AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

AbstractCatalysts having mobile electrons in bulk such as metals and semiconductors are good solid materials for red/ox type of reaction (oxidation) and can be effectively used in gas sensing devices as well. The aims of this work were: (i) to investigate the surface behavior of Pt(0.28%)/Al2O3 and SnO2(2.94%)-Pt(0.28%)/Al2O3 samples in inert atmosphere (He) and in reducing atmosphere containing helium-cyclopropane gas mixture under ambient condition (i.e., room temperature, atmospheric pressure...
Autori: , Cornel Munteanu, Jozsef Kovacs, Mariana Scurtu, Monica Caldararu, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25146

In recent years, the release of volatile organic compounds (VOCs) has received much attention. Catalytic oxidation of VOCs, found in small concentration in industrial gas emissions constitutes an alternative for environmental pollution reduction.In this paper, a comparative study regarding the non-catalytic and catalytic oxidative destruction of non-halogenated or halogenated C6 hydrocarbons (C6H14, C6H12, C6H6, Cl-C6H5, Br-C6H5), is presented. Catalytic oxidation was studied in the presence of ...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25162

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueLignin in crop cultivations and bioremediationAlfred Abaecherli, Valentin I. PopaMaterials for intermediate-temperature solid oxide fuel cells and for proton exchange membrane fuel cellsAnnemarie Huijser, Joop SchoonmanAre interfacial biocatalysts important tools for nonpolluting technologies? 2. Immobilization of lipases and their  representative applications Brindusa Dragoi, Emil DumitriuUASB treatment of fruit canning wastewater: pilot-scale invest...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25180

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractIn this paper we propose system architecture for virtual environmental measurement center based on remote instrumentation. We use Internet facilities for transmission of the information. The station center can be used in remote control mode. Circumstance data can be collected with logging field station (Web-E-Nose or meteorological station). The environmental measurement center collects and automatically save data about the temperature in the air, relative humidity, pressure, wind speed ...
Autori: , Carmen Alexandru, Codrin Donciu, Cristina Schreiner, Marius Branzila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25216

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractThe paper reports experimental refractive indices of binary systems iso-propanol - water and iso-propanol - toluene over the entire range of composition at different temperature. Excess refractive indices were evaluated from the experimental data obtained. This derived property was fitted to variable-degree polynomials. The results obtained have been discussed and interpreted in terms of the type and nature of the specific intermolecular interactions between the components....
Autori: Catalin Lisa, Cerasela Huhurez, Gabriela Lisa, Ramona-Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25256

AbstractConsidering the importance of transfer phenomena in chemical engineering and environmental protection, in particular heat transfer modelling, numerical methods are applied to investigate the transient heat transfer inside an elliptic cylinder. The temperature of the surrounding medium was considered constant and equal to the temperature on the surface of the cylinder. The heat balance equation was solved numerically in elliptic coordinate system. The computations were focused on the infl...
Autori: Gheorghe Juncu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25269

AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

AbstractTheoretical and experimental studies of gas drying processes by adsorption in fixed bed of grains are presented in this paper. Based on an extensive literature study, some of the most representative mathematical models describing gas adsorption in fixed bed and consequently gas drying processes by adsorption in fixed bed are also presented. Using a mathematical model from those mentioned describing adsorption under isotherm regime, the temperature and gas flow velocity effects over the d...
Autori: Marius Sebastian Secula, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25272

AbstractThe efficient management of electricity consumption is an important tool to approach the basic objectives in the field of energy efficiency and environment protection. The paper describes an artificial neural network (ANN) approach to the problem of electric load profile prediction for a water supply system. The analysis was directed towards two main objectives: to determine the optimum input structure of the ANN with respect to the electric load profiles’ history and to determine the ...
Autori: Gilda Gavrilaş, Mihai Gavrilas, Ovidiu Ivanov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25278

AbstractThis paper presents experimental and theoretical studies regarding the behavior after heat treatment of an AlCu4Mg1 aluminum alloy with positive effect on corrosion resistance. On the basis of these experiments and the regression data obtained, an analysis regarding the influence of heating parameters on quenching and aging in order to obtain a certain stress was made. Two cases were considered: stress and quenching temperature are fixed and aging temperature was determined; stress and a...
Autori: Adrian Dima, Alina Adriana Minea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25281

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

AbstractDark fermentation hydrogen production from a mixture of food components using two different methods of methanogenic inhibition (autoclaving and BES) and three different temperatures (37, 60, and 70 Â?C) was examined in batch assays for two different mixed anaerobic cultures - one suspended sludge (S) obtained from an anaerobic digester and one granular sludge (G) obtained from a brewery wastewater treatment plant. In general, BES-inhibition of sludge was more robust when compared against...
Autori: Angela A. Abreu, Anthony S. Danko, Francisco Pinheiro, Maria Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25308

AbstractThe sorption of Pb(II) and Hg(II) ions from aqueous solutions by moss peat (from Poiana Stampei, Romania) was studied in a batch system. The data obtained from experiments of a single-component sorption were analyzed using Langmuir and Freundlich models. The Langmuir equation describe sorption isotherm of Pb(II) and Hg(II) with high correlation coefficients, and better than Freundlich model. According to the Langmuir model, the maximum uptake capacities of moss peat for Pb(II) and Hg(II)...
Autori: Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu, Mioara Răţoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25311

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractNatural hemp fibers have been evaluated for Zn (II) ions sorption from diluted aqueous solutions. In order to establish the optimum conditions, the effect of initial pH of solution, hemp dose, Zn (II) concentration, temperature and contact time of phases on the Zn (II) sorption by natural hemp has been studied. To model the Zn (II) sorption at three different temperatures the Langmuir and Freundlich isotherms have been used. The Langmuir maximum sorption capacities were determined as bei...
Autori: Carmen Paduraru, Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25336

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

AbstractThe main aspects refer to metals and refractory materials behaviour, at high temperature, to materials purifying and to achieve some chemical syntheses.The main technological parameter of the heating is temperature, heating obtained by focusing Sun's rays. The heating can be used inside the furnace to produce metallic material into a crucible, without any complementary power source.For the future, a bigger interest presents some other metals melting, more expensive than steel, such as ti...
Autori: Petrica Vizureanu, Cornel Samoila, Daniel Cotfas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25387

AbstractThe adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated. The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed at 30, 40 and 50 ?C. Thermodynamic potentials ?H, ?S, and ?G and isosteric heats of adsorption were calculated from experiment performed at different temperatures (30-50?C...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25393

AbstractEquilibrium data of water vapor adsorption from wet air on several materials were experimentally determined at temperature values of 313 and 333 K and air relative humidity values ranged between 30 and 90 %. Experimental data were correlated with Langmuir and Freundlich models. The obtained results emphasize the significant difference between the water retained on the adsorbent materials impregnated with various salt solutions, and on classic adsorbents....
Autori: Ioan Mămăligă, Constantin Baciu, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25394

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract This paper presents a comparative study of natural and mechanically mixed composting processes of marc resulting as a byproduct during the production of alcohol obtained from fermented fruits. Moisture, temperature, pH values, soluble fraction, total organic carbon, Kjeldahl nitrogen and ash content were monitored for 60 days. During this period the atmospheric temperature varied from 18Â?C to 21Â?C. The composting process could be considered a combination of three stages: mesophilic...
Autori: Anca-Ileana Penu, Daniela Simina Stefan, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25407

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract The paper presents the capacity of biodegradation of selected microorganism, cultivated on liquid culture media to which diesel was added in different amounts, to determine petroleum products and process efficiency. The optimum necessary conditions for development of microbial strains (pH, temperature, the quantities petroleum product / inoculum) have been established with the help of an experimental optimization program, SIMPLEX....
Autori: Dana-Camelia Cocut, Cornel Cojocaru, Mariana Diaconu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25414

Abstract The etching of iron materials in sulphuric acid solutions allows the dissolution of the iron oxides with formation of iron sulphates. The relatively low solubility of the formed sulphates imposes their separation for avoiding the contamination of the etching bath, as well as for preventing the environmental pollution through the wastewater. Within the flow sheet of the processing of the hot or cold rolled steel, a stage of separation by crystallization of iron sulphate is foreseen. T...
Autori: Liliana Lazar, Ion Balasanian, Florin Bandrabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25415

Abstract The waste recycling done in order to obtain composite products with performant properties and also, with long life cycle is the main purpose for the sustainable development. The present paper describes the way in which, different kind of solid wastes are immobilised in an organic resin as a binder matrix. Composites with different proportion of waste as, rubber/plastic, glass and silica sand have been obtained. The physical-mechanical properties and chemical stability of such organic...
Autori: Ioan Ropota, Emilia Zamfirache, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25450

Abstract The flotation tailing pond Bozinta is located at 5 Km West from Baia Mare town. It is closed and is preparing for ecological reclaiming. Preliminary investigations have been made on the meteorological and climatologic indicators of the site. The temperature, air relative humidity, the wind speed, the rain values and the soil temperature have been measured during the vegetation period of 2008 year. The air temperature on the tailing pond is always 1?ˇ2 0C higher than the values regist...
Autori: Vasile Oros, Mirela Coman, Monica Marian, Leonard G. Mihaly, Anca Mihaly
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25452

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract Peat moss has been widely used as low-cost adsorbent to remove a variety of pollutants, including organic compounds and metal ions from aqueous effluents. Various functional groups allow such compounds to bind on active sites of peat moss. The adsorbent used in this study was Romanian peat moss sampled from Poiana Stampei (Romania). The adsorption of Co(II) ions from aqueous solutions on Romanian peat moss was studied in batch experiments, in order to establish the influence of initi...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25533

Abstract The constructed wetlands are considered as a low-cost alternative system for nitrogen removal. Shale was selected as a media in constructed wetlands, on the basis of adsorption capacity and suitability for plant growth. The specific objective of this study was to evaluate nitrogen adsorption capacity for using as a media in constructed wetlands. Shale was sieved into 5 particle sizes Shale A-E. The physical and chemical characteristics of shale showed that it is suitable to be use as...
Autori: Amara Daothaisong, Jareeya Yimrattanabovorn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25535

Abstract Geopolymerization is a continuous developing field of research for utilizing solid waste and by-products. It provides a solution to many problems where hazardous residue has to be treated and stored under critical environmental conditions. Consumption of fly ash in the manufacture of geopolymer is an important strategy in making materials more environmentally friendly. Fly ash has been chosen as a base material in order to utilize this industrial waste. Previous researches have show...
Autori: Maria Harja, Marinela Bărbuţă, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25542

Abstract Starting from the disadvantages of the polystyrene system – the most important being that they are not biodegradable and their life cycle is relatively small, up to fifteen years – there were conceived several structures for outside walls made of perforated bricks vertically disposed and filled with granular materials. In this manner the thermal resistance is improved knowing that in gaps bigger than twenty millimeters there appear convective streams which substantially decrease ...
Autori: Răzvan Giuşcă, Vladimir Corobceanu, Raluca Giusca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25551

Abstract The paper examines the effects of high temperature corrosion of the surfaces of heat exchange due to corrosive components formed in the co-combustion of biomass and coal. High temperature corrosion of the surfaces of heat exchange becomes a priority in the combustion of biomass with high chlorine and alkali metals, as alkali chlorides formed deposited on the surfaces of heat transfer, leading to serious consequences for them. Forms of manifestation of corrosion are numerous, the most...
Autori: Ionel Pisa, Corina Rădulescu, Lucian Mihăescu, Gheorghe Lăzăroiu, Gabriel Negreanu, Simona Zamfir, Danut Vairenu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25553

Abstract The efficient understanding and application of mathematical models in the study of environmental phenomena keep up with the latest results in the mathematical domain which could provide solutions for controlling, analyzing, predicting and study of risk phenomena. This paper presents a browsing through some mathematical categories of interpreting statistical data, examples and their analysis in connection with the degree of polluting the water down the Danube River with the help of qu...
Autori: Valerian Antohe, Constantin Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25562

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Abstract The Environment Action Program foresees the development of a Thematic Strategy concerning the sustainable use of natural resources and waste management (Report EUR 21002 EN, 2004). In this context, the activities regarding the research and industrial development related to waste valorization through recycling and reusing have been grown. The wastes resulted from the fine ceramic technological process (scraps, used molds etc.) may be valorized. The used molds can be valorized in other...
Autori: Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25582

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

Abstract The use of biomaterials as biosorbents for treatment of wastewaters will provide as a potential alternate to the conventional treatment methods. The main advantages of biosorption are high selectivity , cost effectiveness and good removal performance. World wide numerous low cost bio materials have tried for biosorption of dyes. In this present investigation, the dead biomass of Penicillium sp. fungus and wood sawdust was used as biosorbents and their capacity to removed malachite gr...
Autori: Cornel Pohontu, Florin Luca, Igor Creţescu, Manea Liliana, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25593

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract The Schiff base N,N??(salicylidene)-methylenediamine, known as Salmen in combination with Cr(III) forms at pH = 4.5 a greenish precipitate, which is stable at room temperature but decomposed on heating. The study of the Infrared spectra, Electron Spin Resonance (ESR), X-ray diffraction and thermogravimetry has pointed out that the precipitation form is a complex, while the molar ratio showed that the combination rate of Cr(III): N,N?-bis(salicylidene)-methylenediamine is 1:1. The new...
Autori: Doina Sibiescu, Ioan Roşca, Irina Spatarescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25619

Abstract Equilibrium and kinetics of sorption of Zn (II) ions from aqueous solutions of pH 5 on indigene (Romanian) peat moss were investigated in batch system. The experimental equilibrium sorption data at three temperatures were analysed by Freundlich, Langmuir, Tempkin and Dubinin-Radushkevich sorption isotherm models. Results indicate the following order in to fit the isotherm equations: Langmuir > Tempkin > Dubinin-Radushkevich > Freundlich. The equilibrium sorption capacity determine...
Autori: Angelica Kicsi, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25632

Abstract Textile dyeing process is an important source of contamination responsable for the continous pollution of the environment. Control of water pollution has importance for both organisms, which live in water and those who benefit from water. Many dyes reaching the water source are difficult to decompose and cause many problems due to their carcinogenicity. Consequently, it is important to remove these pollutants from wastewater before their final disposal. This paper reports the resuls ...
Autori: Alina Dughila, Alina Stefanache, Cornel Pohontu, Igor Creţescu, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25633

Abstract Two different inocula - acclimated and non-acclimated to fat- were used to evaluate the methane production of cow manure, food waste and oily waste in batch assays. The inoculum adapted to fat had a better performance in the methanisation of substrates with significant lipids content. Furthermore, it is demonstrated that an increase in the ratio inoculum/substrate can enhance the initial methane production rate of oily waste when using a non-adapted inoculum, improving also the ultim...
Autori: Lucia Neves, Maria Madalena Alves, Raquel Ferreira, Rosario Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25634

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? EFFECT OF ELECTRICAL CURRENT ON H2/ H2O2 GENERATION IN NON-THERMAL PLASMA GLIDING ARC REACTORS ? ADVANCES IN THE VISUALIZATION OF THREE-DIMENSIONAL SEISMIC VOLUME DATA ? CHARACTERIZATION OF ELECTROMAGNETIC RADIATION FROM A PATIENT MONITOR ? METHODS OF ELECTROMAGNETIC INTERFERENCE REDUCTION IN ELECTROCARDIOGRAPHIC SIGNAL ACQUISITION ? SPHERICAL MODEL OF THE HUMAN HEAD EXPOSED TO ELECTROMAGNETIC FIELD ? BRAIN ELECTRICAL ACTIVITY RECORDING IN SOME ELECTROMAGNETIC ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25667

Temperature distribution in the vacuum directional solidification system influenced seriously on the impurities concentration andmicrostructure in Polycrystalline Silicon. In this study, a numerical model for the transient global heat transfer for directionsolidification process has been developed by the finite element method (FEM). A two-dimension numerical simulation fortemperature distribution of directional solidification process was carried out using software Multi-physics Comsol 3.5a. Ther...
Autori: Guoqiang Lv, Wenhui Ma, Hua Wang, Xiangyang Mei, Kuixian Weihttp://www.ecozone.ro/reviste.php?RID=25671

It is a promising way for CO2 capture and sequestration by hydrates crystallization. In this study, the characteristics of CO2 hydrate formation are investigated in a small scale dynamic reactor under pressure conditions from 2.0-3.5 MPa and temperature varied between 0.5-4.0Â?C. The effects of supercooling degree and pressure on hydrates formation were discussed. Hydrates formation can be completely finished within 150 min and the final pressure-temperature points of system are just located on ...
Autori: Ni Liu, Xiaobo Xuan, Daoping Liu, Yingming Xiehttp://www.ecozone.ro/reviste.php?RID=25689

Ecological adaptation of heavy metal polluted environments is significantly enhanced through plants inoculated with plant growth-promoting bacteria (PGPB), and the cost of phytostabilization in metal tailings can be reduced. On the basis of the systematic investigation of manganese tolerant plants which grew on Xiangtan manganese tailings, rhizosphere soils of th Chenopodium album Linn. were collected. One yellow manganese-resistant strain named XZL01 was isolated from the rhizosphere of fresh p...
Autori: Shengguo Xue, Yameng Ma, Xiaohua Zhou, Xiyan Zhou, Fenghao Liuhttp://www.ecozone.ro/reviste.php?RID=25696

In this study, the application of freeze-concentration method to treat low-concentration polluted water was demonstrated. The effects of stirring, the temperature in a freezing cabinet and the volume of water involved in the freeze-concentration treatment of pollutants were investigated under laboratory conditions. The removal of pollutant by freeze-concentration treatment was also attempted. Results had shown that the ratio of pollutants removed was about 83% when the experiment was carried out...
Autori: Yingjie Dai, Ying Zhang, Baiyin Liu, Masahiro Teduka, Yongbo Lin, Shunitz Tanakahttp://www.ecozone.ro/reviste.php?RID=25709

