An aliphatic-amine-bearing chromatographic support, based on commercial silica, was prepared and tested as potential matrix for affinity immobilization of a copper/topaquinone-containing amine oxidase from lentil seedlings. The support proved to be noticeably effective in immobilizing the enzyme with concomitant purification and activity retention. The immobilization yields and some properties of this preparation were also determined and compared with those of the soluble enzyme. High activity r...
Autori: Barbara Noli, Enrico Sanjust, Francesca Sollai, Giovanni Floris
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25108

<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

Iinclude urmatoarele articole:� Process water of papermaking: model building and characterization� Landfill inventory in the Republic of Moldova: problems and solutions� Floodplain revegetation and river basin restoration� Environmental problems of copper complex in Bor area� Researches on air micro flora determination from public indoor spaces and hospital wards in an urban area� Current practice of solid waste management in Malaysia and its disposal� An assessment of potential he...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25199

AbstractThe paper discusses some environmental problems caused by the presence of the copper mining and processing complex in the Bor area (Eastern Serbia). The Bor area is a serious hot spot in Serbia. Unsupervised operation of the mining company RTB Bor, without any protective measures, has led to extreme pollution of the Bor River, the Danube and underground waters, soil pollution with heavy metals, air-pollution with sulfur-dioxide etc. Recommendations are suggested as follows: a sustainable...
Autori: Slavka Zeković
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25137

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

Contain all the articles from this issueEnvironmental analysis by capillary electrophoresis. Atmospheric samplesCamelia Draghici, Gheorghe Coman, Mihaela Sica,Dana Perniu, Mihaela Badea   The ecological farms - A solution for sustainable agriculture. II. Position and perspectives of the ecofarms in the frame of the productive agricultural system Stela Axinte, Alina Stanciu, Lorica Axinte  The extraction and clean up of organochlorine pesticides and PCB's from water using solid phase ex...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25170

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

AbstractThe extraction of some pollutants from different matrices, the treatment of hazardous and infectious wastes, the destruction of refractory compounds and the prevention of noxious emissions are the main environmental applications of microwave-assisted chemistry. The advantages and disadvantages of this technique are also considered....
Autori: Carmen Zaharia, Georgiana G. Surpăţeanu, Mioara Surpăţeanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25217

AbstractAn assessment of acide drainage forming potential for a mining waste material resulted in a former mine of nonferrous and precious metals ore has been made. The waste material has the following contents: 2,20?ˇ2,28% sulphide sulphur, 2,53?ˇ2,58% Fe, 0,07% Cu, 0,05% Zn, 0,36?ˇ0,40% Pb, 0,008?ˇ0,013% Ca and 3,85?ˇ7,97% sulphate. Bacterial leaching tests in percolating columns during 380 days have been made. The leaching liquor has been recirculated at a liquid:solid ratio of 1L:1kg. After ...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25239

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractThe comparative study on reactive extraction of p-hydroxybenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar s...
Autori: Anca-Irina Galaction, Dan Caşcaval, Maria Cămăruţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25250

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractIn Serbia, the more recent sustainable development policy faces a number of serious problems, which are emphasized by the slow pace at which post-socialist r,eforms have been performed. Environmental aspects of transition reforms have hardly been tackled so far, the copper complex in the area of Bor (Eastern Serbia) being a notable example of such a delay. In effect, the practice of a more rigorous and systematic ex ante evaluation of possible future development scenarios is at its very ...
Autori: Miodrag Vujosevic,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25282

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractSoil pollution causes significant damage to the environment and human health as a result of their mobilities and solubilities.Significant progress has been made in regulating soil pollution, with a parallel development of methodologies for soil assessmentand remediation. The selection of the most appropriate soil and sediment remediation method depend on site characteristics, concentration, type of pollutants to be removed, and the end use of the contaminated medium. The approach include...
Autori: Attar Singh Sheoran, Poonia Poonam, Vimla Sheoran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25291

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractA greenhouse experiment was conducted to determine the phytotoxic effect of heavy metals such as Cd, Cu, Ni, Pb and Zn on the growth of Sunflower (Helianthus annuus): on the seed germination, root/shoot growth and uptake of metals in soil-vermicompost media. The selected metals were dosed at various concentrations ranging from 0, 5, 10, 20, 40 and 50 ppm separately in soil - vermicompost media (3:1) in pot experiment. The seed germination, root and shoot growth were found significantly a...
Autori: Chhotu D. Jadia, Madhusudan H. Fulekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25306

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractThe work presents the negative environmental impact produced by an extraction of crude oil activity. To highlight and quantify the negative effects on the environment produced from such activity, the experimental part has been focused on evidence of samples of soil, water from groundwater aquifers and surface, and the air emissions. The values of quality indicators are presented in graphs and tables, highlighting an activity with all major impact on the environment....
Autori: Aurica Grec, Corneliu Maior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25326

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractPaint sludge of automotive industry contains heavy metals and other toxic substances. Due to this matter, it has a high pollution potential. Incorrect disposal of paint sludge led to kinds of environmental pollution. Recycling and reusing of wastes can be one of the best solutions for decreasing of pollutant entrance to environment. The purpose of this study was to present a new method of extracting the main components of paint sludge, for determining concentration of elements in paint s...
Autori: Azadeh Akhavan Bloorchian, Seyed Mostafa Khezri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25346

AbstractA present challenge for research is to determine how to use the combination of oil, gas and coal most efficiently with the minimum environmental damage. In this paper the authors have compared technologies to produce the electricity using natural gas and coal. The objective of this paper consists in evaluation of the life cycle assessment of the natural gas and coal in order to compare their greenhouse gases (GHG) emissions. In this way, three systems with and without CCS were examined: ...
Autori: Adrian-Alexandru Badea, Cristian Dincă, Gheorghe Lăzăroiu, Tiberiu Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25355

AbstractPulsed high voltage discharge technology is a newly developed method for knock out viruses in blood with various electrohydraulic discharge reactors. The aim of this study is to investigate the effect of an electrohydraulic discharge treatment system on Hepatitis C virus (HCV) behaviour. The electrohydraulic discharge (EHD) reactor consist of high voltage point discharge electrode above blood surface and cylindrical ground copper electrode containing the blood (in the same time act as th...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25362

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract Spent hydroprocessing catalysts from petroleum refining industries have been classified as hazardous wastes due to their content in heavy metal and persistent organic pollutants (POPs). The aim of our paper determine the polycyclic aromatic hydrocarbons (PAHs) residues contents in spent catalysts samples from four different units of the Romanian refinery Rompetrol Rafinare,Constanta: Hydrogen (H), Gas Desulfurization Sulfur Recovery (GDSR), Hydrofining Turbojet Kerosene (HTK) and Pet...
Autori: Camelia Draghici, , , Gabriela Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25449

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract The paper presents the results obtained when using thin films (doctor blade) of titanium oxide powder (Degussa P25) and fly ashactivated with NaOH, for advanced treatment of complex waters resulted in the textile industry. There are studied the heavy metal(cadmium, copper) adsorption and the dyes (methyl orange and methylene blue) photo-degradation using these novel substrates.The thin films crystallinity (XRD), morphology and roughness (AFM) were evaluated and no significant changes...
Autori: Anca Duta, Luminita Andronic, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25500

