AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractThe cost sensitivity analysis of a chemical process was carried out through a sequence of three stages, using three different software applications. In the first stage an alkylation process was optimized with GAMSÂŽ software, the objective function being the profit. This optimization was repeated for the values of five different costs in the frame of a factorial experiment. In the next stage, the objective function-costs dependence was quantified with an artificial neural network, obtain...
Autori: Alexandru Woinaroschy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25273

AbstractA study was fulfilled concerning the source and the distribution of PAHs in the effluent proceeding from an oil refinery. The monitoring of the PAHs concentration in the refinery’s effluent also was performed during a year long. The practical goal of the work was to observe the complying with the limits imposed by the current legislation and to identify the potential risks of exceeding these limits in the future. For this study, gas chromatographic and HPLC methods were used. The metho...
Autori: Anca Iuliana Birladeanu, Claudia Irina Koncsag, Mariana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25357

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract The efficiency of Cd (II) removal from aqueous solutions was investigated using Sphagnum moss peat as sorbent. A 23 orthogonal central composite design was successfully employed for experimental design and analysis of results. The combined effect of the initial solution pH, peat dosage and initial Cd (II) concentration was studied and optimized using Response Surface Methodology (RSM). The optimum values of these variables were found to be pH = 4.72, 14.7 g peat /L and 13.64 mg Cd /L, ...
Autori: Catalin Balan, Corneliu Cojocaru, Petru Bulai, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25399

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract The aim of the study is to outline new opportunities of improving buildings ambient comfort and thus to determine energy consumption cut down. The second half of the XX century witnessed the development of society disregarding the extent to which environment was affected by the industrial production; pollution was triggered by the widespread industry which made use of technologies whose main target was the increase of production output at any cost, an aggressive industry with respect...
Autori: Vladimir Corobceanu, Răzvan Giuşcă, Raluca Giusca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25549

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract Mathematical models have become a valuable tool to study the anaerobic digestion process, to guide plant design and optimize operation strategies. Models require accurate and significant parameter values for being useful. Although the identification problem is an issue of concern, often is neglected. The described method for model calibration consists on the performance of simultaneous batch experiments (SBE), which requires simple and usually available equipment, and is based on the...
Autori: Belen Fernandez, Jordi Palatsi, Josep Illa, M. Angels Colomer, Xavier Flotats
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25636

On the basis of spot investigation of dozens of cities and hundreds of towns and villages in different regions in China, combining with the fundamental methods of municipal solid waste management (MSWM), three development modes of MSWM were proposed according to the land area, economic level, nature condition and population distribution of various geographical units and urban systems. They were respectively for the city/district system, the city/town (district)/village system and the city/ count...
Autori: Haibin Chen, Li Zhang, Jingcheng Zhou, Yang Huhttp://www.ecozone.ro/reviste.php?RID=25707

Abstract:This work concerns studies related to strategic development of products in which bio-based plastics are or will be applied, referredto as bio-based products. The studies cover (1) current and potential benefits of bio-based products in extended value chainsincluding activities after end-of-life of products, (2) value communication between stakeholders in extended value chains, and (3)creating an integrated development approach for optimized bio-based products. Most existing models for v...
Autori: J.W. Lin, Jarmila Kopecká, Kim Ragaert, Ludwig Cardon, Maarten De Groote, Rolf Koster
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25728

Abstract:A comparative analysis is drawn on the energetic responses numerically simulated for Brasov, Romania location, delivered bytwo mono-axial pseudo-equatorial STCs (solar thermal collectors): a flat plate STC and a STC with heat pipes; the two systemsare destined for future implementation on Transilvania University Campus. Accordingly, two tracking programs are consideredfor the diurnal motion: a) of 1h constant duration steps, for school courses interval (September-June) and b) 1-step pro...
Autori: Maria M. Vatasescu, Veronica E. Dombi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25740

Abstract:The paper aims to present the new pattern of modular agriculture, as evolution of agri-food production in the coming decades aswell as to highlight the direct relation between this pattern and the massive energy support it requires.The paper basically deals with reactions to climate change, reductions of carbon emission, in addition to high quality and safetyrequirements for food production. The author envisages the PAC measures called for in order to ensure a sustainable developmentof ...
Autori: Romulus Gruia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25746

Abstract:The paper presents a method to improve the efficiency of a photovoltaic (PV) string by employing a mono-axis trackingmechanism. The tracking system was optimized so that it has minimum energy consumption during tracking. The PV stringsimultaneously changes the daily position using a linear actuator which transmits the motion to all modules by a rack-pinion gearmechanism. The system is designed in virtual prototyping concept with the following software solutions: for the solid modeling -...
Autori: Cătălin Alexandru, Nicoleta-Irina Tatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25766

