Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

AbstractThe paper presents original results concerning concentrations of eight heavy metals in soils adjacent to two improperly built municipal waste deposits located in Eforie Sud and Techirghiol, Constanta County, Romania. Measurements have been done on surface and depth soils, during April-October 2006. The applied analytical technique for metal determination was flame atomic absorption spectrometry (FAAS). The mean measured values ranged as follows (in mg/kg dry weight): Cd: 0.09 - 0.15; Co:...
Autori: , Elisabeta Chirilă, Narcisa Elena Ilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25213

AbstractThe aim of this work was to obtain Ag - doped zeolite as antibacterial material using natural and sodium form of zeolite from Mirsid Romania with the dimensions ranged between 0.8-1.2 mm. The comparative structural characterization of natural and Ag - doped zeolite were performed using Laser Induced Breakdown Spectroscopy (LIBS), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), and Infrared Spectroscopy (IR). In addition, the ion exchange total ...
Autori: Aurel Iovi, Corina Orha, Cornelia Ratiu, Florica Manea, Georgeta Burtica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25220

AbstractSome industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the s...
Autori: Alina Soceanu, , Simona Dobrinas, Vasile Magearu, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25227

AbstractThe health effects caused by air pollutants may range from slight biochemical and physiological changes to difficulty breathing, wheezing, coughing and aggravation of existing respiratory and cardiac conditions. This paper presents an experimental study of air quality in the city of Tg. Jiu, Gorj County, by evaluating the air-floated powders of the PM10 fraction and lead from air. The analysis was performed by measurements in sampling points using the method presented in the European Nor...
Autori: Camelia Capatana, Claudia Maria Simonescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25247

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractThis study deals with the radiolytical decomposition of water molecules, in the presence of some catalysts, getting out hydrogen as unpolluting and cheaper energy vector. Instead of the spent nuclear fuel elements taken out from nuclear power plants, as irradiation source it was used the 60Co radionuclide having a specific activity of 1.1.105 Ci. It was observed that the radiolytic yield of resulted molecular hydrogen from water radiolysis in the presence of used catalysts decreased as:N...
Autori: Ada Macovei, Alexandru Cecal, Dumitru Ganju, , Oana R. Haută
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25354

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

AbstractThe quantification of heavy metals presence in the environment is a very important aspect regarding water quality control. The limits for those metals are very well established by Romanian laws and the essence of every validation report is to prove that the method, the apparatus and the operator can reach the established limits. In the present paper such a validation report is presented, proving the appropriate use of Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICP-AE...
Autori: Irina Dumitriu, , Ioana Raluca Bunghez, Rodica - Mariana Ion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25380

Abstract Human exposure to heavy metals requires special surveillance measures on these elements in human body in order to detect a relation between heavy metal exposure and adverse health effects. The aim of this paper is focused on biomonitoring contamination with heavy metals in fish foodstuffs and in blood, and corroboration of contaminant levels with immunotoxicological effects on target groups of consumers. The final goal is to establish some recommendations on human diet with fish food...
Autori: Aurelia Meghea, Alina Murariu, Cristina Tanase, Eleonora Codorean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25398

Abstract Nanotechnologies may have properties of self-assembly, stability, specificity, drug encapsulation and biocompatibility as a result of their material composition. Nano-particles are being actively developed for tumour imaging in vivo, bio-molecular profiling of cancer biomarkers, and targeted drug delivery. These particles are stable, environmentally benign, and their chemical properties can be easily tailored by chemically modifying their surfaces. Conjugated with pharmacological a...
Autori: Simona-Florentina Pop, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25484

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract When plants are exposed to heavy metals influence, the processes of growth inhibition, ion leakage of all membrane, distribution of pigment and even more death of plants are produced. The physiological and biochemical changes in germinating seedling and cultivation in plastic pots experiments of different plant species (maize, bean, oat, and spinach) were investigated under the influence of copper ions as stress agent. Differences between tolerances against copper excess in the case ...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25578