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract The use of appropriate leaching tests and leaching models can help to predict the hazardous components release from cementbased solidified waste during either utilization or disposal. Numerous parameters influence the leaching rates such as grain size/specimen size,ccc liquid-to-solid ratio, pH value of the leachate, leaching time etc. This study evaluates the effect of initial liquid-to-solid ratio of cement paste on the release of copper from cement-based solidified waste. Dynamic ...
Autori: Constantin Bobirica, Liliana Bobirica, , Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25527

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract The paper makes qualitative and quantitative analyses of heavy metal contamination of surface waters in Iasi City. The examination of data acquisited from the specific sections of the rivers Bahlui (upstream section, Iasi water treatment plant, Holboca section, downstream section, Iasi water treatment station), Nicolina (quarterly data from the established monitoring system) was performed, based on data provided by the Environmental Protection Agency of Iasi District and Prut Water D...
Autori: Corneliu Horaicu, Florea Cornel Gabrian, Irina Grozavu, Catalin Constantin Calu, Monica Horaicu, Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25546

Abstract White mustard (Sinapis white) is an annual plant of the Cruciferae family originating from the Mediterranean region and is cultivated in Europe and Asia, mainly for its seeds, but also for animal feed or crop rotation. White mustard seed is also an important source of vegetable oil that can be used as fuel. The chemical composition of mustard seed (Sinapis alba) includes glucosinolate (sinalbozida, sinapina free), essential oils, fatty oils (glycerides of oleic acid, linoleic, linole...
Autori: Camelia Ciubota-Rosie, Rodica Diaconescu, Irina Volf, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25561

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract When plants are exposed to heavy metals influence, the processes of growth inhibition, ion leakage of all membrane, distribution of pigment and even more death of plants are produced. The physiological and biochemical changes in germinating seedling and cultivation in plastic pots experiments of different plant species (maize, bean, oat, and spinach) were investigated under the influence of copper ions as stress agent. Differences between tolerances against copper excess in the case ...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25578

Abstract The present paper proposes an integrated-treatment process of leachate from a municipal landfill, which involves two treatment steps. The first step consists in diminishing the organic content through an advanced oxidation process using ozone and hydrogen peroxide. The second step is performed in order to diminish the content of heavy metals through a sorption process on a natural low-cost biosorbent, thus the traces of organic substances remained after oxidative degradation or oxida...
Autori: Carmen Paduraru, Corneliu Pohontu, Igor Creţescu, Lavinia Tofan, Marius Sebastian Secula, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25589

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

Abstract The Air Quality Management problem calls for detailed, case-specific knowledge and requires, due to legal mandates, the development of operational, environmental parameter related, incident forecasting. Both targets can be met by applying Artificial Intelligence (AI) methods, and by employing relevant computational algorithms that are capable of producing reliable results. The current paper provides with an overview of the problem domain, identifies goals and proposes methods that ma...
Autori: Kostas D. Karatzas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25616

Abstract The olive mill wastewater (OMW) is a stable emulsion composed by water, olive pulp and residual oil. An approach for using this waste as a renewable resource is of greater interest. Several authors have been studding physicochemical treatment methods. However, the biological treatments allow not only the treatment, but also the effluent valorization, by producing several valuable products. This effluent is also a source of natural antioxidants and its extraction is economically attra...
Autori: Carina Pereira, Cristiana Goncalves, Isabel Belo, Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25635

? SUSTAINABLE CONCRETE HARDENING PROCESSES IN NORMAL CLIMATIC AND THERMAL TREATMENT CONDITIONS ? THE ENVIRONMENTAL DIMENSION ? AN INTERDISCIPLINARY RESEARCH AREA ? MENU PLANNING STRATEGY BASED ON ECOLOGICAL FOOTPRINT ? EVALUATING ENVIRONMENTAL IMPACT OF NIGERIAN COMPOSTED WASTES USING LABORATORY EXTRACTION TEST ? IN SITU RADIOFREQUENCY FIELD LEVEL ASSESSMENT IN TWO URBAN AREAS IN ROMANIA: OPEN QUESTIONS TO ELECTROMAGNETIC POLLUTION ? INNOVATIVE SOLUTION FOR WARNING ON HI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25657

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

Abstract:The oxidation of low grade complex concentrates (Cu, Pb and Zn) in aqueous media (weak alkaline) oxidized nonferrous metalsconcentrates is carried out at high pressure. Leaching is the subsequent processing step in metal extraction. The paper studies theinfluence of some parameters (temperature, time, L:S ratio, excess) on the leaching efficiency of nonferrous metals from oxidizedconcentrate. The optimum parameters determined are: S/L ratio of 10/1, 25% reactive excess, leaching tempera...
Autori: Cornelia Lupu, Dragoş Taloi, Liliana Gherghe, Luminita Mara, Teodor Velea, Vasile Predica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25774

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

Polycyclic aromatic hydrocarbons (PAHs) are by-products of petrol transformation; a report prepared by ICON, London, United Kingdom in 2001, showed that the principal sources of polycyclic aromatic hydrocarbons in wastewater are domestic usage, storm runoff and commercial effluent. This work presents the results on 14 commonly occurring and/or highly carcinogenic PAH compounds listed as priority pollutants by the United States Environmental Protection Agency and the European Union. Wastewater sa...
Autori: Dumitru Ristoiu, Edward Muntean, Livia Alhafez, Nicoleta Muntean, Radu Mihaiescu, Tania Mihaiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25847

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The metal sensitivity and selectivity of two fluorescent proteins was investigated. The studied proteins are mutant forms of the red fluorescent protein (DsRed); according to our results, both proteins showed sensitivity to the presence of copper[II] and nickel ions. The fluorescence intensity of the proteins has decreased significantly in the presence of copper ions in the micromolar range. Metal binding by these proteins is a reversible process, as addition of a chelating agent liberates the b...
Autori: Beata Abraham, Ildiko Miklossy, Judit Petres, Laszlo Szilagyi, Maria Szabo (Palfi), Szabolcs Lanyi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25870

The herbicide use can be seen as an auxiliary path for new farming methods, providing more advantageous farming and land use capabilities and increasing crop yields. Some of them are quickly degraded but others persist in the environmental compartments being toxic for human health and the environment.The aim of this study was to evaluate the impact of some triazine herbicides from agricultural sources on quality of well and surface water, in two regions of Romania with different agricultural act...
Autori: Andreea Dragus, Mihail Simion Beldean-Galea, Radu Mihaiescu, Tania Mihaiescu, Dumitru Ristoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25889

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractThis paper deals with the experimental investigation related to removal of hydrogen sulfide from simulated groundwater byadsorption/oxidation on activated carbons. Carbonaceous adsorbents were synthesized from peach stones by physical-chemicalactivation method and modified by oxidation following impregnation with Cu2+ by ion-exchange method. Obtained carbonaceousadsorbents were characterized by specific surface area and micropore volume. Surface chemistry properties were evaluated usingB...
Autori: , , Vasile Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26026

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

AbstractThe paper intends to contribute to the stages of bioremediation technologies elaboration, by means of experiments and efficiencydemonstrations of adequate biological depollution and ecological reconstruction methods. During the 2009-2011 period, heavymetals and metalloids, etc phytoextraction tests were performed with Lolium perenne L, from tailing samples collected fromwaste heaps and tailings dams of the mining exploitations (Rodna, Bistriţa–Năsăud, Fundu-Moldovei, Sucea...
Autori: Alexandru Crihan, Alin Bolonyi, Bianca Malschi Florian, Cecilia Roman, Dana Malschi, Dorian Brăhaiţa, George Ghira, , Marin Şenilă, Mirela Miclean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26044