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

AbstractWastewater streams and particularly industrial effluents tend to increase in volumes and to get more complex in terms ofpollution. Nevertheless, nowadays the focus is directed towards recycling or reuse of treated wastewater so as to close the wateruse loop. Advanced wastewater treatment allows these possible applications by achieving good quality effluent to suit the newpurposes, but the implementation of this treatment stage is a difficult task. This study gives an example on how to ap...
Autori: , Daniela Cailean, Florina Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25971

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractThis paper presents the most recent developments regarding the square spiral inductors inductance evaluation. The study wasperformed in order to develop, implement and validate powerful software, CIBSOC able to determine the inductances of spiralinductors and also to optimize the spiral inductors layouts.We have studied the inductance variation of square spiral inductors. The four modules of the CIBSOC software were described,applied for the computation of inductance and the optimization...
Autori: Adina Racasan, Calin Munteanu, Claudia Hebedean, Claudia Pacurar, Vasile Topa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25997

AbstractThe developing of the infrastructure for wastewater collection and treatment in Romania is leading more and more to theproduction of huge quantities of activated sludge, as direct result of the application of state of wastewater treatment. The rapidand rational development of a national policy for management of activated on short, medium and long term has emerged as anecessity, and must be implemented urgently.The EU 27 countries consider environmental management of activated sludge as a...
Autori: Ilie Vlaicu, Ioan Neamt, Ioana Ionel, Mihail Reinhold Wächter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26019

AbstractThere are many treatment methods used to remove color from textile wastewater, and Fenton oxidation, a well known AdvancedOxidation Process is one of the most efficient. Apart of Fe(II), other metal ions have been used as catalysts in Fenton’s Reagent,and Cu(II) proved to be a good alternative.In this study the effect of the concentration of dye, catalyst and hydrogen peroxide were studied and optimized for thediscoloration process of Reactive Black 5 using a Fenton-like process, H2O2/Cu...
Autori: Andrei-Petru Bertea, Armand-Florin Bertea, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26042

AbstractExperiments were designed to optimize the Cr(VI) adsorption on Salvinia cucullata. The significance of different adsorptionparameters along with their combined effect on the adsorption process has been established. A regression equation wasformulated by representing percentage of Cr(VI) adsorption as a function of different independent variables such as contact time,pH, adsorbate concentration and adsorbent dose. The insignificant terms were assessed through student ‘t’ test and are remo...
Autori: Saroj Sundar Baral
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26084

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

AbstractWith the rapid development of the city, people feel increasingly great pressure. Community Parks are playing more significantroles in people’s daily life. Community Parks with the theme of leisure and recreation provide communication platforms forresidents and have enriched their outdoor activities. The parks not only ease people’s life and work pressure, but also improvecommunication among neighbours. An excellent Community Park not only needs to satisfy residents’ utility requirements,...
Autori: Wenting Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26176

AbstractElectrostatic Precipitator draws many researches on flue gas treatment technology and very few researches on its structural design. The conventional structural design of electrostatic precipitator casing uses stiffened flat sheet as wallboard which consumes a great amount of steel. Consequently, a new structural idea was explored to optimize the conventional design which applies profiled steel sheet and locates wall beam and wall column. Optimization codes were programmed to select the o...
Autori: Dengfeng Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26178

AbstractIn this work, a four factor three-level Box–Behnken factorial design based on response surface methodology (RSM) wasemployed to optimize the removal of phosphate from synthetic wastewater (mineral salts medium-MSM) by the bacterialconsortium (Bacillus sp. RS-1, Pseudomonas sp. YLW-7, Enterobacter sp. KLW-2). A mathematical model was then developedto show the effect of each medium composition and their interactions on phosphate removal. The effect of the lactoseconcentration (X1), pH (X2)...
Autori: Krishnaswamy Usharani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26235

AbstractWater system integration can minimize both fresh water consumption and wastewater discharge from the paper mills. In thepresent study, Pinch Technology was used to analyze and optimize the water network of an integrated paper mill. A system wasdeveloped and a limiting constraint (COD concentration) was identified based on investigations for water quality, and thenminimum fresh water and wastewater targets were determined without considering water losses. The analysis was extended byestim...
Autori: Sudheer Kumar Shukla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26240

AbstractHealthcare waste management is one of the most important environmental problems in the world and particularly in Tunisia,because of the potential environmental hazards and public health risks. The collection of infectious healthcare waste is a highlyvisible and important service that involves large expenditures. This study discusses the off-site transport problem of infectioushealthcare waste from the 12 hospitals in the governorate of Sfax (Tunisia) to a planned steam sterilization disp...
Autori: Wafik Hachicha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26252

