental quality indicators was done by sampling and a...
Autori: Aurica Grec, Florin Dumescu, Corneliu Maior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25547

Abstract The aim of this study was to assess nitrate removal using impregnated activated carbon (AC) with MgCl2. After impregnating of AC using heat treatment, the MgCl2 is converted to efficient MgO. The denitrification was conducted at pH 6.2, 25?C, and initial concentrations of 20 mg/L nitrate-N. The effects of the operating parameters including AC dosage, pH, and contact time have been investigated. Experimental data show that AC modified by MgCl2 was more effective than virgin AC for nit...
Autori: Abbas Rezaee, Hatam Godini, Sahand Jorfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25618

Abstract Mathematical modeling of the ultrafiltration (UF) process is motivated by the complexity of retention phenomena that occur during the UF in conjunction with the complexity of wastewater matrices submitted to ultrafiltration, as well as by the need to predict the process behavior in extreme conditions, such as high pollution loads for UF-membrane cleaning cycles optimization or for automated control of the process. Thus, series of laboratory-scale ultrafiltration experiments were perf...
Autori: , George Barjoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25630

Abstract The structural modification of external surface of NaY was investigated in order to enhance efficient biosorption systems consisting of a bacterial biofilm, Arthrobacter viscosus, supported on that zeolite, for removing hexavalent chromium from aqueous solutions. The supported bacterial biofilm reduces Cr(VI) to Cr(III) and this cation is then retained in the zeolite by ion exchange. NaY zeolite was modified by alkali-treatments using NaOH 2.0 M, with two different contact periods of...
Autori: Bruna Silva, Cristina Quintelas, Hugo Figueiredo, Isabel C. Neves, Manuel F.R. Pereira, Teresa Tavares
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25637

A series of sodium bentonites as raw material were prepared to the modified inorganic iron-nickel montmorillonites and organic composite montmorillonites. The structural characterization and morphology of the iron-nickel crosslinked modified bentonites were observed by means of IR spectroscopy, X-ray diffraction, scanning electron microscopy. The effects of the amount of bentonites, adsorption time and pH change on the adsorption of Cr(VI) have also been studied. The results indicated that the a...
Autori: Shao Hong, Cao Ninghttp://www.ecozone.ro/reviste.php?RID=25695

Abstract:An efficient conversion of kinetic energy of river waters into mechanical or electrical energy without building barrages isprovided by micro-hydropower stations. Increased efficiency is achieved by an optimum position of the blades withhydrodynamic profile. The formulation used to compute the hydrodynamic forces is an inviscid - boundary layer model. Microhydropowerstation provides kinetic energy conversion of river water into mechanical or electrical energy without buildingbarrages. In...
Autori: Anatol Sochireanu, Ion Bostan, Ion Dicusară, Nicolae Trifan, Oleg Ciobanu, Radu Ciobanu, Valeriu Dulgheru, Viorel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25723

Abstract:Ash is a waste that can be an efficient substrate in wastewater treatment for the immobilization of heavy metals and for dyesremoval. For an up-scalable wastewater treatment process, efficient substrates, with relatively constant behavior are needed andmodifying the adsorbent surface can be a feasible solution. Fly ash, resulted from coal burning, and wood ash are mixtures mainlycontaining metal oxides and carbon in various proportion, depending on the initial raw material.The paper pre...
Autori: Maria Visa, Mihaela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25771

Abstract:Based on the fuzzy logic principle, a modified Fuzzy Synthetic Evaluation (FSE) is proposed to assess water quality status ofWeihe River (Baoji, China). The potential application of the FSE has been tested in a case study. Twelve sampling locations ofWeihe River and its tributaries in Baoji area were selected and seven water quality parameters of BOD5, COD, fluoride, ammonia,total phosphorus (TP), total nitrogen (TN) and permanganate index, were monitored from 2008 to 2009. The findings...
Autori: Chundi Xu, Jun Zhang, Qi Zhou, Yani Geng, Yaqian Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25780

Abstract:Surface exploitations in the limestone quarries have a major impact on the environment both by area and intensity. The valuationof the impact can be carried out through different means, one of them being the satellite remote sensing. In this article we analyzethe effects that limestone exploitations in the outskirts of BraÂ?ov city have on the landscape, using RGB combination, vegetationindices and spectrum profiles. A series of Landsat 5 TM satellite images taken in 1984, 1989 and 2009...
Autori: Iosif Vorovencii
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25784

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

The first part of this work presents the development and implementation in the Benchmark Simulation Model No 1 (BSM1) of a modified Activated Sludge Model No 3 (ASM3). The enhanced ASM3 presented in this study has three modifications compared to the original ASM3. The first modification is the representation of the simultaneous heterotrophic biomass growth on the primary substrate and on the internal storage products. Second, nitrification is modeled as a two-step process with nitrite as an inte...
Autori: George Simion Ostace, Paul Şerban Agachi, Vasile Mircea Cristea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25865