AbstractThe scope of the present paper is water management dimensioning closed to the copper mining area in the Medet region(Bulgaria). The mining works left an open pit and several waste rock dumps within the catchment area of Medetska River. Atpresent although the flooding of open pit is going on, it will be finished approximately in 2018. Water treatment is necessary dueto the high concentrations of pollutants (sulphate and copper) in the waters influenced by mining. The objective of the stud...
Autori: Gabriela Biali, Petra Schneider, Ralf Löser
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26077

AbstractThe present study reports the efficiency of almond shell as a cheap and available material for the removal of Cu (II) fromcontaminated aqueous solutions. The equilibrium experiments indicated that Cu (II) sorption obeyed the Langmuir isotherm at26, 40 and 55oC. The highest value of the maximum uptake (Qo) from the Langmuir equation was found 6.783 mg g-1 at 40oC.The various thermodynamic parameters such as ΔGo, ΔHo and ΔSo were also calculated. The values of ΔGo varie...
Autori: Soheil Aber
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26080

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Waste recycling represents a very significant issue for the protection of our environment. Large waste quantities (slag and ashes) are products of the coal extraction industry and its subsequent combustion in thermal power stations. The possibilities of obtaining crystallized glasses in the CaO-Al2O3-Fe2O3-SiO2 system by introducing in the raw materials mixture ashes from Mintia Deva thermal power station have been studied. The physical and chemical characterization of the...
Autori: Firuţa Goga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26121

Abstract Heavy metals are common contaminants of freshwaters and they can produce toxic effects on aquatic fauna and flora. The ions of heavy metals existing in freshwaters are well known as toxicants for the aquatic organisms. Duckweed is an aquatic plant of small size that floats on fresh water surface of lakes and marshes. The small plants are highly exposed to aquatic pollutants and as a result they are very sensitive to the toxic effects. As consequence the duckweed plants are...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26122

Abstract Avocado post-harvest losses and cultivar-oriented trade are relevant issues in Cameroon that affect producers and retailers incomes. Identifying specific chemical characteristics of avocado oils would give an added value to underutilized species. Five avocado varieties, Booth 7, Booth 8, Collinson, Hickson and Lula, were subjected to aqueous extraction and the Attenuated Total Reflectance-Fourier Transformed Infrared spectrometry coupled with chemometrics (ATR-FTIR) profil...
Autori: Brice Ulrich Saha Foudjo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26143

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractThe Iraqi Marshlands, the largest wetland in the Middle East and one of the most outstanding in the world have been lost mainlyas result of drainage and damming. This study analyzed the dynamics of land use/cover change in Iraqi Marshlands Region from1973 to 2011. In this process, we established the land use/cover classification system and remote sensing interpretationcharacteristics. A laminar extraction technique was used in the identification of typical attributes of land use/cover ty...
Autori: Hongxia Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26168

AbstractThe solidified waste drilling mud has been landfilled into slurry ponds with impermeable layer at oil & gas field since 1990s. Thisarticle aims to elucidate the heavy metal contaminations from landfill ponds at semiarid region. The heavy metal concentration inthe waste and its potential mobility based on its binding forms was studied. Furthermore, the blocking effect of impermeable layer was used to elaborate the environmental effects of heavy metals. From the analysis, Cr was found ...
Autori: Yun Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26171

AbstractPotential of unmodified Wheat Straw as an adsorbent for the removal of lead and copper was studied. Effect of pH, adsorbentdose, contact time and initial metal concentration on the removal of the metal ions were also investigated. Maximum removal oflead was found to be 43.55% by wheat straw under optimum conditions (pH=5, adsorbent dose=16g/L, contact time= 240minutes, metal concentration=100 mg/L). Unmodified Wheat straw removed 0.381 mg/g of lead. While 56.36% copper removalwas achieve...
Autori: Mehwish Anis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26209

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractIn this work the adsorption of Cu2+ and Zn2+ from industrial wastewater by peanut shells without any pretreatment wasinvestigated through optimization techniques such as a feed-forward back-propagation artificial neural network and a simplexalgorithm. The Levenberg-Marquardt algorithm was the best back-propagation algorithm, with a minimum mean squared error of0.000217 for Cu(II) and of 0.000229 for Zn2+. Mean square error on the validation set is used as an estimate for variance.Accordi...
Autori: Başak Mesci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26227

AbstractFluoride content in some available teas, dry leaves and tea infusions were determined, in order to check the influence of brewingtime on fluoride content in tea and to compare the percent extraction of fluoride releasing during tea infusion time. A fluoride ionselective electrode was used to determinate the fluoride content in tea samples (Hypericum perforatum, Tilia cordata andCamellia sinensis). Total fluoride contents of tea leaves were determined to be 91.1 - 162 mg/kg d.w., and 0.09...
Autori: Semaghiul Birghila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26242

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractThe road infrastructure has a major environmental impact by covering important land surfaces and consuming enormous amounts of raw materials for construction and maintenance. The impact of transport pavements needs to be considered from the design stage and to be examined during the whole life cycle of the infrastructure: raw materials extraction and initial transformation, manufacturing, placement on site, exploitation, maintenance, and demolition. This paper evaluates the impact of asp...
Autori: Isabela Maria Simion, Laura Dumitrescu, Maria Gavrilescu, , Radu Andrei, Sebastian George Maxineasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26297

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractThe distribution and fractionation of nine heavy metals (Cr, Co, Ni, Cu, Cd, Zn, V, Pb and As) in the sediments of Lake Chaohu,a shallow eutrophic lake, were investigated using the BCR sequential extraction procedure. The level of pollution attributed tothese nine heavy metals was evaluated employing the potential ecological risk index (RI) and geoaccumulation index (Igeo). Metalconcentrations in sediments ranged from 65.00~104.00 for Cr, 14.50~21.70 for Co, 28.50~50.90 for Ni, 25.40~51....
Autori: Beidou Xi, Fengyu Zan, Guangchao Zhao, Jing Su, Kevin M. Yeager, Shouliang Huo, Xiujuan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26321

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractThis paper discusses some environmental problems caused by the mine waste from the Copper Mine Bor in Serbia. The CopperMine Bor and the Smelter generated about 2x109 tones of waste materials, located in the vicinity of the Bor. They cover mining,flotation tailings and smelting slag wastes. The existing mine waste have been formed during a hundred-year-old of mining andmetallurgical activities in Bor. Also, new quantities of wastes (up to ten thousand tones) have been produced daily by u...
Autori: Jovica M. Sokolović, Novica Milosević, Rodoljub D. Stanojlović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26334

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

AbstractThe supply of building materials in the city of Kinshasa is one of the major challenges for sustainable development andespecially at this time when the authorities are committed to rebuild the country and to rehabilitate the basic infrastructure,mobilization and knowledge of these materials appears to be of paramount importance. In this context, the Kinshasa morphologywill change day by day because of the operations of construction materials extraction, to meet the needs of the populatio...
Autori: Holenu Holy Mangenda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26428

AbstractThe main objective of the current research is to determine the content of heavy metals from the Bistrita river banks, respectivelyupstream of Bacau city, Romania, in Bogdan Voda area, and downstream of Bacau city. Because of their bio-accumulationtendency heavy metals can generate a negative impact on soil, as well as on certain physiological and biochemical indicators ofplants and animals metabolism. The selection of sampling points (upstream and downstream of Bacau city) took intoconsi...
Autori: Cristian Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26436