AbstractThe purpose of the undertaken research work is to degrade the biopolymeric pigments present in the distillery spentwash. This isdone by direct electro-oxidation using iridium oxide coated titanium mesh as catalytic anode. The effects of current intensity,dilution, pH and time of electro-oxidation were studied. The combined effects were analyzed using Box-Behnken design foroptimization and statistical analysis. The rate constant for first order electrochemical kinetics relating the rate c...
Autori: R. Krishna Prasad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26253

AbstractIn the present work an optimized experimental condition has been developed for the treatment of pulp and paper mill wastewater using an electrocoagulation process. The removal efficiency of 85 % COD and 94 % of color with a good repeatability of results (RSD <3%) has been achieved under the optimal experimental conditions of pH-7, treatment time of 2 h and a current density of 15 A/m2. In this study, wastewater from paper mill has been used and thus, high efficacy of removing the poll...
Autori: Chhaya Sharma, Rajni Sharma, Satish Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26281

AbstractThe objectives of this study were to investigate of cadmium and chromium adsorption from aqueous solutions by using orange (Citrus sinensis var Tampson) and sour orange (Citrus aurantium) mesocarp. The chemometric approach was applied for the optimization of removal percent of Cd2+ and Cr6+. To optimize Cd2+ and Cr6+ removal percent, the effect of four experimental parameters on removal percent was investigated by means of multivariate analysis. The considered factors were Cd2+ and Cr6+ ...
Autori: Maryam Bagheri Ardebilian, Mohammad Ali Zazouli, Pouneh Ebrahimi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26287

AbstractA deep understanding of the relationship between the solids deposition and head losses is vital to optimize the backwashing inbiological aerated filters (BAFs). In this article, the deposition solids were classified into four types: heterotrophic biomass,autotrophic biomass, inert biomass and extracellular polymeric substances (EPS). A concept model was developed to simulatethe solid deposition and the head loss development. The temporal and spatial distributions of the four types of sol...
Autori: Chengda He, Dongsu Bi, Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26347

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractWireless sensor network (WSN) has been widely used in national defense, military and security, environmental monitoring andmany other fields. It’s of great significance to design WSN which consumes little energy but supports service quality flexibly andeffectively. To further improve the performance of WSN, this article, focusing on aspects of low energy consumption and longlife cycle of the WSN and taking energy limits and coverage requirements in WSN into account, attributes the covera...
Autori: Wenjuan Cheng, Yiming Tian, Yourui Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26359

AbstractFor efficient, economical and environmentally disposing the waste rock underground, based on principles of waste directbackfilling in fully mechanized coal mining, this paper carries out a field test in 6304-1 working face of Jining No.3 Coal Mine.We first design a waste rock direct underground processing system, including screening-crushing system, transportation system,transfer system, stope backfilling system and coal mining system. Then optimize the waste backfilling and coal miningt...
Autori: Jixiong Zhang, Qiang Zhang, Xu Zhao, Yanli Huang, Zhan Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26383

AbstractThe simulation of different situations that may occur in the operation of the mine ventilation network is performed on its virtualmodel, developed and optimized using dedicated software. Depending on the chosen scenario, on the network model are applieda number of changes (addition of new ventilation workings, addition / removal of branches and nodes, changes in aerodynamicparameters: pressure, air flow driven by the fan etc.), the ultimate goals being: to assess how the new model obtain...
Autori: Marius Cornel Șuvar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26408

AbstractThe study aimed the diversification of fodder yeast assortments with viable economic effects while reducing the environmentpollution by capitalization of wastewaters with high monosaccharides content from pulp and paper industry and residual wheyfrom milk industry. Using the Response Surface Methodology the fabrication recipe has been optimized according to anexperimental program based on a mathematical model with biomass, protein and residual sugar as response functions. Theculture medi...
Autori: Livia Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26429

AbstractThe sludge treatment processes represent a priority when we refer to the municipal wastewater treatment, but can implicate verycomplex studies and applications if we consider the industrial wastewater recovery and treatment processes. Even if the industrialsludges are seen as wastes, they can represent an important resource if are properly managed in the storage, treatment andrecovery processes. This paper aims to identify some methods to optimize the coagulation and flocculation process...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26444

AbstractThis paper presents an optimization procedure to minimize the cost of drying in a solar cabinet dryer based on the results of amathematical model. The model has been developed previously for performance analysis of a solar cabinet dryer. The optimalvalues for geometry of the solar collector, mass flux of air through the collector, and initial moisture content are obtained in away that the drying cost is minimized. The results indicate that to optimize the drying cost, the best values of ...
Autori: Samaneh Sami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26564

