Plants as biomarkers, biosensors and biomonitorsModelling of wastewater treatment of a pulp and paper mill for monitoringCatalysts for heterogeneous photocatalysts. Part I. Possibilities to improve photoefficiency through catalysts modificationThe global assessment method of the water qualityAspects regarding the wood certification in RomaniaDecolorizing of pulping effluents by ammonium lignosulphonate oxidationPowder coatings-based organic filmsOn environmental effects of the pulp and paper mil...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25172

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueBiosorption of Cu2+ ions from aqueous solution by Enteromorpha sp.Loredana Brinza, Matthew Dring, Maria Gavrilescu  Environmental impact assessment for steel processingBrindusa Robu, Carmen Zaharia, Matei MacoveanuEnhanced primary treatment of municipal wastewater by ion exchange and membrane processesDaniela Teleman, Peter A. Wilderer, Carmen Teodosiu, Thilo K?śtzle Best practices in kraft pulping - benefits and costs Dan GavrilescuAspects of waste m...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25177

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract This paper is the investigation concerning the removal, from surface water, of humic acids and of some cations (Cu2+, Al3+) on activated carbons AG-3, BAU, CASO-16 from individual solutions as well as from their mixtures both in static and dynamic conditions. The conclusions of the paper are that, when humic acids are adsorbed from micellar solutions, semiassociates are formed on the surface of activated carbon BAU (in its porous structure), while humic acids adsorption on activated ...
Autori: Tudor Lupascu, Mihail Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25539

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract In this study the possibility to apply the oxidation process for treating textile effluents, by using hydrogen peroxide and Fenton process was evaluated through determining the color and chemical oxygen demand (COD) removal. The experimental variables studied include the dosages of hydrogen peroxide and iron salts, oxidation time and pH value. The result showed that oxidation process using hydrogen peroxide alone is inefficient in COD and color removal, since only 25 % of COD removal...
Autori: Abdelnaser Omran, , Marniyanti Mamat Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25631

? RESEARCH ON NaCl SALINE AEROSOLS I. NATURAL AND ARTIFICIAL SOURCES AND THEIR IMPLICATIONS ? DECISION SUPPORT MODELS FOR SOLID WASTE MANAGEMENT ? AN OVERVIEW ? POLICY AND STRATEGY FOR IMPROVING SUSTAINABLE SOCIAL DEVELOPMENT PROGRAMMES ? APPLICATION OF SHALLOW POND SYSTEM USING WATER HYACINTH FOR DOMESTIC WASTEWATER TREATMENT IN THE PRESENCE OF HIGH TOTAL DISSOLVED SOLIDS (TDS) AND HEAVY METAL SALTS ? TRENDS OF THE COMMUNITARIAN COHESION POLICIES AND ADVERTISING FOR EC...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25658

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? EFFECT OF ELECTRICAL CURRENT ON H2/ H2O2 GENERATION IN NON-THERMAL PLASMA GLIDING ARC REACTORS ? ADVANCES IN THE VISUALIZATION OF THREE-DIMENSIONAL SEISMIC VOLUME DATA ? CHARACTERIZATION OF ELECTROMAGNETIC RADIATION FROM A PATIENT MONITOR ? METHODS OF ELECTROMAGNETIC INTERFERENCE REDUCTION IN ELECTROCARDIOGRAPHIC SIGNAL ACQUISITION ? SPHERICAL MODEL OF THE HUMAN HEAD EXPOSED TO ELECTROMAGNETIC FIELD ? BRAIN ELECTRICAL ACTIVITY RECORDING IN SOME ELECTROMAGNETIC ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25667

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

Four processes have been used to enhance the ozonation of phenol in water: I-pH increasing (O3-pH), II- hydrogen peroxide addition (O3- H2O2), III- UV irradiation (O3- UV), and in the presence of both H2O2 and UV; IV-(O3- UV- H2O2). In each of these processes the rate of phenol degradation has two components: direct and indirect....
Autori: Eszter Arany, Ildiko Bartalis, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25904

AbstractThis paper deals with the experimental investigation related to removal of hydrogen sulfide from simulated groundwater byadsorption/oxidation on activated carbons. Carbonaceous adsorbents were synthesized from peach stones by physical-chemicalactivation method and modified by oxidation following impregnation with Cu2+ by ion-exchange method. Obtained carbonaceousadsorbents were characterized by specific surface area and micropore volume. Surface chemistry properties were evaluated usingB...
Autori: , , Vasile Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26026

AbstractThere are many treatment methods used to remove color from textile wastewater, and Fenton oxidation, a well known AdvancedOxidation Process is one of the most efficient. Apart of Fe(II), other metal ions have been used as catalysts in Fenton’s Reagent,and Cu(II) proved to be a good alternative.In this study the effect of the concentration of dye, catalyst and hydrogen peroxide were studied and optimized for thediscoloration process of Reactive Black 5 using a Fenton-like process, H2O2/Cu...
Autori: Andrei-Petru Bertea, Armand-Florin Bertea, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26042