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

This research investigates the influence of certain vitamins (A and D2) on the possibility of hydroxyapatite formation on polymer surfaces. A coating method based on biomimetic techniques was used to form a crystalline hydroxyapatite thin layer on porous polyurethane matrix. The method is based on a wet process of hydroxyapatite formation that involves porous polyurethane film soaking in a modified synthetic Simulated Body Fluid (SBF) solution. This modified SBF solution contains vitamin A and v...
Autori: Alina Costina Luca, Constantin Luca, Gabriela Ciobanu, Simona Ilisei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25884

Fly ash and fly ash based zeolites are inorganics used for improving soil quality. In the current paper, the hydrothermal modification of fly ash was studied. Three methods have been employed for this purpose. The first method involved the use of an autoclave, where synthesis has been performed at a temperature of 120 0C and a treatment time of 4 to 8 hours. Within the second method, the modification of the ash at a temperature of 600 0C by fusion was carried-out. In this method, a mixture of as...
Autori: Corneliu Munteanu, Daniel Bucur, Lacramioara Rusu, Maria Harja, Marinela Barbuta, Ramona Carla Ciocinta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25885

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

AbstractThe adsorption of hexachlorocyclohexane (HCH) by modified meerschaum was studied. The comparison of the meerschaummodified by anion and cation surfactant was conducted to explore their effect on HCH adsorption. The results showed that theabsorbability of HCH by the CTMAB-M (cetyltrimethylammonium bromide-modified) is better than that of SAS-M (sodiumdodecyl sulphonate-modified) because the CTMAB-M has fluffier fibers structure. The addition of amount of adsorbents shouldimprove the adsor...
Autori: Chanjuan Gao, Shengke Yang, Wenke Wang, Yaqian Zhao, Yue Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25948

AbstractIn this study, palygorskite clay calcinated at different temperatures from 200 to 900 °C was used as adsorbent to removephosphate from aqueous solutions. The crystal structure and the surface property of the thermally modified material wasinvestigated to determinate the relationship between the adsorption capacity of the adsorbent and the changes of the crystalstructure and surface property. The results indicate that palygorskite clay calcinated at 700 °C had the highest adsorptioncapaci...
Autori: Chengsong Qing, Chengzhu Zhu, Dong Chen, Jiayuan Wang, Jingjing Xie, Tianhuhu Chen, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25949

AbstractWastewater from butyl rubber production is causing an increasing environmental problem due to its large quantity and complexquality. In this paper, two types of wastewaters generated from rubber synthesis, i.e. alkaline wastewater (AW) and cleaning andflushing wastewater (CFW), were investigated. Coagulation and flocculation were firstly applied to remove suspended solids(SS) from the AW. By single factor experiment, the optimum operational conditions were obtained as pH 8, PAC dosage 40...
Autori: Lujun Chen, Rui Liu, Wei Li, Wei Zheng, Yan Zhang, Ying Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25950

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractDue to high energy costs and the rising consciousness of energy issues in the textile industry, saving energy became a significantproblem. Since a large amount of the energy required in textile finishing is needed in the form of steam for various processes,recovering wastewater heat has great potential for cost reduction. In this research, it was studied the heat recovery from cellulosictextiles finishing wastewater, based on a case study in a textile company. After examining the wastewa...
Autori: Armand F. Bertea, Gheorghe Condurache, Răzvan Berariu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26013

AbstractThe increased concentrations of priority pollutants in wastewaters have imposed the completion of conventional treatment withadvanced treatment stages (such as catalytic oxidation, membrane processes, adsorption, ion exchange, etc.) for their removal bychemical degradation and/or physical separation.In this study, 4-chlorophenol (4-CP) is proposed as model-pollutant for the priority organic pollutants present in syntheticwastewaters and several processes which can act as advanced treatme...
Autori: Carmen Teodosiu, Corina Petronela Musteret, Daniela Arsene, Daniela Cailean, George Bârjoveanu, Petru Apopei, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26022

AbstractThis paper deals with the experimental investigation related to removal of hydrogen sulfide from simulated groundwater byadsorption/oxidation on activated carbons. Carbonaceous adsorbents were synthesized from peach stones by physical-chemicalactivation method and modified by oxidation following impregnation with Cu2+ by ion-exchange method. Obtained carbonaceousadsorbents were characterized by specific surface area and micropore volume. Surface chemistry properties were evaluated usingB...
Autori: , , Vasile Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26026

AbstractIn this work, cyclic voltammetry (CV) and differential-pulsed voltammetry (DPV) were used to detect pentachlorophenol (PCP)at two types of multi-walled carbon nanotubes (CNT)-based composite electrode, i.e., TiO2-modified-CNT-Epoxy (TiO2-CNTEpoxy)and CNT-Epoxy in 0.1 M sodium sulphate solution supporting electrolyte. The electrochemical behaviour of theelectrodes was investigated in the absence and presence of UV irradiation. A single oxidation peak at a potential value of about+1 V vers...
Autori: , Ágnes Jakab, Aniela Pop, Cornelia Bandas, Florica Manea, Joop Schoonman, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26033