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract In this work the method for the treatment of industrial waste waters effluents containing hexavalent chromium in three companies during process of treating metal surface with chromic acid is described. Industrial water polluted with hexavalent chromium is collected in separate sewage system. Polluted water is collected in precipitation tanks which are directly connected with neutralization reservoirs. The treatment process includes pre-neutralization by lime-milk, sedimentation, floc...
Autori: Igor Creţescu, Mirjana Cvijovic, Predrag Djurdjevic, Slavica Cvetkovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25596

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

PM10-2.5 and PM2.5 samples were collected from December 2007 to January 2008 at six sampling sites in Urumqi Xinjiang, China. The concentrations of seven kinds of water-soluble ions––SO4 2-, NO3-, Cl-, NH4 +, K+, Na+, and Ca2+––were analyzed using ion chromatography. The concentrations of heavy metal elements, Cr, Co, Cd, Pb, and Hg were measured using inductively coupled plasma mass spectrometry (ICP-MS). The results indicated that, in PM2.5 and PM10-2.5, the average mass concentration ...
Autori: Talip Dilnur, Tursun Yalkunjan, Manabu Igawa, Yimit Abulizihttp://www.ecozone.ro/reviste.php?RID=25683

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

Pollutants transfer via the food chain was investigated in a wetland ecosystem from the Lower Prut Floodplain Natural Park in Romania. Trace elements (Cd, Cu, Pb and Zn) were determined by Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) from samples belonging to primary producers and primary and secondary consumers, and also from water and sediments samples. Non-essential trace elements as Cd and Pb exhibited low concentrations in molluscs and fish, but zinc had shown conc...
Autori: Alin Tudorache, Gabriel Chisamera, Gabriel Lucian Radu, Iulia Gabriela David, Laurentiu Rozylowicz, Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25855

This paper presents original studies about the influence of mineral and/or organic fertilization on the minerals contents (P, Na, K, Ca, Mg, Fe, Mn, Zn, Cu, Ni and Pb) in leguminous plants from permanent grassland situated in a hill area of Banat County. Determination of minerals in grassland is very important both for the nutritional or toxic effects of these elements and their compounds, in the plants, animals and environment. Phosphorous was analyzed colorimetric and all the others metals hav...
Autori: Alexandru Moisuc, Iosif Gergen, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25858

The aquatic species are permanently subjected to various stresses through the ecosystem and the food habit. Elucidating the impact at the cellular level allows us to understand the ways in which the polluting elements and their derivatives can disrupt the metabolism of aquatic organisms triggering apoptosis in individual cells or necrosis affecting groups of neighbouring cells. The aim of this preliminary study is to highlight the influence of the environmental factors on two fish population by ...
Autori: , Camelia Ureche, Dorel Ureche, Gabriel Lazar, Ileana Denisa Nistor, Irina Loredana Ifrim, Iuliana Mihaela Lazar, Marius Stamate, Valentin Nedeff
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25861

In this study, we have tested the possibility of utilization of three types of natural low-cost sorbents: (Sphagnum moss peat, natural moss peat and alkaline treated moss peat) for the active biomonitoring of air quality from Căliman National Park area (Dorna Basin), during of two months (September – October 2010). The concentrations of some heavy metals (Pb, Cd, Cu, Mn and Fe) in the sorbent samples were used as an indicator of the level of air pollution in the studied region. After expo...
Autori: Iulian-Ovidiu Sandu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25868

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Measurements of radium concentrations in water are important from the health protection point of view, so simple and reliable analytical methods must be available. In this paper we have determined the radium activity concentration in 24 spring waters which are used as potable water reservoirs. For this purpose we used radon emanation technique and also alpha spectrometry method. This work gives details of sample processing, Lucas cell and the methodology used in the emanation method. In the meas...
Autori: Alida Timar Gabor, Constantin Cosma, Oana Alexandra Rusu, Robert Csaba Begy, Simina Dreve
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25878

Quantification of the floristic matrix is important both for animal’s nutrition and for the biodiversity monitoring of plants species under the influences of substance flow. Our researches have the main aim to study the possibilities offered by Infrared Spectroscopy in rapid, unpolluted and non-destructive analysis of floristic matrix modification from perennial grassland fertilized with organic and/or mineral fertilizers. It was performed three different FTIR models: for Poaceae (R2=0.949; RM...
Autori: Iosif Gergen, Moisuc Alexandru, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25892