Semi-dry FGD with fabric filter has been extensively studied in recent years. After a series of industrial tests on 300MW boiler with semi-dry FGD and fabric filter, some operation notes were obtained. The test results show that CFB-FGD with fabric filter can be run longer and stable, and its actual performance is even higher than the design parameters. Moreover, the pressure drop of fabric filter after CFB-FGD is 600~800Pa (higher than normal). The fabric filter, which contributes to the desulf...
Autori: Tong Li, Han Yi, Han Xu, Reti Hai, Wang Wenxinghttp://www.ecozone.ro/reviste.php?RID=25716

Abstract:The article presents a method of monitoring the solar radiation components taking into consideration the isotropic model. Thewireless solar radiation monitoring system developed is innovative and original in comparison with the systems already availableon the market. The use of the wireless device, of the rechargeable batteries, of the sensors used for measuring the solar radiationcomponents and the temperature make this system an autonomous and a portable one. An experimental prototype...
Autori: Cornel Samoila, Daniel T. Cotfas, Doru Ursutiu, Paul Borza, Petru A. Cotfas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25735

Abstract:Incineration plants are used since the beginning of the twentieth century to transform the mixed municipal waste into thermalenergy and to convert the hazardous components of waste into harmless compounds. To minimize the environmental pollutionand maximize the energy efficiency of the produced energy, the control of the complex processes that occur into the waste toenergy conversion is of major importance. In this work, the system identification approach is used to determine the dynami...
Autori: Adrian Danila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25739

Abstract:A comparative analysis is drawn on the energetic responses numerically simulated for Brasov, Romania location, delivered bytwo mono-axial pseudo-equatorial STCs (solar thermal collectors): a flat plate STC and a STC with heat pipes; the two systemsare destined for future implementation on Transilvania University Campus. Accordingly, two tracking programs are consideredfor the diurnal motion: a) of 1h constant duration steps, for school courses interval (September-June) and b) 1-step pro...
Autori: Maria M. Vatasescu, Veronica E. Dombi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25740

Abstract:One of the most complex aspects of water accounting is the assessment of point and diffuse source pollution. At present, thebuilding sector in European countries is responsible for 40% of the total energy consumption. To reduce the European Uniondependency on energy import, the strategy undertaken in Lisbon is to reduce as much as possible the energy consumption ofbuildings and to increase the share of renewable energy sources. As an average, house heating represents about 75% from the ...
Autori: Ferenc Kalmár, Tünde Kalmár
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25750

Abstract:The concept of passive and low energy houses became fashionable in the last years and the European Parliament also initiated aproposal to build only near zero energy houses from 2018. The regulations already in force aim at low energy consumption (mostlikely influenced by the wide spreading of the �Passivhaus� concept in Europe) and by 2018 harmonized regulations andstandards will require the near zero energy building. According to the concept of the Energy Performance of Building D...
Autori: András Zöld, Tünde Kalmár
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25751

Abstract:The paper presents a computer modelling and experimental validation for the thermodynamic performance of parabolic troughsolar collectors (PTSC) used in a micro-combined cooling,e heating and power (mCCHP) system. The thermal efficiency, fluidoutlet temperature, heat gain and heat and optical losses of the collector are calculated depending on the collector geometry,optical properties, fluid properties, fluid inlet temperature and flow rate, solar insolation, wind speed and ambient temp...
Autori: Ion V. Ion, Lizica Simona Paraschiv, Spiru Paraschiv
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25760

Abstract:The increasing of energy consumption and fossil fuel emissions (especially CO2, SO2 and NOx) and the limitation of crude oilreserves, determined a growing trend toward renewable energy technologies, like solar, wind, geo-thermal energy and biomass forbiofuels.From all the renewable energies sources, biomass attracts more and more interest being a renewable resource with economicpotential, which can be found all over the world, with positive environmental properties due to neutral emissi...
Autori: Anca Sauciuc, Angela Potetz, Georg Schlaub, Gerald Weber, Hermann Hofbauer, Lucia Dumitrescu, Reinhard Rauch, Ziad Abosteif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25762

Abstract:A thermodynamic model for studying the overall efficiency and power output of a solar assembly using a Stirling engine ispresented. It is based on the application of the energy and exergy balance equations to the system components. The results of theproposed model are generated as a function of solar incident radiation whose analytical estimation is presented. The numericalapplication is set for a solar assembly operating in Bucharest, composed by a parabolic dish mirror, a plane receiv...
Autori: Adina Gheorghian, Alexandru Dobrovicescu, Camelia Stanciu, Dorin Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25764

Abstract:The work presents the results in investigating the thermal behaviour of passive solar elements, for expanding the existing analysisand prediction methodologies. The interest focuses on solar control through natural shading with deciduous plants. This providesa natural path for incorporating all advantages the passive behaviour, available throughout the year. The simulation of thedynamic energy performance of building elements is developed, starting with a physical modelling of the vario...
Autori: Angelos D. Tzachanis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25768

Abstract:The oxidation of low grade complex concentrates (Cu, Pb and Zn) in aqueous media (weak alkaline) oxidized nonferrous metalsconcentrates is carried out at high pressure. Leaching is the subsequent processing step in metal extraction. The paper studies theinfluence of some parameters (temperature, time, L:S ratio, excess) on the leaching efficiency of nonferrous metals from oxidizedconcentrate. The optimum parameters determined are: S/L ratio of 10/1, 25% reactive excess, leaching tempera...
Autori: Cornelia Lupu, Dragoş Taloi, Liliana Gherghe, Luminita Mara, Teodor Velea, Vasile Predica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25774

Abnstract:In recent years, solar receivers have been employed in several applications where high temperature fluids are involved, such aspower plants and solar thermal reactor. The possible presence of high temperature gradients could determine reduced receiverefficiency and a short life of the material. Thermal and fluid dynamic analysis of the receiver allows to highlight possible presenceof temperature gradients and to evaluate their values and the more critical zone of the material. Compress...
Autori: Alina Adriana Minea, Oronzio Manca, Salvatore Tamburrino, Sergio Nardini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25779

Abstract:One of the basic conditions for the operation of nuclear installations is security operation. The complexity of the phenomena inheavy water detritiation plants, determine the use of advanced equipment for technological processes involved. Pilot Plant forTritium and Deuterium Separation developed the cryogenic technology of tritium separation from tritiated heavy water. Theprocess is based on an catalyzed isotopic exchange module, where the tritium is extracted from tritiated heavy water...
Autori: Sorin Gherghinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25787

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract: The paper focuses on eutrophication due to nutrients load into a reservoir. A thermally stratified reservoir water body is divided in vertical layers and horizontal zones according to water temperature and depth. The layers show different compositions of limiting nutrient because of the density of flow and due to inhabitants on the bottom of the reservoir exposed to sunlight. The bioassay for algal growth potential test (AGPT) is the most direct and effective way to determine a limitin...
Autori: Dimitri Solomatine, Ioana Popescu, Jae-Ki Shin, Nahm-Chung Jung, Peter Kelderman, Roland K. Price
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25798

Abstract:Alkaline protease from Conidiobolus coronatus which is optimally active at pH 10 and 40°C finds application in leather and detergent industries as well as for recovery of silver from waste photographic films. The protease was immobilized in Ca-alginate, polyacrylamide gel and alkali treated waste fungal biomass (ATWFB). ATWFB was found to be most suitable among the matrices tested. Glutaraldehyde marginally increased the binding to ATWFB. Binding of protease to ATWFB seems to be through...
Autori: Ryali Seeta Laxman, Shiv Shankar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25807

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The availability of good quality water is an indispensable condition for preventing diseases and improving the quality of life. Water is one of the most important renewable resources, which must be prevented from deterioration in quality. Various physicochemical parameters like pH, alkalinity, total hardness, total dissolved solids, calcium, magnesium, nitrate, have a significant role in determining the potability of drinking water. In this study, samples were collected from wells situated in vi...
Autori: Maria Cioroi, Mirela Praisler
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25853

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Among the different types of waste products tested, the bark of different Pinus species have been identified as a promising class of low- cost sorbents for heavy metal binding. In this context, the potential of Romanian pine bark wastes as green and economical sorbent for cadmium (II) ions removal from aqueous solutions has been tested in batch conditions as function of initial pH, contact time, sorbent dose, metal ion concentration and temperature. The equilibrium data at three different temper...
Autori: Anca Miron, Brindusa Robu, Carmen Paduraru, Lavinia Tofan, Roxana Laura Mihailescu Amalinei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25871

The indoor climate of educational institutions (kindergartens, secondary schools and universities) in Estonia is investigated. The main hazards for students’ health are: the high concentration (over 800 ppm) of carbon dioxide in the classrooms that refers to the inappropriate ventilation; the non-ergonomic computer workplaces where the direction of the natural light (without blinds for the windows) is causing glare on the monitors; the low humidity of the air in winter; the low air temperature...
Autori: Ada Traumann, Piia Tint, Viiu Tuulik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25873

Newly prepared SnO2-CeO2 catalyst samples used as depollution catalysts were characterized applying low-temperature nitrogen adsorption (BET), X-ray diffraction (XRD), thermo-gravimetry (TG-dTG) and temperature-programmed reduction (TPR) methods. Pure SnO2 has higher surface area (17 m2/g) than the pure CeO2 (8 m2/g). Addition of organic tin oxide precursor to ceria in amount of 5 wt% slightly decreases the surface area of CeO2 (SSn5-Ce= 7 m2/g). The increase of tin oxide content to 10 and 20 wt...
Autori: , Anca Vasile, , Cristian Hornoiu, Jozsef Kovacs, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25875

This paper presents an experimental study on the energy requirement for greenhouse heating. The evaluation of necessary energy for crop plants was made by systematic measurements of the thermal behavior for three non heated tunnel greenhouses, covered with polyethylene. From the comparative analysis of the measured temperatures inside and outside the tunnel, it was established the relationship for estimating the inside greenhouse average temperature (tmi), lower than the minimum temperature nece...
Autori: Maria Harja, Roxana Dana Bucur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25879

Fly ash and fly ash based zeolites are inorganics used for improving soil quality. In the current paper, the hydrothermal modification of fly ash was studied. Three methods have been employed for this purpose. The first method involved the use of an autoclave, where synthesis has been performed at a temperature of 120 0C and a treatment time of 4 to 8 hours. Within the second method, the modification of the ash at a temperature of 600 0C by fusion was carried-out. In this method, a mixture of as...
Autori: Corneliu Munteanu, Daniel Bucur, Lacramioara Rusu, Maria Harja, Marinela Barbuta, Ramona Carla Ciocinta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25885

The paper proposes a method and a technology that allows the generation of a very high intensity magnetic field, at a high pressure and within an extremely short period of time into a ferrous material, in order to study the behavior of such material from the magnetic and structural perspective. The method consists in producing the �compression� of an initial magnetic flux that is generated in a coil that has inside a ferrous material cylinder (the armature), subject to testing, done by a con...
Autori: Nicolae Badara, Octavian Tarabuta, Vasile Dobref
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25887

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

Abstract Effects of the aeration rate on nutrient removal from synthetic domestic wastewater using an intermittently aerated sequencing batch reactor (IASBR) were studied at ambient temperature. Two aeration rates, 0.8 and 1 L air/min, were studied. At the aeration-rate of 0.8 L air/min, removals of COD, NH4+-N, total nitrogen (TN) and PO43--P were 84%, 96%, 75% and 99%, respectively. At the aeration rate of 1 L air/min, removals of COD, NH4+-N, TN and PO43--P were 90%, 99%, 70% and 66%, re...
Autori: Liam G. Henry, Liwen Xiao, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25941

AbstractIn this study, palygorskite clay calcinated at different temperatures from 200 to 900 °C was used as adsorbent to removephosphate from aqueous solutions. The crystal structure and the surface property of the thermally modified material wasinvestigated to determinate the relationship between the adsorption capacity of the adsorbent and the changes of the crystalstructure and surface property. The results indicate that palygorskite clay calcinated at 700 °C had the highest adsorptioncapaci...
Autori: Chengsong Qing, Chengzhu Zhu, Dong Chen, Jiayuan Wang, Jingjing Xie, Tianhuhu Chen, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25949

AbstractIn this paper, we report a study on structural evolution, magnetic susceptibility and arsenic content of colloidal pyrite fromXinqiao deposits in Tongling, Anhui Province, China. The pyrite was treated under N2 atmosphere and charaterized with X-raypowder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), magnetic susceptibility analysis, and atomicfluorescence spectroscopy (AFS). We observed that heating of colloidal pyrite in N2 atomosphere did not change the crys...
Autori: Dong Chen, Ping Li, Tianhu Chen, Xiao Zhu, Yadan Shi, Yan Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25951

AbstractThis paper focused on estimating climate change impact on the future water availability in the Yellow River Basin,China. However, climate change and its impact on water availability are subject to large uncertainties. In order todeal with uncertainties, scenarios were used to explore possible future states of climate variables under uncertainty,and probabilities were attached to represent uncertainty explicitly according to the Principle of Maximum Entropy.Probabilistic scenarios of futu...
Autori: Congli Dong, Gerrit Schoups, Nick van de Giesen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25957

AbstractA rapid increase of wastewater treatment plants (WWTPs) has made the disposal of excess sludge from WWTPs a seriousproblem. In order to enhance the management of sludge, both development of sludge reduction technologies and sludgeevaluation system are of great importance. Based on the survey data from 696 plants in China in 2009, an empirical model wasdeveloped to simulate the production and discharge of excess sludge, which considered influent, temperature, Chemical OxygenDemand (COD), ...
Autori: Chengwen Wang, Tao Xie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25963

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractIn this paper we describe a wireless system, including smart sensing nodes for indoor air quality and unobtrusive cardiorespiratorymonitoring. The sensing nodes include a set of solid state gas sensors, sensors for temperature and relative humidity, amicrowave Doppler radar sensor for cardio-respiratory function, and appropriate conditioning circuits expressed by active filtersand amplifiers. The analog signals provided by the signal conditioning circuits is applied to a data acquisition...
Autori: Gabriela Postolache, Octavian Postolache, Pedro Silva Girăo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26007

AbstractDue to high energy costs and the rising consciousness of energy issues in the textile industry, saving energy became a significantproblem. Since a large amount of the energy required in textile finishing is needed in the form of steam for various processes,recovering wastewater heat has great potential for cost reduction. In this research, it was studied the heat recovery from cellulosictextiles finishing wastewater, based on a case study in a textile company. After examining the wastewa...
Autori: Armand F. Bertea, Gheorghe Condurache, Răzvan Berariu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26013

AbstractThe aim of this work is to characterize the flocculation process of a bentonite synthetic suspension with characteristics close toBega River from Timisoara, Romania. The time stability of the synthetic suspension was firstly investigated. After a few days ofcontinuous mixing a stable suspension was reached, stability being confirmed by monitoring the main physicochemicalparameters (pH, temperature, turbidity, dissolved organic carbon and initial particle size). In order to determine the ...
Autori: Alain Liné, Cosmina-Mariana Militaru, Ligia Barna, Teodor Todinca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26027

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe performance of two cation exchanger resins, Amberjet UP1400 and Amberlite IR120 in the process of Cs(I) ions removalfrom aqueous solutions was examined. Batch experiments were carried out to determine the influence of several parameters(resin dosage, contact time, temperature and initial concentration of Cs(I) ions) on the removal process. The equilibrium wasreached after 60 min for Amberlite IR120 and after 120 min for Amberjet UP1400, with an overall adsorption performance of~97% f...
Autori: Adina Negrea, Cornelia Muntean, Corneliu Mircea Davidescu, , Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26032

AbstractThe paper presents the application of cross-spectrum analysis (CSA) to air pollution and meteorological time series collected fromseven air quality monitoring stations located in three urban agglomerations of Romania, affected by industrial and trafficpollution: Braşov, Ploieşti and Târgovişte. Data have been collected from November 2011 till March 2012, at one hour samplingrate. The purpose of the analysis was to reveal the correlations between two series at different fre...
Autori: Ştefania Iordache, Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26057

AbstractThe global diming means a gradual reduction on the earth's surface of global direct irradiance. The global dimming blocks thesunlight that would otherwise cause evaporation, thereby interacting with the global warming. In order to determine somecharacteristics confirming the global dimming were conducted a series of measurements of temperature and luminosity in Iasi.The purpose of the study was to link the urban pollution to the decrease in the solar luminosity during the time of a month...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26065

AbstractThe removal of residual oil from palm oil mill effluent (POME) using boiler fly ash was studied in this paper, with focus on theadsorption isotherms and kinetic studies by measuring the residual oil concentration using UV-spectrophotometer. The percentresidual oil adsorbed decreased from 80% to 5% as contact time was increased from 10 mins to 120 mins but increased from2.74% to 72.98% as initial concentration of residual oil increased from 0.04812 mg/L to 0.2406 mg/L. Pseudo-second order...
Autori: Jude C. Igwe, Stella N. Anioke, Uche Arukwe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26078

AbstractThe present study reports the efficiency of almond shell as a cheap and available material for the removal of Cu (II) fromcontaminated aqueous solutions. The equilibrium experiments indicated that Cu (II) sorption obeyed the Langmuir isotherm at26, 40 and 55oC. The highest value of the maximum uptake (Qo) from the Langmuir equation was found 6.783 mg g-1 at 40oC.The various thermodynamic parameters such as ΔGo, ΔHo and ΔSo were also calculated. The values of ΔGo varie...
Autori: Soheil Aber
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26080