Abstract The Black Sea is seriously affected by a large range of pollutants, despite severe laws regarding the protection of sea ecosystems. Heavy metals are among the most important xenobiotics from the environment, presenting also toxicity for humans. The studies upon heavy metals have proven that the sediments have the highest concentrations and they can release metals back to water and this fact represents a risk for the humans and aquatic ecosystem life. The use of aquatic ...
Autori: Oana Jitar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26112

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractWater-based printing ink has been used widely and perfectly in printing the packaging of food, drug, and wine products etc.However, due to the need of altering different colors of ink, most water-based printing ink wastewater was generated from theequipment cleaning process. Coagulation combined with Fenton process has been used for this kind of wastewater treatment inthis study, results showed that coagulation using polyaluminium chloride (PACl) as coagulant and ferrous sulfate (FeSO4) ...
Autori: Xiangjuan Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26214

AbstractIn this work the adsorption of Cu2+ and Zn2+ from industrial wastewater by peanut shells without any pretreatment wasinvestigated through optimization techniques such as a feed-forward back-propagation artificial neural network and a simplexalgorithm. The Levenberg-Marquardt algorithm was the best back-propagation algorithm, with a minimum mean squared error of0.000217 for Cu(II) and of 0.000229 for Zn2+. Mean square error on the validation set is used as an estimate for variance.Accordi...
Autori: Başak Mesci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26227

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThis investigation compared the performance of Fenton and photo-Fenton oxidation processes in the treatment of sulfidic spentcaustic wastewater. Response surface methodology, particularly central composite design was used to investigate the effect ofFe/H2O2 and H2O2/COD in assessing treatment process efficiency. Empirical models were developed to describe the relationshipbetween the factors and responses. The models were validated through analysis of variance and were further used in pro...
Autori: Azmi Aris, Mohd Ariffin Abu Hassan, Sharifah Hanis Yasmin Sayid Abdullah, Siti Fadilah Md Noor, Zainura Zainon Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26307

AbstractSeed priming has been reported to be a simple technique for enhancing seedling establishment in environment and cropproduction under stressed condition. In this study, we investigated osmo and hydropriming effect in two salt stressed chickpeacultivars. This research monitors the changes in growth factors, proline content, lipid peroxidation and H2O2 scavenging enzymesactivities in osmo (mannitol 4%) and hydro (water) primed plantlets of two salt stressed chickpea cultivars (Arman and Biv...
Autori: Akbar Mostajeran, Fatemeh Khodabakhsh, Rayhaneh Amooaghaie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26315

AbstractPetroleum tanker trucks are integral vehicles for delivering fuel and other petrochemical products from place to place and must becleaned regularly. Pressure washing with hot or cold water serving to remove oil and filth from the tanker truck container,produces oily waste water with an oil concentration of about 300-500 mg L-1 which, according to environmental standards andregulations worldwide, must be disposed of and treated properly. In the present paper an integrated electrochemical ...
Autori: Konstantinos Dermentzis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26520

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

Abstract In this study, the COD removal of Azithromycin from synthetic wastewater (produced to have a composition similar to industrial wastewater) using a Fenton-like (Fe°/H2O2) system in combination with coagulation has been investigated. Chemical oxygen demand (COD) was selected as the main parameter to assess treatment efficacy in the current study (COD° = 390mg/Lequivalent to 200mg/LAzithromycin). First, the coagulation process was carried out on the synthetic wastewater and the...
Autori: Ahmad Reza Yazdanbakhsh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26586

Abstract Biochar derived from agricultural biomass waste is increasingly recognized as multifunctional material for various applications according its characteristics. It is therefore essential to investigate biochar properties before large-scale application. In this study, rice straw-derived biochars produced at different temperature (550, 650, 750 oC). The resulting biochars were subjected to liquidphase oxidation by different agents including KOH, HNO3, H2SO4, H2O2 and KMnO4 to obtain bio...
Autori: Sobhy M. Yakout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26661

Abstract Nowadays, an efficient wastewater management involves the use of advanced treatment technologies able to decompose hardly biodegradable compounds with reasonable costs at the lowest possible environmental impact. In our work we used one of the most efficient advanced wastewater treatment, the Fenton reaction and its photo-assisted version. The hydrogen peroxide was the oxidizer; despite its relatively high cost, its high activity in oxidizing of a large variety of organic persistent...
Autori: Vasilica-Ancuta Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26677

