ecozone editura ecozone iasi
Reviste:

» Environmental Engineering and Management Journal

» European Journal of Science and Theology

» Sănătate Sport și Nutriție


» Autentificare

E-mail:
Parola:
   
  Cont nou
Va rugam sa va autentificati pentru a putea comanda carti

» Cautare

  » Ultimele cautari

Enhancement of separation performances of a new azoic derivative from industrial water and the posibility to recover its complex as nanomaterial
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
Data aparitiei: January 2010
Revista: Environmental Engineering and Management JournalVol. 9Nr. 1
ISSN: 1843-3707
Pret: Gratuit    
Format PDF Format PDF
Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metallic atom, the methods applied were: pH-metry, conductometry, UV-VIS spectrophotometry. Also, the stability constants for new obtained compounds were determined using Molar Ratio method (J.H.Yoe and A.L.Jones), Continuous Variation method (Job) and Harvay-Manning method. The stability of the new obtained compounds is studied by varying the pH of its solution. The values are K1 = 2.56?106 L/mol for FeL1; K2 = 19.76?1013 L/mol for Fe L2 and K3 = 30.03?1032 L/mol for Fe L3. The higher value for stability is assigned to the compound with molar ratio 3:1 (ligand: metal) in the 1.5?6.5 pH range. The maxim value for the absorbance was measured at ?»max= 601 nm for FeL1, ?»max= 601 nm for FeL2 and respective ?»max= 600 nm for FeL3. The studied complexes are very stable in the above-mentioned pH range and could be used for spectrophotometric determination of Fe(III) in visible domain. Another practical importance is represented by wastewater treatments by membranar separation. Thus, the separation process is improved by increasing the volume of these complexes in comparison with both ligand and Fe(III) and further the iron recovery by calcinations was accomplished.


Sus

Acasa · Carti editate · Reviste · Despre editura · Abonament · Contact · Cos cumparaturi · Cum platesc? · Termeni si conditii
VisaMaster CardPayU

2001 - 2024 © Copyright Editura EcoZone Iasi Toate drepturile sunt rezervate.
Gazduire skaleweb.ro

SkaleWeb