Abstract The biological removal of organic matter from a cosmetic wastewater by sequencing batch reactors has been optimized by analyzing the influence of the hydraulic retention time as well as the inclusion of anoxic and/or aerobic stages in the process sequence. Hydraulic retention time of 5 d led to the highest total organic carbon and chemical oxygen demand removal regardless the sequence used. Although a completely aerobic sequence can be used for cosmetic wastewaters treatment, the al...
Autori: Montserrat Tobajas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26589

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract A model of an irreversible combined thermionic-thermoelectric generator with internal and external irreversibilities is established in this paper. The performances of the combined generator, in which the heat transfers obey radiative heat transfer law, are analyzed and optimized by using the combination of finite time thermodynamics and non-equilibrium thermodynamics. The general expressions for power output and efficiency versus drop voltage are derived. The influence of finite rat...
Autori: Zemin Ding
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26624

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract 18F-FDG is a glucose analog in which the hydroxyl group on the second carbon is substituted with 18F, being used as an indicator of glucose uptake and cell viability. The aim of this work was to synthesize the 18F-FDG and to validate the methodology for the assessment of its both radiochemical and chemical purities, according to the European Pharmacopoeia. The proposed methodology encompasses three chromatographic methods: radio-HPLC, radio-TLC and HS/GC. Radiochemical impurities ...
Autori: Mirela Mihon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26640

Abstract The development strategy of the European Union until the year 2020, Europe 2020, militates for an intelligent economy, sustainable and favorable to inclusion. Following these principles, each Member State establishes its targets and action plans at a national level. On the other hand, the rural zones benefit from diverse forms of renewable energy which can assure their development and energetic autonomy, bringing important advantages to the rural community: the diminishing of energy...
Autori: Liliana Topliceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26644

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Response surface methodology and central composite experimental design were used to model and optimize the operational parameters of the excess sludge protein extraction yield by ultrasonic wave-assisted extraction. The three variables involved in this research were the ultrasonic extraction time, pH, and temperature. In the range studied, statistical analysis of the results showed that selected variables had a significant effect on protein extraction yield. The optimized extraction...
Autori: Yulin Xiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26736

Abstract The traditional industrial parks (TIPs) in China has been rapidly developed in the past 30 years, which have contributed to stable and continuing GDP growth, but also caused severe pollution. In order to solve the conflict between local economic development, environmental pollution and resource shortage, the TIPs in China should be transformed to eco-industrial parks (EIPs). However, the eco-transformation of China's TIPs is still at an exploratory stage. So, the paper studies e...
Autori: Jiang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26855

Abstract This work presents the optimization of process variables to maximize the percent of Fe (II) removal, R (%), by chelating resin Purolite S930 from 34% CaCl2 solutions. To study the combined effect of the initial solution pH, initial Fe (II) concentration and resin dosage was used a 23 orthogonal central composite design and Response Surface Methodology (RSM) for analysis of experimental data. To optimize the regression equation was used The Gradient method. The study discovered that ...
Autori: Camelia Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26856

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Conductive-diamond electrochemical oxidation processes are promising technologies for treating biorefractory industrial wastes with organic loads below 20000 mg L-1. In this work, electrochemical oxidation of a real industrial pharmaceutical wastewater with conductive-diamond anodes has been studied. The electrolyses were carried out in discontinuous operation mode under galvanostatic conditions, using a bench-scale plant equipped with a single compartment electrochemical flow cell. For optim...
Autori: Joaquín Ramón Domínguez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26927

In this work, coagulation features and characteristics of dissolved organic matter (DOM) in combined sewer overflow (CSO) wastewater were investigated. Ferric chloride (FeCl3) and polyaluminum chloride (PAC) were employed in the coagulation process. Results showed that both FeCl3 and PAC are effective in removing turbidity and total phosphorus (TP). Removal efficiencies were all above 90% when dosages were reasonable. Chemical oxygen demand (COD) removal efficiency was between 60% and 70%. T...
Autori: Wei-gang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26931

Eco-efficiency is a key concept which brings together two essential aspects for economic progress and ecological aspect. Ecoefficiency indicators are very relevant and play an important role for environmental cost management. For a thermal power plant, which has a great impact on the environment, these indicators involve lower costs and efficient use of energy, water and fuel. The paper proposes a number of eco-efficiency indicators applicable to a thermal power plant, according with specific...
Autori: Roxana Grigore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26938

Every year a lot of hectares of forest are burn in Europe, especially in the south part of Europe, where the climate is hot and dry during the summer. Last decades, with climate change, this part of the Europe becomes dryer and increase of the field fires is observed. The same problems arise in northern America, Australia and other dry regions. A model field fire spread can have several applications. The prevision of the fire front can help the fireman to optimize their work, and to reduce th...
Autori: Stefka Fidanova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26973