AbstractIn this paper, we report a study on structural evolution, magnetic susceptibility and arsenic content of colloidal pyrite fromXinqiao deposits in Tongling, Anhui Province, China. The pyrite was treated under N2 atmosphere and charaterized with X-raypowder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), magnetic susceptibility analysis, and atomicfluorescence spectroscopy (AFS). We observed that heating of colloidal pyrite in N2 atomosphere did not change the crys...
Autori: Dong Chen, Ping Li, Tianhu Chen, Xiao Zhu, Yadan Shi, Yan Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25951

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe paper intends to contribute to the stages of bioremediation technologies elaboration, by means of experiments and efficiencydemonstrations of adequate biological depollution and ecological reconstruction methods. During the 2009-2011 period, heavymetals and metalloids, etc phytoextraction tests were performed with Lolium perenne L, from tailing samples collected fromwaste heaps and tailings dams of the mining exploitations (Rodna, Bistriţa–Năsăud, Fundu-Moldovei, Sucea...
Autori: Alexandru Crihan, Alin Bolonyi, Bianca Malschi Florian, Cecilia Roman, Dana Malschi, Dorian Brăhaiţa, George Ghira, , Marin Şenilă, Mirela Miclean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26044

The ELSEDIMA International Conference on “Environmental Legislation, Safety Engineering and Disaster Management” held its 9th edition in 2012. This edition was organized by the “Babeş-Bolyai” University of Cluj-Napoca - Faculty of Environmental Science and Engineering, together with the Ministry of Administration and Interior - General Inspectorate for Emergency Situations, the Disaster Preparedness and Prevention Initiative for South – Eastern Europe and S.C. I...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26102

Abstract Being involved in the synthesis of precursors for amphetamine and amphetamine-like drugs, pyridine (Py) may be also regarded as a by-product found when these drugs are obtained via the Leuckart method. Also, pyridine is well known as a biomarker of microorganisms, when those are subjected to pyrolysis before analysis by various instrumental techniques. Consequently, since Py is not commonly found in the air, its presence as a contaminant at trace levels in a room could ind...
Autori: George-Bogdan Ghira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26109

Abstract Avocado post-harvest losses and cultivar-oriented trade are relevant issues in Cameroon that affect producers and retailers incomes. Identifying specific chemical characteristics of avocado oils would give an added value to underutilized species. Five avocado varieties, Booth 7, Booth 8, Collinson, Hickson and Lula, were subjected to aqueous extraction and the Attenuated Total Reflectance-Fourier Transformed Infrared spectrometry coupled with chemometrics (ATR-FTIR) profil...
Autori: Brice Ulrich Saha Foudjo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26143

AbstractThe aim of this study is to elaborate a survey on the efficiency of three anti-aging cosmetic formulations by applying FourierTransform Infrared Spectroscopy (FTIR) with Attenuated Total Reflection (ATR) in order to characterize and identify thespecific recognition markers of the active ingredients. FTIR (ATR) spectrometry in specific regions was applied also to theingredients used in these products, depending on their role in the specific cream. Comparing the different composition of th...
Autori: Anca Maria Juncan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26261

AbstractLithuania is planning to construct a new nuclear power plant nearby the closed one. The possible radioactive pollution can be one of the main problems in its surroundings. Results of investigations of the gamma radiation equivalent dose rate (EDR) at new nuclear power plant sites are presented. Main factors influencing the level of the EDR are identified and evaluated, and geological structure of alternative sites is discussed. The gamma spectrometry data showed that the dominant influen...
Autori: Raselė Girgždienė, Vigilija Cidzikienė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26277

AbstractLead (II) can bind with papain at its active site, destroying the enzymatic activity. Papain a sulfhydryl protease has beenimmobilized in calcium alginate bead for the purpose of removal of lead (II) from industrial waste water. Effect of lead (II) onthe enzyme activity of immobilized papain, has been observed. A detailed kinetic study has been carried out and the data arefitted to different kinetic models. EDS (Energy Dispersive X-Ray Spectrometry) and desorption study suggest that meta...
Autori: Aparupa Bhattacharyya, Parameswar De, Soumasree Chatterjee, Srabanti Basu, Susmita Dutta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26338

