AbstractVolatile organic compounds (VOCs) constitutes an important class of environmental pollutants, which, together with other contaminants as NOx, SOx, CO, NH3, CO2 etc. participate in degradation of atmosphere and exhibit a potential risk for human health. VOC emissions may be generated in more than 25 percentages through the use of solvents in different industrial or house holding activities. For applying a certain plan concerning the pollution reduction, any user of organic solvents contai...
Autori: Florin Bandrabur, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25218

AbstractThe comparative study on reactive extraction of p-hydroxybenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar s...
Autori: Anca-Irina Galaction, Dan Caşcaval, Maria Cămăruţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25250

AbstractThe paper is a short review on the soil decontamination applying ex-situ techniques. Some sources and pathways of soil  contamination are discussed. It was revealed that available techniques for soil decontamination can be divided in two parts, depending on where the action have place: in-situ or ex-situ. Also, depending on the nature of the process, these techniques can be biological, physical-chemical and thermal. In order to decontaminate soils properly, the primary contaminants ...
Autori: Lucian Vasile Pavel, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25318

AbstractThe use of adhesives for floor covering have been deeply modified for longtime, by formulations of polymer-based products in aqueous dispersion as an alternative to organic solvents. These advances envisaged ways for obtaining nonpolluting products. Developing these adhesives required the parallel development of methods for monitoring and analyzing the emissions over time. This paper shows the results of some research devoted to identify the indoor presence of volatile organic compounds ...
Autori: Irina Ioniţă, Domnica Ciobanu, Monica Tulbure, Iulian Tanţoş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25388

Abstract A crucial stage which makes the other directions of development of membrane processes is getting new membrane materials, to meet increasingly stringent of selectivity and productivity. Polyetheretherketone shows high stability against chemical and physical agents but is poorly soluble in most common solvents. Present studies on obtaining the support of the polyetheretherketone membranes were limited by: solubility of polyetheretherketone in concentrated sulfuric acid and fast speed a...
Autori: Mihaela Emanuela Craciun, Aurelia Cristina Nechifor, Florin Aldea, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25475

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractThe huge emission of greenhouse gases from fossil-fuelled power plants is emphasizing the need for efficient Carbon Captureand Storage (CCS) technologies. The biomimetic CO2 absorption in aqueous solutions has been recently investigated as apromising innovative alternative for post-combustion CCS. The carbonic anhydrase (CA) - a broad group of ubiquitous enzymes– may catalyse the CO2 hydration reaction and then to promote CO2 absorption rate into aqueous solutions. Nevertheless theresear...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Maria Elena Russo, Piero Salatino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25976

AbstractWaste management includes all activities of collection, transport, treatment, recovery and disposal of waste, includingsupervising of such operations. The framework law that regulates waste management activities in Romania is Law no. 27/2007,approving Government Emergency Ordinance no. 61/2006, amending and supplementing Government Emergency Ordinance no.78/2000 on waste regime. This legislation sets the responsibilities for waste management from generation to disposal, thepriorities in ...
Autori: Constantin Mircea Orlescu, Ioana Alina Costescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26020

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

AbstractGlobal warming is happening due to increasing level of carbon dioxide and other greenhouse gases into the atmosphere. In orderto reduce this rising level of CO2 emitted by human activities, carbon capture and storage technologies are being developed.The present paper investigates and compares, from a techno-economical point of view, two of the most used conceptual methods(post- and pre- combustion) for CO2 capture generated from the fossil fuel power generation sector. For post-combustio...
Autori: Anamaria Padurean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26217

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The results of batch tests of anaerobic dechlorination on groundwater samples collected downgradient from an industrial site in Northern Italy are presented and discussed. The experiments were carried out using sucrose as electron donor at equimolar concentration and at selected excess with respect to the total reducible species. The purpose of the study was to investigate the effectiveness of sucrose to achieve a complete chlorinated solvents degradations at the specific site, and ...
Autori: Luca Di Palma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26895

The renewable sources of energy represent a viable alternative for satisfying the energetic needs of humanity in case the fossil fuels reserves are exhausted, which is estimated to occur in maximum 25 years if the current rate of exploitation is maintained. Nowadays, there are several concerns about the valorization of the energetic potential of these resources (wind, water flows, solar, geothermal energy etc.), but also a series of extremely beneficial practical uses (i.e. wind parks, photov...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26989

The production process of wine and distilled generates several by-products (20-30% of total production). Currently, most of the solid by-products (pomace, stalks, lees and seeds) obtained as downstream of the vinery industry, are conferred to the distillery or, less frequently, used in agriculture and for energy production. As a consequence, much of the antioxidant compounds contained in the grape is unused in the products of processing and is lost. These substances (among which the most impo...
Autori: Paola Zitella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27135

The monomer with ketimine side group, 2-(1-(benzylimino)ethyl)phenol (2-BEP), was synthesized from the condensation of 2- hydroxyacetophenone and benzyl amine. The enzymatic oxidative polymerization of 2-BEP was performed in the presence of hydrogen peroxide using horseradish peroxidase (HRP) as catalyst. The oxidation reaction was carried out in various solvents and phosphate buffers at room temperature. These studies have shown that a dark brown polymer was successfully synthesized by utilizin...
Autori: Senem Tapan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27377

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27782

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27729

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27730

Debris from deciduous trees in the form of park green waste was investigated as a potential biosorbent for the removal of chlorinated solvents from water. The sorption properties of beech leaves and cupules, oak leaves and acorns, birch leaves and lime leaves (all tree species common for a moderate climate) in a non-modified form were investigated with regard to the removal of perchloroethylene, 1,1,2-trichloroethane and 1,1,1,2-tetrachlorothane. The preliminary results showed that these biosorb...
Autori: Marek Tobiszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27760

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

Extracts of Bifurcaria bifurcata seaweed were obtained by diverse conditions. Different extraction techniques, such as hydrothermal and ultrasounds, and three different solvents (water, ethanol and water/ethanol (50:50)) depending on technique were used. Moreover, supercritical CO2 (SC-CO2) with 10% of ethanol as co-solvent using different extraction times (30, 45 and 60 min) was also used as extraction technique. Extraction yield, phenolic content and antioxidant activity were measured for e...
Autori: Rubén Agregán
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28039

Printed circuit boards are the most important component of any electrical and electronic device. The average metal content in waste printed circuit boards is ~30-35% whereas the rest of the material is a non-metal fraction (NMF). Metals in the waste printed circuit boards are recycled for their value whereas the NMF is mostly sent to landfills or incinerators for disposal. The circuit board laminates contain flame retardant chemicals that pose potential hazards to the environment and to public h...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28216

Groundwater at an abandoned industrial area near Bergamo, Italy, was historically contaminated by tetrachloroethylene (PCE) (>100 μg/L) and, to a lesser extent, by trichlorethylene (TCE), dichloropropane (DP) and 1,1,2,2-tetrachloroethane (R-130). A liquid reagent (EHC® Liquid) was selected for remediation of groundwater at the site. The reagent is provided in two parts: EHC® Liquid Mix (a soluble organo-iron salt), and ELS® Microemulsion (a lecithin-based carbon substrate), a...
Autori: Alberto Leombruni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28300