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractIn this study, a computer program, the Land Surface Temperature Calculator (LST Calculator) was developed in Visual Basic.NET (2008) which employs the Radiative Transfer Equation (RTE) method. The LST Calculator is a valuable tool to studythermal environments using the thermal band of Landsat TM/ETM+ data and make the land surface temperature retrieval muchsimpler and faster. LST can be retrieved with this tool by inputting required parameters in the program. Thus, this program willbe he...
Autori: Hakan Oguz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26093

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract A set of 500 water samples collected from various sites of Tarnava Mare River, between Medias and Copsa Mica were analyzed, during three years (2010-2012). The physicochemical parameters like: temperature, pH, electrical conductivity (EC), total dissolved solids (TDS), salinity, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), lead (Pb2+), chloride (Cl-), sulfate (SO4 2-), ammonium (NH4 +), nitrite (NO2 -) and nitrate (NO3 -) were determined. The results were co...
Autori: Ioana Piştea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26114

Abstract The article presents the development of a mathematical model concerning thermal desorption in a tubular electric furnace, using the linear regression analysis principle. With a range of experimental data obtained from some laboratory tests on water evaporation plus pollutant (Hexaclorocyclohexane - HCH), evaporation resulting from the application of thermal desorption on some soil samples; a mathematical model was developed to calculate the mass of substance evaporated fro...
Autori: Calin Vasile Prodan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26125

Abstract This research analyses time series of air temperature and wind speed. Trends and periodical components are defined for both time series with no significant statistical relationship between them. The spectral analysis of temperature series with no trends shows the peak frequency fc = 1/12, corresponding to a seasonal periodical component. The graph of the spectral density function of the wind speed time series does not manifest a seasonal periodic component. Forecasting of ...
Autori: Rasid Burtiev
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26135

Abstract The paper presents several aspects regarding the optimization of the operation for a mixed cycle gas turbine, Titan 130S type, installed at S.C. CET S.A. Bacau, during the warm season. The optimization entails the partial loads operation and has been done using the multicriterial analysis, taking into consideration the operation restrictions required for this type of gas turbine. The criteria that regard this analysis are: thermal energy requirements, the global efficiency...
Autori: Marius-Ion Stanila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26145

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

Abstract The reason for carrying out this research is related to the significant risk of heavy metals present in wastewater on the environment and human health. The removal of heavy metal ions from aqueous solutions was performed in a batch system, using peat (from Poiana Stampei, Romania) as adsorbent. The efficiency of the process was predicted with high accuracy (correlation with experimental data more than 0.99) based on a feed-forward neural network with two hidden layers. The...
Autori: Gabriel Dan Suditu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26150

Abstract Municipal waste landfill leachate results in different stages of waste stabilization and has a negative impact on the environment. When implementing a new policy on waste handling, monitoring landfill leachate should be carried out under conditions of a modern solid waste landfill. The paper discusses the quality of leachate observed in old and recently built landfills in Vilnius - the capital city of Lithuania. The landfills are situated at a distance of 20 kilometres fro...
Autori: Kristina Baziene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26151

Abstract The biosorption of Pb(II) and Cd(II) ions from aqueous solution on marine green algae biomass (Ulva lactuca sp.) was studied in batch systems, at initial solution pH of 5.0 and biomass dose of 8.0 g/L, considered as optimum experimental conditions. The obtained results from experiments of a single-component biosorption were analyzed using Langmuir, Freundlich and Dubinin- Radushkevich isotherm models. The Langmuir equation describe the biosorption isotherm of Pb(II) and Cd...
Autori: Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26152

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractGallinaceous feathers are an abundant solid waste from the poultry processing industries, which poses disposal problems. Akinetic study dealing with the adsorption process of wool reactive dye, Yellow Lanasol 4G (CI Reactive Yellow 39), ongallinaceous (Gallus gallus, Cobb 500) feathers was carried out. The main research goals of this work were to evaluate theviability of using this waste as adsorbent and to study the kinetics of the adsorption process, using a synthetic effluent. Thechar...
Autori: Sónia Adriana Figueiredo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26203

AbstractThe dominant litter samples Pinus sylvestris L. needle litter and Acer platanoides L. leaf litter were collected in the coniferousmixed forest located at 54ş43‘ N 25ş19‘ E (Vilnius, Lithuania) in April 2010. Different heating temperatures (150, 250, 350, 450and 550şC) and 2 hour heating duration were used to produce ashes. The selected heating temperatures affected mass loss, colour, pH, electrical conductivity (EC), C/N ratio, nutrient concentrations of the ash. The darkness of Munsell ...
Autori: Jolita Dūdaitė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26208

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractIn this study, as part of developing a green recycling process of spent lead-acid battery that can avoid both smelting and electrowinning, leaching agent citric acid and other additives (such as sodium citrate and hydrogen peroxide) in aqueous media were reacted with spent lead-acid battery paste. PbO, PbO2 and PbSO4, which are the three main components in a spent lead-acid battery paste, were leached to form lead citrate precursor which was crystallized and then separated from the solut...
Autori: Xinfeng Zhu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26215

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractKohonen Self-organizing map (KSOM) modeling have been applied increasingly for analysis, estimation and prediction ofseveral water quality processes, which are embedded with high complexity, dynamism and non-linearity. KSOM or unsupervisedneural networks were applied to microbial data (Escherichia coli, faecal streptococci, and total coliforms) from the effluent of atwo year data set (2008-2010) on two permeable (pervious) pavement systems used to treat storm water runoff contaminated wi...
Autori: Kiran Tota-Maharaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26226

AbstractBased on the measurement at a coastal site in the Yangtze Delta, the temporal variation characteristics of ozone and theinfluences of the precursors (NO, NO2, and CO) and meteorological conditions were analyzed. Also the crop yield loss by ozoneexposure at the site was estimated and discussed. The variation of daytime ozone showed a two-peak pattern during the year with one peak in spring and the other in summer, while the nighttime ozone just presented one peak in spring. The diurnal va...
Autori: Wenpo Shan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26231

AbstractIn this article, hydrodynamic parameters and overall Oxygen mass transfer coefficient of petroleum based micro-emulsions in anairlift reactor were investigated. Four different petroleum-in-water micro-emulsion systems containing kerosene, heavy naphtha,light naphtha and diesel as oil based were used with concentrations of 3% and 7 % (v/v). The experimental data were supportedby simulation results obtained from the Computational Fluid Dynamics (CFD) method. The CFD was properly able to si...
Autori: Mostafa Keshavarz Moraveji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26234

AbstractIn this study, changes induced in milk processed at ultra high temperature (UHT) were investigated following exposure to UVand white-light, by employing fluorescence spectroscopy. Two important indicators, namely Riboflavin (Rb) and vitamin A,were monitored to evaluate the light-induced damage in milk. It was noticed that the photo-degradation of Rb is due to thephotochemical decomposition and photosensitization. Moreover, it was found that the wavelength of the exposure light has agreat...
Autori: Maria Iliut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26241

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe Lake Bafa is an alluvial bar lake located in the Aegean Region in the Big Meander river basin in Aydın and Muğlaprovinces. However, the lake is currently threatened by severe pollution, being under the risk of serious degradation because of(i) uncontrolled urbanization; (ii) point and non-point source pollution; (iii) algae bloom; (iv) sediment transportation andpollution via influent creeks to the lake; and (v) severe degradation of the natural wetlands within its drainage...
Autori: Ebru Yilmaz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26267

AbstractThe main objective of this study is to investigate the utilization potential of oil well-derived drilling waste (DW) in the firedshale-brick production. Different mixtures were suggested for the experimental work with the DW content varying from 20% to40%. The prepared briquettes from different mixture were fired at a temperature ranging from 950°C to 1050°C for 1 h, with aheating rate of 2~3°C /min. Water absorption, apparent porosity, bulk density, weight loss by ignition, firing shrin...
Autori: XiangGuo Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26269

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractIn this study, the experimental performance of a single slope solar still coupled with an evacuated tube collector was investigated. A single slope passive solar still (PSS) and single slope active solar still (ASS) integrated with an evacuated tube collector were fabricated with an area of 1 m2 and tested in the composite climate of Coimbatore, Tamilnadu, India, (Latitude: 11°N; Longitude: 77°E and an altitude of 409 m above sea level). High water  temperatures in the range of 84.2...
Autori: Karuppusamy Sampathkumar, Palanisamy Senthilkumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26286

AbstractWorldwide, waste materials are produced as a by-product of industrial manufacturing and placed in storage areas. One of the waste materials is filter cake (FC). FC is formed during the infiltration of cooling water in steel factories. The main aim of this research is determination of optimum usage of FC in the production of impermeable layer on ground by using fuzzy model approach. Because of this, in the study, FC as a waste material was hardened with cement and an impermeable layer was...
Autori: Ä°lker Bekir Topďż˝u, Murat Karacasu, Tayfun Uygunoğlu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26288

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractThis study aims to investigate the environmental impacts of the municipal waste disposal facility of Pata Rat, Cluj-Napoca, Romania during dry periods of the year. The environmental impact assessment on the landfill site was carried out on the basis of the measurements of environmental quality indicators. Environmental indicators were measured in the surface water, soil and air. For the assessment of the environmental impacts generated by landfill on surface water measurements were carri...
Autori: Ákos Rédey, Anca Gurzau, Antoanela Popovici, Constantin Măruţoiu, Fazekas Bence, , Ildiko Varga, Raluca Mariana Haţegan, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26296

AbstractThe efficiency of solar disinfection (SODIS) was evaluated and enhanced by concentrating sunlight at low pH values in a solar collector disinfection (SOCODIS) system at different sunlight intensities and is highlighted in the author’s earlier findings. In order for further improving the rainwater disinfection, simple technique like wrapping the PET bottles with heat-resistant plastic bags (Wp) were used for enhancing the thermal/synergistic effects of solar radiations. An analysis of the...
Autori: Abdulrahman Ali Alazba, Mooyoung Han, Muhammad Nasir Amin, Muhammad Tahir Amin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26298

AbstractThe effect of the number of surrounding droplets and distance between evaporating droplets on evaporation rate of the targetdroplet is studied experimentally in an evaporator which has been validated based on the d-square law. It can be found that theevaporation rate of the target droplet decreases with the increase of the number of surrounding droplets and the decrease of thedistance between evaporating droplets. The results analyzed experimentally and theoretically show that there is a...
Autori: Li Xiang-Rong, Liu Fu-Shui, Ma Yupo, Wang Xiang-Yuan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26304

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractA septic tank is an essential part of the decentralized wastewater management system. The aim of the experiment described inthis paper was to evaluate the impact of the method of sampling and hydraulic retention time (HRT) on the performance of acircular three chamber septic tank and to design a septic tank for a single household with four residents and wastewater flowrateof 0.6 m3/d. It was found out that the difference between suspended solids (SS) and chemical oxygen demand (COD) remo...
Autori: Ala Kirjanova, Mindaugas Rimeika, Regimantas Dauknys
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26329

AbstractThis paper presents a study of the thermoaerodynamic spectrum inside an asymmetrically heated vertical channel of a doubleskinfaçade. A double-skin façade is an envelope construction that consists of two transparent surfaces separated by an airchannel. The numerical modeling was developed using the Ansys-Fluent simulation software under conditions of forcedconvection, using a three-dimensional geometry and a “k-ε standard” turbulence model. Then, experimental tests were performedon ...
Autori: Cătălin George Popovici, Cătălin Grigoraş, , Theodor Mateescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26332

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractIn this work, the effect of the addition of some nutrients on fungal growth and removal of Cr(III) were investigated. Theconsidered fungi, isolated from real tanning factory environment were Phanerochaete chrysosporium, Aspergillus niger and A.oryzae. Firstly, the optimal conditions for fungal growth were determined as a function of pH, contact time, temperature andagitation speed. Secondly, the effect of the addition of some nutrients on fungal growth was examined. Without the addition ...
Autori: Abdeltif Amrane, Mansur Zarrabi, Mohammad Noori Sepehr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26337

AbstractGlobal climate change affects the temperature and precipitation. These changes have serious impacts on the availability of waterresources on regional basis. Turkey, being located in the Mediterranean Basin, is predicted to be severely affected by the adverseeffects of global climate change, particularly in terms of water resources. It is important to figure out the situation of the countryin terms of water scarcity induced by anthropogenic climate change in order to provide rational meas...
Autori: Özgür Aktaş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26342

AbstractThe removal of phosphorus by strongly basic anion exchanger was investigated. Removal efficiency increased with contact time,resin mass and initial solute concentration, while temperature showed a reverse effect. Equilibrium data were best fitted ontoLangmuir isotherm model (R2>0.99). Maximum sorption capacity of the resin was 66.22 mg/g, namely significantly higher thevalues reported in the literature. The Freundlich parameter (n = 4.3) and the Langmuir separation factor (RL = 0.067-...
Autori: Abdeltif Amrane, Hamid Reza Ghaffari, Mansur Zarrabi, Mohammad Mahdi Soori, Mohammad Noori Sepehr, Saied Borji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26343

AbstractThe survival of Formosan landlocked salmon has been threatened by the change of habitat ambience. Because of the potentialtoxicity of nitrite (NO2-) and ammonium (NH4+) to salmonid fisheries, we studied the evolution of nitrogen compounddistributions in stream water and their relationship with ambient abiotic factors. The water was sampled at five sites surroundedwith various land-use types in bi-monthly intervals for seven years. The results indicated that a high NO2- concentration occu...
Autori: Wen-Hui Kuan, Yi-Lang Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26351

AbstractThis study was conducted to generate a hierarchical modelling based on ecological land classification in the Yukarıgokdere forestdistrict of the Mediterranean region, Turkey. Two ways indicator species analysis was applied to obtain response variables fromthe relevant vegetation matrix at each level. Response variables were modelled by using classification tree technique at eachlevel. Validation tests (i.e. multi-response permutation procedures for determination of differences of pl...
Autori: Kürşad Özkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26352

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractThe problem the paper deals with is the determination of ground heat distribution on different distances inside a cylindrical minework. Both interior radius and the exterior radii of the cylinder are known. The use of the range of temperatures is useful for thecalculation of the heat exchange rock - air. Results dissemination allow the development of a mathematical, model which may be applied to a seriesof natural conditions as well as to different geometrical shapes closer or not to the...
Autori: Dan Codruț Petrilean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26417

AbstractThe industrial development, the demographic growth and the limitation of the natural regions have determined a continuousdegradation of the water quality due to high concentrations and complexity of pollutants from the wastewater. The centralizedand decentralized treatment systems apply treatment procedures and techniques which can be complementary in solving theenvironmental pollution problems due to wastewater. In the present paper a three-dimensional mathematical model waselaborated b...
Autori: Narcis Barsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26422

AbstractAir quality in urban areas mostly depends on the type and size of industrial activities, traffic intensity, municipal and industrialwaste management. In addition to these factors, air quality in urban areas also depends on the size and quality of green areas,population density, geographic and climatic conditions. This paper reveals the correlations between air quality aspects in BacauCity, Romania (related to 2011) and the most representative climatic factors that influence the pollutant...
Autori: Doina Capsa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26424

AbstractMunicipal wastewater, characterized by temperatures of 14-22°C in the inflow of Wastewater Treatment Plants and above 35-40°C in domestic outflows, represents a relevant thermal energy source. A feasibility study of the implementation of heatrecovery from a specific sewer system should take into account several aspects: potential heat capacity (depending on wastewatertemperature and flow rate in the considered area and climate conditions, and on the sewer characteristics), users that cou...
Autori: Silvia Fiore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26427

AbstractThe purpose of this article is to elaborate a mathematical model for the prediction of average monthly environmental/outsidetemperature (T) levels in the region of Ruse, Bulgaria. Based on the method of harmonic analysis, amplitudes and phases of themain harmonic oscillations were defined. The results show the dominance of the first three harmonics for the period of theresearch. Visualization of experimental and theoretical values of the model shows a high degree of consistency between t...
Autori: Stoyan Yanev
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26446

AbstractIn order to diminish the climat changes due to greenhouse gases, the capture from the source, transport and storage of carbondioxide is one of the environmental priorities of the EU until 2050. Transportation of this gas through pipelines (one of thesolutions with most advantages in transport) can be done at ambient temperature only at high pressures, so the carbon dioxide toremain in the supercritical state. In case of underground pipelines, there is a risk of cracking at the wall of th...
Autori: Valentin Zichil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26447

AbstractThis work presents an original method and an automated installation to recover by combustion the waste gas obtained in theignition process of xylites in rotary kiln. The flue gas resulting from the combustion of waste gas, with light fuel support areused in the technological processes of obtaining activated carbon, satisfying the conditions where the oxygen content does notexceed 0.3 % vol. and the temperature is above 1200°C, conditions imposed by the Project Manager of the European pro...
Autori: Aurel Gaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26461

AbstractThe present contribution describes the investigation of a solar air collector for space heating in order to develop more efficientand cost effective energy process. Various configurations of absorber and different air flows through the collector were tested.The influence of the air mass flow on the air outlet temperature and thermal efficiency has been studied. The thermal efficiency,fluid outlet temperature, heat increase and heat losses of the collector are calculated depending on the ...
Autori: Lizica Simona Paraschiv
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26468

AbstractWastewater treatment processes with activated sludge are described in the specialized literature by complex models withnonlinear parameterization, such as for example Activated Sludge Model ASM1, ASM2 or ASM3. Under these conditions, thedesign of control structures using the state space representation is very difficult. Suitable techniques to approach the control ofthese processes are using control structures based on an input-output model or using control structures obtained without eve...
Autori: Daniela Carp
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26470