AbstractThe objective of this paper is to investigate the effect of expansive soil treatment with Eco-Cement (EC) stabilizer, as beingcomposed of an alternative binder that partly substitutes the Ordinary Portland Cement (OPC). The extended use of EC in soilstabilization will carry several significant environmental benefits. Firstly the by-product resulted from the production of iron in ablast furnace will be reused, that otherwise will be stored on the ground in deposits representing an importa...
Autori: Anghel Stanciu, Irina Lungu, Mircea Aniculăesi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26069

AbstractThe evaluation of the environmental impact of transport infrastructure entails a complex characterization of factors, attitudes andconsequences. In the frame of an ecologically friendly approach, sustainable alternatives and solutions for road asphaltpavements production and exploitation must be identified. A comparative evaluation of the environmental impact for recycledand traditional road pavements asphalt mixtures, expressed as the amount of equivalent carbon dioxide, per ton of mixt...
Autori: Alina Mihaela Nicuţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26096

Abstract Using lab experiments, the heavy metal tolerance of young ectomycorrhizal trees was assessed in two axenic systems, co-cultures on germination medium and a sandwich technique system with Modified Melin-Nokrans medium. Sterilized seeds of the tree species Scots pine (Pinus sylvestris) and Norway spruce (Picea abies) were inoculated with the ectomycorrhizal fungi Paxillus involutus and/or Tricholoma vaccinum in media containing either 10 mM CsCl or 0.25 mM CdCl2. The behavio...
Autori: Maria Lucia Bizo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26119

AbstractThe transport of hazardous substances is an essential economic activity because it represents a quite relevant percentage of thetotal goods transportation. The risk associated to such an activity is fundamentally related to the possibility of an accidenttriggering that may cause negative environmental and public health consequences. A recent example is the Viareggio accident(2009), which involved the blast of tank wagons containing liquefied petroleum gas (LPG) and caused more than thirt...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26200

AbstractSimultaneous uptake of Cd(II) and Pb(II) by corn in two artificially contaminated soils (sandy and sandy loam) amended withtwo doses of natural (NM) and modified (MM) montmorillonite were investigated in a pot experiment under greenhouseconditions. Results showed that the addition of NM and MM to sandy loam soils didn’t have significant effect on the uptake ofCd(II) by roots, then is translocated to the aerial tissues. On the contrary, uptake of Cd(II) by shoots was increased in potscont...
Autori: Hadis Hosseini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26205

AbstractPotential of unmodified Wheat Straw as an adsorbent for the removal of lead and copper was studied. Effect of pH, adsorbentdose, contact time and initial metal concentration on the removal of the metal ions were also investigated. Maximum removal oflead was found to be 43.55% by wheat straw under optimum conditions (pH=5, adsorbent dose=16g/L, contact time= 240minutes, metal concentration=100 mg/L). Unmodified Wheat straw removed 0.381 mg/g of lead. While 56.36% copper removalwas achieve...
Autori: Mehwish Anis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26209

AbstractThe reuse of a wastewater treatment system was investigated using intermittent media infiltration (IMI) to evaluate the fecalcoliform (FC) removal efficiency with natural zeolite containing clinoptilolite from the state of San Luis Potosí, Mexico and itszinc-modified form (Zeo-Zn). The municipal wastewater, which was from Saltillo, Coahuila, Mexico, was treated for FC analysisfor four months. The physicochemical properties of zeolite were analyzed, and their behavior as filter media for ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26212

AbstractWhite Storks (Ciconia ciconia L.) may cause severe outages in electric networks leading to poor power quality service.Furthermore, bird fatalities often occur as consequence of electrocution. Therefore, equipment damages, economical losses ofindustry and electric corporations and bird deaths persuaded the main electric distribution operator and the regulator toimplement management programs of storks’ activities in the vicinity of electric distribution substructure to minimize storkfatali...
Autori: Pedro M.M. Araújo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26229

AbstractFor the purpose of coping with oil spills successfully, it is important to establish effective response and preparedness plans. Inprevious study, we proposed the use of Case-Based Reasoning (CBR) technology to develop environmental emergency responseand preparedness plans. In this paper, we present how to develop a CBR-Oil Spill Response and Preparedness System (CBROSRPS). In particular, the Frame method is employed to do case representation, the modified Heterogeneous Euclidean-Overlap ...
Autori: Zhenliang Liao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26247