The adsorption characteristics of nitrate ions from aqueous solution using Lewatit FO 36 was investigated as a function of pH, biomass dosage and contact time. Results showed that optimum conditions were obtained at pH 8, adsorbent dosage of 160 mg/L and contact time of 60 min. At the optimized experimental parameters, the maximum nitrate adsorption capacity of Lewatit FO 36 was 200 mg/g and nitrate adsorption followed Freundlich model. Among seven kinetic models used in this study, the adso...
Autori: Mehdi Ahmadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26996

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

The arsenic removal from aqueous medium was investigated through adsorption by employing finely powdered bark of Pinus roxburghii Sarg. The batch mode laboratory scale experiments were conducted to investigate the removal efficiency of Pinus bark against total arsenic and the effect of pH, contact time, adsorbent dose and initial adsorbate concentration on adsorption to optimize the process. Langmuir and Freundlich isotherms were used to validate the adsorption data and respective constants w...
Autori: Syed Hasnain Shah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27013

Semi-conductor oxide enhanced photocatalysis is a sustainable technology suitable for disinfection of water contaminated with pathogens. Disinfection of Escherichia coli was investigated using an immobilized thin film tungsten trioxide (WO3) photocatalyst in a visible light-driven photoelectrocatalytic batch cell (PECB). Disinfection efficiency was monitored under dark electrocatalytic, photolytic and photoelectrocatalytic conditions and assessed using a culture-based approach. Optimal disin...
Autori: Efetobor Scott-Emuakpor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27014

The aim of this study was the diversification of fodder yeast assortments with viable economic effects while reducing the pollution to the environment by capitalisation of wastewaters with high monosaccharides content from pulp and paper industry. As inoculum, in the bioreactor, a mixture of two species of yeasts Candida utilis and Candida arboreea (1:1 ratio) was used at 38°C, pH 5.5 and an air flow of 0.02 L/h was insured. Wastewaters from technological process of pulping of softwood wi...
Autori: Andrei I. Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27028

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

A quick and efficient response to an emergency incident is critical to avoiding further damage, so its evaluation is important before taking real action. In this study, a framework for response strategy evaluation is proposed based on a whole-process risk analysis of historical accidents, which provides a method to compare the efficiency of different response strategies in a hypothetical scenario. The framework is a multi-step procedure consisting of three major steps: system definition, inde...
Autori: Lei Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27041

Hospitality is the main industry in the service sector in Spain, contributing to more than 10% of the gross domestic product and approximately 12% of all employees. Firms in this industry are beginning to adopt eco-innovations to reduce their environmental impact and optimize the use of natural resources. However, most companies do not have the necessary resources to tackle ecoinnovation on their own and need to cooperate with different agents. The purpose of this paper is to examine how open...
Autori: Francisco José Sáez-Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27073

The present study investigates the effect of addition of calcium hypochlorite in the titanium dioxide (TiO2) mediated degradation of bio-recalcitrant wastewater from pharmaceutical industry. The degradation studies were carried out in photoreactor irradiated with ultraviolet (UV) light at 365 nm under slurry mode. The reduction in chemical oxygen demand (COD) was estimated as an index of degradation. The influence of process parameters viz., catalyst dose, pH, oxidant concentration and source...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27097

Rapeseed meal (RM) is an abundant and cheap by-product of oil extraction process. RM is a rich source of nitrogen, carbon, and minerals. Thanks to these features, RM has a striking potential for eco-friendly production of high value products in biotechnological processes. In this study, the possibility of using a low-cost medium based on the water soluble fraction of RM for laccase production by the fungus Pleurotus ostreatus has been evaluated and compared with the use of synthetic complex ...
Autori: Lucia Guarino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27129

In this study, chitosan-iron(III) was used as adsorbent of the dye acid red 29. The effect of pH, temperature and concentration of the dye on the adsorption capacity were evaluated. The maximum adsorption capacity was calculated from the adsorption isotherms which were well fitted by Sips isotherm model. The process followed the kinetic model of pseudo-second-order. The activation parameters showed that the adsorption process is spontaneous and favorable. A decrease in adsorption capacity was ob...
Autori: Carla Albertina Demarchi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27181

Banana stalk (BS) waste is used to remove Pb2+ from aqueous solution. Equilibrium data were analyzed with Langmuir and Freundlich adsorption models, which fit better in the former equation. The qmax (maximum metal uptake capacity) for Pb2+ adsorption was 105.14 mg/g of BS at pH 5.0, which followed pseudo-second order kinetics model. IR spectra confirmed the participation of hydroxyl, amino, and acidic functional moieties in the removal of Pb2+. The major mechanism involved in the biosorption of ...
Autori: Kashif Iqbal Sahibzada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27214

