AbstractIt was investigated the bioleaching of uranyl ions from uranium ores, in aquatic medium with algae: Scenedesmus quadricauda and Nostoc linkia under different experimental conditions. The oxidation of U(IV) to U(VI) species, like uranyl ions was done by means of the atomic oxygen generated through photosynthesis by the aquatic medium from solution above of uranium ores.After almost 10 days of direct contact with the given microorganisms, it was observed a bioleaching degree between 10% an...
Autori: Alexandru Cecal, Rodica Calmoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25107

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

AbstractThe paper describes the synthesis and characterization of layered double hydroxides (LDH) intercalated with 4,6-dinitro-o-cresol(DNOC) and 2,6-dichlorobenzonitrile (2,6DBN) by anionic exchange method. The incorporation of the organic pesticides in the structure of layered double hydroxides can offer premises to increase the pesticide active life by reducing its volatilization, controlling the release of the pesticide from the layered structure and decreasing the pesticide adsorption in s...
Autori: Gabriela Lisa, Marcel Ionel Popa, Mihaela Frunza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25144

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei, Gabriela Apostolescu, Ioan Rosca Studies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monit...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25175

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractThe perovskite structure was synthesized by sol-gel method type citrate. Three perovskite LaMnO3 samples were obtained after calcination and were characterized by XRD, XPS and TPR. The catalytic testing was carried out in SCR-HC equipment (HC=C3H6 and C3H6 respectively) in presence and also in absence of oxygen atmosphere. The results pointed out a good activity in NOx reduction but only in oxygen absence. As it was expecting, LaMnO3 perovskite has shown a good activity for hydrocarbons ...
Autori: Helmut Papp, Ion Balasanian, Liliana-Mihaela Chirilă, Wladimir Suprun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25222

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractThe synthesis of some grafted polysiloxane and azo-polysiloxanes with potential applications as rheology modifiers or surfactants for waterborne paints is reported. Nowadays it became very important to design environmentally friendly systems exhibiting the best end-uses properties. Due to their complex architecture and their sensitivity to UV radiation the studied polymeric systems exhibit very interesting rheological properties. All the polymers containing the azobenzenic groups in the ...
Autori: Constanta Ibanescu, Ioana Moleavin, Iulian Nor, Nicolae Hurduc, Viorel Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25252

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

AbstractThe technological process of basic chemical organic compounds synthesis is included among the economic activities that can affect the environment quality. The environmental impact of chemical organic synthesis is evaluated using the alternative method of global pollution index that considers the concentric circles graphical methodology proposing a scale of the arithmetic mean values for the evaluation scores of each environmental components (e.g. water resources, gaseous emission, soil a...
Autori: Carmen Zaharia, Ilie Murăraşu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25352

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract Mesoporosity of about 7 nm in ETS-10 titanosilicate was generated by postsynthesis treatment with hydrogen peroxide under microwave irradiation, resulting in an increased external surface area of the materials (55 m2/g). The influence of titanosilicate porosity and its surface modification by phosphorus atoms (ET(P)S-10) on the retention of some nanoions (??-emitting radioactive U(VI) and Th(IV) ions) and biomolecules (the proteins cytochrome c, papain, and ??-globulin) was investiga...
Autori: Robert Gradinaru, Sorin O. Valu, Stefan Postolache, Claudiu C. Pavel, Ion Sandu, Karin Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25455

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract Highly dispersed nanoparticles of transition and noble metals are utilized for hydrocarbon reactions and rearrangements important to the chemical industry. The need to obtain 1 to 3 nm particles with narrow size distributions has prompted the development of alternative processing methods. Due to widespread speculation concerning the enhanced properties of nanoparticles over their bulk and atomic material equivalents, nanoparticle synthesis has become an active field of research withi...
Autori: , Irina Dumitriu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25482

Abstract It is known that carbonhydrates are precursors of all bioactive substances we tried in thes paper work to do some investigation on these substances in the environmental area of Iasi. To observe the influence of some chemical mutagens substances on carbohydrates biosynthesis we conducted investigations on plant material (leaves) taken from the Calendula officinalis L species. We used this assay to examine the effects of the herbicide 2,4- dichlorophenoxyacetic acid (2,4-D), etidium br...
Autori: Constantin Leonte, Roxana Vatavu, Teodor Robu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25502