Abstract In this study, the efficiency of Fenton’s process to remove nickel (II) from industrial plating effluent was investigated. The effect of pH, contact time, concentrations of Fe2+ and H2O2 were surveyed. Kinetic experiments were performed in order to predict the nickel (II) removal rate from wastewater. At pH 1 to 4, nickel (II) removal efficiency increased and declined at pH > 4. The maximum nickel (II) removal efficiency was 98% at 60 min contact time, pH: 4, and Fe2+ and H...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26704

Abstract Free cells of Rhizopus oryzae were used to study adsorption of several cations (Cu2+, Zn2+, Mn2+, Ni2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The influence of biomass dosage, pH and temperature on the removal process was investigated. The sorption efficiency increased with increasing the temperature in the range from 25 ºC to 30 ºC and pH from 5 to 8. The maximum removal percentage was achieved at a biosorbent concentration 0.25 – 0.3...
Autori: Kolishka Tsekova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26857

Abstract The aim of this study was to determine the content of the main essential trace (Co, Cr, Cu, Mn, Se and Zn) and toxic (As, Cd, Hg and Pb) elements in milk by inductively coupled plasma-mass spectrometry (ICP-MS) and cold vapor atomic fluorescence spectrometer (CV-AFS) following priory microwave-assisted digestion with HNO3-H2O2. The milk samples were collected from local small-scale producers of different parts of Rodnei Mountains, Eastern Carpathians, Romania. Mean concentrations in...
Autori: Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26876

Abstract Trace metal elements commonly exist in drinking water. Excessive exposing on them may result in lots of health problems. This paper mainly focuses on the accumulations of Cu2+, Cd2+, and Pb2+ in drinking water supply networks with amorphous Al(OH)3 formation. The effects of pH, water flow rate, and metal element contents were investigated at laboratory bench scale. It was found that chemical adsorption mainly occurred at pH > 7.0. Suspended Al(OH)3 showed a strong adsorption capa...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26906

Treatment of agrochemical industry wastewater is difficult to carry out unless integration with some advanced oxidation process (AOP) is used. The present study deals with treatment of an agrochemical industry wastewater, first using activated sludge and then with sulfuric acid treated activated carbon (SAAC) in presence of Fenton reagent. During the activated sludge treatment the food-to-microorganisms (F/M) ratio is varied from 0.1 to 0.2 mg chemical oxygen demand (COD) per mg mixed liquor ...
Autori: Makarand Vasant Karkare
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26957

The present study investigates the effect of addition of calcium hypochlorite in the titanium dioxide (TiO2) mediated degradation of bio-recalcitrant wastewater from pharmaceutical industry. The degradation studies were carried out in photoreactor irradiated with ultraviolet (UV) light at 365 nm under slurry mode. The reduction in chemical oxygen demand (COD) was estimated as an index of degradation. The influence of process parameters viz., catalyst dose, pH, oxidant concentration and source...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27097

This study was carried out to monitor the presence of organophosphorus in drainage water (Kafr El-Sheikh (Kotshinar Drainage), Fowa (Fowa Drainge No.11), Metobess (El-Hokss Drainage), Beila (Karakat Drainage), Balteem (Hafeer Shihabeldeen Drainage), Nashart Drainage and El-Hamoul (El-Hamoul Drainage) in Kafr-El-Sheikh Governorate, Egypt. Furthermore, the efficacy of chemical (advanced oxidation processes) and bioremediation (effective microorganisms) for chlorpyrifos removing in drainage wat...
Autori: Aly Derbalah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27104

The removal of quinoline from synthetic wastewater by heterogeneous photo-Fenton in a novel internal circulating fluidized-bed reactor was investigated systematically. The flow field in the reactor was simulated by FLUENT software conjoined with tracer particles experiment, and the influence of reaction parameters such as initial quinoline concentration, catalysts dosage and H2O2 dosage were evaluated. Results indicated that the designed reactor was suitable for the heterogeneous photo-Fenton...
Autori: Ran Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27142

An electro-Fenton process was carried out using undivided cell containing tridimensional graphite felt cathode for treatment of real textile wastewater. The study is essentially focused on effects of pH, applied current and transition metal types (Fe2+ and Cu2+) as catalysts on the electrochemical degradation efficiency based on color and COD removal and BOD5/COD value. The results indicated that pH 3 and applied current of 150 mA are the optimum conditions for decolorization and COD removal of ...
Autori: Akbar Eslami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27167

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

This study aims to evaluate the effects of Fe2+ present in carbonated natural mineral waters on the decomposition of hydrogen peroxide (H2O2) used as sanitizing agent of the collector water tanks and the oxidation of NH4+ to NO3– and NO2– nitrogen compounds from bottled carbonated natural mineral water by the Fenton process. This evaluation suggests that the distribution of the nitrogen compounds, at certain concentrations of H2O2 is influenced by facilitated Fenton reaction in the p...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27279