AbstractThe extent of the problem of the excessive fluoride in drinking water remains an important health issue. In the present work,strong-base anion resins were investigated to assess their sorptive removal capacity of fluoride from water. It was found that theremoval of fluoride was high at natural pH (7) and was improved for increasing contact time and adsorbent dosage. Themaximum sorption of the resin was 13.7 mg/g according to the Langmuir model, namely higher than the values reported in t...
Autori: Mohammad Taghi Samadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26273

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThe road infrastructure has a major environmental impact by covering important land surfaces and consuming enormous amounts of raw materials for construction and maintenance. The impact of transport pavements needs to be considered from the design stage and to be examined during the whole life cycle of the infrastructure: raw materials extraction and initial transformation, manufacturing, placement on site, exploitation, maintenance, and demolition. This paper evaluates the impact of asp...
Autori: Isabela Maria Simion, Laura Dumitrescu, Maria Gavrilescu, , Radu Andrei, Sebastian George Maxineasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26297

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractIn this study artificial neural network (ANN) has been applied to predict noise pollution level in Chandigarh, a newly plannedcity of India. Factors that predominantly influence noise pollution level in a traffic noise model framework were classified intotwo categories: traffic volume and traffic speed. Volume, speed and noise level data of traffic were collected at nine identifiedlocations in the city. For development of ANN model, classified traffic volume (Car/Jeep/Van, Scooter/ Motor...
Autori: Kranti Kumar, Manoranjan Parida, Vinod Kumar Katiyar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26336

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

AbstractThe paper analyses the hydrologic parameters of the Tarata perimeter with alluvial soils, in order to estimate the values of theTazlau River behaviour, in case of flooding. Tazlau River flow rate has an annual average value of 4.9 mł/s, with a torrentialcharacter when the level of precipitation is increasing. The analysis of this perimeter is of interest today as a result of the existingexcessive erosion. We identified a possible solution to reduce soil erosion through the exploitation o...
Autori: Stelian Cartacuzencu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26469

AbstractIn this study, TiO2-zeolite modified carbon nanotubes-epoxy (TiO2-Z-CNT-Epoxy) and TiO2-zeolite modified carbon nanofibersepoxy(TiO2-Z-CNF-Epoxy) composite electrodes were applied for pentachlorophenol (PCP) degradation and determination inaqueous solution. The morpho-structural characterization of the composite electrodes was studied by scanning electronmicroscopy. The electrochemical behaviour of the electrodes was investigated under UV irradiation presence/absence, usingcyclic voltamm...
Autori: Ágnes Jakab
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26491

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractEnd-of-life tires are waste materials that pollute landscapes when they are disposed of in tire dumps. However, its life cycle is notfinished when they are scrapped. The rubber of end-of-life tires could be used for new purposes as construction material in roadrehabilitation. A gap-graded mix characterization was carried out in this work by means of laboratory and field performancetests. The mixture has a high content of crumb rubber (CR) by weight of bitumen. Crumb Rubber was added to t...
Autori: Victor F. Vázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26577

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Biochar derived from agricultural biomass waste is increasingly recognized as multifunctional material for various applications according its characteristics. It is therefore essential to investigate biochar properties before large-scale application. In this study, rice straw-derived biochars produced at different temperature (550, 650, 750 oC). The resulting biochars were subjected to liquidphase oxidation by different agents including KOH, HNO3, H2SO4, H2O2 and KMnO4 to obtain bio...
Autori: Sobhy M. Yakout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26661

Abstract This paper presents a medical diagnosis method, based on the interaction of the infrared laser beam and the human body, in a hospital environment, for inflammatory diseases, avoiding infected wastes. The main advantage of the laser bio-photometry is a rapid localization of the inflammation source, deep under the skin up to 5 cm, in emergency cases, when there is not enough time for classical medical procedures. Other advantages consist in the pollution absence for environment and pa...
Autori: Ala Bondarciuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26696

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Chitosan was cross linked with gluteraldehyde and chemically modified by introducing xanthate group onto its backbone using carbon disulfide under alkaline conditions. This crosslinked xanthated chitosan flakes (XC) was used as an adsorbent for the removal of mercury ions from contaminated water streams near the coal mines. XC was found to be far more efficient than the conventionally used adsorbent activated carbon. FTIR studies indicated the interaction both amine and the xanthate...
Autori: Avinash Gupta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26725

Abstract This paper aims to analyze the characteristic of Road deposited sediment (RDS) using West Chang Tan highway, Hunan, China as a study site. RDS samples were collected at five representative highway sites and the particle size distribution was generally less than 150μm. Particles with the grain size (<150μm) had high metal concentrations among all sampling sites (unit: mg/kg): Cu 74-178, Zn 309-2737, Pb 601-1160, Cd 9.8-44.5. There is significant spatial variability between t...
Autori: Yunbo Zhai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26728

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract Wind erosion, which strongly affects both plant and soil development in arid environments, is dependent on soil properties, wind characteristics and plant cover. In a semiarid zone in SE Spain, a new technique consisting of dusting plants with a forced wind stream reduces tillage and significantly increases productivity. By using a blower once a year, dust is raised and partly retained by plants, and eventually ends up in the understory. To assess the influence of this technique on ...
Autori: Carlos Asensio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26735