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractA soot transducer based on the measurement of the electrical resistance value of the soot layer deposited on a finger structure wastested at different thermophoretic potentials. The soot, similar to that issued from the Diesel engines, in terms of particle numberand size distribution, was obtained by the incomplete burning of propane and subsequent dilution. The decrease of the resistancevalue in time was directly proportional with the temperature gradient. Thus a soot transducer is aime...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26503

AbstractGreenhouse gases emissions represent a first-degree concern in power generation from fossil fuels combustion. Over the past twoand a half centuries, since the dawn of the industrial era, huge amounts of carbon dioxide have been released into the atmospherefrom combustion processes, most of it coming from fossil fuel-fired power plants. The effects of CO2 accumulation in theatmospheric environment become more and more apparent due to the increasingly strong greenhouse effect leading to gl...
Autori: Bogdan Horbaniuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26505

AbstractEvaluation of the quality of natural waters used as sources for drinking water supply is very important for selection of the propertechnological treatment system that would ensure the compliance of physical, chemical and microbiological parameters with thespecific standards. The current study aims at investigating the quality of two natural waters used as sources for drinking watersupply of Iasi City: Prut River (surface water) and Timisesti (groundwater). The experimental analysis of th...
Autori: Maria Cohl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26509

AbstractThe alkylation of light hydrocarbons leads to produce the high octane number gasoline blending components. The homogeneouscatalytic alkylation reaction is usually carried out at low temperature in the presence of H2SO4 and HF. The use of heterogeneouscatalysis for this reaction is a promising solution for the replacement of hazardous acids to environmentally friendly zeolitecatalyst. The alkylation reaction of isobutane with 1-butene was studied on selected zeolite catalysts. The objecti...
Autori: Tatjána Juzsakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26514

AbstractIn European countries with temperate climates, heating represents approximately 70% of the total energy consumption of aresidential building. Different Directives of the European Parliament and Council prescribe the enhancement of energy efficiencyand the reduction of energy demand of buildings. Consequently, the control of delivered heat is indispensable. The properoperation of the control system is possible only for balanced central heating systems. In the case of central heating syste...
Autori: Sándor Hámori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26537

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractThe aim of this work is to study the valorisation of two regenerated low density polyethylene (LDPE) coming from dirty wastesby blending with polypropylene (PP) in presence of compatibilizer. The first step was the determination of the physico-chemicalproperties of the two regenerated samples (density, melt flow index, water absorption, melting temperature and oxidation index)and the mechanical properties (tensile and shore D hardness).The second step was the characterization of the phys...
Autori: Nabila Guerfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26565

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract Carbon capture and storage is one of the critical technologies that can enable the reduction of carbon dioxide (CO2) emissions of large industrial sites worldwide. The injection of CO2 into saline water formations is related with many factors and processes that control the safety of its long-term storage. This paper analyzes the leakage risks and the factors that influence the integrity of the cap rock in deep saline aquifer formation. Several pathways have leakage potential risks d...
Autori: Xiaojuan Qiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26585

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract Air temperature is certainly the most measured surface meteorological parameter and accurate forecasting of air temperature is usually performed worldwide. This fact inspired the idea that a predicted value of air temperature may be used as input in solar radiation air temperature-based models, aiming to generate the reference solar radiation year or to forecast solar irradiation. Following this, a Takagi-Sugeno fuzzy model for estimating global solar irradiation via air temperature...
Autori: Remus Şt. Boata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26599

Abstract This article covers the investigation of the catalyst waste (T.R.M 1 and T.R.M 2) produced in the reactor of oil catalytic cracking. The analysis of this waste was carried out. The properties of T.R.M 1 and T.R.M 2 were investigated and determined, the mineralogical analysis of catalyst waste was implemented, the analysis of thermal effects during the burning was performed. Catalyst waste materials investigated were used in a ceramic system (from 7  to 20  of the ove...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26600

Abstract The present study deals with the removal of Cr (VI) from aqueous solution by polypyrrole (PPy). Response surface methodology (RSM) was applied for the design and analysis of experiments in the optimization of pH, temperature, initial concentration, contact time and adsorbent dose during the removal of the Cr (VI). The optimum adsorbent dose, temperature, initial concentration of Cr (VI), pH and contact time were found to be 0.8 g, 46.5 oC, 187.5 mg/L, 5.3 and 15.4 min respectively. ...
Autori: Ehsan Hasani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26614

Abstract This study is focused on the dissolution kinetics of zinc oxide in ammonium acetate solutions to recover the zinc from alkaline and zinc-carbon spent battery powders. This study represents a first step for further studies in which actual waste powder is to be used. Therefore, the experiments were performed by using pure zinc oxide powder to evaluate the dissolution behavior of zinc. The effects of ammonium acetate concentration, reaction temperature, stirring speed and solid to liqu...
Autori: Nizamettin Demirkıran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26618

Abstract A model of an irreversible combined thermionic-thermoelectric generator with internal and external irreversibilities is established in this paper. The performances of the combined generator, in which the heat transfers obey radiative heat transfer law, are analyzed and optimized by using the combination of finite time thermodynamics and non-equilibrium thermodynamics. The general expressions for power output and efficiency versus drop voltage are derived. The influence of finite rat...
Autori: Zemin Ding
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26624

Abstract The effects of nitrogen (N) and phosphorus (P) addition to peatland ecosystem on emissions of nitrous oxide (N2O) were measured using the closed chamber method during one growing season within a peatland on the Tibetan Plateau. The highest N2O fluxes occurred during late spring (May), while fluxes of N2O were lowest during early autumn (September). No significant correlations were found between N2O emissions and soil temperature. Because of the sites stable hydrological conditions n...
Autori: Yongheng Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26626

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract This paper presents the results obtained using the prehydrolysis treatments of rapeseed stalks depending on regime and the catalyst. The vegetal materials were subjected under different temperature conditions and then characterized for the yield reducing substances. The differences between samples have been established by using FTIR and depend on the successive hydrolytic treatments of dynamic and static regime in the presence of various catalysts. The experimental data show that th...
Autori: Corina Măluţan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26654

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract Biochar derived from agricultural biomass waste is increasingly recognized as multifunctional material for various applications according its characteristics. It is therefore essential to investigate biochar properties before large-scale application. In this study, rice straw-derived biochars produced at different temperature (550, 650, 750 oC). The resulting biochars were subjected to liquidphase oxidation by different agents including KOH, HNO3, H2SO4, H2O2 and KMnO4 to obtain bio...
Autori: Sobhy M. Yakout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26661

Abstract Adsorption equilibrium and effective diffusion coefficients of water vapor, in cylindrical particles of activated alumina (A) and activated alumina impregnated with calcium chloride (MCA), are experimentally determined. The experiments were conducted at 303 K and 323 K using cylindrical particles with 2.5 mm in both length and diameter. Diffusion coefficients were determined from the kinetics of water sorption. The measurements were conducted in a constant pressure unit based on a m...
Autori: Eugenia Teodora Iacob Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26665

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon material was found to adsorb vitamin B2 from aqueous solution at room temperature. The obtained ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26679

Abstract As natural landscapes are increasingly replaced by impervious surface materials associated with urbanization, urban areas tend to experience higher surface temperatures when compared to rural areas, which is known as the urban heat island (UHI) effect. In this study the impact of urbanization on land surface temperature (LST) and the UHI effect were examined based on two Landsat Thematic Mapper (TM) imageries of 1987 and 2007. Results show that Wuhan experienced rapid urban expansio...
Autori: Qijiao Xie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26684

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract The degradation and adsorption behavior of dibutyl phthalate (DBP) in methanogenic phase refuse was investigated through laboratory microcosm experiments. The results showed that the half-life of DBP in the sterilized refuse was 5.9 times higher than in unsterilized samples, but that it decreased by 35.8% when dominant bacterial strains were added. Different concentrations of DBP did not have obvious effects on its degradation. The half-lives of DBP were decreased by 53.0%, 37.2% an...
Autori: Chengran Fang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26690

Abstract In this research, a small-scale biogas plant using methane fermentation was developed. The electrical energy consumed by the heater/pump and the outside temperature of the small-scale biogas plant were logged from 1 July 2007 until 31 July 2009. The thermal efficiency of the small-scale biogas plant was calculated based on the electrical energy consumed by the heater/pump and the generated gas quantity. The results showed that a total thermal efficiency of 17.5% was obtained in the ...
Autori: Daisuke Tashima
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26694

Abstract The main purpose of this research was to study the biodegradation ability of atrazine by using Arthrobacter sp. as free and immobilized cells of the strain DNS10, under several important environmental factors such as temperature, pH, salinity, substrate concentration. Furthermore, this paper objective was also to assess the process considering the immobilization under extreme conditions, such as high salinity and high atrazine concentration. DNS10 was immobilized on a sodium alginat...
Autori: Zhang Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26702

Abstract The present study explores the potential of Streptococcus epidermis, an indigenous isolate for biotransformation of phenol and phenol derivatives. Different phenolic derivatives such as 4-methylphenol, methylbenzene, 2,4-dichlorophenol, 2,6- dichlorophenol and 4-nitrophenol were attempted for biotransformation study. The results have shown that 4-nitrophenol was best transformed. The effect of degradation parameters like pH and temperature was studied, showing the value of 7.0 as o...
Autori: Bhavana V. Mohite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26705

Abstract Adsorption has proved to be an excellent way to treat industrial wastewater, due to its significant advantages like easy availability, inexpensive, ease of operation and highly efficient, compared to conventional expensive adsorbents like activated charcoal, alumina etc. The present investigation focused on utilization of Mangifera indica seed shell substrate for the removal of toxic heavy metals like Fe(II) and Mn(II) from wastewater. Mangifera indica seed shell substrate as an eff...
Autori: Tikaram D. Kose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26713

Abstract Maximum removal (94±1.2%) of 2, 4 dichlorophenol (50 mg.dm-3) was achieved on silica with agitation of 4 hours, at pH 8 and 42°C. The positive enthalpy (ΔH) and negative free energy values (ΔG315K) suggested the endothermic and a spontaneous nature of sorption. The free energy of the process at all temperature was negative and increased with the increase in temperature. The values of free energy suggested a spontaneous process where the spontaneity decreased w...
Autori: Abdul Ghaffar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26718

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Response surface methodology and central composite experimental design were used to model and optimize the operational parameters of the excess sludge protein extraction yield by ultrasonic wave-assisted extraction. The three variables involved in this research were the ultrasonic extraction time, pH, and temperature. In the range studied, statistical analysis of the results showed that selected variables had a significant effect on protein extraction yield. The optimized extraction...
Autori: Yulin Xiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26736

Abstract In Hungary, 0.5 million m3 of thermal water is exploited every day for diverse purposes. After utilization, this enormous amount of thermal water becomes sewage water with a high concentration of salts, heavy metals, ammonia, nitrate, an unfavorable ion composition and high temperature. A common treatment is to dispose of waste water into a surface recipient through uninsulated channels surrounded by arable land. By infiltration, sewage water can cause potential salinization/sodific...
Autori: Andrea Farsang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26742

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract An experimental study of mixing in autoclave vessel equipped with an anchor impeller was performed on the sludge proceeding from the treatment of mixed municipal and industrial wastewater. This unit operation is part of a process for the recovery of sludge. The mathematical modelling of the mixing was done having in view the scaling-up of this process. The mathematical model allows the calculation of the mixing power N as a function of the impeller diameter d, the vessel diameter D,...
Autori: Ancaelena Eliza Sterpu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26744

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract New and end of life tires have been pyrolyzed in an innovative pilot plant that processes whole tires, thus saving the energy costs of shredding while allowing energy and materials recovery. Furthermore, the presence of a hydraulic guard guarantees high process safety. Several tests at different temperatures have been performed and the collected solid, liquid and gaseous products have been quantified and characterized. The influence of the maximum process temperature on yields and c...
Autori: Loris Giorgini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26783

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract Recently several innovative suggestions on how industrial wastes can be utilised in new products have been presented in literature, e.g. as filler or additives in concrete, incorporated in ceramic materials to produce glass-ceramics and pavement construction. In this work, metallurgical materials from secondary aluminium scrap processing and glass waste derived from treatments of packaging and fluorescent lamps were considered for fabrication of new ceramic materials using powder te...
Autori: Rosa Taurino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26794

Abstract The feasibility of humidification-dehumidification utilizing waste heat from exhaust gas was investigated. The exhaust gas below 100°C was used as the heat resource and to evaporate the salt water. The effect of operation conditions on the fresh water productivity and thermal efficiency was studied, including the salt water flow rate, exhaust gas flow rate and temperature. The performance of this process was discussed from the view of temperature field, and the temperature field...
Autori: Huaigang Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26812

Abstract Vacuum-tube thermal collectors are used to collect heat radiated by the sun. This heat is then used to drive the forced evaporation of concentrated seawater (saltwater) released by reverse osmosis and the extraction of NaCl. This paper reports heat consumption during evaporation. About 78.90% of seawater has to be evaporated in advance through insolation to initiate forced evaporation. This step is conducted to precipitate the NaCl because only CaSO4·2H2O are initially precip...
Autori: Huaigang Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26813

Abstract Based on the study on the reformation of Dawsonite-bearing sandstones with CO2 fluids at different temperature (100oC 200oC and 300oC) and different CO2/H2O/sandstone systems, it is suggested that as the temperature increases, the corrosion intensity of dawsonite-bearing sandstones is gradually increased, but the stability of the sandstone is reduced. The SEM study shows that there are radiated aggregate sediments of boehmite in all samples. At 200oC, with the dissolving of dawsonit...
Autori: Xi-Yu Qu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26814

Abstract Treatment experiments for mature landfill leachate were conducted by using combined aged refuse bioreactor (ARB) process and sulfate radical oxidation. In the ARB process, the effects of wet/dry ratios, hydraulic loading, and influent introduction time on contaminant removal were investigated. In the oxidation process, Na2S2O8 was activated by heat to generate powerful oxidants, such as sulfate radicals, to oxide residual contaminants in the effluent. The removal of chemical oxygen ...
Autori: Zhanmeng Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26818

Abstract Drying wood requires a significant amount of energy. This includes both thermal energy, necessary to heat-up wood, evaporate the water inside it and cover the insulation and vent losses, as well as electric energy consumed to force air circulation through the stacks. When wood is frozen, both energy consumptions increase; on one hand because frozen water requires a supplementary heat for transformation into liquid and then into gaseous state, and on the other hand, because of the lo...
Autori: Maria Bernadett Szmutku
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26841

Abstract The paper describes a numerical analysis concerning the behaviour of Cu and Ni based catalysts having different mole ratios of Ni to Cu in the process of glycerol hydrogenolysis. The impregnation technique was used to prepare the copper and nickel based catalysts. Our study revealed that their performances are different and depends on the Ni/Cu ratio. The catalysts were tested using various reaction conditions, such as time and temperature, and their performances analysed based on t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26843

Abstract This article presents the result of investigation on the spatial and temporal changes in water quality of Uluabat Lake. It examines the relationship between water and sediment quality parameters, and assesses the factors affecting eutrophication. Water and sediment quality are examined at 8 stations in the lake between May 2008, and May 2009. Water and sediment quality parameters measured are T, pH, EC, SD, NH4-N, NO3-N, TN, PO4-P, TP. Also DO, alkalinity, hardness, SS, BOD, COD, Ch...
Autori: Feza Karaer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26850

Abstract Free cells of Rhizopus oryzae were used to study adsorption of several cations (Cu2+, Zn2+, Mn2+, Ni2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The influence of biomass dosage, pH and temperature on the removal process was investigated. The sorption efficiency increased with increasing the temperature in the range from 25 ºC to 30 ºC and pH from 5 to 8. The maximum removal percentage was achieved at a biosorbent concentration 0.25 – 0.3...
Autori: Kolishka Tsekova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26857

Abstract On the basis of a generalized irreversible Carnot heat engine (GICHE) model with the losses of heat resistance, heat leakage and internal irreversibility, the local stability of the heat engine at the maximum ecological function (MEF) is studied with Newton’s heat transfer law between working fluid and heat reservoirs. It is derived that a general expression of relaxation time described as stability of the system refers to heat capacity C, overall heat transfer surface area F,...
Autori: Lingen Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26859

Abstract The atmospheric air is considered a large and renewable source of fresh water. The present work investigates the application of solar energy to heat wick clothes impregnated with calcium chloride to extract water from atmospheric air. A wick desiccant solar collector is erected at Tanta – Egypt for this purpose. The desiccant concentration at the beginning of regeneration is determined according to the climatic conditions. The saturated wick desiccant is exposed to an ambient ...
Autori: Abd elnaby Kabeel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26861

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The present study analyzes the background pollution in Romania using official data reported for recorded air pollutants from the automated regional stations located at three mountain sites. A series of key figures regarding the trend of background pollution at Romanian mountain sites was extracted based on annual average concentrations recorded between 2010 and 2013 i.e. 8.8 ± 5.2 μg NO2/m3, 5.3 ± 1.6 μg SO2/m3, 0.075 ± 0.035 μg CO/m3, 3.2 ± 0.9 ...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26897

Abstract The objective of this study is to manufacture a geopolymer by replacing part of the metakaolinite by calcined oil-contaminated clay (OCC) and investigate its properties. The effects of the calcination temperature, the mix design of the alkali activator, and the degree of calcined OCC replacement on the properties of the geopolymer were studied. Evaluation of pozzolanic activity and compressive strength as well as micro structure observation by SEM and XRD were performed in this stud...
Autori: Huan-Lin Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26905

The influence of the Black Sea on the continental climate is generally limited, comparatively with other maritime basins. Nevertheless, the influence is important for local scale environment, with several applications in the economy, i.e. building industry, agriculture, forestry. The extension of the Black Sea influence inside the Dobroudja Plateau has been tackled constantly by the Romanian climatologists, the main methodological problem being the low number of meteorological stations in Do...
Autori: Sorin Constantin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26963