AbstractVegetables are an important part of a healthy diet because of their nutritional value. Contamination in vegetable may provehazardous for population. Polycyclic aromatic hydrocarbons (PAHs) are compounds widespread in the environment, many ofthem showing carcinogenic effects. These compounds can reach the food chain by different ways and, therefore, the analysis ofPAHs in food is a matter of concern.The present work provides data regarding levels of PAHs: acenaphthene (Ace), acenaphthylen...
Autori: Alina Soceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26510

AbstractThe mining waste facilities in the Baia Mare region, Romania, resulted from the extraction of poly-metallic ores (including Au,Ag). Metal sulphide minerals from the mining waste facilities have a potential to produce acid rock drainage (ARD) and togenerate risk for the environment, including for the water resources. Some of the mining waste deposits from the region arelocated near the town of Baia Mare, close to the residential areas, the agricultural lands and the surface water. The sho...
Autori: Oana-Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26512

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractAtomic absorption spectrophotometry (AAS) technique was applied in order to identify the occurrence of certain heavy metals insamples of pork products, such as bacon, ham, sausage and salami, taken from four commercial centers in Romania. Lead levelsin samples varied from 0.58 to 0.96 mg/kg, Cadmium values from 0.11 to 0.21 mg/ kg, Copper from 0.73 to 1.32 mg/kg, whileZinc levels were detected between 32.19 and 42.12 mg/kg. Lead, Copper and Zinc found in samples were lower than themaximu...
Autori: Gabriel Vasile Hoha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26522

AbstractHeavy metals in sludge have been one of the limiting factors for sludge reclamation, and therefore the changes of heavy metalsduring sludge treatment process should be concerned. This study investigated the detailed profile of changes of seven typicalheavy metals (As, Cd, Cr, Cu, Ni, Pb, and Hg) in the activated sludge during ultrasonic treatment process. The influences ofsonication time and ultrasonic power density were studied. Results showed that heavy metals in sludge were released i...
Autori: Tian Wan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26563

AbstractThis study aims to understand the acid-leaching behavior of metals from 2 to 4 mm waste printed circuit boards (WPCBs)containing 22.0% ą 1.1 Cu, 6.7% ą 0.2 Ca, 0.68% ą 0.02 Sn, 0.59 ą 0.01 % Pb, 2.71% ą 0.08 Al, 0.22% ą 0.01 Fe, etc..Copper leaching was increased for sulfuric acid concentrations up to 1.2 mol/L and hydrogen peroxide concentrations of 10.0vol% for a pulp density of 100 g/L at 50°C over 4 h, whereas for the same concentrations of sulfuric acid and hydrogen peroxidecopper l...
Autori: Manoj Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26566

AbstractPresent study was envisaged to study chelators-metal interaction in phytoaccumulation of metals as a bioremediation technologyto decontaminate metal pollution and adsorption of metals on soil. Lactuca sativa was used as model plant for phytoaccumulationto identify uptake of Cadmium (Cd) and Lead (Pb) and their subsequent accumulation in edible tissue of plant. Cadmium andlead were two selected metals for phytoaccumulation and copper was also studied for adsorption experiment. Green house...
Autori: Audil Rashid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26568

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract The present study was conducted to determine the heavy metals (Fe, Mn, Zn, Cu, Pb, and Cd) and essential oils content in the berries of Juniperus phoenicea L. grown in two different geographic origins; Dana conservation and Al-Hisha forest in Jordan. Atomic absorption and Hydrodistillation methods were used to determine heavy metals concentrations and oil contents in plant samples of J. phoenicea L., respectively. Results showed that, the oil yielded from J. phoenicea L. berries in ...
Autori: Mohammad Sanad Abu-darwish
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26595

Abstract This study evaluates the potential of Crambe abyssinica press cake, a residue from crambe oil extraction and/or biodiesel production, as an adsorbent for removal of cationic dyes from wastewaters. Batch adsorption tests were performed at 30, 40 and 50oC. Adsorption kinetics and equilibrium were satisfactorily described by the pseudo second-order and Freundlich models, respectively. Adsorption was spontaneous and exothermic. Fixed bed adsorption (breakthrough curve) was satisfactoril...
Autori: Adriana S. Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26597

Abstract Due to its very low moisture content, the solid waste from the two-phase olive oil extraction process (dry olive mill residue, DOR) can be easily stored and used as a readily available basal liquid culture medium via its reconstitution with water. Five white-rot fungi (namely Phanerochaete chrysosporium NRRL 6361, Lentinus tigrinus CBS 577.79, Pleurotus pulmonarius CBS 664.97, Phlebia radiata DABAC 9 and Botryosphaeria rhodina DABAC P82), previously selected in a screening program, ...
Autori: Alessandro D’Annibale
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26598

OPTIMIZATION OF REDUCTION OF COPPER USING Stenotrophomonas maltophilia PD2 BIOMASS AND ARTIFICIAL NEURAL NETWORK MODELING ...
Autori: Arpita Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26616

Abstract Samples were collected for six months (nine storm events) to observe the contaminant loads from three highway segments at Rawalpindi, Pakistan. The contaminants analyzed include total suspended solids (TSS), total dissolved solids (TDS), total nitrogen (TN), chemical oxygen demand (COD), total organic carbon (TOC), total phosphorous (TP), sulphate (SO4), chloride (Cl-), iron (Fe), copper (Cu), zinc (Zn), lead (Pb), and chromium (Cr). Mass vs. volume [M (V)] curves were drawn to inve...
Autori: Hamid Iqbal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26617

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The caraway (Carum carvi L.) samples were collected from little meadows situated in Harghita Mountain (Mădăraş Ciuc, Harghita Băi, Jigodin, Tuşnadu Nou), where a relatively small area was covered by a group of rich populations of wild cumin. The harvested plants are dried by: a) convective laboratory dryer in thick layer, b) static outdoors in sunshine, and (c) static in a warm indoor place in darkness. The hand-picked seeds were separated from debris by sie...
Autori: Csaba Dezső András
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26646

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Supercritical fluid and ultrasound assisted extractions were applied as a first step in a complex processing of spruce bark in order to recover polyphenols compounds. The aim of the study was to compare the efficiency of these "green" processes with a conventional extraction technique (ethanolic extraction). Supercritical fluid extraction was carried out in two steps: (i) static extraction for 15 min at 1000 psi with pure CO2 and (ii) dynamic extraction for 45 min at 35, 4...
Autori: Adina Iulia Talmaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26680

Abstract In the process of chitin extraction, shrimp shell powder was treated by Lactobacillus plantarum culture. The efficiency of microbial demineralization (DM) under aerobic and anaerobic conditions was investigated. The shrimp shell powder was incubated at 30 °C for 6 days with L. plantarum. In order to prepare microbial culture, inoculums size was 5% for culture inoculation. Date syrup with total reduce sugar concentration of 30 g.L-1 was used. The value of pH in anaerobic conditio...
Autori: Marjan Khorrami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26692

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract The removal efficiency of algal biomass Chlamydomonas reinhardtii for Pb and Cu metal ions was evaluated in single and binary metal systems. Biosorption experiments were performed in solutions containing 0.2 g L-1 of algal biomass at 30oC and pH 6. Initial metal ion concentrations ranged from 10-7 M to 10-6 M. Thermal analysis of the biosorbent indicated that algal cells are composed of groups containing C, H, N, and S. The presence of ionisable functional groups responsible for bio...
Autori: Roula Flouty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26709