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractConcentrations of seven heavy metals (Cd, Cr, Cu, Fe, Ni, Pb and Zn) in the discharged effluents of four wastewater treatmentplants located on the Romanian Black Seacoast, evaluated as average values for four seasons, during 2010-2011 are presented.Total and dissolved metals occurrence was investigated from seasonal samples, to assess the bioavailability of the heavy metalsin the discharged effluents. The analytical measurements were performed by flame atomic absorption spectrometry (FAA...
Autori: Elisabeta Chirilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26498

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractGreywater (GW) has attracted global attention as an alternative water source over the last few decades. GW treatment andreliable reuse require the overall qualitative characterization of samples from different sources. This paper represents aninvestigation of household-generated GW in the Northern Great Plain Region of Hungary. Modern and reliable analyticaltechniques and instruments (ion chromatography, microwave plasma atomic emission spectrometry, Zetasizer Nano Z analysis,etc.) were ...
Autori: Ildiko Bodnar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26528

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract This article presents the results of investigations addressing the accumulation of heavy metals in different layers of the Lake Talkša, Lithuania. For the sampling from the ice of intact structure of the sediment the turf borer was used. Concentrations of these heavy metals in sapropel layers were determined in the extracts of sapropel. After the preparation of samples, the concentration of Pb, Ni, Cr, Zn and Cu were measured in the laboratory by means of atomic absorption sp...
Autori: Justyna Kozlovska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26615

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract Flame atomic absorption spectrometry (FAAS) and X-ray fluorescence spectrometry (XRF) were used as investigation techniques in the assessment of soils contaminated with metals such as Pb, Cu and Zn. The investigation focused on the comparability of the concentrations determined by the two methods, in order to identify the most suitable approach for Pb, Cu and Zn quantification, with respect to metal monitoring in brownfields. Generally, the concentrations obtained through FAAS were...
Autori: Maria Lucia Bizo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26875

Abstract The aim of this study was to determine the content of the main essential trace (Co, Cr, Cu, Mn, Se and Zn) and toxic (As, Cd, Hg and Pb) elements in milk by inductively coupled plasma-mass spectrometry (ICP-MS) and cold vapor atomic fluorescence spectrometer (CV-AFS) following priory microwave-assisted digestion with HNO3-H2O2. The milk samples were collected from local small-scale producers of different parts of Rodnei Mountains, Eastern Carpathians, Romania. Mean concentrations in...
Autori: Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26876

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract Ash resulting from wood combustion constitutes a waste disposal problem to facility owners. The use of ash fertilizer or soil amendment could provide nutrients for agriculture if its nutrient content is adequate and it does not contain harmful amounts of heavy metals. The recycling of nutrients bound in ash would provide an inexpensive solution to waste problem. In our study, we aimed to characterize ash and clinker resulted from incineration of oak waste resulted from wood industry...
Autori: Ioan Oroian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26885

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Various plants were investigated here as bioindicators for control of the environment. Grass, moss and leaves of maple, birch and oak from different locations, i.e., mining, chemical industrial sites and open green area in a small industrial town in the southwestern Poland (Zloty Stok) were examined. Concentrations of As, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Se, Sr, Ti, V and Zn were measured by the ICP-OES and CVG-ICP-OES techniques. Infrared spectroscopy (FT-IR) was used to inves...
Autori: Lukasz Zarebski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26951

Air quality became a concern of highest priority in cities and town agglomerations, worldwide. Professional environmental monitoring strategies are prerequisites for supplying appropriate programmes destined to maintain air quality. Due to their capacity of bioaccumulation, tree species may be used as biomonitoring agents within programmes of monitoring air quality in urban spaces. The present study aims to emphasize the ability of A. hippocastanum L., and T. cordata Mill. leaves to be used a...
Autori: Ilie Covrig
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27026