During three years, 2011-2013, time series of 222Rn (radon) and 220Rn (thoron) progeny concentration measured at Bacau, Romania have been analyzed with different deterministic instruments in order to extract valuable information about their deterministic behavior. The time series of data were obtained within the framework of the monitoring program performed by the Environmental Radioactivity Monitoring Station, Bacau. Correlations with the deterministic nature of atmospheric temperature and ...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26982

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

Biomass is a very important source for the production of biofuels. During the hydrolysis step of the process for obtaining biofuels the rate of decomposition of biomass is strictly related to its organic matter content and the operating mode of the facilities. This paper highlights the effect of different pretreatments on the composition of biomass at the molecular level using Fourier Transform Infrared Spectroscopy (FTIR) and Principal Component Analysis (PCA). For this experiment, a mixture...
Autori: Andreea Cocarcea Rusei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26986

Air pollution has a significant impact on human health and natural ecosystems. The principal gaseous pollutants compounds result from different types of combustion processes. In this category there are included carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), dust and hydrocarbons. Nitrogen oxides are a group of highly reactive gases, which contain nitrogen and oxygen in varying amounts. Most of the nitrogen oxides are colorless and odorless gas. This paper highlights the c...
Autori: Doina Capşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26988

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

In this study, it was aimed to determine the relationship between the temperature decrease of the air passing through the pad and flow rate of pad wetting water for pad evaporative cooling. In the experiments, a commercially available cellulose based evaporative cooling pad (CELdek®7060-15 pad) was used. Experiments were conducted at three different water flow rates (2 L min-1 m-2; 4 L min-1 m-2 and 6 L min-1 m-2) and two different air velocities (1.0 m sec-1 and 1.5 m sec-1). The tempera...
Autori: Cengiz Karaca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27006

Adsorption studies of cadmium(II) were conducted on 623oK or 723oK carbonized banana peels named as BP623 and respectively BP723 as well as on the dried ones (BP). Carbonization enhances the quality of organic by-product used as adsorbent, reduces the equilibrium time and improves the quality of the final product (water). Evaluation of the effects of pH, contact time and solution temperature showed that the uptake of cadmium(II) ions was highly dependent on these factors, and increased with ...
Autori: Josiane Ponou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27009

Rice is one of the main staple foods in China and plays an extremely important role in ensuring the country’s food security. Therefore, the impacts of climate change on rice yields have garnered considerable attention. In this study, meteorological and rice yield records during 1951-2011 from the Reclamation area (RA) and general agricultural area (GAA) in the Heilongjiang province of Northeast China were used to assess the impacts of climate change on rice yield trends using multiple r...
Autori: Yang Zhou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27019

The multi-parametric quality index (ICPM) is a dimensionless number used to evaluate the overall water quality and it is a useful tool for policy makers and for the public. This study aims to introduce the ICPM algorithm. The ICPM was developed to assess the water quality of the Lower Danube River using information obtained from the analysis of 41 water quality indicators from a monitoring program during 2011-2014. ICPM used the data for the previous 28 months as reference to evaluate the lat...
Autori: Violeta-Monica Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27035

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

The concentrations of isopropyl alcohol were monitored during the working time (8 hours) in three different printing plants (two sheet-fed offset and one digital) in Novi Sad, Serbia, using portable gas chromatograph. The concentration levels were below the recommended limits by the U.S. National Institute for Occupational Safety and Health. Unequal presence of isopropyl alcohol in printing plants involved a multiple linear regression analysis of microclimate parameters using program ORIGIN 5...
Autori: Jelena Kiurski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27096

Greenhouse gas (GHG) emissions from vegetable land are of great concern because agricultural land is one of major sources contributing to global GHG emissions. In this study, the emission of GHG (methane, CH4; nitrous oxide, N2O; and ammonia, NH3), as well as the factors affecting GHG and NH3 emission were investigated in land planted with Lactuca sativa L. and treated with different animal manure composts in a greenhouse located in Beijing. Methane emission flux was significantly affected by so...
Autori: Zhen Ge
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27153

Ozonation of oxytetracycline in aqueous solution with an activated carbon (AC)-supported cerium oxide (CeO2/AC) catalyst was conducted. The activity and stability of CeO2/AC, and the effects of ozone dosage, catalyst dosage, reaction temperature, initial oxytetracycline concentration, and initial pH on the catalytic activity of CeO2/AC for the removal efficiency of total organic carbon (TOC) were investigated. It was found that CeO2/AC catalyst was efficient in TOC removal during ozonation of...
Autori: Zheng-Qian Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27156

The effectiveness of thermal insulation materials mostly depends on their thermal conductivity. The low thermal conductivity is predetermined by density, structure, moisture content and temperature of material and, considerably less, by other indices. Loosefill cellulose insulation is allocated to the group of materials, the density of which fluctuates within large limits. This property is related not only to application of cellulose wool in different constructions, but also to technological ...
Autori: Sigitas Vėjelis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27165

A new material containing 2-(2′ thiazolylazo) p-cresol (TAC) grafted poly acrylamide (PAA) was prepared and its adsorption ability was studied for the removal of inorganic mercury from aqueous media. Adsorption of Mercury (II) ions from aqueous solution was investigated in detail as a function of mercury concentration, pH, ionic strength, and temperature. The adsorption data were analyzed by using the Langmuir, Freundlich and Dubinin-Radushkevich (DR) models. The adsorption of Mercury (...
Autori: Selçuk Şimşek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27170

In this study, chitosan-iron(III) was used as adsorbent of the dye acid red 29. The effect of pH, temperature and concentration of the dye on the adsorption capacity were evaluated. The maximum adsorption capacity was calculated from the adsorption isotherms which were well fitted by Sips isotherm model. The process followed the kinetic model of pseudo-second-order. The activation parameters showed that the adsorption process is spontaneous and favorable. A decrease in adsorption capacity was ob...
Autori: Carla Albertina Demarchi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27181

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

Hesperaloe funifera was studied as a new raw material for paper manufacturing and lignin recovery. An experimental design was carried out to improve the quality of the obtained pulp varying the process temperature (155, 170 and 185 ºC), time reaction (20, 40 and 60 minutes) and soda concentration (5, 10 and 15 %). All experiments were carried out with 1% anthraquinone. Lignin content, holocellulose content, α-cellulose, viscosity, Kappa number and drainability were determined in the d...
Autori: MŞ Ángeles de Andrés
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27185

In this paper, we propose to present real solutions for close self-monitoring of older adults, given the permanent assistance and rapid intervention needed in emergency medical situations. The recent medical devices integrate existing or in development technologies that are easy to use, affordable, accessible and sustainable solutions that address a range of needs because the ultimate goal is the ensuring of a “living actively and independently at home” environment for older adults. ...
Autori: Iuliana Chiuchisan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27200

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

Maize (Zea mays L.) is considered one of the most popular grain crops in China. Among various agricultural technologies, soil mulching is the one that is used more and more in recent years. Mulches influence the soil temperature, retard the loss of soil water, and limit the growth of weeds; and these are important factors in the production of maize. A two-year field experiment was carried out at Shanghai, in southeast of China, in order to evaluate the effects of water hyacinth residues as mulch...
Autori: Dayong Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27229

In this study, an upflow anaerobic sludge blanket (UASB) bioreactor at the mesophilic temperature (38ºC) was successfully used for the treatment of petroleum refinery effluents. Response surface methodology (RSM) was applied for the design and analysis of experiments to predict the behavior of the initial COD and the hydraulic retention time (HRT) in the bioreactor. A statistical analysis indicated that the models adequately represented the experimental data. At the optimal conditions, the ...
Autori: Seyed Omid Rastegar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27233

The present study was aimed at examining the ability of the natural zeolitic tuff from the Zlatokop deposit in Serbia to remove Pb(II) ions from aqueous solutions under various conditions. It has been found that the adsorption proceeds via an ion-exchange reaction in which the Na+ ions from the clinoptilolite phase of the tuff are replaced to a high degree by aqueous Pb(II) ions. The removal capacity of the clinoptilolite at 298 K varies from 78 mg Pb g–1 (for C0 = 100 mg Pb dm–3) to...
Autori: Djordje Stojakovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27234

Reuse of grey water is an attractive option when available water supplies are limited, and can reduce demand on water supplies and provide additional water resource. This comparative research was conducted to assess the suitability and effects of reusing grey water, treated and untreated, as irrigation water for vegetables, compared with tap water. Tomato (Lycopersicon esculentum) and green bean (Phaseolus vulgaris) plants were selected as examples. The collected grey water samples were treated ...
Autori: Jehad Y. Al-Zou by
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27254

The present work reports the gaseous emissions of the following industries, Interloop Textile (IP Tex), Crescent Textile (CT Tex), Kalash Textile (KH Tex), Noor Fatima Textile (NF Tex), Bashir Textile (BP Tex) and Hina Sana Texile (HS Tex), which are located in Faisalabad, Pakistan. Industries were tested for the mixture of gases containing carbon monoxide (CO), nitrogen oxides (NOx), sulphur oxides (SOx), carbon dioxide (CO2) and hydrogen (H2) emitting from these industries. The maximum amounts...
Autori: Muhammad Zubair
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27256

Carbonaceous materials were obtained from waste tyres and their potential application as hydrogen sulphide adsorbents was investigated. The adsorbents were obtained by pyrolysis of waste tyres and physical (CO2) or chemical (KOH) activation at 550 and 800ºC. The effect of modification conditions on the performance of waste tyres based materials as adsorbents of H2S at room temperature in dry and wet conditions was investigated. Sorption capacity of such adsorbents was found to strongly depe...
Autori: Magdalena Hofman-Bieniek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27263

Water quality index is an essential tool for water quality assessment. Considering the frequent use of automated water quality monitoring systems, their importance in generating data and information for the efficient management of water treatment plants, the design of such an index would allow the detection of point-pollution episodes, which otherwise would occur undetected and would have a significant impact on the water quality and its further treatment. In this study, a versatile weighted wat...
Autori: Ioana Gabriela Dascalescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27271

Ammonium is an environmental contaminant encountered in water and soils, its admissible concentrations in soils and waters being established by legislation. Removal of ammonium ions from aqueous solutions from different matrix can be done with several sorbents, among which nano-adsorbents, such as oxidized exfoliated graphite nanoplatelets (ox-xGnP) offer practical solutions, based on their high specific surface area, associated sorption sites and efficiency of application. Several parameters su...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27273

This research offers a novel approach for potato wastewater (PW) bioconversion to alcohol by microwaves gelatinization, liquefaction and simultaneous saccharification and fermentation (SSF). Concentrated PW from potato processing to obtain fries was treated by gelatinization, enzymatic hydrolysis through liquefaction and saccharification, and fermentation; a mini-bioreactor was used, with low oxygen, temperature, pH and mixing control. The yeast Saccharomyces cerevisiae and a commercial mix of l...
Autori: Maria Iasmina Moza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27275

The Romanian peat was used as low-cost adsorbent to remove Cd(II) ions from aqueous solutions. The cadmium adsorption capacity of the peat was studied as a function of the solution pH (3-5.5) and temperature (293 – 333 K). Adsorption capacity was found to increase with the pH increasing and temperature decreasing and attained a maximum value of 27.9 mg/g at pH = 5±0.1 (acetate buffer) and 293 K. In addition, various thermodynamic parameters such as free energy change (ΔG0), en...
Autori: Catalin Balan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27276

The paper discusses the pollution status in the case of an important NE Romanian watercourse (Siret River) in Pascani town area based on the analysis of some water quality indicators (pH, temperature, dissolved oxygen, organics (COD and BOD5), conductivity, fixed residues, nitrogen-based nutrients (N-NH4+, N-NO3-, N-NO2-), phosphates, total phosphorus (P), total calcium (Ca2+), magnesium (Mg2+), iron (Fe2+, Fe3+), turbidity and suspended solids content) measured at three local strategic control ...
Autori: Carmen Zaharia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27281

There are industrial processes where cold and heat are used. In such a process, a heat pump integrated into a refrigeration system lead to energy savings. This paper analyzes two-stage compression refrigeration combined with a compression heat pump. A case study is made based on a proposed mathematical model and on the measurements performed in an ice cream company. Three operation regimes are simulated for different hot water temperatures obtained from the heat pump. The energetic efficiency, e...
Autori: Aneta Hazi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27297

Acetone-Butanol-Ethanol (ABE) industrial production by fermentation is strongly affected by the low concentration of solvent (<25 g/L) that affects the cost of the recovery process. To decrease the overall cost of the butanol production, alternative routes for the recovery have proposed in literature. This paper presents a techno-economic analysis of an innovative butanol recovery process from ABE fermentation broth based on gas stripping technique. The comparison with a recovery process bas...
Autori: Lucia Salemme
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27346

Deforestation is a vital problem at global level, being one of the main causes of climate change. Volume of wood used in construction, furniture and pulp and paper industries increases year by year. Stopping the decrease of forests surface is of imperative importance from the point of view of sustainability. Pulp and paper industry faces with severe lack of pulpwood and for this reason other raw materials are taken into consideration. Chemical pulp can be partially replaced with recovered paper ...
Autori: Adrian Cătălin Puiţel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27348

Working in confined (limited) spaces represents a risk factor generating unwanted accidents or events, having an impact on human health. The success of intervention and rescue operations in toxic or chemical aggressive environments lies in optimal and efficient design of the training process for rescue personnel, which also includes rescue operations in confined spaces. The paper presents the scientific research behind designing and building a complex training facility with different training t...
Autori: George Artur Găman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27353

Explosion-proof equipment must be designed so that the ignition of the surrounding explosive atmosphere to be avoided. This is very important because an explosion can have particular implications over goods, life and not least over the environment. One of the ignition sources of an explosive atmosphere is represented by hot surfaces. Each equipment designed to operate in explosive atmospheres develops a maximum surface temperature. The specific standards used to assess explosion protection chara...
Autori: Lucian Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27358

A major issue in the undergrounding mining is providing the thermal comfort parameters at the work sites and among those the temperature it’s the most important. Also, in calculus of underground mine ventilation, the air temperature must be taken into account. The rate of dimensionless heat flux has a major influence in the mining environment by heating or cooling the air which flows through a mine work. The present paper studies the complex problem of heat transfer between air and the s...
Autori: Dan Codrut Petrilean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27361

Intervention and rescue activity in special conditions may be conducted only by trained and authorized personnel using individual protective breathing equipment. While working with the insulating respiratory device, there are a number of factors that make work stressful. As a rule, those working under protection of the insulating respiratory devices, besides carrying on their back a device weighing 14-18 kg, are also subject to great difficulty, in terms of securing their own safety, saving liv...
Autori: Daniel Pupăzan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27364

The occurrence of spontaneous combustion phenomena in coal mines is generated by the reaction of mineral substance with atmospheric oxygen and favoured by the oxidation (self-ignition tendency) of coal, an oxidant environment and by the conditions in which heat exchange with the environment takes place. Preventing / Fighting against this phenomenon is regulated in the specific OHS requirements and in the General mining plan, comprising the technical and organisational measures for prevention an...
Autori: Cristian Tomescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27369

The monomer with ketimine side group, 2-(1-(benzylimino)ethyl)phenol (2-BEP), was synthesized from the condensation of 2- hydroxyacetophenone and benzyl amine. The enzymatic oxidative polymerization of 2-BEP was performed in the presence of hydrogen peroxide using horseradish peroxidase (HRP) as catalyst. The oxidation reaction was carried out in various solvents and phosphate buffers at room temperature. These studies have shown that a dark brown polymer was successfully synthesized by utilizin...
Autori: Senem Tapan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27377

This study was to optimize the fermentation process for protein enrichment of potato starch residue (PSR) by solid state fermentation with mixed strains. Three single-factor experiments were conducted to optimize the fermentation conditions, and a Plackett-Burman design followed by a central composite design of response surface methodology was investigated to optimize the medium constituents. The optimal fermentation conditions were fermentation temperature 28°C, fermentation period 72 h and...
Autori: Heng Lei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27380

Effective adsorbents were developed from sewage sludge by chemical activation with different activators (5M ZnCl2, 3M H2SO4, 3M H3PO4, 5M ZnCl2: 3M H2SO4, and 5M ZnCl2: 3M H3PO4). The developed adsorbents were used for the removal of the heavy metals Cd (II), Pb (II), Cu (II) and Mn (II) from wastewater. The effect of several parameters (pH, initial metal ion concentration, adsorbent dose, contact time and solution temperature) on the metal adsorption capacity were evaluated by batch experiments...
Autori: Mohamed Nageeb Rashed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27385

This work presents an experimental analysis of the influence of a monocrystalline photovoltaic (PV) panels’ temperature on its main operating parameters. Victron Energy, SPM 30-12 PV panel is tested, using a double climatic chamber. The PV panel is placed as a barrier between the two rooms of the climatic chamber. The study is focused on the establishing the effect of raising temperature of PV panel over electrical parameters: voltage, current and power produced and also over the effici...
Autori: Sebastian Valeriu Hudisteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27397

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

The data presented in this work has been obtained from experimental research aiming towards the usage of natural resources of the National Park of Sila in Calabria, Southern Italy. Such resources are: “Laricio” pine resin, beeswax, mineral inert and charcoal to make natural glues. Furthermore, research has been done to find out if by using small quantities of carbon nanotubes, the strength of adhesion of prepared glues improves. Raw materials were characterized by physico–ch...
Autori: Pierantonio De Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27402

This research was focused on the valorization of agro industrial waste/by products available in the local industry with the kilometer zero (km 0) concept, as a replacement of virgin raw materials (clay) to elaborate lightweight aggregates (LWAS). The alternative raw materials were employed as pore forming agent, in order to reduce sintering temperature and energy consumption of the furnace. The three technical nutrients studied were provided for local food industries: sludge from wastewater trea...
Autori: Romina D. Farias
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27405