In this research, Response Surface Methodology (RSM) was employed to optimize five operating variables including initial pH, current, reaction time, initial hexavalent chromium concentration and dosage of polyaluminum chloride as a coagulant for the removal of hexavalent chromium and its relative operating cost by electrocoagulation process. Central Composite Design (CCD) was applied for the optimization process. The results showed that increase of polyaluminum chloride dosage was beneficial for...
Autori: Sepideh Sadeghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27230

Studies about microwave (MW) sludge conditioning method have dealt mainly with municipal secondary sludge processing. We considered necessary to examine the applicability of the microwave process for other type of sludge, such as primary sludge originating from the food industry. The aim of our work is to identify the main influential operating parameters of MW pre-treatments applied for primary meat processing wastewater sludge (MPWS) as a conditioning process, followed by their optimization fo...
Autori: Sándor Beszédes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27236

Construction industry uses a huge quantity of traditional and modern building materials which generally are produced to satisfy different demands, such as: resistant and safety requirements, friendly with the environment, architectural aspects etc. Researches must solve any requirements related to materials properties and offer a large diversity from which the proper solution must be considered. For improving the mechanical properties of polymer concrete, the use of fibers of different types is ...
Autori: Vasilică Ciocan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27306

The paper aims to present the sorption properties of two sorbent substrates (composts) prepared by aerobic fermentation from vegetables waste composted with beech sawdust (BR2) and beech ash (BC1) to be used for Cu2+ removal from wastewaters. The composts structures and surface properties were characterised in terms of active groups (FTIR), crystallinity (XRD), morphology (SEM), topography (AFM) and specific surface and pores analysis (BET), and the changes in properties after Cu2+ sorption were...
Autori: Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27323

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

This study was to optimize the fermentation process for protein enrichment of potato starch residue (PSR) by solid state fermentation with mixed strains. Three single-factor experiments were conducted to optimize the fermentation conditions, and a Plackett-Burman design followed by a central composite design of response surface methodology was investigated to optimize the medium constituents. The optimal fermentation conditions were fermentation temperature 28°C, fermentation period 72 h and...
Autori: Heng Lei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27380

The paper deals with the demonstration of the technical and environmental advantages related to the use of a tannin based coagulant in textile wastewater treatments. The natural coagulant was tested to evaluate its performance in the coagulation/flocculation process, the level of biodegradability in both aerobic and anaerobic conditions and the eco-toxicological risks for aquatic systems. Results were compared with a common inorganic metal based coagulant. The findings at lab scale showed th...
Autori: Antonio Giuliano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27407

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

The phenol degradation capacity of Serratia marcescens NSO9-1 isolated from olive mill wastewater was evaluated and optimized in this study. Plackett-Burman design coupled with Box-Behnken methodology was used to evaluate the effects of medium components and significant parameters on phenol degradation by this relevant strain. According to Plackett-Burman-based statistical screening, seven of the eleven components of the medium had a significant effect on the metabolism of phenol degradation. Th...
Autori: Nurdan Saraç
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27495

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

In this study major factors affecting the phenolation process of lignosulfonate (LS) waste liquor (recovered from pulp and paper industry) were optimized in order to improve LS substitution for replacing petroleum-based phenols during phenolic resin manufacturing. Four different parameters, namely phenol/lignosulfonate ratio, time, temperature and lignosulfonate waste liquor concentration, were varied in an experimental program having as response function the reaction yield. Response Surface Met...
Autori: Andrei Ionuţ Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27551

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

The present work aimed to optimize a new economic medium for biopolymers production by Rhizobium leguminosarum. Biopolymers were poly-β-hydroxybutyrate and exopolysaccharide (EPS and PHB). They were extensively used in various industrial sectors. Statistical experimental designs and Response Surface Methodology were employed to optimize the medium components. A central composite design was applied to increase the production yield and predict the optimal values of the selected factors. An op...
Autori: Mohamed Sellami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27609

β-glucosidases are very important in the improvement of cellulose degradation rates by diminishing the inhibition of end products. Although, cellulase cost has reduced significantly in last decade but still the high costs of biomass saccharification is one of the main challenges for the commercialization of ethanol from LC biomass. In this work, β-glucosidase immobilization in calcium alginate was optimized using response surface methodology. 89% immobilization efficiency was achieved ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27614

The enzyme-based biosensor stability and its analytical performance depend on both the immobilization process and the matrix used for immobilization of the enzyme into a stable layer. In this paper, the development and evaluation of an optimal enzymatic layer for stable encapsulation of the acetylcholinesterase enzyme (AChE) through the sol-gel method onto mediated carbon-ink screen-printed electrodes was performed, obtaining electrochemical enzyme-based biosensors. The enzyme was immobilized on...
Autori: Melinda David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27636