The multi-parametric quality index (ICPM) is a dimensionless number used to evaluate the overall water quality and it is a useful tool for policy makers and for the public. This study aims to introduce the ICPM algorithm. The ICPM was developed to assess the water quality of the Lower Danube River using information obtained from the analysis of 41 water quality indicators from a monitoring program during 2011-2014. ICPM used the data for the previous 28 months as reference to evaluate the lat...
Autori: Violeta-Monica Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27035

The aim of this study was to determine the impact of mercury pollution on soil, surface water, and sediment ecosystems in the area of old mercury mines. The study was performed in the touristic area of Sântimbru Băi and Sâncrăieni villages from the Harghita County, Romania. More than twenty years ago, a mine for the extraction of mercury operated in Sântimbru Băi. The area was decontaminated, but no monitoring studies have been made for over 15 years. During t...
Autori: Luisa Roxana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27038

In this article we present the results of the study concerning the relationship between the concentration of trace elements (lead, chromium, cadmium, cobalt, copper, zinc and nickel) in soil and in the leaves and bark of Populus nigra L. The samples were collected in the period May 2010 – October 2010 in two areas from the Romanian North Littoral of Black Sea. The concentrations of the trace elements in soil, leaves and bark were determined using Flame Atomic Absorption Spectrometry (F...
Autori: Lucica Barbeş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27239

Different bioleaching processes were applied to mining wastes deposited in the highly polluted post-industrial region - Lower Silesia in Poland. The chemical characterization of the wastes before and after bioleaching processes was performed. The characterisation was based on the distribution of selected elements (Fe, Mn, As, Co, Cr, Cu and Ni) between operationally-defined phases. The phases were defined using a six-step extraction procedure optimised according to the properties of the studie...
Autori: Joanna Pałdyna
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27259

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

Mining activity implies a series of environmental issues that can have short or long term consequences: deterioration of natural landscape, air, water and soil pollution, negative impact on aquatic and terrestrial ecosystems and on human health. The present study was performed on a mine dump from the Giumalau Mountains, Eastern Carpathians, Romania. A number of 28 samples were collected and analysed by ICP-MS for 9 minor elements (As, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn) and also by XRD for the m...
Autori: Madalina Paiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27330

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

This study presents mercury (Hg) assessment in water from tailing dumps collected form NW Romania by using commercial Diffusive Gradients in Thin-films (DGT) devices and Thermal Desorption - Atomic Absorption Spectrometry method (TD-AAS) technique. Additional aim of this study is to present Hg method validation and measurement uncertainty estimation for selected samples. An atomic absorption spectrometer based on thermal desorption for mercury vapor generation and DGT devices specific for Hg (c...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27383

The electronic waste (e-waste) is increasingly flooding Asia, especially in developing countries. E-waste could precipitate a growing volume of toxic input to the local environment if it was not handled properly. This brings the evaluation of environmental impact from electronics an essentially important task for the life cycle assessment (LCA) and the end-of-life management of electronic products. This case study presented a quantitative investigation on the environmental impact analysis on ele...
Autori: Srivalli Chellvarajoo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27384

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

This study analyses the relationship between the scattering properties and the chemical compounds internal mixture of the aerosols near Bucharest, Romania. Several cases of local aerosols influenced by heating sources, like wood or fossil fuel, are characterized in order to retrieve the winter period specificity. Correlation between organic and inorganic aerosols composition from mass spectrometry measurements made with Compact Time (CT) of Flight Aerosol Mass Spectrometer (AMS) and scatteri...
Autori: Luminita Marmureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27444

The paper presents results obtained by analysis of some soil and wastes samples in order to establish the heavy metal (HM) content from these samples. The analyzed wastes were sewage sludge from municipal waste treatment and hydrotechnical basin sludge. These types of wastes were mixed with soil from Oltenia Sub-Carpathian area, obtaining the substrates useful for different types of plants. It was studied the migration potential of the metals from substrate to apple trees, the results being comp...
Autori: Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27476

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

Weakly acidic Litavka and alkaline Malín soils are some of the most contaminated soils by multiple risk elements in the Czech Republic. The aim of this paper was to determine the effect of P sources (rock phosphate, superphosphate), each applied at three rates on the mobility of risk elements (Cd, Zn, Pb, As) and micronutrients (Fe, Mn) in soils and to compare their effectiveness with lime and dolomite tested in our previous study. In 7, 14, 28, and 42 days, we determined CaCl2-extractabl...
Autori: Stanislava Vondráčková
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27521