Abstract In this work the experimental conditions to synthesize, by direct hydrothermal synthesis, self-bonded pellets of ETS-10 phase containing iron were studied. The following gel composition was used: xNa2O-0.6KF-1.28xHCl-yFe2O3-0.2TiO2-1.49SiO2-39.5H2O with 0.8Â???xÂ???1.4 and 0.015Â???yÂ???0.08. The products obtained were characterized through X-ray diffraction on powders (XRD), thermal analysis (TG, DSC, DTG), scanning electron microscopy (SEM) and microanalysis (EDS). The data obtai...
Autori: Pierantonio De Luca, Danilo Vuono, Monica Filice
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25544

Abstract The Schiff base N,N??(salicylidene)-methylenediamine, known as Salmen in combination with Cr(III) forms at pH = 4.5 a greenish precipitate, which is stable at room temperature but decomposed on heating. The study of the Infrared spectra, Electron Spin Resonance (ESR), X-ray diffraction and thermogravimetry has pointed out that the precipitation form is a complex, while the molar ratio showed that the combination rate of Cr(III): N,N?-bis(salicylidene)-methylenediamine is 1:1. The new...
Autori: Doina Sibiescu, Ioan Roşca, Irina Spatarescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25619

? POLLUTION PREVENTION, A KEY TO ECONOMIC AND ENVIRONMENTAL SUSTAINABILITY ? A COMPARISON BETWEEN DIFFERENT SCENARIOS OF ROMANIAN MUNICIPAL SOLID WASTE TREATMENT BEFORE LANDFILLING ? A STUDY ON ENERGY CONSUMPTION IN ROMANIA ? ENVIRONMENTAL INFLUENCES ON STRESSED METALLIC SURFACES ? ASPECTS OF HYDRODYNAMICS AND MASS TRANSFER IN DIFFUSED AERATION SYSTEMS ? THE STATUS OF SOME SELECTED HEAVY METALS IN ROADSIDE SOILS OF BURSA PROVINCE, TURKEY ? PREPARATION AND CHARACTERI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25656

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? COMPARATIVE CONSIDERATIONS ON THE STRUCTURE OF SOME MOLYBDENUM/NIOBIUM DOUBLE PEROVSKITES OXIDES ? THE INFLUENCE OF THE STORAGE TIME ON THE STABILITY OF BUTTER ? CaCO3 CONTROLLABLE SYNTHESIS BY DOUBLE EXCHANGE METHOD USING CaCl2 RESIDUAL SOLUTIONS ? OPTIMIZATION OF COAGULATION-FLOCCULATION IN THE TREATMENT OF CANAL WATER ? ANODIC DETERMINATION OF PENTACHLOROPHENOL FROM WATER USING CARBON NANOFIBER-BASED COMPOSITE ELECTRODE ? STUDY OF PRECIPITATES GROWTH IN COAGULATION ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25663

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

Our investigation in 2007 revealed that the concentration of microcystin (MC-LR) in Miyun reservoir was 0.224 μg L-1, below the safety limit of surface drinking water in China (1.0 μg L-1). The phytoplankton community in Miyun reservoir was composed of 8 divisions and 84 species (including genera and varieties). The density of phytoplangkton was 393.71?—104 cells L-1 including 24.6% of Chlorophyta, 32.5% of Cyanophyta and 15.3% of Bacillariophyta. The toxin-producing cyanobacteria incl...
Autori: Huimin Li, Guisen Du, Yumei Wu, Dianwei Wu, Jingshi Wanghttp://www.ecozone.ro/reviste.php?RID=25691

Calcium zincate as an active material in Zn/Ni secondary battery has been successfully synthesized by microwave method. The sample was characterized by X-ray diffraction (XRD), thermogravimetric analysis, scanning electron microscope (SEM), chargedischarge test (CT) and cyclic voltammetry (CV) analysis. The results show that the chemical composition of sample is Ca(OH)2¡2Zn(OH)2¡2H2O with regular spherical shapes. The results from CV and CT measurement indicate that the battery has very high d...
Autori: Mengliang Tong, Xuanyan Liuhttp://www.ecozone.ro/reviste.php?RID=25700