Common issues of the gasification systems relate to filtering apparatus. Dry filtering processes are simple and reliable. However, the filtering material defines the maximum and minimum temperature at which the filter can operate properly. In addition, dry filtration is not effective on light tar compounds (i.e. benzene and toluene) or ammonia compounds. On the other hand, despite being very efficient, wet filters drop the gas temperature below the line of condensation of tar, ammonia and ste...
Autori: Giulio Allesina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27412

Organic solid waste and the current lack of sound treatment for its valorisation are of high priority for decision makers in developing countries. Despite the remarkable use of composting processes in those areas, an appropriate scientific literature as well as databases are still lacking, hampering the sustainable implementation of composting process. This paper contributes to cover this gap, presenting a full-scale case study in Maxixe, Mozambique. Technical characteristics and detailed ope...
Autori: Andrea Perteghella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27419

In the present study, anaerobic treatment of food wastes from restaurants of a fermentation industry and methane gas production yields produced during the treatment were investigated. For this purpose, food wastes with a Total Solid Contents (TS) ratio of 5- 7-10% were digested in a 100l experimental reactor. Batch anaerobic digestion studies were conducted at mesophilic temperatures (36.5 oC) for 30 days and optimum Volatile Fatty Acids (VFA) and alkalinity values for methane gas production ...
Autori: Sevgi Fersiz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27429

The efficient use of fresh water sources and proper modeling of the water quality can only be possible when flows in the dam reservoir are well defined. Therefore, in this study, a hydrodynamics model of an actual dam reservoir in three dimensions for simulating a real dam reservoir flows for summer season is created. The model is developed using nonlinear and unsteady continuity, momentum, energy and k-ε turbulence model equations. In order to include the Coriolis force effect on the...
Autori: Fatih Üneş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27430

Eutrophication is water pollution initiated by high amounts of plant nutrients. With the excess influx of nutrients from human activities, the eutrophication process begins and causes a breeding ground for algae. The amount of nutrients present in any given cycle will be higher than the levels present in previous cycles. Therefore, it is very important to manage water quality in lakes and dams to prevent and to slow or to reverse the eutrophication process. This can be ensured by using effect...
Autori: Saeed Bashiri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27442

One of the environmental problems caused by the large-scale livestock industry in China is odor pollution. Using the microbial strains with high deodorization efficiency is a feasible strategy to handle this problem. In this study, a Lactobacillus strain A2 with high efficient deodorization was isolated. To find the optimal deodorization conditions of strain A2, the deodorization efficiencies at different temperatures and inoculation quantities were tested. Our result showed that suitable tem...
Autori: Zhiying Yan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27447

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

The negative effects of acid mine drainage (AMD) on the natural and human environments are well understood in South Africa, yet a robust and economic AMD treatment technology has not been developed. The current study aimed at exploring the performance of synthetic zeolite F9 in AMD treatment with specific focus on iron and manganese removal. For this, batch adsorption mode was adopted for which the effects of adsorbent dosage, initial pH and temperature were investigated. As a result, it was fou...
Autori: Mike Masukume
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27454

The partial nitrification bioreactor (PNBR) was operated at a constant temperature and an influent synthetic wastewater pH of 35°C and 8.5, respectively. The effects of dissolved oxygen concentrations (DO), hydraulic retention times (HRT), and the nitrogen loading rates (NLR) on the ammonium removal efficiencies and the NO2-N/NOx-N ratio were investigated. The activity of nitrite oxidizing bacteria was stimulated at high DO concentrations. The highest NO2-N/NOx-N ratio of 0.76 was obtained a...
Autori: Sukru Aslan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27455

The purpose of this paper is to present the results regarding the obtaining of reducing sugars at the enzymatic hydrolysis of the lignocellulosic material, wheat straws. For these, the lignocellulosic material was submitted to a preliminary pretreatment for destruction of the cellulose crystalline structure and to increase the material's susceptibility to the enzymatic attack. The preliminary pretreated material with diluted acid (0.5%-4%) or with water at different temperatures (120-170&ord...
Autori: Eufrozina Albu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27463

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

In recent years, increasing temperatures and extreme weather conditions have had a significant impact on quality of life, especially in terms of the environment. Governments have made environmental preservation a priority and have received public support in turn. We formulate models to investigate a company’s optimal production quantities over two periods, including green technology efforts, to examine the impact of a carbon trading policy. We build separate inter-temporal production mode...
Autori: Changsong Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27469

The delignification of wood pulp using hydrogen peroxide and xylanase enzyme in an ultrasonicator was studied at different process conditions. The factors influencing the chemical delignification were studied simultaneously using the Box-Behnken design of experiments. The mathematical model for Kappa reduction as functions of consistency of the pulp, concentration of peroxide and the temperature of delignification was developed. The response optimization studies for minimizing the Kappa numb...
Autori: Palaniappan Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27480

Three modified bentonites, hydroxy-aluminum pillared bentonite (Al(OH)-Bent), cetyl trimethylammonium bromide modified bentonite (CTAB-Bent), and both cetyl trimethylammonium bromide and hydroxy-aluminum modified bentonite (Al(OH)-CTAB-Bent) were prepared and characterized by Fourier transform infrared spectroscopy (FTIR) analysis. Batch experiments were conducted on the adsorption of phenol at different temperatures, pH and initial concentration. The results indicated that adsorption capacity o...
Autori: Xiping Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27481

In the current work, a numerical model for the prediction of temperature, air velocity, relative humidity and ammonia distribution released by sheep and goats manure inside a naturally ventilated livestock building is presented. Given that noteworthy amount of gaseous pollutants are emitted by the agricultural and animal husbandry activities, the study of the indoor microclimate is essential to be investigated for the healthy growth of the breeding livestock. The developed numerical model is sat...
Autori: Catherine Baxevanou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27482

An experimental study of the wires-two plates is presented in this paper. The principal running of these types of electrostatic precipitators is based on the corona discharge on which depend their performances. The factors affecting corona formation on wire - to- plate gaps are investigated experimentally. There are many factors affecting such corona formation. The investigated factors were the interspace between the two wires, gap length between the wire and the plate, ambient temperature, r...
Autori: Nouri Hamou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27485

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

A large number of microorganisms are capable of producing cellulases; however, fungi are considered among the most active enzymes producers. Different strains of white rot fungi (WRF) were reported to have a great potential for biotechnological applications and cellulase enzymes is much involved in this effect, especially for bioethanol production. Misiones is included in a forest region characterized by a vast biodiversity, and within this environment, a large number of microorganisms can be...
Autori: Ernesto M. Giorgio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27489

Nowadays, the polyolefins (polyethylene, polypropylene) are increasingly consumed in large amounts for many applications. This issue causes a concern regarding the environmental impact of the waste materials generated after the first use. Mechanical recycling of polyolefin wastes helps to conserve oil and gas resources and reduce the polymeric waste accumulation in environment. In this paper, the modification of some post-consumer polypropylene (rPP) properties coming from packaging processi...
Autori: Maria Râpă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27493

The phenol degradation capacity of Serratia marcescens NSO9-1 isolated from olive mill wastewater was evaluated and optimized in this study. Plackett-Burman design coupled with Box-Behnken methodology was used to evaluate the effects of medium components and significant parameters on phenol degradation by this relevant strain. According to Plackett-Burman-based statistical screening, seven of the eleven components of the medium had a significant effect on the metabolism of phenol degradation. Th...
Autori: Nurdan Saraç
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27495

This study aims to obtain high performance cement under friendly environmental conditions, through the optimization of clinkerization process. The influence exerted by mineralizers i.e. fluoride (NaF, KF) or oxide (CuO, TiO2) on the Portland clinker characteristics and derived cement properties is presented in this experimental study. The presence of these additions in low concentration (i.e. 0.5-0.8 wt. %) permits the reduction of the burning temperature (with 20oC up to 70oC) of raw mix and mo...
Autori: Jenica Paceagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27500

This paper highlights the utility of rice husk ash for the adsorption of Cr(VI) ions from aqueous solutions. Rice husk ash (RHA) is produced when rice husk is burnt for various purposes. Application of Treated Rice Husk Ash (TRHA) as an adsorbent for the removal of Cr(VI) from aqueous solutions has been investigated. For this purpose, RHA was thermally treated. RHA and treated RHA (TRHA) were characterized by XRD, SEM and FTIR to investigate the effect of treatment on the nature and surface char...
Autori: Varsha Srivastava
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27504

This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multi-active blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than ...
Autori: Jacob Kitinya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27505

Influence of process variables like pH, adsorbent dosage (D), initial dye concentration (C0), particle size (S) and temperature (T) on adsorption of a direct dye on carbon derived from mango leaf were studied using a 25 factorial design. The main effects and interaction effects were determined using statistical methods. Maximum uptake obtained was 55.7 mg/g (pH = 2, T = 40 °C, D = 0.5 g/dm³, C0= 100 mg/dm³ and S = 53 μm). It was found that the effects of process variables namely...
Autori: Varadarajan Gunasekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27506

The potential use of a novel low-cost adsorbent, Eupatorium adenophorum Spreng, as a solution to remove Cr(VI) ions from aqueous was reported. Effects of various regulating parameters, such as pH value of reaction, adsorbent dosage and temperature, were investigated. To fit the adsorption equilibrium data, Langmuir isotherm and Freundlich isotherm were invoked. Additionally, thermodynamic parameters of the adsorption process, such as ΔG, ΔS and ΔH, were also calculated. The res...
Autori: Chen Jin-fa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27535

In this study major factors affecting the phenolation process of lignosulfonate (LS) waste liquor (recovered from pulp and paper industry) were optimized in order to improve LS substitution for replacing petroleum-based phenols during phenolic resin manufacturing. Four different parameters, namely phenol/lignosulfonate ratio, time, temperature and lignosulfonate waste liquor concentration, were varied in an experimental program having as response function the reaction yield. Response Surface Met...
Autori: Andrei Ionuţ Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27551

Two multiple linear regression (MLR) models were developed with the aim to estimate the decomposition temperature of a series of polyimides. Two parameters, Tni and Tai, corresponding to the temperature of 10 % weight loss of the sample, determined by dynamic thermogravimetric analysis under conditions of N2 inert atmosphere and air, respectively, were used as a criterion for thermal stability. The obtained MLR models correlate thermostability with a series of characteristics of the studied poly...
Autori: Catalin Lisa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27556

The solid-liquid extraction process and some of its influencing factors such as solid-liquid ratio, temperature and salt initial amount have been investigated. Also, mathematical modeling for mass transfer coefficients calculation was applied. An inert porous solid material (coal), impregnated with 10% and 20% mass NaCl or 15% and 30% mass CaCl2, was used. The leaching was conducted in a fixed bed column, in laminar flow. The CaCl2 impregnated samples were investigated in a column with a height...
Autori: Marcel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27557

Dielectric measurements were carried out on a series of bent-core liquid crystals based on resorcinol and 2, 7-dihydroxinaphtalene cores and presenting B mesophase in between 30-160°C. The dielectric constants in the liquid crystalline phase were measured as a function of frequency and temperature. The dielectric relaxation of bent-core compounds has been analyzed by dielectric constants/frequency curves. The variation of the dielectric strength with temperature has been determined as well. ...
Autori: Irina Carlescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27568

Estrogens excreted by humans and animals are groups of endocrine disruptors, which degrade rapidly in soil and water as reported. This review focuses on biodegradation of estrone (E1), 17β-estradiol (E2) and 17α-ethynylestradiol (EE2) in surface water, STPs (sewage treatment plants), manure, soil and sediments, and illustrates possible pathways and mechanisms. In general, half-lives of EE2 are much longer than E1 and E2, because an ethinyl group at one hydroxyl group containing C-atom...
Autori: Hai-Liang Song
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27571

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

Phenolic compounds are known as recalcitrant pollutants in many industrial wastewaters, e.g. olive mill wastewater. An efficient treatment is therefore needed before the discharge of phenol-containing wastewaters into the environment. The possibility of removing some natural occurring phenolics, namely tyrosol, p-coumaric acid and vanillic acid, by micellar-enhanced ultrafiltration (MEUF) using a cationic surfactant, cetylpyridinium chloride (CPC), and polyethersulfone membranes of 20 and 50 kDa...
Autori: Abdelilah El-Abbassi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27607

β-glucosidases are very important in the improvement of cellulose degradation rates by diminishing the inhibition of end products. Although, cellulase cost has reduced significantly in last decade but still the high costs of biomass saccharification is one of the main challenges for the commercialization of ethanol from LC biomass. In this work, β-glucosidase immobilization in calcium alginate was optimized using response surface methodology. 89% immobilization efficiency was achieved ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27614

The aim of this study is the treatment of Chlorothiazide in an aqueous medium by Electro-Fenton process using a Platinum anode. This pharmaceutical product is used to treat hypertension. Removal rates and mineralization efficiency have been analyzed under different operational conditions. Degradation kinetics well fitted to a pseudo–first–order reaction. Apparent rate constant of the oxidation of Chlorothiazide by electrochemically generated hydroxyl radicals was determined to be 9.4...
Autori: Saied Taieb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27616

Copper pollution is common across the world and has caused serious public health problems recently. Among the conventional methods, adsorption has proved effective, economic, versatile and simple for the removal of aqueous Cu(II) contaminants. Deposits of natural Kaolin are abundant around the world, and are regarded as valueless due to its limited usage in industry. In this study, the adsorption behavior of natural Kaolin towards Cu(II) was evaluated. According to the results, the isothermal ad...
Autori: Qiang Tang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27651

Dam construction in Cuba and their use for freshwater aquaculture development are explained. Some of the environmental impacts of Cuban freshwater reservoirs, particularly in fisheries, the salinization of coastal lands, and effects on marine fisheries, are reviewed and analyzed. Some argumentation and explanations given are in response to remarks on the impact of Cuban dams on species composition of reservoir fishery landings and on coastal marine fisheries. The main impacts of dams are on estu...
Autori: Luis Alvarez-Lajonchčre
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27653

Magnesium wastes are among the gradually ascending and therefore challenging metal wastes, which are produced by many industrial activities. The purpose of this study is the usage of magnesium waste, a raw material in magnesium borate production by hydrothermal synthesis. Boron sources (boric acid (H3BO3) and boron oxide (B2O3)) react with magnesium wastes in order to synthesize the magnesium borate mineral of admontite (MgO(B2O3)3ꞏ7(H2O)). In addition to the synthesis from waste magne...
Autori: Azmi Seyhun Kipcak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27657

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

This study presents a Rough Set Analysis (RSA) application, partially based on dominance in relation to air micro-pollution management in an industrial place with a high environmental risk rate, such as the industrial area of Siracusa, located in the South of Italy. This new data analysis instrument has been applied to different decisional problems in various fields with considerable success. Therefore, it is believed that it could also be used for the environmental issue related to multi-att...
Autori: Agata Matarazzo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27663

This paper proposes a study on the estimation of daily solar irradiation (global and diffuse irradiation) under real-sky conditions and the validation of proposed estimation models by analyzing the most important statistical indicators. Two types of regressions are proposed for the estimation of solar daily global irradiation; the first type is based on the second order degree Ångström-Prescott correlations; the second type uses the second order Ångström-Prescott correla...
Autori: Elena Eftimie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27670

This paper presents an assessment of the toxic compounds released from metalworking fluids (MWFs) used in aluminum solid waste processing and from aluminum slag landfills, and their impact on environmental quality and human health. The mean concentrations of dust, oil mist, aldehydes, volatile organic compounds (VOCs) released from metalworking fluids were determined in machine shops. The exposure in machine shops was quantitatively dominated by VOCs, whose concentrations varied in the range...
Autori: http://www.ecozone.ro/reviste.php?RID=27677

One of the main challenges for the development of biomass algal system production is the high operational and capital costs for these technologies. A great opportunity to overcome these challenges may however exist in the integration of wastewater treatment with algal biomass production. The algae are used for treatment of industrial wastewater, for purification of effluent originating from livestock production, while the studies concerning the use of algae species for the treatment of aquacultu...
Autori: Katya Velichkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27684

Adsorption, desorption, and kinetics behavior of Gd(III) ion on chelating resin were investigated in this paper. Batch adsorption studies were carried out with different pH, contact time, and temperature. The adsorption of Gd(III) follows the Langmuir model better than the Freundlich model. The apparent activation energy Ea and adsorption rate constant are k308 4.16 kJ/mol and 6.01×10-5 s-1, respectively. Thermodynamic parameters such as ΔH, ΔS and ΔG indicated that Gd(II...
Autori: Leilei Pi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27688

Though Scirpus triqueter plays an important role in protecting the ecological functions of Yangtze River estuary wetland which is frequently contaminated by petroleum, knowledge is limited about the mechanisms involved. In this study, comparative analysis of soil properties, microbial community structure and soil enzymes in the rhizosphere of S. triqueter and bulk soil was conducted throughout one year to provide an insight into the phytoremediation mechanism in the field. The total petroleum hy...
Autori: Jing Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27697

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

One of the main causes of global climate change is deforestation. Wood is largely used in construction, furniture, and pulp and paper industries, which consume hundred of millions of cubic meter of wood year by year. Forest surfaces decrease rapidly at global level and this reality is of crucial importance for world global ecological footprint. Shortage of pulpwood for paper industry became a great challenge and, for this reason, other raw materials must be taken into consideration. Recovered pa...
Autori: Ana Maria Cheșcă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27703