Tobacco is one of the most important agricultural products in the Republic of Macedonia. Elemental composition of tobacco and soil from different agricultural areas was studied for monitoring purposes. The main purpose was to determine the intensity of accumulation of various elements in tobacco plants and to determine possible relationships between certain chemical and physical properties of soils (pH, clay, cation exchange capacity - CEC, organic matters - OM and total organic carbon - TOC). T...
Autori: Biljana Jordanoska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27625

Bottled water (commonly called mineral) makes an important source of minerals for humans. Its consumption has been systematically rising in the highly industrialized countries, even though not every water type has appropriate health properties. As a result, drinking bottled water ought to be supported with understanding its qualities and physicochemical content. The following article presents the results of the research into pH levels, electrical conductivity, selected inorganic anions (F-, Cl-...
Autori: Rajmund Michalski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27693

The aim of this study was to evaluate the content of Zn, Mn, Cu and Ni in the aboveground and underground shouts of Glyceria maxima and in the bottom sediments of the Słupia River. These studies allow for assessment of the existing and potential hazards resulting from toxic influence of heavy metals on water environment and human health. The concentration of research elements was determined by atomic absorption spectrometry (AAS). Results indicate that the concentration of heavy metals in t...
Autori: Agnieszka Parzych
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27701

Huge amount of red mud has been disposed for the past several decades and it is still generating all over the world. Red mud is a waste of the bauxite processing industry obtained during the alkaline extraction of alumina from bauxite ore. The red mud is a potential raw material containing several valuable components including iron, titanium and rare earth metals. The aim of the research was to develop an appropriate acid digestion technique for the red mud in order to determine the amount of...
Autori: Tatjána Juzsakova1
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27780

The quantification of heavy metals in dry and wet weather derived (runoff and snowfall) sediment from roads, under three different environmental conditions, has indeed the potential to allow improved understanding on urban diffuse pollution. With that aim, the reported study determined the concentrations of Cd, Cu, Pb, Ni, Cr and Zn in road sediment, which are reported to be found in elevated level in the road-traffic environment, and associated pollution levels at four different sites, represen...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27776

The present paper focuses upon the analysis of 226Ra, 232Th and 40K radionuclides, making use of high-resolution HPGe γ-spectrometry devices. By means of this technique, the radiological risk is investigated in the case of various sand samples. The natural concentrations for 226Ra, 232Th and 40K, from sand samples, ranged from (9.3-20.0 Bqkg-1), (9.1-23.7 Bqkg-1) and (203.5-403.3 Bqkg-1), respectively. The radium equivalent activity of sands under investigation was also analyzed and ranged...
Autori: Dorin Vasile Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27775

This study investigated the spatial variability of heavy metal emission patterns and associated measures of contamination on Riccarton Campus at Heriot-Watt University in Edinburgh, Scotland. Road deposited sediments were collected from 12-different sites representing typical urban/sub-urban road layout over a 10 month period covering seasonal variations. The heavy metal concentrations of the road sediments collected from different sites of a road were determined by strong nitric acid digestion ...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27738

Capillary gas chromatography coupled with mass spectrometry technique was used for the assessment of low concentration of dinitrophenol pesticide, Dinocap in different spiked samples. For this purpose it has been spiked with Dinocap (15- 200 μg/mL) five environmental matrices (a soil sample and two each samples of wine and grapes). The Dinocap degradation grade in these samples was also monitored. The extraction was performed in dichloromethane. The assessment of the Dinocap in the samples we...
Autori: Nicoleta Grigoriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27746

A study was conducted to determine the composition and concentration of trace metals in suspended particulate matter (PM10) and indoor dust in two academic buildings of Universiti KebangsaanMalaysia. One building was in the final phases of renovation (UR) and the other building had just finished renovation (AR). PM10 sampling of air was performed using a low volume sampler (LVS), and samples of indoor dust were obtained using a brush and a small plastic bag. The compositions of trace metals in b...
Autori: Mohd Talib Latif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27758