Abstract Total anthocyanins were extracted from six sweet cherry cultivars grown in Sakarya, Turkey. In vitro inhibition effects of the extracted total anthocyanins on purified carbonic anhydrase I and II were investigated using CO2 as a substrate. All the extracted total anthocyanins inhibited the activity of the human carbonic anhydrase (hCA) I and II enzymes. Among all the cultivars, ‘Karakiraz’ was found to be the most active on both hCA I (IC50 = 30.59 μg/mL) and hCA II a...
Autori: Taki Demir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26715

Abstract Response surface methodology and central composite experimental design were used to model and optimize the operational parameters of the excess sludge protein extraction yield by ultrasonic wave-assisted extraction. The three variables involved in this research were the ultrasonic extraction time, pH, and temperature. In the range studied, statistical analysis of the results showed that selected variables had a significant effect on protein extraction yield. The optimized extraction...
Autori: Yulin Xiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26736

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract The aim of this paper is to determine the heat of combustion of plastic wastes resulted from municipal solid waste, automotive shredder facility waste and building and construction waste. The plastic wastes have been separated by flotation technique using as flotation media: water, ethanol, their mixtures and magnetic fluid. Resulted fractions have been analyzed aiming to determine the most effective fraction from the heat of combustion point of view. The obtained results have been ...
Autori: Liviu Costiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26750

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract This study was aimed to stimulate laccase production by Trametes pubescens MUT 2400 by using a tomato-based medium. Two sequential 2x2 factorial designs were used to determine the effect of carbon (C) and nitrogen (N) source concentration on laccase activity and biomass concentration; copper was used as the sole inducer (0.75 mM). Analysis of the first factorial design showed that N had a strong positive effect on the maximum laccase activity, which occurred at day 12 of cultivation...
Autori: Federica Spina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26795

Abstract Vacuum-tube thermal collectors are used to collect heat radiated by the sun. This heat is then used to drive the forced evaporation of concentrated seawater (saltwater) released by reverse osmosis and the extraction of NaCl. This paper reports heat consumption during evaporation. About 78.90% of seawater has to be evaporated in advance through insolation to initiate forced evaporation. This step is conducted to precipitate the NaCl because only CaSO4·2H2O are initially precip...
Autori: Huaigang Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26813

Abstract It has been shown that the scale of damage in buildings with steel reinforcement, due to direct lightning strikes, is insignificantly small compared to lightning effects on buildings with no such steel reinforcement. Observed small-scale damages are also confined to points of strike; hence the only risk for occupants and properties is injury or damage caused by falling materials. A large number of such cases have been observed in Sri Lanka and Malaysia. All damaged structures, obser...
Autori: Chandima Gomes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26821

Abstract The paper describes a numerical analysis concerning the behaviour of Cu and Ni based catalysts having different mole ratios of Ni to Cu in the process of glycerol hydrogenolysis. The impregnation technique was used to prepare the copper and nickel based catalysts. Our study revealed that their performances are different and depends on the Ni/Cu ratio. The catalysts were tested using various reaction conditions, such as time and temperature, and their performances analysed based on t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26843

Abstract Urban Tree Canopy (UTC) is an important asset in the urban ecological system by reducing the heat, runoff and improving air quality. Estimating the available urban tree canopy is important for decision makers for better understanding of urban ecosystems and helps to improve environmental quality and human health in urban areas and plan conservation activities. This paper reports on an object-oriented tree extraction method developed by using spectral and textural information of High...
Autori: Muneeswaran Mariappan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26858

Abstract The aim of this study is to investigate the copper (Cu), nickel (Ni) and chromium (Cr) levels in cultivated black tea in north of Iran. The infusions of Cu, Cr and Ni in tea after 5, 15 and 60 min brewing time were measured. Results showed that the highest (2.32±2.63 mg/kg) and the lowest (2.16±1.84 mg/kg) mean levels of Cu were observed after 15 and 60 min, respectively. The mean levels of Ni and Cr at 60 min were the highest (13.72±8.09 mg/kg and 1.30±1...
Autori: Azita Mohagheghian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26865

Abstract Parkinson's disease (PD) is a neurodegenerative disorder that occurs due to a progressive degeneration of dopaminergic (DA) neurons. Brain area affected by progressive destruction of neurons controls movements, and patients with PD reveal rigid and uncontrollable gestures, postural instability, small handwriting and tremor. There are some risk factors that have been proven to trigger PD with a certain probability (for example insecticides exposure, and genetic and environmental ...
Autori: Oana Geman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26868

Abstract Municipal (urban) wastewater treatment creates environmental problems, especially in urban areas where urban waste water and industrial waste water have a common treatment system. The present paper aims at describing a method which facilitates the mixing of resulting sludge with metallurgical coke in the process of iron agglomeration due to the heat input brought about by the combustibles in their composition. This method may be applied to reduce the huge quantities of sewage sludge...
Autori: Catalina Iticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26870

Abstract The adsorption of phosphorus (P) on sediment plays a significant role in phosphorus transport in aquatic systems. This research examined the effect of the main components of sediments (including iron (Fe), manganese (Mn) oxides and organic matter (OM)) on P adsorption and to evaluate their relative contribution with different sediment particle sizes. The sediments were separated into four particle-size fractions: 0-30 μm, 30-62 μm, 62-90 μm, and 90-125 μm, and then selec...
Autori: Yang Xiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26873

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract This paper presents the results of electrocardiography (ECG) signal acquisition, the heart rate variability (HRV) extraction method and the statistical processing of the extracted features on human exposed below the maximum level of exposure of the electromagnetic field. The ECG recordings were acquired in common situation of electromagnetic fields exposure occurring in hospitals: the power line supply (50 Hz), the fluorescent lights tubs (5 KHz - 150 KHz) and the electrosurgical un...
Autori: Narcis Iulian Adochiei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26904

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Abstract The present study was designed to determine the sound effects of ultrasonic treatment and the biologically mediated extraction of uranium from low grade black shale. Low grade uranium was subjected to fungal treatments assisted by sonication by conventional methods. In situ fungal leaching of black shale with different fungal strains in the presence of molasses as growth substrate resulted in highest leaching yield of uranium by Phoma tropica (57.73%) compared to Penicillium chrysog...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26919

Ferric sulfate and aluminum sulfate were applied to stabilize the available arsenic in solid waste residue (SWR) from the organic arsenic industry, previously pretreated by the semi-solid Fenton process. NaOH, Ca(OH)2, and MgO were introduced to adjust the matrix pH. Toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), and sequential extraction procedure (SEP) were carried out to evaluate the effect and difference on the fixation treatments of ...
Autori: Li-Fang Hu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26956

The work studies the degree of heavy metal pollution in water, sediment and soil in the industrial platform area from Ramnicu Valcea, Romania. The water and sediment samples were collected from three locations of the Olt River, in two distinct periods, February and June 2010. Concentrations of nickel, copper and cadmium were analyzed. The soil samples were collected from eight points and the same elements were analyzed, in the above mentioned interval of time. The results of water and sedime...
Autori: Mihaela Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26961

Ranunculus rionii and Ceratophyllum demersum develop aquatic dense stands, which lately started to represent a major ecological concern for all the ponds and/or lakes in Romania. The potential relationships between the phytochemical compounds detected in these plant extracts (acids, phenols, heterocycles, alcohols, hydrocarbures) and the allelopathic properties against Gram positive and Gram negative bacterial strains and microalgal cultures were investigated and discussed in the current stud...
Autori: Mariana Lupoae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26971