`Abstract End of life tires require sound accounting of environmental performances to design sustainable procedures for material recovery. Their use in rubber modified asphalt provides could lead to the improvement of technical and environmental performances of asphalt roads, but the effectiveness of simplified procedures is to be proved. During LIFE+ project ROADTIRE, a rubber modified asphalt road prototype, with the upper surface layer containing 10% crumb rubber in the bituminous binder,...
Autori: Irene Bartolozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26741

Abstract Waste management does not try to dispose waste anymore but is searching for the best solution to manage valuable and scarce resources and reduce the negative impact on the environment. Preoccupation in Germany with regard to optimization of waste recuperation and valorization increases and separate collection systems for different waste fractions are taken into consideration. Within this study a pilot project was set up and its results are presented below. The investigation evaluate...
Autori: Mihaela Berechet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26758

Abstract This study concentrates on the reactive biosorption of dyes such as Reactive Red 3:1 (RR3:1), Reactive Orange 13 (RO13), Reactive Blue 13 (RB13), Reactive Blue 72 (RB72). The modified fungal biosorbent, Paecilomyces sp., had a higher dye biosorption yield in our study. 100% of biosorption yield observed on RR3:1 and RB13 and 94.09% of color removal of RO13 with the chemically modified biosorbent were great. Also, such modified biosorbent exhibited remarkable performance in simulate...
Autori: Ahmet Çabuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26860

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Abstract This study presents enhanced reduction of soluble contaminants in a modified electrocoagulation process that is capable of treating a mixture of aqueous contaminants. By incorporating an iron foam cathode, the process can remove aqueous trichloroethylene (TCE) by 99.1% and nitrate ions by 98.2%, which represents 58.1 and 20 percent higher than the removal rates achieved by iron plate cathode, respectively. pH and ORP measurements indicate the development of a reducing electrolyte c...
Autori: Xuhui Mao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26915

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

Our study aims to analyse soil quality based on the concentrations of potentially toxic elements (PTEs) in natural or slightly modified anthropogenic soils, technosols and landfill deposits in Iasi. The pollution level analysis based on lognormal distribution plot allows the differentiation of elements coming from the parent material (Mo, Cd, Ni and As) of those with anthropogenic origin (Pb, Zn and Cu). The enrichment factor (EF) calculated based on manganese (Mn) as reference in the parent ...
Autori: Cristian Vasilica Secu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26991

This paper presents a research on ways to reduce waste and to diminish sound pollution by recovery of fir sawdust and recycled rubber granules and use in making sound absorbing composite materials. Four materials were prepared using raw materials (fir sawdust and recycled rubber granules) in various percentages, and polyurethane binder. Materials mechanical and acoustic properties were characterized, proving these materials have useful properties. Materials acoustic performance was compared w...
Autori: Ancuţa Elena Tiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27039

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

This study highlights the potential use of yellow Zea mays seed chaff (YZMSC) biomass as a biosorbent for the removal of Cr3+, Cd2+ and Pb2+ ions from aqueous solutions. Fourier transformed Infrared analysis of the biomass suggests that YZMSC biomass is basically composed of cellulose and methyl cellulose. The biosorption capacities, qmax, of YZMSC biomass for Cr3+, Cd2+ and Pb2+ are 14.68, 121.95 and 384.62 mg/g respectively. Biosorption equilibrium was achieved at 20, 30 and 60 min for Cr3+...
Autori: Jonathan Oyebamiji Babalola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27083

Membrane technology has become a fundamental unit operation in the industry and society of nowadays and fouling is, probably, the most important concern related with this technology. Fouling is a complex process that can limit the performances of facilities using membranes. Many research efforts have been done in order to reduce fouling tendency. Ceramic membranes can play a major role in fouling mitigation due to its high hydrophilic nature. This paper describes the characterization of a new...
Autori: Mihaela-Elena Dascalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27089

This study proposes a modified fractional fuzzy simulation (MFFS) method to predict the toluene and oxygen concentrations in aquifers under microbial attenuation conditions. The method integrates the modeling of groundwater flow contaminant transport and fuzzy parameters analysis within a general framework. Compared to conventional fractional fuzzy simulation (FFS), decreased interior points of fuzzy parameters need to be used, thus reducing the simulation time. The method is applied to an a...
Autori: Li He
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27106

It is of great concern to reduce greenhouse gases (GHG) and ammonia (NH3) emissions from animal manure composting in China. The purpose of this study was to investigate effects of adding red mud on emissions of GHG (methane (CH4), nitrous oxide (N2O)) and NH3 in full-scale swine manure windrow composting. Two full-scale swine manure windrow composting experiments were carried out to compare emission of GHG and NH3 with and without addition of red mud. Results showed that the addition of modified...
Autori: Chenyang Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27158