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

In the mineral matter of coal there are microelements chemically bounded to organic matter or mineral impurities in various combinations that catalyzes the evolution / involution of a spontaneous combustion phenomenon as an accelerator in the oxidation reaction or which slows down these processes. Specialised literature analyzes the phenomenon of coal self-heating based on several theories of which we exemplify the theory of coal oxidation, the theory of pyrite and the theory of the microele...
Autori: Cristian Tomescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27966

In order to highlight the impact of environmental pollution for Romanian nursing mothers we evaluated the concentration of heavy metals and trace elements in their blood and breast milk. The evaluation was done taking into account the pollution level of mother’s residence: Bucharest (an industrial and heavy transited town, identified as the highly polluted area) and a small town (without industrial plants, identified as less polluted area). The determination of heavy metals and trace eleme...
Autori: Larisa Prioteasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27973

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

The development of green eco-friendly inhibitors for the corrosion of metallic surfaces in acid media is still considered as a major challenge and target for corrosion-mitigation engineers. We have prepared in this work 4 different extracts from the plant Ruta Chalepensis using methanol, chloroform, ethyl acetate, and aqueous ethyl acetate solvent systems. The flavonoids content, as well as the other oxygenated compounds, in the 4 extracts was carefully screened using the gas chromatographic&nda...
Autori: Meryem Amal Benghalia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28063

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

Wastewater generated from industrial activities has delivered elevated heavy metal concentrations into fresh and salted aqueous systems. Herein, the migrated trace metals were studied from their initial location through a coastal aquifer up to the seawater. The experiments were carried out at lab scale using a sandbox with glass beads and two attached chambers containing natural groundwater and seawater. The study focused on the transport behaviour of heavy metals such as copper, zinc and lead i...
Autori: Abdelkader Tawfeek Ahmed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28111

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

The contamination of aquatic and terrestrial environments by pesticides is highlighted by their possible toxic properties and poor biodegradability on the environment. The development of low cost by products from agricultural sectors as a suitable solution for contaminated areas remediation is of great environmental interest. Straw wastes can be considered as a promising alternative to remove different chemical compound that are environmentally toxic. In this study, some materials derived from ...
Autori: Irina Gabriela Cara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28161

The paper covers the results of a study, carried out during 2005 and 2018, regarding the impact of sludge dump of a wastewater treatment plant from Iasi city, Romania, on the soil characteristics. Experimental research was conducted to highlight the evolution of the heavy metal content of both the material in the storage site and the soil in its proximity. The following heavy metal concentrations were analyzed with atomic adsorption spectrometry method: Zn, Ni, Cr, Pb, Co, Cu and Cd. Research ha...
Autori: Georgiana Cezarina Bartic Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28164

Traditional winemaking for subsistence is at the heart of rural households in traditional cultural landscapes where the bioclimatic conditions allow wine production. As these wines are typically not assessed for their elemental content, their consumers could be exposed to various contaminants. Our goals were the followings: (i) to understand the elemental composition of non-commercial traditional wines from three cultural regions of Eastern Europe (Romania) and (ii) to find the main chemical fac...
Autori: Xintia Odett Dembroszky
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28189

Cultural heritage objects represent valuable testimonies of the past, which must be kept in the right condition to transmit to future generations. Together with the spectacular progress recorded by humankind regarding technology, opportunities to obtain valuable data on heritage objects so as to preserve them have started to emerge. The current researchers aimed to determine the internal composition of the colors and materials used in some paintings from a historic wooden church monument, from ...
Autori: Elena Demenchuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28230

In this paper, seawater heavy metal concentrations (Al, As, Cu, Ba, Zn, Fe, Cd, Co, Cr, Pb, Mn, Mo and Ni) measured by ICP-OES and water quality parameters (NH4-N, NO3-, N, NO3, PO4-P, PO4-3, suspended solids, temperature, conductivity, pH and dissolved oxygen) were evaluated in Izmit Bay (The Marmara Sea). The study was carried out seasonally between December 2016 and September 2017 at four separate sampling stations. The mean concentrations of heavy metals in mg L-1 were: Al: 0.074, As: 0.020...
Autori: Arzu Morkoyunlu Yuce
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28333