In the present study, Dowex HCR-S/H, cationic resin was used as a resin for the removal of cadmium from aqueous solutions. The experiments were carried out in a batch vessel. Subsequent experiments were performed as a function of initial solution pH, resin dosage, agitation time, initial Cd2+ concentration, solution temperature and agitation speed. Ion exchange rate increased with the increase in initial cadmium concentration, stirring speed and temperature. The Langmuir, Freundlich, Elovich,...
Autori: Baybars Ali Fil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27777

Gaseous toluene biofiltration as affected by ryegrass (Lolium perenne L.) roots was investigated in this study. The results revealed that the populations of bacteria, actinomycetes were larger in the ryegrass rhizosphere than in the bulk soil since ryegrass provided root exudates as major nutrients available for the microorganisms. An increase in the microbial populations in a ryegrass-growing biofilter would significantly stimulate toluene biodegradation in comparison with a vegetation-free bio...
Autori: Zhongjun Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27772

Changing wastes into raw materials is one of the most favored options for waste management, as it diverts wastes from landfill and saves resources. Fibers, either vegetable (cellulosic) or synthetic, may be added to cement pastes in order improve the properties of concrete or mortar by reinforcement. At the same time, if the source of fibers is wastes, then such processes make ways for recycling. In the work described here we studied the compatibility of residues from the nonwoven textile indust...
Autori: Hugo Monteiro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27766

Bare zero-valent iron nanoparticles (bare-ZVIN) have a great tendency to aggregate, which drops their reactivity with pollutants. To address this issue, polyvinylpyrrolidone stabilized-ZVIN (PVP-ZVIN) was synthesized and used for the removal of Cd2+ from aqueous solution in a batch system. The effects of operation conditions such as the pH of aqueous solution (2-8), reaction time (0-120), adsorbent concentration (1-6 g L-1) and the initial Cd2+ concentration (10-60 mg L-1) on the removal efficie...
Autori: Amirhosein Ramazanpour Esfahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27764

Indoor air quality (IAQ) improvement potential of rotor turbine ventilator (RTV) was researched by setting up an RTV on the outer part of the chimney of a kitchen, located in a “windy” city, Çanakkale, Turkey. Efficiency of RTV was assessed by preliminary tests, conducted in a three-storey restaurant. After obtaining positive results in terms of airborne bacteria count (TBC) from these tests, long-term measurements were carried out in a cafeteria by air sampling before and aft...
Autori: Sibel Mentese
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27734

This paper aims to pioneer the research into the dry nitrogen deposition in reservoirs serving as drinking water sources. For this purpose, several field experiments were performed to investigate the dry deposition in Xiaotaipingyang, Danjiangkou Reservoir (Henan) from September 2015 to August 2017. Sample concentrations were measured for NH4+-N, NO3--N and total dry deposition (TDN). Then, dry deposition flux of NH4+-N, NO3--N and TDN were estimated based on the measured concentrations and samp...
Autori: Luo Ling
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27749

Indoor environment significantly affects occupants’ health and productivity. However, in smart buildings and cities, it can be improved thanks to the implementation of innovative ICT systems and services. Thermal comfort is one of the most complex aspects to be considered to enhance occupants’ well-being, because of the relevant role played by subjective parameters (physiological, psychological and cultural) in its evaluation. This challenge can be tackled by integrating wearable dev...
Autori: Andrea Calvaresi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27783

The current trends in Mediterranean climate indicate longer periods of drought and hot temperature in summer and shorter and more intense precipitation in spring and autumn, which require reconsidering the current water management. The Emilia-Romagna coastal area (Northeastern Adriatic Sea, Italy) is entirely drained by a network of channels connected to more than 70 water pumping stations. Although drainage is fundamental in wet periods to keep the land dry, during long periods of stable wea...
Autori: Nicolas Greggio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27792

The aim of this paper was to investigate and understand the relationship between several physical and chemical parameters such as temperature, chemical oxygen demand (COD), and biochemical oxygen demand (BOD) on the one hand and dynamics of bacterial populations involved in the breakdown (hydrolysis) of macromolecular organic matter, on the other. The study was carried out during July-November 2009 at Cernavoda Wastewater Treatment Plant and included quantitative estimation of proteolytic, amylo...
Autori: Constantin Ioan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27872

Activated sludge (AS) is the mainly used biological process in water treatment; therefore, assessing the influence of various operating conditions on this process is relevant. This study aimed to evaluate at laboratory-scale the influence of the gas-to-liquid volume ratio (RG/L) and the stirring speed (SS) on the biodegradation of carbamazepine (CBZ) by activated sludge. For this purpose, a central composite design (CCD) was used in association with response surface methodology (RSM). Batch cult...
Autori: Samer Semrany
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27869

The corrosion inhibition of mild steel in acidic media at 303 – 333K in 0.1 - 0.5M acids (hydrochloric acid - HCl and trioxonitrate (v) acid - HNO3) and 0.01-0.03g/L Aloe Vera extract (AVE) were investigated by standard weight loss method. The corrosion rate was calculated in the absence and presence of the inhibitors. The inhibition efficiencies of AVE in both acid media increased with increase in concentration and decreased with increase in temperature and period of immersion. Results sh...
Autori: Maureen Ndibe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27870

The present study describes the results of air quality analysis and surfaces inside the Orthodox Church in Oradea City, Romania, a wooden monument (BH-II-m-B-20958), originally built in the village Letca from Sălaj County and displaced in 1991 to the campus of the University of Oradea. The paper focuses on the degree of microbial and fungal contamination of surfaces and air inside the wooden church. It also identifies various microbial species with potential risk on the health of parishione...
Autori: Dorina Camelia Ilieș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27858

Indigenous Pseudomonas veronii 2E, Klebsiella oxytoca P2 and Klebsiella ornithinolityca 1P were tested as catalysts for the transformation of Cr(VI) to Cr(III) for Cr(VI)-containing wastewater biotreatments. The Cr(VI) biotransformation was assayed during bacterial growth and by using pre-grown quiescent cells. Proof of the unsuitability of a biotreatment based on Cr(VI)-reduction during bacterial growth was found: the reduction rate and the maximum Cr(VI) concentration able to be reduced were t...
Autori: Mauricio Javier Alessandrello
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27853

The macrophyte Pistia stratiote was used as biosorbent for the removal of Black Krom KJR (BK-KJR) dye in synthetic aqueous solution. Initially, some tests were performed to verify the best operational conditions such as pH, biosorbent particle size, sorption temperature and stirring speed, which were later used in the kinetic and equilibrium tests. All tests were performed in duplicate. The highest removal rates of the pollutant were achieved at the process conditions of initial pH 2, granulo...
Autori: Aparecido Nivaldo Módenes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27843

This study was carried out to determine the feasibility of applying a freeze concentration technique to rarefy milking wastewater using either a stationary wastewater vessel (the first series of tests) or a rotary ice–making machine (the second series of tests). In this study, we investigated the impact of freezing temperature, initial milking wastewater concentration and vessel depth upon the removal rate of chemical oxygen demand (COD). Results show that when the freezing temperature ...
Autori: Yingjie Dai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27845

This paper presents the results of experimental researches regarding the optimization of a decontamination process through thermal desorption of soils contaminated with crude oil. The optimization was performed for the following desorption parameters: heating temperature of the soil and the treatment duration, by increasing the temperature from 300°C to 350°C and decreasing the treatment duration from 10, 15 and 20 minutes to 5, 10 and 15 minutes. The economic calculation of the decontam...
Autori: Dorina Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27846

This study emphasis the hydrogen fermentation from de-oiled Jatropha waste (DJW), a secondary and promising waste from biodiesel industry via influence of various combination of heat pretreatment using sewage sludge as inoculum. Batch experiments were carried out at a DJW concentration of 50 g/L, temperature of 55oC and an initial cultivation pH of 7. The peak hydrogen production rate and hydrogen yield of 16.3 mmol H2/L-d and 1.10 mmol H2/g volatile solids (VS), respectively, were obtained ...
Autori: Gopalakrishnan Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27874

This study was carried out to determine the feasibility of applying a freeze-concentration technique to purify wastewater polluted with dye, such as methylene blue (MB) using a stationary wastewater vessel. In this study, we investigated the impact of freezing temperature, initial MB wastewater concentration and vessel depth upon the removal ratio of MB. Results showed that when the freezing temperature was decreased (from –5 °C to –15 °C), the freezing rate increased. The...
Autori: Yingjie Dai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27878

The effect of synthesis conditions on sorptive properties of glycerol-derived mesoporous carbon materials were studied. Sorption properties of the synthesized carbon-based materials regarding to different adsorbate molecules, as well as water vapors, phenol and methylene blue molecules were analyzed. The sorption capacity of the synthesized mesoporous carbons depends upon synthesis conditions, namely upon pyrolyzing temperature and carbon precursor to silica weight ratio, being determined by ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27880

Air cooled and water cooled slag samples were obtained from a demonstration plasma gasification / vitrification unit. The leachability of the major heavy metals present (Cr, Cu, Mn, Fe, Pb and Zn) in both the air cooled and water cooled slag when in contact with acidic solutions was investigated under different temperature, stirring and contact time conditions. Water cooled slag showed better resistance to heavy metals leaching. The vitrification process immobilised Cr and Pb. The leachabilit...
Autori: Konstantinos Moustakas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27882

The main topic of this study is the photo-optical and electrochemical behavior of a series of fluorinated copolyimides containing both oxadiazole and perylene moieties in the main chain. The polymers prove a strong photo-optical stability on a large temperature domain and display different types of photoluminescent behavior in solution and in solid state, with emission maxima in the bluish and green–yellow domains. Cyclic voltammetry investigations suggest that the polymers can be easil...
Autori: Radu-Dan Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27883

The catalytic hydrogenolysis of glycerol, a by-product of the biodiesel manufacturing process was studied on copper chromite catalysts with different chemical composition. The obtaining of propylene glycol was studied under mild reaction conditions (180- 240oC temperature range, 8 hours reaction time and moderate pressures). These important parameters have significant effects on the glycerol conversion and that is way the actual study was concerned to the obtaining of a superior selectivity t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27892

The aim of this study was to determine how temperature conditions (max. 72oC, 81oC and 43.5oC) during sewage sludge composting affect the distribution of organically bound heavy metals in humic substances (HS). To accomplish this, the content of Cu, Ni, Zn and Fe was measured in the two main fractions of HS, humic acids (HAs) and the fulvic fraction (FF). In the feedstock, the FF was mainly responsible for binding all metals except Ni. During composting in the two series with thermophilic con...
Autori: Dorota Kulikowska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27894

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

The influence of initial metal ion concentration and temperature on the adsorption of Zn(II) from aqueous solution onto amino ethyl cellulose (AEC) functionalized with Orange 16 reactive dye, was examined. Batch experiments were performed at pH of 4.0 and adsorbent dose of 8.0 g/L previously established as optimum, ranging the initial Zn(II) concentration between 22.74-181.92 mg/L and temperature between 2 and 60 C. Three isotherm models (Langmuir, Freundlich and Dubinin – Radus...
Autori: Gabriela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27904

Latest analysis regarding the climate change phenomenon arises issues related to air quality, human comfort within urban environments and an increased energy demand attributed to the building sector. The Urban Heat Island (UHI) phenomenon is directly responsible for the poor quality of life in cities and for increased energy consumption. Characteristic features pertaining to a specific urban environment, such as local microclimatic conditions, urban morphology and anthropogenic heat release ...
Autori: Adriana Lucia Kadhim-Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27913

Biosorption of copper(II) by lyophilized and thermally treated bacterial biomass of Pseudomonas aeruginosa PAO1 and Pseudomonas fluorescens BME in aqueous suspension was studied. The cell surface properties were characterized and the experimental conditions, e.g., pH, adsorption time, and initial metal concentration were optimized for efficient biosorption. The surface charge was negative at pH above 2.5 for P. aeruginosa, and above pH 4 for P. fluorescens. The highest copper(II) uptake was ...
Autori: Anikó Kőnig-Péter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27917

The applicability of an electrocoagulation process with the biological treatment for the color removal of C.I. Basic Red 46 (BR46) dye was studied. It was shown that decolorization efficiency increased by increasing current density (j), pH, temperature (T) and agitation speed (ω) and decreased with the initial dye concentration [BR46]0. The optimal conditions in presence of a grid electrode (waste) used as cathode were found to be j=9 mA cm-², pH 8, T=35°C, [BR46]0=30 mg L-1 an...
Autori: Katia Madi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27927

The aim of this study was to produce high quality activated carbons from Diplotaxis harra biomass by potassium hydroxide activation and their application in heavy metals removal. To reduce the number of experiments, full factorial experimental design at two levels (24) was carried out to occur optimal preparation conditions for efficient removal of cadmium and cobalt ions from aqueous solutions. Different variables influencing activation process, such as carbonization temperature (500–6...
Autori: Hanane Tounsadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27934

Removal of excessive ammonium nitrogen (NH+4-N) from aqueous solution has been of considerable concern for several decades. It can be removed by air stripping, a necessary prerequisite is adding enough alkali. This study presented the first attempt to investigate the potential use of ceramsite coated with magnesium hydroxide (CCMH) on the effectiveness of NH+4-N removal coupled with air stripping at ambient temperature without alkali addition. The results showed that the CCMH coupled with air...
Autori: Tianpeng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27940

Livestock farming in rural areas in Jilin Province is producing a huge amount of organic pollutants like livestock and poultry manure, of which, a large portion is directly dumped into the Yitng River, bringing serious harm to the environment. Taking Soonlng Village as an example, this paper investigates the environmental pollution caused by the livestock husbandry in this village and builds a biogas heat storage greenhouse ecosystem, which, by using solar energy to heat the biogas digester, ...
Autori: Songying Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27943

Yizhang, located in south of Hunan province of China is rich in geothermal resources. This paper aimed to study the concentrations of cations, e.g., K+, Ca2+, Na+, Mg2+ and conducted the analysis of the environmental isotope characteristics of δD, δ18O and 13C. Further there are explained the rules of the generation and evolution of geothermal groundwater in Yizhang. The temperature of geothermal groundwater in Yizhang was between 34.2 and 45.4 °C, with a neutral pH and a high...
Autori: Junjie Ba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27944

The related European directives in force stipulate that product testing shall be performed in conditions that reproduce as accurately as possible the real ones that may be encountered during their operation. These are products whose intended use are specified in the safety data sheet or within the instructions for use, and whose limits of the micro-climatic parameters that can be encountered (temperature, humidity, wind - for the outside ones, temperature, humidity, generation of restricted t...
Autori: Ilie Ciprian Jitea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27956

Fire and explosion prevention requires the knowledge of the explosive or flammability parameters of combustible gases and vapours that can be found in industrial and civil environments, as well as the influence of certain substances in the process on these parameters. In some cases, pyrophoric sulphides can be formed and it is supposed that they may influence the known flammability parameters of the substances used in various industrial processes. In order to track the influence of iron sulp...
Autori: Maria Prodan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27963

Human behavior in critical situations is at the core of all concerns about the fire safety of buildings, regardless of their destination. The way in which the human caught in the fire reacts to the risk factor to which he is exposed, his behavioral response to the direct action of the fire, or his psychological response to the effect of the fire (temperature, smoke opacity, reduced visibility, exposure to toxic combustion gases), are all factors that can drastically influence the required saf...
Autori: Marius Cornel Şuvar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27965

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

The present paper is a multidisciplinary investigation of the indoor air quality inside the Multipurpose Hall of the University of Oradea, based both on specific monitoring and questionnaire-based survey to identify people’s perception in this regard. The monitoring, carried out during October-November 2016 when the heating did not work, was focused on: relative air temperature and humidity (Thermohygrometer data logger Klimalogg Pro), carbon dioxide (CO2) (Extech Instruments CO250 model a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27981

This study presents the influence of the storage recipients’ material and of the use and the type of stirring on the drinking water quality. The kinetics of drinkable water quality alteration under stationary conditions and under magnetic and sonical stirring have been monitored for a two weeks period. The microbiological parameters (total number of germs developed at 37°C and 22°C, lactose-positive and lactose-negative bacteria, coliform bacteria and Echerichia coli), as well a...
Autori: Laura Damian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27999

Ambient temperature can modulate neurotransmission in the peripheral nervous system. Transmission at the neuromuscular junction is also influenced by ambient temperature. Myasthenia Gravis (MG) is an autoimmune disease of the neuromuscular junction characterized by impaired transmission of the nerve impulses to the muscle fibers. The aim of the study was to determine if there is in fact a statistically significant correlation between environmental fluctuations and MG exacerbations among myast...
Autori: Dan Iulian Cuciureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28004

Bangladesh is highly vulnerable to climate change along with the adverse impacts of climate change. This paper aims to reveal the debates about climate change and extreme weather events. It considers Bangladesh as a case to understand the debates, the impacts of climate change on people’s livelihoods. This paper used secondary sources to select and scrutunize recent literatures about climate change, extreme events, the impacts of climate change on livelihood patterns and future trends. ...
Autori: Shah Md. Atiqul Haq
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28006

As one of the largest coastal wetlands in northern China, the ecological function of Caofeidian wetland has gradually degraded due to the influence of climate and surrounding environment. In order to regulate and repair the water area of the wetland, it is necessary to study and analyse the historical changes and influencing factors of the water area of Caofeidian wetland This paper extracts the water area of Caofeidian Wetland in 1984~2013 from the images collected by Landsat satellites usin...
Autori: Shaoxiong Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28022

This article addresses CO2 dynamics in school classrooms and analyses the improvement of ventilation and indoor air quality resulting from the simple window-opening ventilation strategies. CO2, temperature and relative humidity were measured in four different naturally ventilated classrooms of a Northeastern Portuguese education institution for a wide range of environmental conditions. Indoor CO2 levels were also simulated with a numerical model to help manage the indoor air quality of these ...
Autori: Filipe Rodrigues
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28030