This paper presents a mathematical model developed to solve the problem of adequate blending composition for copper smelting process and it is exclusively for the purpose of the case study in "RTB BOR" (Copper Smelter in Bor). The model proposes an objective function, which maximizes the profit by calculating both the “penalties” for the hazardous concentrate elements and “benefits” for the useful ones. Apart from the basic constraints of the existing mathema...
Autori: Ivan Jovanović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27002

Pain levels may interfere with a patient`s decision when it comes to choosing an appropriate intrauterine system. To our knowledge, there is no study which compares the pain levels during and in the first weeks after the insertion of the levonorgestrel-releasing intrauterine system (LNG-IUS), opposed to copper T380A intrauterine device (C T380A IUD), considering the structural differences between the two devices. In the Department of Obstetrics and Gynecology of University Emergency Hospital...
Autori: Monica Cirstoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27022

The multi-parametric quality index (ICPM) is a dimensionless number used to evaluate the overall water quality and it is a useful tool for policy makers and for the public. This study aims to introduce the ICPM algorithm. The ICPM was developed to assess the water quality of the Lower Danube River using information obtained from the analysis of 41 water quality indicators from a monitoring program during 2011-2014. ICPM used the data for the previous 28 months as reference to evaluate the lat...
Autori: Violeta-Monica Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27035

The aim of this study was to determine the impact of mercury pollution on soil, surface water, and sediment ecosystems in the area of old mercury mines. The study was performed in the touristic area of Sântimbru Băi and Sâncrăieni villages from the Harghita County, Romania. More than twenty years ago, a mine for the extraction of mercury operated in Sântimbru Băi. The area was decontaminated, but no monitoring studies have been made for over 15 years. During t...
Autori: Luisa Roxana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27038

Renewable resources, biopolymers and bio-based materials are keywords of the sustainable development and environmental sustainability concepts. Biopolymers, the green alternatives to fossil fuel based polymers, have already found different feasible applications, from consumer goods to regenerative medicine. Keratin is the biopolymer contained in the skin derivatives and appendages and is one of the the proteins with the most sophisticated architecture nature could produce. It is found in huge...
Autori: Hossein Rajabinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27043

The paper deals with the amounts of total and plant available forms of heavy metals (Pb, Cr and Cu) and relation between soil properties in three catenas in postglacial area of the Łyna River valley, NE Poland. The results were presented on the background of four geochemical landscapes distinguished within the study area: eluvial or trans-eluvial, eluvial accumulative, trans-superaqual and super-aqual. The average total content of heavy metals amounted to: Pb – 14.05 mg kg-1 d.m., ...
Autori: Paweł Sowiński
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27058

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

Three different winter wheat production systems for three European countries (United Kingdom, France and Italy), all with different climatic conditions, soil management and input levels (e.g. tillage, fertilizers, herbicides and pesticides) were analysed from an environmental perspective. The intended applications were the analysis and comparison from a Life Cycle Assessment (LCA) perspective and the identification of the key parameters which have the greatest influence on final results. The ...
Autori: Daniele Cambria
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27102

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

This work focuses on treatment of lead polluted waste glass from urban collection (Pb≈5% wt) for its valorization as support in the immobilization of lipase, because soda-lime glasses are used in enzymatic catalysis. First of all, an extraction process of surface Pb was performed. The process is based on nitrilotriacetic acid (NTA) chelating agent. The operating conditions are: T=80°C, t=1h, pH 10, solid/liquid weight ratio=1/10, reagent concentration=0.1 M. Leaching tests at contr...
Autori: Luisa Barbieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27122

Rapeseed meal (RM) is an abundant and cheap by-product of oil extraction process. RM is a rich source of nitrogen, carbon, and minerals. Thanks to these features, RM has a striking potential for eco-friendly production of high value products in biotechnological processes. In this study, the possibility of using a low-cost medium based on the water soluble fraction of RM for laccase production by the fungus Pleurotus ostreatus has been evaluated and compared with the use of synthetic complex ...
Autori: Lucia Guarino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27129

The production process of wine and distilled generates several by-products (20-30% of total production). Currently, most of the solid by-products (pomace, stalks, lees and seeds) obtained as downstream of the vinery industry, are conferred to the distillery or, less frequently, used in agriculture and for energy production. As a consequence, much of the antioxidant compounds contained in the grape is unused in the products of processing and is lost. These substances (among which the most impo...
Autori: Paola Zitella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27135

A submerged membrane bioreactor (MBR) was applied to treat digested piggery wastewater (DPW). The removal of chemical oxygen demand (COD), ammonium-nitrogen (NH4-N), two kinds of heavy metals and ten kinds of antibiotics were studied. The hydraulic retention time (HRT) was gradually shortened from 12 days to 2.7 days, by which correspondingly the volumetric COD loading rate was increased from 0.4±0.1 to 2.8±0.6 kg /(m3·d) and volumetric NH4-N loading rate was increased fr...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27150

Animal manure is widely used as organic fertilizer for crops. However, high concentrations of heavy metals in animal manure are of great concern. In this study, we found that chicken and pig manure compost contain high concentrations of arsenic (As), cadmium (Cd), copper (Cu) and zinc (Zn), and the concentrations of these heavy metals in the pig manure were higher than those in the chicken manure. Chicken or pig manure compost fertilization elevated the concentrations of these heavy metals in th...
Autori: Guilan Duan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27155

Occurrence of antibiotics and heavy metals, together with concentrations of conventional pollution indicators were assessed in digested piggery wastewater (DPW) generated in ten large-scale pig farms in Jiaxing City, China. Results showed that water quality of DPW varied in different farms as well as in different seasons. Digested piggery wastewater pollution tended to be less serious in Summer than in Spring, Autumn and Winter. Conventional pollution indicators of chemical oxygen demand (COD...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27159

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

In this article we present the results of the study concerning the relationship between the concentration of trace elements (lead, chromium, cadmium, cobalt, copper, zinc and nickel) in soil and in the leaves and bark of Populus nigra L. The samples were collected in the period May 2010 – October 2010 in two areas from the Romanian North Littoral of Black Sea. The concentrations of the trace elements in soil, leaves and bark were determined using Flame Atomic Absorption Spectrometry (F...
Autori: Lucica Barbeş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27239

Different bioleaching processes were applied to mining wastes deposited in the highly polluted post-industrial region - Lower Silesia in Poland. The chemical characterization of the wastes before and after bioleaching processes was performed. The characterisation was based on the distribution of selected elements (Fe, Mn, As, Co, Cr, Cu and Ni) between operationally-defined phases. The phases were defined using a six-step extraction procedure optimised according to the properties of the studie...
Autori: Joanna Pałdyna
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27259

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

The paper aims to present the sorption properties of two sorbent substrates (composts) prepared by aerobic fermentation from vegetables waste composted with beech sawdust (BR2) and beech ash (BC1) to be used for Cu2+ removal from wastewaters. The composts structures and surface properties were characterised in terms of active groups (FTIR), crystallinity (XRD), morphology (SEM), topography (AFM) and specific surface and pores analysis (BET), and the changes in properties after Cu2+ sorption were...
Autori: Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27323

In the current context of industrialization, chemical and radioactive pollution is a concern for environmental protection and interference with human health. Care for environmental protection also includes vegetation that grows spontaneously in potentially contaminated places, thus avoiding illness among the population if consumed. The study area is located at 4.5km SSE from downtown Bacău City, Romania and is the result of the manufacture of H3PO4 through the wet method. In this study, t...
Autori: Mioara Săndulache Rachieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27331