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

The paper aims to present the sorption properties of two sorbent substrates (composts) prepared by aerobic fermentation from vegetables waste composted with beech sawdust (BR2) and beech ash (BC1) to be used for Cu2+ removal from wastewaters. The composts structures and surface properties were characterised in terms of active groups (FTIR), crystallinity (XRD), morphology (SEM), topography (AFM) and specific surface and pores analysis (BET), and the changes in properties after Cu2+ sorption were...
Autori: Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27323

This study was conducted to evaluate the cyanide removal efficiency by coupled process of Fenton and coagulation/precipitation from aqueous solution. The study was performed at laboratory scale in a batch system. Variations of pH, Fenton and precipitation reagents (molar ratios of Fe2+/H2O2 and ferric chloride), contact time and initial concentration of cyanide were investigated, and the optimum conditions obtained from each of the Fenton and precipitation processes were followed in the coupl...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27426

Decolorization of C.I. Acid Orange 7 (AO7) via TiO2-assisted photocatalysis under UV illumination in the presence of H2O2 has been investigated. The effect of pH on decolorization efficiency of AO7 was investigated in TiO2/UV/H2O2 process. The performance of TiO2/UV/H2O2 system was also evaluated by using synthetic dye-bath effluent of AO7. Solar driven TiO2 photocatalysis was found significantly efficient for the decolorization and degradation of AO7. The rates of decolorization and degrada...
Autori: Ozlem Esen Kartal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27433

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

In the present study the potential of a gene fusion between the arsB promoter from Synechocystis 6803 and the bacterial luxAB genes was evaluated to be used as a cyanobacterial bioreporter for monitoring the bioavailability of inorganic arsenic species. A whole-cell bioreporter strain, designated arsLux, was constructed based on this fusion. In concert with the specificity of the promoter presented earlier, luminescent signal could be detected upon exposure to arsenite, arsenate and antimonite, ...
Autori: Loredana Peca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27473

Galvanocoagulation (GC) utilizing metallic iron chips and granular coke was studied as a potential technique for decolorization of dye-containing aqueous solutions. GC and chemical coagulation by inorganic metallic coagulants such as iron sulfates (Fe2+, Fe3+) were examined for the removal of individual dyes, used in the fur industry, from model aqueous solutions. The role of metal cations when progressively electrogenerated in situ was compared to when they are added simultaneously. The superio...
Autori: Marina R. Sizykh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27526

This paper investigates the macrophyte Azolla pinnata modified with sodium hydroxide, as a bioadsorbent for Cu2+ and Pb2+ ions in synthetic solutions. Biomaterial characterization was performed using Scanning Electronic Microscopy (SEM); Energy- Dispersive X-Ray Spectroscopy (EDX); Fourier Transform Infra-red (FTIR) spectroscopy techniques and through the blocking of carboxylic and sulfonic functional groups. Kinetics of the process has highlighted a quick and efficient adsorption, even in low ...
Autori: Arielle Barros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27532

This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

A wide range and globally active agro-industries such as olive oil processing, winery, tannery, textile and food production discharge a large volume of wastewater containing tannins. Tannins are complex structured chemicals which cause high organic content, requiring high dissolved oxygen in wastewater treatment plants or producing oxygen depletion in the aquatic environment. Tannins are known to be hardly degraded in biological treatment. There has been evidence that the presence of natural ...
Autori: Giusy Lofrano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27885

Advanced oxidation process is getting tremendous importance in the treatment techniques for the removal of nonbiodegradable organics from wastewater due to its ability to completely mineralize the pollutants. It uses different methods to produce hydroxyl radicals which are responsible for oxidation of pollutants. In this work, studies on Fenton, ultraviolet radiation (UV) and UVhydrogen peroxide processes for removing acetamiprid, a neonicotinoid insecticide from aqueous solution are carried ...
Autori: Puthenkattil Abdukunji Fasnabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27895

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

In this research, optimization of Homogeneous Fenton process was performed using Multi-Criteria Decision Analysis (MCDA) and Taguchi method to remove Ciprofloxacin (CIP) from an aqueous phase. Analytic Hierarchy Process (AHP) is one of the most comprehensive systems designed for multi-criteria decision making. In this study, paired comparisons based on the AHP method were performed for three criteria including (i) CIP removal, (ii) COD removal and (iii) Sludge to iron ratio (SIR) to select th...
Autori: Marjan Salari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28040

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

The study is focused on creating magnetic mesoporous materials through the insertion of a nickel ferrite into the structure of kaolintype clay. Sol-gel auto-combustion method was employed to synthesize the materials, using glycine and tartaric acid as chelating/combustion agents. This is the first study on the combined effect of different fuel agents and of clay-to-ferrite molar ratio on the structural, textural, magnetic and adsorptive properties of nanocomposites. The value of the average por...
Autori: Stefana Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28210

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249