This paper reviews the recent developments and implementations for greenhouses facilities, focusing on recent progress regarding greenhouse environment monitoring and control with many available application examples. State of the art and current trends concerning the main parts of the greenhouse environment automation are discussed: i) greenhouse climate models, ii) wireless sensor networks, iii) remote monitoring/command and supervisory control and data acquisition (SCADA) systems, iv) image pr...
Autori: Eugen Horatiu Gurban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27644

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

The aim of this study is the treatment of liquid effluents from a petroleum industry (NAFTAL /Algeria) by an electrochemical treatment process (electrocoagulation). The electrocoagulation has proved to be useful for the treatment of wastewater, but in order to enhance its ecological characteristic we found it would be essential to carry out our experiments with ecological energy derived from a photovoltaic solar module, which would contribute to sustainability objectives. The electrocoagulation ...
Autori: Kahina Ighilahriz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27679

The reuse of sewage sludge will be increasing in the future, with expansion of sewerage works and advanced sewage treatments. During anaerobic digestion of sewage sludge from wastewater treatment plants the humification of organic matter will have an important effect on the physico-chemical forms of heavy metals. The aim of our paper was to investigate mobility of zinc from dried anaerobic sludge (DANS) from municipal wastewater treatment plant (WWTP) via single step (simultaneous) extraction pr...
Autori: Vladimír Frišták
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27695

The development of Multi-Energy Systems (MES) or District Energy Systems (DES) requires suitable design and operation optimization tools, in order to assess their feasibility and economic profitability. These tools can be helpful in choosing the proper technologies and also in the perspective of defining proper incentive or taxation schemes. A critical result of the analysis of MES is that, when optimizing their design, the operation strategy and the part load behavior of the units must be consi...
Autori: Matteo Zatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27795

The development of Multi-Energy Systems (MES) or District Energy Systems (DES) requires suitable design and operation opti-mization tools, in order to assess their feasibility and economic profitability. These tools can be helpful in choosing the proper technologies and also in the perspective of defining proper incentive or taxation schemes. A critical result of the analysis of MES is that, when optimizing their design, the operation strategy and the part load behavior of the units must be cons...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27796

The development of Multi-Energy Systems (MES) or District Energy Systems (DES) requires suitable design and operation opti-mization tools, in order to assess their feasibility and economic profitability. These tools can be helpful in choosing the proper technologies and also in the perspective of defining proper incentive or taxation schemes. A critical result of the analysis of MES is that, when optimizing their design, the operation strategy and the part load behavior of the units must be cons...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27803

This paper exposes the research activities regarding REBAF (Energetic Recover of River Biomasses) project, focused on the maintenance operations self-sustainability of the Secchia river (Italy). Poplar was found as the most abundant and representative wood plant of Secchia riverbanks, with a good behavior during gasification process: from 1 hectare of maintenance every three year, it was possible to produce 23 MWh of electrical power and 31 MWh of thermal power. The biochar obtained was characte...
Autori: Vittorio Vezzali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27804

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

Greywater reuse is widely accepted as a suitable response to the increasing demand of fresh water in urban areas. On the other hand, strict environmental regulations have obligated the development and implementation of membrane separation technologies for production of municipal potable water, in industrial water supply and in wastewater treatment. Potential energy crisis in the future has highlighted the importance of using renewable source of energy for membrane separation processes. This r...
Autori: Mohammad Ramezanianpour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27889

Advanced oxidation process is getting tremendous importance in the treatment techniques for the removal of nonbiodegradable organics from wastewater due to its ability to completely mineralize the pollutants. It uses different methods to produce hydroxyl radicals which are responsible for oxidation of pollutants. In this work, studies on Fenton, ultraviolet radiation (UV) and UVhydrogen peroxide processes for removing acetamiprid, a neonicotinoid insecticide from aqueous solution are carried ...
Autori: Puthenkattil Abdukunji Fasnabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27895

Biosorption of copper(II) by lyophilized and thermally treated bacterial biomass of Pseudomonas aeruginosa PAO1 and Pseudomonas fluorescens BME in aqueous suspension was studied. The cell surface properties were characterized and the experimental conditions, e.g., pH, adsorption time, and initial metal concentration were optimized for efficient biosorption. The surface charge was negative at pH above 2.5 for P. aeruginosa, and above pH 4 for P. fluorescens. The highest copper(II) uptake was ...
Autori: Anikó Kőnig-Péter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27917