This paper presents the research performed in view of emphasizing the effects of mineral aggregates extraction on the geomorphological and hydraulic features of Moldova body of water. The effect on the geomorphological features was assessed by overlapping the cross profiles (22 profiles) and long profiles (2 profiles) from the entire area studied. These profiles were obtained by topographical measurements on the starting date (July 2013) and on the research end date, respectively (March 2015). T...
Autori: Paula Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27335

The objective of this study was to develop a naturally dyeing process of 70% wool /30% Angora mohair blended yarns by using bio-mordants as an environmentally friendly alternative for the conventional metallic salts. Bio-mordanting operation was achieved by using of condensed tannin extract from quebracho bark trees. Conventional mordanting has been performed using the conventional mordants like copper sulphate and tin chloride. Another specific objective of this study was to investigate the pos...
Autori: Ioana Stanculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27337

Although the main reason for the extraction of methane from coal beds continues to address ensuring the safety of workers, an important driver is the need to reduce emissions of greenhouse gases. In order to identify potential technical problems specific for available technologies implementation, we performed a comparative critical analysis, based on which the technically feasible systems resulted, their further selection being based on detailed analysis in financial and investment terms. The re...
Autori: Lucian-Ionel Cioca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27350

Discomfort caused by noise is ever-present, having numerous physiological, psychological and social implications. One of the most important discomfort factors for personnel working in the processes of surface coal extraction is represented by noise. This paper examines how noise generated by the process of lignite extraction influences the working capacity of employees. The covering effect of voice or different sound and verbal signals, during work, leads to tiring efforts of attention, thus de...
Autori: Sorin Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27366

In the process of underground coal mining a complex network of vertical, horizontal and inclined mine workings with the purpose of extraction, transportation and evacuation to the surface are utilized. The mining workings are also being utilized for ventilation network system, which is also used for ensuring the oxygen supply necessary for workers, as well for diluting explosive gases and/or toxic substances and, ultimately, for exhausting the heat resulted from underground workings. For air flo...
Autori: Marius Simion Morar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27372

Drilling waste management for oil and gas industry involves collection, transportation, processing, recycling, disposal, and monitoring of waste materials in order to reduce their effects on health and environment. In the Exploration and Production industry, environmental concerns have made effective management of drilling waste at well sites a great priority. Effective waste management is thus a key element in a successful drilling project. The industry therefore relies on effective expertise a...
Autori: M. Enamul Hossain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27375

The utilization of agro-industrial waste as a potential substrate for producing enzymes may serve a dual purpose of reducing the environmental pollution along with producing a high value commercial product. Twelve different agro-industrial wastes were evaluated for extracellular BGL (β-glucosidase) production by a mutant of Bacillus subtilis on solid state fermentations (SSF). The Citrus sinensis bagasse was found to be the most suitable substrate with highest BGL titer (35 U/gds). Optimum ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27378

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

Timber harvesting and log extraction with conventional ground-based skidding systems in steep, mountainous terrain often results in severe damage to residual stands and forest sites. In this study, the impact of rubber-tired skidders on standing trees along sides of the trails was investigated 5 to 20 years post-harvest in terms of frequency and development of decay at the points of wounding. The study was located in the Hyrcanian mountainous forests of Iran. All standing beech trees (healthy or...
Autori: Davoud Kartoolinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27457

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

This paper reports the possibility of using zinc ash as a secondary source for zinc oxide, which can be further used as white pigment. For the extraction of zinc from zinc ash, sulphuric acid was used. The impact of different parameters (ash fraction, contact time, sulphuric acid concentration and liquid:solid (L:S) ratio) upon the extraction degree of metallic ions from zinc ash was studied. The optimum conditions for the metallic ions extraction are: 20 % H2SO4, 30 minutes contact time, 1:1 L:...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27475

The paper presents results obtained by analysis of some soil and wastes samples in order to establish the heavy metal (HM) content from these samples. The analyzed wastes were sewage sludge from municipal waste treatment and hydrotechnical basin sludge. These types of wastes were mixed with soil from Oltenia Sub-Carpathian area, obtaining the substrates useful for different types of plants. It was studied the migration potential of the metals from substrate to apple trees, the results being comp...
Autori: Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27476

Mobilization of micro- and macronutrients and their uptake by Zea mays L. and Triticum aestivum L. in response to EDTA additions to risk metal contaminated agricultural soil was monitored over a three year period on the field scale. EDTA addition effectively increased the mobility of total water-soluble micronutrients (Cu, Fe, Mn) and macronutrients (Ca, Mg, P) in soil extracts. Mobilization was highest in the first year and decreased strongly over time. Elements with a high affinity for EDTA (C...
Autori: Reinhard Rauch
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27477

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

The aim of the studies was to evaluate the influence of the 30-year operation of a small retention reservoir fed with water from a forest-agricultural catchment area on the contents of selected mineral elements substances in bottom deposits. The studies were carried out in the Łoje dam reservoir (N 53o7’28’’, E 20o48’20’’), supplied by the regulated Łojówka stream. Deposit samples were collected in four transects perpendicular to the reservoir...
Autori: Ireneusz Cymes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27518

The present study aims to compare the efficiency of a single extraction and a 3-stage cross-current extraction of PAHs from both lowly contaminated (LC) and highly contaminated (HC) sands using palm kernel and soybean oils (PKO, SO). It is observed that 3-stage cross-current extractions increase the total efficiencies compared to single extractions by 18.7–22.7% and 27.2–30.6% for LC and HC sands, respectively. Maximum efficiencies of 94.3% and 98.4% are obtained for phenanthrene (PH...
Autori: Ee Von Lau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27530

This paper investigates the macrophyte Azolla pinnata modified with sodium hydroxide, as a bioadsorbent for Cu2+ and Pb2+ ions in synthetic solutions. Biomaterial characterization was performed using Scanning Electronic Microscopy (SEM); Energy- Dispersive X-Ray Spectroscopy (EDX); Fourier Transform Infra-red (FTIR) spectroscopy techniques and through the blocking of carboxylic and sulfonic functional groups. Kinetics of the process has highlighted a quick and efficient adsorption, even in low ...
Autori: Arielle Barros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27532

A series of column experiments were conducted to study volatile contaminant (benzene) removal and process principles using soil vapor extraction (SVE) under different thermal conditions. Compared with the normal SVE method, two thermal methodssteam injection and electrical resistance heating effectively increased the benzene vapor diffusion and removal rates. The removal efficiency of benzene with the electrical resistance heating method was 96.5%, which was significantly higher than that with t...
Autori: Peng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27534

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

There is an increasing interest in the food industry and in protective health care for the expansion of natural antioxidants from plant materials. The solid wastes generated by the winemaking industry represent about 30% of the material used and it consists mainly of grape pomace (containing seeds, pulp, stem and skin). It is well known that high quantities of valuable compounds like dietary fibre, oils from the seeds, anthocyanins and phenolic compounds still remain within the grape marc. The p...
Autori: Valeriu V. Cotea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27553

The solid-liquid extraction process and some of its influencing factors such as solid-liquid ratio, temperature and salt initial amount have been investigated. Also, mathematical modeling for mass transfer coefficients calculation was applied. An inert porous solid material (coal), impregnated with 10% and 20% mass NaCl or 15% and 30% mass CaCl2, was used. The leaching was conducted in a fixed bed column, in laminar flow. The CaCl2 impregnated samples were investigated in a column with a height...
Autori: Marcel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27557