Aspergillus fumigatus has been selected to bioleach the metals ion from brown shale. Process parameters like pH (5.0, 5.5, 5.8, 6.0, and 6.5), substrate concentration (2, 4, 6, 8, and 10%), pulp density (1, 5, 10, 15, and 20%), temperature (30, 35, 40, 45, 50oC) and agitation (100, 150, 200, 250, 300 rpm) were optimized according to L25 Taguchi orthogonal experimental array design that resulted in the twenty five batch bio recovery experiments. After biorecovery experiments, optimum value of ...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28035

In this work we aimed to examine the influence of the main abiotic factors (temperature, rainfall, relative humidity, atmospheric pressure) on the synthesis of active compounds (phenolics, flavonoids), with antioxidant and therapeutic effect of two herbs - Capsella bursa-pastoris (shepherd's purse) and Marrubium vulgare (horehound) collected from two different areas of Romania: Dobrogea (Constanta) and Muntenia (Bucharest). The studies have shown that biogenesis and accumulation of second...
Autori: Elena Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28041

Several theoretical studies were oriented towards the relationship between the main two building design estimators (building energy consumption and indoor environmental quality) but very little experimental research has been carried out in order to underline the correlation between this two parameters. This paper is focused towards the experimental study of the correlation between these two design estimators. Several indoor comfort parameters (air temperature, radiant mean temperature, sound ...
Autori: Mihai Toderaşc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28042

This paper measures the temperatures along a test route through Chenggong District, Kunming, by mobile measurement, and revises the measured data to 4 different time points of the test period, aiming to enhance the data utilization efficiency. The modified data were plotted into isotherm slices at the four time points, and the urban heat island (UHI) features, as well as its influencing factors were analysed on geographic information system (GIS) software. The results of the measurements show...
Autori: Bai Yufu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28044

Evapotranspiration is one of the main sources of water loss in arid regions. Although FAO Penman-Monteith (FAO-PM) method is one of the accurate method to estimate potential evapotranspiration (PET). Nevertheless, it is a point-based method and requires several weather data such as radiation, wind speed, air humidity and temperature, which is not available in all regions. Therefore, this study is aimed to estimate PET equivalent to FAO-PM model using satellite data and Priestly-Taylor (PT) model...
Autori: Azam Sadat Hosseini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28062

Dust explosions are one of the main causes of mining disasters. To avoid them, it is important to understand how they are propagated. In the study reported here, computational fluid dynamics software was used to model a 3D diagonal pipe network then simulated a dust explosion at its inlet to examine its propagation characteristics. The initial conditions, boundary conditions and parameter settings were detailed description in the simulation to analyze possible propagation characteristics, assess...
Autori: Baichao Song
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28067

Most people is aware that outdoor air pollution can impact human health, including indoor air pollution. Human exposure to air pollutants indicate that indoor levels of pollutants may be two to five times, and occasionally more than 100 times, higher than outdoor levels. These levels of indoor air pollutants are of particular concern because most people spend about 90 percent of their time indoors. In this manuscript we monitored indoor pollutants in a school building with two different methodol...
Autori: Patrizia Aversa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28072

The objective of this paper is to investigate the short and long run association, and causality among precipitation (dependent variable), and other climate parameters such as minimum and maximum temperature, wind speed, relative humidity, and atmospheric pressure (independent variables) for Islamabad city. The authors have considered the data set from July 2001 – December 2017, and applied several econometrics techniques such as Augmented Dickey-Fuller, Vectors Auto regression, Multivariat...
Autori: Dalia Streimikiene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28097

The increase of population and the bad management of municipal solid waste (MSW) lead to a spectacular increase of the landfill leachates volume. These effluents represent a very harmful threat that can affect the environment and the ecosystems, their control and treatment became the first occupation of the authorities. In this context, this study contributes to characterize the landfill leachate composition and how its changes over different seasons. The results have shown an intermediate leac...
Autori: Soukayna Rhouat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28100

This study is an attempt to monitor the indoor microclimate and the microbiological contamination of some indoor objects inside a wooden Orthodox church. Standard microbiological techniques were used for the isolation and identification of the fungi present in the dust of the superficial surface of the paintings chosen to be investigated for biodeterioration. Samples were taken from approximately 1 cm2 of the surface of the analysed paintings (cotton canvas, wood, on primer) using the cotton swa...
Autori: Dorina Camelia Ilieș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28114

In this study we present time-related 3D ERI models for a site that was contaminated using waste automobile engine oil. The pristine geo-electrical characteristics of the site were recorded before the contamination was carried out. The purpose of the study was to progressively monitor the geo-electrical responses of the site for possible natural bio-transformations on the waste oil. Data were acquired once every two weeks for a period of three months using eight parallel 2D resistivity profiles....
Autori: Bokani Nthaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28118

Soils are influenced by stand composition and hydrological regime as well as by stress abiotic factors, including forest fires. As such, this study analyzed three stands affected by fires of different severities. Soil samples were gathered during the spring of 2017 from three sample areas in Vrancea County, eastern part of Romania. For each area studied, soil profiles were studied in 3 areas affected by fires and in control areas located close to each other. The soil respiration was determined b...
Autori: Aurelia Oneț
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28120

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

The aim of the study was to determine the relation between the composition of university recyclable material collected (plastic, paper, metal and glass), education-related factors such as the academic calendar and work stoppages, and regional factors such as climate, regional economy and composition of the urban waste collected over an 8-year period. The study was conducted based on the composition of recyclable dry solid wastes at the Federal University of Rio de Janeiro, quantified after th...
Autori: Victor Becker Tavares
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28127

The mesoporous MCM-48 was synthesized at room temperature with different templates such as hexadecytrimethylammonium bromide (C16TABr), hexadecytrimethylammonium chloride (C16TACl) and dodecyltrimethlammonium chloride (C12TACl). The obtained materials were characterized by XRD, N2 adsorption/desorption, FTIR and SEM techniques, and their performance as uranium adsorbent were investigated. In this framework, the effect of contact time, pH of solution, initial uranium concentration and temperat...
Autori: Meriem Chabane Sari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28131

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

As CO2 concentration levels in the atmosphere are steadily reaching a point of no return, it is paramount that actions are taken towards mitigating emissions by improving the efficiency of existing processes. Sorption-enhanced water-gas shift (SEWGS) combines the water-gas shift reaction with in-situ adsorption of CO2 on potassium-promoted hydrotalcite (K-HTC). This enables a direct conversion of syngas into separate hot streams of H2 at feed pressure and CO2 at regeneration pressure, making th...
Autori: Vlad-Cristian Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28149

Soluble dyes are intensively used in various industrial activities. They represent an important class of water pollutants from which they are rather difficult to remove. This paper focusses on the elimination of Congo Red (CR) ionic azo dye by adsorption on a low cost material. Cherry stones were used for activated carbon preparation by carbonization method. A temperature of 600 °C and a time of 4 h were found as adequate parameters for the physical activation and led to a final white powder...
Autori: Cristina-Gabriela Grigoraș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28153

Apart of new equipment’s development such as absorption columns with higher efficiency, for chemical industry, there is a strong need for greenhouse gases reduction in order to assure the environmental protection and, consequently, many studies regarding the purification methods of exhausted gases have been performed. There are several types of reactors used for gases purification, such as: bubbling jet reactor, combined packed and spray tower absorber, cable wet scrubber and packed column...
Autori: Elisabeta Droniuc Hultuana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28160

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162

Growth rate and biomass yield in the case of Arthrospira platensis depend on nutrient availability, temperature and light, which can determine changes in the metabolism and therefore in the biomass composition. The aim of this study is to evaluate the behavior of A. platensis during the growing time in several liquid culture media and their influence on the yield of biomass production. The following culture media have been investigated in this sense: ARS, Zarrouk (Z), modified Zarrouk (MZ), eco...
Autori: Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28163

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

NaA zeolite was successfully synthesised from fly ash through hydrothermal process. The synthesised NaA zeolite was modified with Li+, Ca2+ and Mg2+ through ion exchange at a temperature of 60 °C and contact times of 1 h and 4 h. In this study the crystallinity of the synthesised NaA as well as its modified (LiA, CaA and MgA) was evaluated towards CO2 adsorption capacity using temperature programmed desorption (TPD) process at low temperature (40-150°C) and high temperature (150-700°...
Autori: Muvumbu Jean-Luc Mukaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28175

In cold, high-latitude regions, snow evaporation can significantly influence the snow water equivalent and thus change the regional water balance in early spring. In order to explore how the snowfall event and environmental factors affected the snow evaporation rate in the northern Daxing'an Mountains in China. From the snow melting period of March 2016 to April 2018, the eddy covariance method was used to explore the relationship between environmental factors and snow evaporation. The resul...
Autori: Youwei Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28181

This study aims to evaluate the properties of different wastes obtained from four red ceramic brick industries in the northern region of Santa Catarina, Brazil. The characterization of the clay brick waste (CBW) was performed using the XRD techniques, XRF, FTIR, DTA and SEM. Techniques to determine the pozzolanic activity, particle size, B.E.T. surface area and specific mass were used. The consumption of calcium hydroxide (CH) in the cementitious pastes with the CBWs was also measured. An app...
Autori: Adilson Schackow
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28184

Inorganic ceramic materials is receiving more attention in recent times due to their unique characteristics which include different pore structures, hydrophilic surfaces, high chemical, thermal and mechanical stabilities that offer avenues for application in water treatment. In the present work, cost-effective clay ceramic water filters of different designs were developed from clay (50, 60, and 70) %, sawdust (15, 20, 25, and 35) %, grog (5, 10 and 15)% ratios plus 5% bone char by volume and ...
Autori: Enyew Amare Zereffa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28196

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

A numerical simulation was conducted to investigate the combustion characteristics and effects of Hydrogen-Hydrogen Oxygen (HHO) addition on performance and NOx emission of a spark ignition (SI) biogas engine. At a given operating condition, indicative work cycle Wi increases with increase of HHO, CH4 concentrations and load rate; but it decreases with engine speed increase and reaches peak value as variation of equivalence ratio and advanced ignition timing. Combustion temperature T and NOx con...
Autori: Bui Van Ga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28204

This study investigates the mechanism and efficiency of catalytic ozonation process on iron-loaded rice husk ash (Fe-RHA) and Peanut shell ash (Fe-PSA) for the Erythromycin removal from aqueous solution. In the current study, the COD removal efficiency of Erythromycin was studied in simple ozonation and catalytic ozonation using Fe-RHA/O3 and Fe-PSA/O3 processes. The operational parameters such as pH effect, catalyst dose, and reuse performance of the catalyst were studied. Moreover, the hydroxy...
Autori: Shama Nazir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28208

The paper analyses the possibilities of recycling tannery sludge (TS) in clay brick manufacture. The physico-mechanical properties and microstructure of clay brick and cement mortars vary depending on TS content in the mix. 2.5 %–15.0  TS (by weight) was added to clay bricks fired at 1000 C temperature and maintained at maximum heat for 1 hour. The tests revealed that 2.5  TS addition had a positive effect on physical and mechanical properties of clay brick: reduce drying and mfi...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28209

Healthcare facilities provide a cure from the ailment while maintaining a clean environment. A high indoor environmental quality (IEQ) can improve the recovery process and create a pleasant working environment, while a poor IEQ causes nosocomial diseases that are harmful to the patients as well as the hospital staff. To assess the state of IEQ in selected local hospitals, the current study investigates critical IEQ parameters. Based on a detailed literature synthesis, three parameters are selec...
Autori: Mawara Khan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28217

Techniques such as composting, a controlled process of decomposition of organic materials, have become fundamental to minimize the problems associated with the organic fraction of urban solid waste, as the potential to cause damage to public health, the environment and, consequently, to economic and administrative aspects can be related to this kind of waste. Microbial activity is also highlighted as a relevant factor since the microorganisms are fundamental in the degradation of organic matter...
Autori: Priscila da Costa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28222

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

In this study, the effects of possible climate change in a 36-year period (1980-2015) in different sites on the spatial-temporal distribution of chestnut forests in the Eastern Black Sea region of Turkey were investigated. For this purpose, Giresun, Trabzon- Arsin and Artvin-Hopa in the Eastern Black Sea region were selected as the study areas. The Mann-Kendall and Sen’s trend analyses were applied to the annual temperatures (average, maximum and minimum) and annual total precipitations. ...
Autori: Ayhan Usta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28240

As it spread globally, the new SARS-CoV-2 virus was first confirmed in Romania in February 2020, and since then over 40000 cases were diagnosed with COVID-19. Considering climate charges that showed a continuously increasing temperature and also the fact that nowadays air conditioning devices are used on daily bases not only in personal homes but also in healthcare facilities we raised the question if cooling air devices could contribute to the spread of SARS CoV-2 virus. For that, we searched ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28248

Advanced oxidation processes (AOPs) are used with high efficiency in wastewater treatment due to the formation of hydroxyl radicals with high oxidation capacity. However, there exists many different variables which affect the efficiency of theses processes as it affects the amount of hydroxyl radicals formed; such as reaction time, pH, temperature, reactant concentrations and catalyst amount. In this study, the removal of 2-chlorophenol (2-CP) and 2,4-dichlorophenol (2,4-DCP), which are highly t...
Autori: Aysun Altikat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28251

MABR (Membrane Aerated Biofilm Reactor) consists in an attached-growth process in which a gas permeable membrane is used as a biofilm carrier, and bubble-less oxygen transfer allows for a counter-diffusional mechanism where the electron donor (NH4+, biodegradable organics) and electron acceptor (O2) reach the biofilm from opposing sides. The paper reports results form the largest MABR installation in the world, demonstrating the beneficial impact of the technology in terms of improved process r...
Autori: Giuseppe Guglielmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28299

Biomethane is incentivized in Italy and in many other European countries as a substitute fuel for transport, in order to reduce fossil fuel and cut CO2 emissions. In Italy, Certificato di Immissione in Consumo (CIC) is actually sustaining biomethane production, charging petrochemical companies who need to cover their obligation quotes. Actually, biomethane production has to fulfil sustainability requirements in order to be entitled to get CIC. Sustainability principles are, among others, the typ...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28305

The ocean is an indispensable source of materials and energy for the survival of human beings and social development. It is also an essential factor affecting climate change and ecological balance. In view of the dynamic, three-dimensional (3D), and complex marine environment, this study proposes the construction and dynamic visualization of a marine spatio-temporal process model based on Network Common Data Form (NetCDF) and optimal interpolation. The proposed model combines the advantages of ...
Autori: Xu Shenghua
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28315

This study shows the results of the experimental investigation of refinery wastewater treatment by the electro-Fenton process. The experiments were designed using Taguchi design approach with an orthogonal array (OA) of L16 runs. Four process variables (current density (CD), temperature (T), Fe2+ concentration (Fe2+), and time (t)) at four different levels were considered for the present design. Regression analysis was performed to predict a correlation for the response function (chemical oxyge...
Autori: Zainab I. Abbas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28322

This research presents the efficiency of an air-based solar drying system for providing comprehensive information on optimal management of the wastewater treatment plant sludge (WWTPs) by using renewable energy. The solar drying method was appropriate for utilizing facilities to remove ammonia and able to inactivate environmentally stable Escherichia coli (E. coli) microorganisms which were dropped at 2 logs CFU/gr. The thermal efficiency of the dryer was recognized under the realistic circumst...
Autori: Zeinab Amin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28324

The basic purpose of a hospital is to provide a cure to the ailing patients. Since the patients are already suffering from ailments, the hospital must be a place for comfort and mental peace. Indoor Environmental Quality plays a vital role in maintaining that comfort. The hospital building must be designed on the standards to provide the required thermal comfort. If the building is already built and operational, retrofitting techniques are used to maintain the standard values of indoor environm...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28325

In this paper, seawater heavy metal concentrations (Al, As, Cu, Ba, Zn, Fe, Cd, Co, Cr, Pb, Mn, Mo and Ni) measured by ICP-OES and water quality parameters (NH4-N, NO3-, N, NO3, PO4-P, PO4-3, suspended solids, temperature, conductivity, pH and dissolved oxygen) were evaluated in Izmit Bay (The Marmara Sea). The study was carried out seasonally between December 2016 and September 2017 at four separate sampling stations. The mean concentrations of heavy metals in mg L-1 were: Al: 0.074, As: 0.020...
Autori: Arzu Morkoyunlu Yuce
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28333

In this study, the change of freeze-thaw test result of unconfined compressive strength of clayey soils reinforced with pine tree sawdust and marble dust was investigated. Mixtures containing 5%, 10% and 15% marble dust and 0.5%, 1% and 1.5% pine tree sawdust were compressed by standard Proctor test with optimum moisture content. After curing the mixture samples for 1, 7 and 28 days at a working room temperature of +21°C, they were subjected to the freeze-thaw test at -21°C, +21°C fo...
Autori: Necmi Yarbasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28342

At present, the production of oily sludge is huge, and the micro-emulsion method can effectively separate crude oil and water from the oily sludge by reducing the interfacial tension between oil and cement. In this paper, the micro-emulsion was prepared by using surfactants, such as sodium dodecyl benzene sulfonate (SDBS), cetyltrimethylammonium chloride (CTAB), sodium dodecyl sulfonate (SDS), sodium cetyl sulfate (CAS), and alkylphenol polyoxyethylene ether (OP-10) as the main raw materials. T...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28344

The simple way to deal with obnoxious hexavalent chromium is to reduce it to its trivalent form, which is comparatively less toxic. In this article, Cr(VI) was reduced to Cr(III) using hydrazine. The effect of various process parameters such as molar ratios of Cr(VI) to N2H4, the temperature of the reaction, and the environmental chemistry of solution on the reduction kinetics have been evaluated. Experiments demonstrate an order of three for the reaction. The reaction was first order with resp...
Autori: Bharti Verma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28348

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349