The adsorption of tartrazine from aqueous solution was evaluated using an iron (III) modified zeolitic tuff. The adsorbent was characterized by scanning electron microscopy and X-ray power diffraction; the modification process does not affect the crystalline structure of the zeolitic tuff. Sorption kinetic, isotherms, dose and pH effects were determined and the adsorption behavior was analyzed. The sorption equilibrium was reached in 72 hours, the adsorption capacity determined by the Langmuir m...
Autori: Adrián Alcántara-Cobos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27182

Various azodyes containing one or more sulfonic groups were removed from aqueous solutions by biosorption on untreated wood shavings from Picea abies. The sorption kinetics was described by the pseudo-first-order (PFO), pseudo-second-order (PSO) and modified pseudo-n-order (MPnO) equations, from which the MPnO model provided the best fit to the experimental data. The surface reaction was identified as a rate-limiting step governing the dye sorption on wood shavings, but a mixed kinetics (with a ...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27207

Intensive cereal crops planted on soils from the Western part of Romania determine, annually, significant losses of essential microelements and macronutrients for plant development from the agricultural soil, which lead to the depletion of such lands. Fly ash (FA) resulted from coal combustion at the CET Timisoara power plant, can be used as supplement to an organic fertilizer, such as manure (M) to restore the balance of micro- and macronutrients, important to obtain healthy cereal crops and hi...
Autori: Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27208

In this study, an upflow anaerobic sludge blanket (UASB) bioreactor at the mesophilic temperature (38ºC) was successfully used for the treatment of petroleum refinery effluents. Response surface methodology (RSM) was applied for the design and analysis of experiments to predict the behavior of the initial COD and the hydraulic retention time (HRT) in the bioreactor. A statistical analysis indicated that the models adequately represented the experimental data. At the optimal conditions, the ...
Autori: Seyed Omid Rastegar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27233

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

The paper discusses the pollution status in the case of an important NE Romanian watercourse (Siret River) in Pascani town area based on the analysis of some water quality indicators (pH, temperature, dissolved oxygen, organics (COD and BOD5), conductivity, fixed residues, nitrogen-based nutrients (N-NH4+, N-NO3-, N-NO2-), phosphates, total phosphorus (P), total calcium (Ca2+), magnesium (Mg2+), iron (Fe2+, Fe3+), turbidity and suspended solids content) measured at three local strategic control ...
Autori: Carmen Zaharia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27281

Pharmaceuticals contaminants in waters exhibit a significant threat on the human health and the ecosystem quality. This research demonstrates the utility of a silver-doped zeolite-modified carbon nanofiber-epoxy (AgZ-CNF) prepared by two-roll mill method in development of the fast methodology for the detection of fluoxetine (FXT) in the aqueous solution. The results showed the role of zeolite that improved the sensitivity and the limit of detection of FXT resulted to the possibility to propose a...
Autori: Magdalena Ardelean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27328

Conversion of natural ecological systems has been one of the greatest human impact on terrestrial ecosystems. The expansion of anthroposphere altered virtually all biogeochemical cycles of elements. Nitrogen holds a key place in sustaining life and presents unique traits such as broad chemical speciation and mobility within the environmental compartments. With historically adapted ecosystems to low bioavailable nitrogen, understanding the complexity of the nitrogen disruption is a continuous cha...
Autori: Andreea Csolti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27329

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

Common issues of the gasification systems relate to filtering apparatus. Dry filtering processes are simple and reliable. However, the filtering material defines the maximum and minimum temperature at which the filter can operate properly. In addition, dry filtration is not effective on light tar compounds (i.e. benzene and toluene) or ammonia compounds. On the other hand, despite being very efficient, wet filters drop the gas temperature below the line of condensation of tar, ammonia and ste...
Autori: Giulio Allesina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27412

Lignocellulosic residues are relatively recalcitrant to bioconversion during anaerobic digestion (AD) for biogas production. Pre-treatments with cellulolytic enzymes or diluted alkali can facilitate biomass hydrolysis and enhance the process. Both pre-treatments require low energy and chemical inputs, without accumulation of inhibitor. Milled wheat straw was pre-treated with hydrolytic enzymes or with diluted NaOH before AD. The pre-treatments were performed on sterilized, stabilized with formic...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27420

In this work, magnetic alginate was synthesized by encapsulating of Nickel Zinc Ferrite nanoparticle within Ca-alginate. The synthesized magnetic alginate was modified by ethylenediamine using microwave radiation to remove anionic dye from wastewater. The characteristics of magnetic nanoparticle, magnetic alginate and magnetic alginate amide (MAA) were studied using Fourier transform infrared (FTIR) and Scanning electron microscope (SEM). FTIR analysis confirmed the amidation of alginate. Di...
Autori: Niyaz Mohammad Mahmoodi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27424