The aim of this study was to produce high quality activated carbons from Diplotaxis harra biomass by potassium hydroxide activation and their application in heavy metals removal. To reduce the number of experiments, full factorial experimental design at two levels (24) was carried out to occur optimal preparation conditions for efficient removal of cadmium and cobalt ions from aqueous solutions. Different variables influencing activation process, such as carbonization temperature (500–6...
Autori: Hanane Tounsadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27934

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

The coal gas is a potential risk for the safety production in coalmines. The practical experiences in coalmine show that the gas may suffer massive desorption and migration after coal seam mining and deformation of overlying strata. Therefore, gas extraction in mines focuses on mining ground pressure relief gas extraction. In this paper, the study is carried out on gas permeability and migration pathway based on movements of overlying strata over the working face and the spatial location of t...
Autori: Jianwei Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28019

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Aspergillus fumigatus has been selected to bioleach the metals ion from brown shale. Process parameters like pH (5.0, 5.5, 5.8, 6.0, and 6.5), substrate concentration (2, 4, 6, 8, and 10%), pulp density (1, 5, 10, 15, and 20%), temperature (30, 35, 40, 45, 50oC) and agitation (100, 150, 200, 250, 300 rpm) were optimized according to L25 Taguchi orthogonal experimental array design that resulted in the twenty five batch bio recovery experiments. After biorecovery experiments, optimum value of ...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28035

In this research, optimization of Homogeneous Fenton process was performed using Multi-Criteria Decision Analysis (MCDA) and Taguchi method to remove Ciprofloxacin (CIP) from an aqueous phase. Analytic Hierarchy Process (AHP) is one of the most comprehensive systems designed for multi-criteria decision making. In this study, paired comparisons based on the AHP method were performed for three criteria including (i) CIP removal, (ii) COD removal and (iii) Sludge to iron ratio (SIR) to select th...
Autori: Marjan Salari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28040

Agriculture is a highly water-demanding sector. Developed in recent years, the precision farming approach allows to optimize irrigation without compromising crops productivity. WSN networks are a key element of this approach because they allow to monitor continuously large number of parameters providing the possibility of a real-time intervention on field management practices. The WSN networks can be used to measure traditional parameters such as precipitation, soil moisture, or irradiation and ...
Autori: Sara Simona Cipolla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28083

This paper attempts to realize the green logistics of solid waste at ports, enabling the harmless treatment, reduction and recycling of such waste through the entire life cycle. For this purpose, the life cycle assessment and the analytic hierarchy process (AHP) were applied to evaluate the green logistics of solid waste at ports. Firstly, the solid waste logistics system was examined from the perspective of logistics system. Drawing on life cycle evaluation, the author analyzed how the solid wa...
Autori: Xuexin Bao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28107

This work seeks to develop a suitable heavy metals precipitation modeling approach that could give reasonable results in mainstream use with industrial wastewater treatment. This paper is devoted to the thermodynamic analysis of the degree of precipitation of slightly soluble hydroxides and salts in industrial wastewaters in order to optimize the technological schemes of extraction and reuse of heavy metals from industrial waste. Based on the notion of the solubility product, the equations desc...
Autori: Igor Povar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28156

Salinity of irrigation water is one of the main environmental constraints limiting the geographical distribution of several species. In order to understand and to cope with critical environmental constraint, a pot experiment was undertaken to investigate the potential effect of irrigation with various natural saline waters gathered from arid and semiarid regions; on rooting of stem cuttings, growth and on the physiological responses of Mascarene grass (Zoysia tenuifolia Willd.). The obtained res...
Autori: Sihem Soufi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28169

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

Overexploitation and competitiveness over shared fresh water resources are some of the growing problems that affect numerous countries world-wide, in particular those characterized by high water-related risks linked to water scarcity, droughts and baseline water stress. Private and public sectors are driven to find alternative or best-practice strategies to conserve and optimize the water resource and guarantee a future use to all. The affiliate of Philip Morris Manufacturing and Technology Bol...
Autori: Matteo Magagni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28287

Oil-based drilling fluids are widely used in oil and gas exploration and development. Large amounts of oily drilling cuttings are produced in the drilling process, and improper treatment can cause serious secondary pollution. Chemical cleaning is commonly used to treat oily drilling cuttings. However, most degreasing agents are not environmentally friendly and can cause secondary pollution. Thus, the processing requirements of oily cuttings are difficult to meet. In this study, an environmental...
Autori: Zhiyong Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28313

Water treatment has been extensively studied; however, only a few studies have considered it in isolated sites that do not have electric supply, which is a major inconvenience for inhabitants of rural areas. In this paper, the aim was to develop and implement a photovoltaic generator (PVG) that powers a pumping system, and water treatment with ozone. First, the PVG panel’s orientation was optimized using response surface modelling to identify the optimum operating orientation angles. Then,...
Autori: Mohammed Nadjib Brahami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28341

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349