Abstract:The demand for new and high performance products in the automotive industry is increasing exponentially and this trend imposesinnovative concepts for cars. The future solutions for the automotive industry may find their answer in the fabricationtechnologies and also in alternative propulsion and energy production.The car design field cannot ignore the global economic crisis, imposing new approaches in terms of materials and cost effectivetechnologies and by the means of environmental pr...
Autori: Mihai Comşiţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25733

Abstract:In order to capture as much solar energy as possible, the photovoltaic converter has to follow the sun movement during a day; thiscan be achieved by a tracking system. Most tracking systems have complex and costly structures that can provide wide anglevariations. This paper presents a geared linkage that is build up by a planetary system of gears fitted on a linkage, and thus helpsin reaching wide angles. Starting from a patented linkage, which reaches ≈200° angular strokes, by a...
Autori: Dorin Diaconescu, Ioana Hermenean, Nora Creanga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25736

Abstract:For the optimal working of the concentrating photovoltaic systems (CPV), these are usually tracked, and the accuracy required infollowing the sun path is much higher than in non-concentrating system. The paper focuses on the synthesis of the optimal steptracking program of an azimuth tracking system, used for accurate tracking of a CPV system. The paper presents the synthesismodelling algorithm and the numerical simulations for a CPV system, orientated with an azimuth tracking system, i...
Autori: Ioana Sinziana Hermenean, Ion Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25748

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:The increasing of energy consumption and fossil fuel emissions (especially CO2, SO2 and NOx) and the limitation of crude oilreserves, determined a growing trend toward renewable energy technologies, like solar, wind, geo-thermal energy and biomass forbiofuels.From all the renewable energies sources, biomass attracts more and more interest being a renewable resource with economicpotential, which can be found all over the world, with positive environmental properties due to neutral emissi...
Autori: Anca Sauciuc, Angela Potetz, Georg Schlaub, Gerald Weber, Hermann Hofbauer, Lucia Dumitrescu, Reinhard Rauch, Ziad Abosteif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25762

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Fly ash and fly ash based zeolites are inorganics used for improving soil quality. In the current paper, the hydrothermal modification of fly ash was studied. Three methods have been employed for this purpose. The first method involved the use of an autoclave, where synthesis has been performed at a temperature of 120 0C and a treatment time of 4 to 8 hours. Within the second method, the modification of the ash at a temperature of 600 0C by fusion was carried-out. In this method, a mixture of as...
Autori: Corneliu Munteanu, Daniel Bucur, Lacramioara Rusu, Maria Harja, Marinela Barbuta, Ramona Carla Ciocinta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25885

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

AbstractWastewater from butyl rubber production is causing an increasing environmental problem due to its large quantity and complexquality. In this paper, two types of wastewaters generated from rubber synthesis, i.e. alkaline wastewater (AW) and cleaning andflushing wastewater (CFW), were investigated. Coagulation and flocculation were firstly applied to remove suspended solids(SS) from the AW. By single factor experiment, the optimum operational conditions were obtained as pH 8, PAC dosage 40...
Autori: Lujun Chen, Rui Liu, Wei Li, Wei Zheng, Yan Zhang, Ying Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25950

AbstractThe WINGEMS software is a useful tool in analyzing, mathematical modeling and synthesis of chemical processes. Thissoftware can be applied to simulate various stages of the papermaking process. An example of simulation and modeling ofprocess is presented for paper stock preparation line for papermaking. On the basis of data obtained during process analysis, it ispossible to elaborate a strategy for control and monitoring of technological parameters and, while the efficiency of the proces...
Autori: Corina Măluțan, Theodor Măluţan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25981

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractA comparative study regarding the shape, dimension and bactericidal activity of the undoped and Ag-doped TiO2 nanocrystalswas achieved. In this way, two hydrothermal methods, classical hydrothermal and microwave-assisted hydrothermal, was usedfor nanoparticles synthesis. The obtained materials were investigated by X-ray diffraction, DRUV-VIS spectroscopy, BET andSEM/EDX analysis. Antibacterial activity of undoped and Ag-doped TiO2 materials was tested on real water from Bega River.The be...
Autori: Carmen Lazau, Corina Misca, Corina Orha, Cornelia Bandas, Sorin Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26034