The Artificial Neural Network (ANN) model was used to predict dye (Reactive Blue 19) removal efficiency from aqueous solution using modified pomegranate residual based on 124 experimental sets. Three-layer ANN models with different neurons numbers at a hidden layer were developed. The optimum network yielded a network error of 0.0054 and 0.9606 for mean square error and coefficient of determination, respectively. Furthermore, sensitivity analysis of the network revealed that the adsorbent do...
Autori: Elham Radaei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27439

Timber harvesting and log extraction with conventional ground-based skidding systems in steep, mountainous terrain often results in severe damage to residual stands and forest sites. In this study, the impact of rubber-tired skidders on standing trees along sides of the trails was investigated 5 to 20 years post-harvest in terms of frequency and development of decay at the points of wounding. The study was located in the Hyrcanian mountainous forests of Iran. All standing beech trees (healthy or...
Autori: Davoud Kartoolinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27457

Three modified bentonites, hydroxy-aluminum pillared bentonite (Al(OH)-Bent), cetyl trimethylammonium bromide modified bentonite (CTAB-Bent), and both cetyl trimethylammonium bromide and hydroxy-aluminum modified bentonite (Al(OH)-CTAB-Bent) were prepared and characterized by Fourier transform infrared spectroscopy (FTIR) analysis. Batch experiments were conducted on the adsorption of phenol at different temperatures, pH and initial concentration. The results indicated that adsorption capacity o...
Autori: Xiping Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27481

This paper highlights the utility of rice husk ash for the adsorption of Cr(VI) ions from aqueous solutions. Rice husk ash (RHA) is produced when rice husk is burnt for various purposes. Application of Treated Rice Husk Ash (TRHA) as an adsorbent for the removal of Cr(VI) from aqueous solutions has been investigated. For this purpose, RHA was thermally treated. RHA and treated RHA (TRHA) were characterized by XRD, SEM and FTIR to investigate the effect of treatment on the nature and surface char...
Autori: Varsha Srivastava
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27504

This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multi-active blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than ...
Autori: Jacob Kitinya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27505

This paper investigates the macrophyte Azolla pinnata modified with sodium hydroxide, as a bioadsorbent for Cu2+ and Pb2+ ions in synthetic solutions. Biomaterial characterization was performed using Scanning Electronic Microscopy (SEM); Energy- Dispersive X-Ray Spectroscopy (EDX); Fourier Transform Infra-red (FTIR) spectroscopy techniques and through the blocking of carboxylic and sulfonic functional groups. Kinetics of the process has highlighted a quick and efficient adsorption, even in low ...
Autori: Arielle Barros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27532

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

The main objective of this research was to evaluate the environmental impact generated by municipal solid waste during its collection, transportation, treatment and processing in the south-west region of the department of Norte de Santander, Colombia, by means of Life Cycle Assessment (LCA). Three strategies for waste management were considered: the current baseline situation, wherein 100% solid waste was taken to the landfill; plus, an optimistic and a pessimistic scenario in which solid was...
Autori: Oscar Orlando Ortiz-Rodriguez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27665

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

The paper describes a flexible and low cost method regarding the progress of improvement, in terms of foot diseases, in case of wearing orthopedic shoes containing progressive correction orthotic insoles. The research in the field aims at two purposes. The first one is to find an effective method for orthopedic shoe insoles manufacturing, with the role of progressively correcting plantar diseases by using cheap solutions based on the recycled materials. The research focused on an adaptive insole...
Autori: Barbu Braun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27757

Debris from deciduous trees in the form of park green waste was investigated as a potential biosorbent for the removal of chlorinated solvents from water. The sorption properties of beech leaves and cupules, oak leaves and acorns, birch leaves and lime leaves (all tree species common for a moderate climate) in a non-modified form were investigated with regard to the removal of perchloroethylene, 1,1,2-trichloroethane and 1,1,1,2-tetrachlorothane. The preliminary results showed that these biosorb...
Autori: Marek Tobiszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27760

In this paper, an improved engineering model and analysis techniques are presented of the fly ash particles coagulation with droplets in Venturi tubes of industrial scale, based on spatial variation of the collection efficiency of particles on individual droplets, accounting for spray water flow polydispersity and particle size distribution, which allows to define optimal droplets size and spray water flow rate at different modes of thermal power units operation. The model is validated with the ...
Autori: Igor Volchyn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27836

Changes in material properties are examined in this work by vibration diagnostic techniques. In the article examinations of soft poly(vinyl chloride) (PVC) fibers, which were tested as vibrating strings are presented after different UV light induced aging times. The developed experimental system is presented in this manuscript and the main goal is to determine material changes as the results of artificial aging by special vibration diagnostic methods. The damped oscillations, where PVC fibers ar...
Autori: Dénes Kocsis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27841

