Abstract Tartrazine, (CI 19140) is an azo dye widely used in pharmaceuticals, cosmetics and foodstuff, as well as for coloring the textiles, hence it can be easily found in municipal wastewaters or wastewaters originating from textile, food, drugs and cosmetic industry. In this work, the capacity of a Romanian soil to retain Tartrazine from aqueous solution by sorption onto soil particles of different size has been investigated. The sorption kinetics was studied by applying five kinetic model...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25534

AbstractIn the last years many papers have reported about the occurrence of the pharmaceuticals in the surface waters and theirundesirable effects upon the aquatic life. Most of pharmaceuticals pass through the wastewater treatment plants unchangedbecause they are biorefractory compounds and as a result they enter the water bodies. Therefore, it is necessary to improve thebiodegradability of pharmaceuticals effluents (PhEs) before their discharge in the sewerage systems. The aim of this paper wa...
Autori: Carmen Lazău, Florica Manea, Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26021

AbstractThe present study was focused to classify various advanced oxidation processes (AOPs) to degrade sixteen commonpharmaceuticals and personal care products (PPCPs). The classification was based on the degradation rate constant (h-1).Chemometric techniques like principal component analysis (PCA) and cluster analysis (CA) were used to classify AOPs whichcan efficiently degrade a certain class of PPCPs. The bipolt based on first two principal components (PCs) of PCA modelidentified two distin...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26085

Abstract 18F-FDG is a glucose analog in which the hydroxyl group on the second carbon is substituted with 18F, being used as an indicator of glucose uptake and cell viability. The aim of this work was to synthesize the 18F-FDG and to validate the methodology for the assessment of its both radiochemical and chemical purities, according to the European Pharmacopoeia. The proposed methodology encompasses three chromatographic methods: radio-HPLC, radio-TLC and HS/GC. Radiochemical impurities ...
Autori: Mirela Mihon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26640

Abstract Anaerobic processes have been successfully applied in the treatment of municipal and industrial wastewaters. Judicious use of nutrients in anaerobic treatment has not been systematically investigated. The optimal nutrient dosage for anaerobic wastewater treatment systems is largely unknown. In this paper, COD:N:P ratio used by various researchers in anaerobic wastewater treatment systems for treating different types of wastewaters are compiled and critically analyzed. In order to ha...
Autori: Athar Hussain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26697

Conductive-diamond electrochemical oxidation processes are promising technologies for treating biorefractory industrial wastes with organic loads below 20000 mg L-1. In this work, electrochemical oxidation of a real industrial pharmaceutical wastewater with conductive-diamond anodes has been studied. The electrolyses were carried out in discontinuous operation mode under galvanostatic conditions, using a bench-scale plant equipped with a single compartment electrochemical flow cell. For optim...
Autori: Joaquín Ramón Domínguez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26927

Photodegradation caused by sun irradiation may be of major significance in the natural elimination process of pharmaceuticals and personal care products (PPCPs). The fate of metronidazole (MET) in surface water under solar irradiation was investigated. Several parameters affecting the photochemical degradation rate of MET were investigated, including the initial pharmaceutical concentration, continuous input and the presence of other pharmaceuticals like tinidazole (TNZ) with similar structur...
Autori: Bo Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26928

In this study, the toxic effects of binary mixtures of Pharmaceutical Active Compounds (PhACs) that are observed in the effluents from a wide range sewage treatment plants and surface water bodies were investigated using the bioluminescent bacterium Aliivibrio fischeri (Microtox® test). The selected chemicals were the nonsteroidal anti-inflammatory drug (NSAID) diclofenac sodium [DCF] and the anti-epileptic carbamazepine [CBZ]. In addition, caffeine [CFF], a psychoactive stimulant of the...
Autori: Valeria Di Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27126

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

Pharmaceuticals contaminants in waters exhibit a significant threat on the human health and the ecosystem quality. This research demonstrates the utility of a silver-doped zeolite-modified carbon nanofiber-epoxy (AgZ-CNF) prepared by two-roll mill method in development of the fast methodology for the detection of fluoxetine (FXT) in the aqueous solution. The results showed the role of zeolite that improved the sensitivity and the limit of detection of FXT resulted to the possibility to propose a...
Autori: Magdalena Ardelean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27328

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

An innovative strategy significantly increasing data density by introducing a flexible, problem-orientated, and cost-effective water quality monitoring approach is presented. Most current monitoring strategies produce water quality data based on fixed stations conducted on fixed dates throughout a defined period of time and, thus, often give a biased and insufficient picture of the water quality. Establishing a refined picture of water quality while not increasing monitoring costs clearly needs ...
Autori: Wiebke Warner
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27805

Interest in water recycling has provided opportunities to evaluate the potential impact of pharmaceuticals and personal care products (PPCPs) on plants where recycled wastewater is used for watering and irrigation. Most researches have focused on the impact of pharmaceuticals on seed germination and plant physiology or the uptake of pharmaceuticals into plants. We sought to find out whether nutrient and metal uptake into wheat plants were affected by the presence of PPCPs (acetaminophen, caffein...
Autori: Etem Osma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28193

Pharmaceuticals in the environment are considered as emerging contaminants which are particularly persistent and which could represent a threat both for animals and humans following long-term exposure. Pharmaceuticals include, among others, antibiotics, anti-inflammatory drugs, steroid hormones, antidepressants, β-blockers and lipid regulators. Excretion from humans is considered the main source of release of such compounds in the environment. The excreted compounds reach wastewater treatm...
Autori: Cristiana Morosini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28257