AbstractIodine is essential for the synthesis of thyroid hormones which are extremely important in the process of growth and developmentof human body. The effects of iodine deficiency implies thyroid enlargement (goiter) and others disturbances so called iodinedeficiency disorders (IDD). The iodine deficiency is an ancient but still existing problem with medical and environmentalconnotation. Soil and water from various regions worldwide are iodine deficient. This problem is aggravated by defores...
Autori: Carmen Vulpoi, Cristina Cristea, Cristina Preda, Letitia Leustean, Maria Christina Ungureanu, Maria Gavrilescu, Voichita Mogos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26038

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Being involved in the synthesis of precursors for amphetamine and amphetamine-like drugs, pyridine (Py) may be also regarded as a by-product found when these drugs are obtained via the Leuckart method. Also, pyridine is well known as a biomarker of microorganisms, when those are subjected to pyrolysis before analysis by various instrumental techniques. Consequently, since Py is not commonly found in the air, its presence as a contaminant at trace levels in a room could ind...
Autori: George-Bogdan Ghira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26109

AbstractOne of the key issues in building construction is environmental sustainability. Conventional methods of construction do not consider the in-built capacity to adapt over time according to new technical requirements and environmental consequences. Therefore, any change or renovation of the building will result in significant cost and lost use during its lifecycle. Designing flexible buildings for easy change and adaptation will assist the main concept of sustainability by reducing material...
Autori: M. Fauzi M. Zain, Maslina Jamil, Nasibeh Sadafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26293

AbstractTo assess the shares of each indicator of environmental and economic benefits in iron and steel enterprises, the entropy weightfuzzy comprehensive evaluation model is built in this paper based on the consideration of entropy theory and fuzzy mathematicaltheory. The weights of each indicator are determined by entropy optimal theory, and the correlative indicators are processed byfuzzy synthesis evaluation, so as to provide some references for environmental and economic benefits evaluation...
Autori: Bin Wang, Hua Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26375

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract 18F-FDG is a glucose analog in which the hydroxyl group on the second carbon is substituted with 18F, being used as an indicator of glucose uptake and cell viability. The aim of this work was to synthesize the 18F-FDG and to validate the methodology for the assessment of its both radiochemical and chemical purities, according to the European Pharmacopoeia. The proposed methodology encompasses three chromatographic methods: radio-HPLC, radio-TLC and HS/GC. Radiochemical impurities ...
Autori: Mirela Mihon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26640

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon material was found to adsorb vitamin B2 from aqueous solution at room temperature. The obtained ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26679

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Hydrolysates of Arundo donax, a crop offering high productivity in contaminated or salinized soils with no inputs of irrigation and agrochemicals, were used in a discontinuous fermenter to grow the oleaginous yeast Lipomyces starkey, to obtain microbial oils potentially useful for the production of 2nd-generation biodiesel. A mixture of fermentable sugars was obtained by steam-explosion and subsequent enzymatic hydrolysis of the lignocellulosic materials. The concentration of Ni2+ ...
Autori: Domenico Pirozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26789

Abstract Superintensive growth of fish in a controlled environment involves taking a series of measures to ensure the oxygen necessary to provide optimal living conditions for stocks. Considering the fact that oxygen has a relatively low solubility in water, the photosynthesis in basins does not occur and the rate of incoming water may be low, it is imperative to supplement the water with oxygen. The paper presents theoretical researches on mathematical modelling and numerical simulation of ...
Autori: Vasilica Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26871

Abstract The possibility to use release controlled fertilizers in the agriculture of the tropical countries is more important than in the agriculture of the countries of the cold regions. In this context, the purpose of this work is the characterization of an encapsulated commercial Fertilizer of Controlled Release named FERLENT®, which was covered with a polymeric material, obtained in situ, under controlled conditions, which allowed to corroborate the fairly well adjustment of the synt...
Autori: Mayra González Hurtado
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26916

In order to improve the soil fertility, several eco-friendly alternatives to traditional cultivation practices have been proposed. The use of biofertilizers, such as rhizobacteria with different plant growth promoting properties is an environmentally-friendly option to achieve sustainability in agriculture. In this context, two bacterial strains (Bacillus pumilus R3 and Pseudomonas lini R7) isolated from the rhizosphere of runner bean plants were assessed for their plant growth promoting abil...
Autori: Gabriela Mihalache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27108