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

Dairy wastewater has been a major environmental concern because of massive effluents characterized by high pollution load. This study reports the influence of initial pH (pHi), residence time (τ) and elapsed time (t) on the %COD removal (Y1) and specific energy consumed (kWh per kg of COD removed, Y2) for real dairy industry wastewater treatment in continuous stirred tank electrochemical reactor (CSTER) using aluminum electrodes. Central composite design (CCD) was applied for designing th...
Autori: Poonam Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28011

This paper measures the temperatures along a test route through Chenggong District, Kunming, by mobile measurement, and revises the measured data to 4 different time points of the test period, aiming to enhance the data utilization efficiency. The modified data were plotted into isotherm slices at the four time points, and the urban heat island (UHI) features, as well as its influencing factors were analysed on geographic information system (GIS) software. The results of the measurements show...
Autori: Bai Yufu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28044

Substantial quantities of toner cartridges are produced and used in photocopiers and printers every year. Spent toner cartridges are classified as hazardous waste because they contain toner powder with specific chemical composition, making a recovery of waste toner cartridges a very important issue from the aspect of waste management and environmental protection. Spent toner cartridges are mechanically processed to exploit valuable materials such as metals, plastics and magnets and to separate t...
Autori: Ivana Melnjak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28053

The maintenance of flexible roads or roads at end of life service generates high quantities of reclaimed asphalt pavement every year. The reuse of these materials, considered for a long time as waste, allows a substantial saving in transport, energy, and maintains dwindling natural resources. Recycling of asphalt also helps to reduce inert waste storage volumes, and conserve valuable landfill space. The applicability of recycled asphalt was tested in laboratory, and asphalt mixtures containing 2...
Autori: Mehena Oualit
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28117

Different anthropogenic influences and irresponsible actions pollute all the components of the environment and groundwater is no exception. Nitrates, which are one of the most common groundwater contaminants, come from different sources and they are not always easily detectable. The paper presents a study of a groundwater quality at the VaraĹždin wellfield in the north part of Croatia. The nitrate concentration at this location has been above the maximum allowed concentration for several decades...
Autori: Marko Ĺ rajbek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28140

In this work, the removal of methyl orange (MO) and Cd2+ by simultaneous adsorption on adsorbent obtained from modified charcoal (BCBH) coated with TiO2 has been studied. The synthesized materials obtained from wood branches were characterized using atomic force microscopy (AFM) for the roughness and SEM to determine the morphology of the surface. EDX spectroscopy indicates the presence of C, N, O, Na, K, P and Ti on the surface of the adsorbent materials. The micro-porosity and BET specific sur...
Autori: Nicoleta Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28157

Apart of new equipment’s development such as absorption columns with higher efficiency, for chemical industry, there is a strong need for greenhouse gases reduction in order to assure the environmental protection and, consequently, many studies regarding the purification methods of exhausted gases have been performed. There are several types of reactors used for gases purification, such as: bubbling jet reactor, combined packed and spray tower absorber, cable wet scrubber and packed column...
Autori: Elisabeta Droniuc Hultuana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28160

Growth rate and biomass yield in the case of Arthrospira platensis depend on nutrient availability, temperature and light, which can determine changes in the metabolism and therefore in the biomass composition. The aim of this study is to evaluate the behavior of A. platensis during the growing time in several liquid culture media and their influence on the yield of biomass production. The following culture media have been investigated in this sense: ARS, Zarrouk (Z), modified Zarrouk (MZ), eco...
Autori: Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28163

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

NaA zeolite was successfully synthesised from fly ash through hydrothermal process. The synthesised NaA zeolite was modified with Li+, Ca2+ and Mg2+ through ion exchange at a temperature of 60 °C and contact times of 1 h and 4 h. In this study the crystallinity of the synthesised NaA as well as its modified (LiA, CaA and MgA) was evaluated towards CO2 adsorption capacity using temperature programmed desorption (TPD) process at low temperature (40-150°C) and high temperature (150-700°...
Autori: Muvumbu Jean-Luc Mukaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28175

Current landscapes have been intensively modified by humans and forest fragmentation has created substantial increases of forest edges. So far, scale-dependence between observable ecological patterns and the underlying processes affected by forest fragmentation have been widely ignored. To overcome the widespread ambiguity in selecting relevant spatial scales for studying the ecological effects of forest fragmentation, we investigated the effect of forest prevalence and edge length on carbon st...
Autori: Emilia I. Cojoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28242

Impregnation of aluminium ion onto silica gel (SG) surface (Al/SG) is to increase the adsorption capacity of an anionic dye such as Indigo carmine (IC). The impregnation was carried out using wetness impregnation. The change of the functional group was evaluated by FTIR, crystallinity was determined using XRD, surface morphology were studied by SEM-EDX, while surface area and pore size using N2 gas adsorption-desorption analyzer. Meanwhile, the best of IC adsorption condition onto SG and Al/SG ...
Autori: Yudi Aris Sulistiyo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28253