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

The Project “Green - Industrial Symbiosis” (G-IS), in Emilia Romagna region (IT), took place in two phases: phase I, 05.2013 – 03.2014; phase II, 10. 2014 – 10.2015. During the first phase, it was completed the first part of the pilot project of industrial symbiosis (IS) in Emilia-Romagna, which involved 13 companies in the agro-industrial sector, 7 laboratories of the High Technology Network, with Unioncamere and Aster (promoters) and ENEA (technical and scientific co...
Autori: Laura Cutaia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27124

The aim of the present study was to prepare environmentally friendly silver-based materials using Cornus mas L. fruits extract. For this purpose, silver nanoparticles (Cornus mas-AgNPs) were green synthesized using this plant extract. The bioreduction of silver ions was analyzed by UV–VIS and ATR-FTIR spectroscopic studies. Scanning Electron Microscopy (SEM) analysis revealed the formation of spherical phyto-nanosilver particles with size ranging between 12 and 40 nm. Different amounts ...
Autori: Ioana-Raluca Suica-Bunghez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27139

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

In this study, the oleaginous yeasts cultured in tomato waste hydrolysates (TWH) to produce microbial lipids that offer a suitable alternative to vegetable oils as feedstock for the biodiesel synthesis. The TWH were prepared by acid hydrolysis (2.5% H2SO4). To obtain higher growth rates, as well as higher lipid contents, Lipomyces starkeyi were cultured under original nitrogen content (TWHON), lower nitrogen content (TWHLN), attained by alkaline precipitation of TWHON followed by centrifugation ...
Autori: Abu Yousuf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27226

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

In this work, magnetic alginate was synthesized by encapsulating of Nickel Zinc Ferrite nanoparticle within Ca-alginate. The synthesized magnetic alginate was modified by ethylenediamine using microwave radiation to remove anionic dye from wastewater. The characteristics of magnetic nanoparticle, magnetic alginate and magnetic alginate amide (MAA) were studied using Fourier transform infrared (FTIR) and Scanning electron microscope (SEM). FTIR analysis confirmed the amidation of alginate. Di...
Autori: Niyaz Mohammad Mahmoodi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27424

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

Magnesium wastes are among the gradually ascending and therefore challenging metal wastes, which are produced by many industrial activities. The purpose of this study is the usage of magnesium waste, a raw material in magnesium borate production by hydrothermal synthesis. Boron sources (boric acid (H3BO3) and boron oxide (B2O3)) react with magnesium wastes in order to synthesize the magnesium borate mineral of admontite (MgO(B2O3)3ꞏ7(H2O)). In addition to the synthesis from waste magne...
Autori: Azmi Seyhun Kipcak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27657

Until now, humanity has strived to makes efforts for warranting the economic development on a sustainable way for well-being improvement, simultaneously with resource preservation and environmental protection. The industrial production processes, which generate added value and ensure people welfare are in connection with the environment regarding resource consumption and waste generation. In order to work on a sustainable basis, industry should attain a balance between economy, ecology and comm...
Autori: Elena - Diana Comăniță
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27759

The effect of synthesis conditions on sorptive properties of glycerol-derived mesoporous carbon materials were studied. Sorption properties of the synthesized carbon-based materials regarding to different adsorbate molecules, as well as water vapors, phenol and methylene blue molecules were analyzed. The sorption capacity of the synthesized mesoporous carbons depends upon synthesis conditions, namely upon pyrolyzing temperature and carbon precursor to silica weight ratio, being determined by ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27880

The utilization of inorganic carbon by the red macroalgae, Gracilaria edulis (G. edulis) was investigated in this study. G. edulis were grown in brackish water aerated with varying concentration of carbon dioxide - 350 ppm (actual atmospheric carbon dioxide, CO2), 700 ppm and 1400 ppm CO2 gas. Higher growth rate was observed in culture medium aerated with 1400 ppm CO2 and the lowest growth rate was observed at actual atmospheric carbon concentration. Besides that, significant pH drift was obs...
Autori: Lavania-Baloo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27900

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

The paper reports on the preparation of polysiloxane hydrophobized viscose-maghemite/goethite magnetic composite with properties appropriate for uses in oil spill sorption from polluted aqueous media. A multi-step procedure was employed to obtain the polymeric composite. The structures of the prepared samples and precursors were analyzed by Fourier transform infrared spectroscopy (FTIR), whereas their morphology was investigated by means of scanning electron microscopy (SEM). The hydrophobic...
Autori: Răzvan Rotaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28008

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

The aim of this paper is studying light intensity values which maximize the photosynthesis in microalgal cultures by means of models of the photochemical process and by changing cultures strategies. The photosynthetic performances of Graesiella emersonii under batch, fed-batch, semi-continuous cultivation modes and with only air sparged or CO2 added to air were quantified by means of gas exchange measure and pulse amplitude modulated fluorimetry (PAM); kinetics of the photochemical processes...
Autori: Dora Allegra Carbone
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28037

In this work we aimed to examine the influence of the main abiotic factors (temperature, rainfall, relative humidity, atmospheric pressure) on the synthesis of active compounds (phenolics, flavonoids), with antioxidant and therapeutic effect of two herbs - Capsella bursa-pastoris (shepherd's purse) and Marrubium vulgare (horehound) collected from two different areas of Romania: Dobrogea (Constanta) and Muntenia (Bucharest). The studies have shown that biogenesis and accumulation of second...
Autori: Elena Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28041

The mesoporous MCM-48 was synthesized at room temperature with different templates such as hexadecytrimethylammonium bromide (C16TABr), hexadecytrimethylammonium chloride (C16TACl) and dodecyltrimethlammonium chloride (C12TACl). The obtained materials were characterized by XRD, N2 adsorption/desorption, FTIR and SEM techniques, and their performance as uranium adsorbent were investigated. In this framework, the effect of contact time, pH of solution, initial uranium concentration and temperat...
Autori: Meriem Chabane Sari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28131

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Molybdate anions are used in a lot of fields and represent an essential trace element for plant and animal life; however, excessive amounts can cause adverse effect on various organism and environment. Therefore, in the present paper the adsorption performance of MgnFe- layered double hydroxides in the removal process of molybdate from aqueous solutions was studied. The layered double hydroxide (LDH) was synthesized by co-precipitation at low oversaturation method. Different ratio between Mg and...
Autori: Alin Golban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28152

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

Adsorption of diazinon from aqueous solution was studied by using cross-linked Chitosan/Carbon Nanotube (CHN-CNT) in a fixed-bed column. The cross linked CHN-CNT with 2.5% of MWCNT was prepared with a protected crosslinking method. The effects of the initial concentration of diazinon, bed-height, and flow rate on the adsorption of diazinon onto the cross linked CHN-CNT were investigated. The highest bed capacity of 29.47 mg/g was obtained at the initial concentration of 50 mg/L, flow rate of 10....
Autori: Tahere Taghizade Firozjaee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28174

NaA zeolite was successfully synthesised from fly ash through hydrothermal process. The synthesised NaA zeolite was modified with Li+, Ca2+ and Mg2+ through ion exchange at a temperature of 60 °C and contact times of 1 h and 4 h. In this study the crystallinity of the synthesised NaA as well as its modified (LiA, CaA and MgA) was evaluated towards CO2 adsorption capacity using temperature programmed desorption (TPD) process at low temperature (40-150°C) and high temperature (150-700°...
Autori: Muvumbu Jean-Luc Mukaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28175

Healthcare facilities provide a cure from the ailment while maintaining a clean environment. A high indoor environmental quality (IEQ) can improve the recovery process and create a pleasant working environment, while a poor IEQ causes nosocomial diseases that are harmful to the patients as well as the hospital staff. To assess the state of IEQ in selected local hospitals, the current study investigates critical IEQ parameters. Based on a detailed literature synthesis, three parameters are selec...
Autori: Mawara Khan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28217

Oil-based drilling fluids are widely used in oil and gas exploration and development. Large amounts of oily drilling cuttings are produced in the drilling process, and improper treatment can cause serious secondary pollution. Chemical cleaning is commonly used to treat oily drilling cuttings. However, most degreasing agents are not environmentally friendly and can cause secondary pollution. Thus, the processing requirements of oily cuttings are difficult to meet. In this study, an environmental...
Autori: Zhiyong Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28313

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349