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Chemical oxidation of pyrite and chalcopyrite by ferric sulfate (Fe2(SO4)3) solution and biogenic ferric iron obtained by mixed culture of isolated thermotolerant Acidithiobacillus sp. 13Zn and Leptospirilum ferriphilum CC immobilized on natural carriers- zeolite and shungite was studied. Oxidation rate of sulfide minerals was estimated by the decrease of Fe3+ (oxidant) and increase of Fe2+ ions in the solution. It was revealed that chemical oxidation of chalcopyrite by biogenic ferric iron occu...
Autori: Arevik Vardanyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27563

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

The influence of the active compound of Moringa oleifera Lam (MO) seeds was evaluated by different methods for the preparation of the natural coagulant in the treatment of surface water. Nine methods were analyzed, comprising samples of seed powder with different granulometry, aqueous and saline solutions, evaluated before and after oil extraction from MO seeds. Tests of coagulation/flocculation and sedimentation were accomplished using simple Jar Test. Natural coagulant dose of 50 mg.L-1 identi...
Autori: Karina Cardoso Valverde
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27588

This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

The study of binary biosorption of Pb(II) and Cu(II) was performed by pine nuts shell. Results were compared with the single biosorption of Pb(II) and the single biosorption of the Cu(II). Experiments were performed in batch stirred and in a continuous system. The presence of lead caused a slightly decrease of the copper biosorption yield and can be related to the copper equilibrium uptake. This antagonistic action can be related to competition phenomena between metal ions in solution for active...
Autori: Gabriel Blázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27611

A 120 kilometers reach of the Prut River, Romania was surveyed and the concentrations of four trace metals (copper, cadmium, lead and zinc) were determined in water and sediments. These elements are the main pollutants expected in the region, as a steel-producing factory in Romania is located in the close neighborhood of an area under protection, the Lower Prut Floodplain Natural Park. Samples were collected in 2010 and 2011 from the water-sediment interface at six locations along the lower sect...
Autori: Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27612

Pyrometallurgical recycling of lead from spent batteries entails secondary waste fractions generated in the blast furnace as iron stone and lead slags. For further purification of both fractions, hydrometallurgic processing is proposed. This paper focuses on purification of iron stone, in view of recovering metals (mainly lead) and of producing decontaminated iron stone fit for further recycling. The results demonstrate that iron stone is mainly composed of iron and lead; copper, zinc and antimo...
Autori: Bart Van der Bruggen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27642

Copper pollution is common across the world and has caused serious public health problems recently. Among the conventional methods, adsorption has proved effective, economic, versatile and simple for the removal of aqueous Cu(II) contaminants. Deposits of natural Kaolin are abundant around the world, and are regarded as valueless due to its limited usage in industry. In this study, the adsorption behavior of natural Kaolin towards Cu(II) was evaluated. According to the results, the isothermal ad...
Autori: Qiang Tang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27651

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

Sulfide bearing mine tailings generated through mining and processing of mineral ores is one of the serious problems around the world due to their potential environmental hazards. Current study focuses on vertical distribution and potential mobility of metals in New and Old tailings of a Lead and Zinc mining area of India. Mine tailing profiles sampled from New (0-500mm) and Old tailing (0-400mm) dams were chemically (pH, EC, Carbonate content, Cd, Pb, Zn and Mn levels) and mineralogically (usin...
Autori: Malik Anju
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27690

The reuse of sewage sludge will be increasing in the future, with expansion of sewerage works and advanced sewage treatments. During anaerobic digestion of sewage sludge from wastewater treatment plants the humification of organic matter will have an important effect on the physico-chemical forms of heavy metals. The aim of our paper was to investigate mobility of zinc from dried anaerobic sludge (DANS) from municipal wastewater treatment plant (WWTP) via single step (simultaneous) extraction pr...
Autori: Vladimír Frišták
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27695

With the aim of contribute to a bioremediation technology drafting, this paper presents a preliminary research on bioremediation of wastewaters polluted with heavy metals and other toxic contaminants. Bioremediation tests were performed with aquatic species Lemna minor, Vallisneria spiralis, Eichhornia crassipes, Hydrilla verticillata, Pistia stratiotes, Cladophora glomerata, on samples of contaminated waters resulting from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu Co...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27702

Huge amount of red mud has been disposed for the past several decades and it is still generating all over the world. Red mud is a waste of the bauxite processing industry obtained during the alkaline extraction of alumina from bauxite ore. The red mud is a potential raw material containing several valuable components including iron, titanium and rare earth metals. The aim of the research was to develop an appropriate acid digestion technique for the red mud in order to determine the amount of...
Autori: Tatjána Juzsakova1
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27780

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

In this study, the removal of Cu(II) from real industrial wastewater, being taken from galvanotechnic industry, by means of manganese ferrite (MnFe2O4) nanoparticles (NPs) was investigated. The effects of pH, adsorbent dosage, and contact time on Cu(II) removal from wastewater were monitored using the real wastewater while the effect of initial concentration was studied on synthetic aqueous solutions. Optimal conditions were found for copper removal in this study. Cu(II) removal and adsorption c...
Autori: Naim Sezgin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27743

Capillary gas chromatography coupled with mass spectrometry technique was used for the assessment of low concentration of dinitrophenol pesticide, Dinocap in different spiked samples. For this purpose it has been spiked with Dinocap (15- 200 μg/mL) five environmental matrices (a soil sample and two each samples of wine and grapes). The Dinocap degradation grade in these samples was also monitored. The extraction was performed in dichloromethane. The assessment of the Dinocap in the samples we...
Autori: Nicoleta Grigoriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27746

This study aims to monitor Volatile Organic Compounds (VOCs) and odour annoyance perceived by the exposed population living nearby a petroleum plant through an integrated high temporal resolution methodological approach. The area under investigation is considered one of the most critical industrial areas of the South of Italy (Basilicata) because of presence of the largest Italian petroleum plant, called the "Center Olio Val d'Agri" (COVA). In fact, VOCs and odours emitted from ext...
Autori: Alessia Di Gilio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27791

The construction sector has evolved a lot over the last few years promoting the design and manufacturing of innovative and environmentally sustainable materials and products. In accordance with European and national guidelines, with a growing awareness of environmental issues several experiences are showing the interest of companies to qualify their products as green and environmentally sustainable. In the European context many directives have been introduced which, among their themes, speak of ...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27806

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

Within this study a total content of 20 elements was determined in 25 soil samples taken from the vicinity of the "Buchim" mine, Republic of Macedonia, covering an area of 14.2 km2. The results have been compared to new Dutchlist and NOAA standards and it was concluded that the content of As, Cd, Cu, Pb and Zn in most of the samples is over the corresponding optimal or action values probably due to the anthropogenic activities. Thus As values ranged 13.1-225 mg kg-1 with 20 above the o...
Autori: Todor Serafimovski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27844

Sand contamination is an important factor when assessing the health hazard potential of public beaches. The goals of this study are to assess the performance of four sand washing procedures on the removal of surface adsorbed chemical species, and to identify which chemical components are best suited for monitoring the health quality of beach sand. Four washing treatments were investigated: contact, stirring, sonication, and boiling. Sand samples were collected from three Portuguese beaches an...
Autori: Mário Dias Almeida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27890

The catalytic hydrogenolysis of glycerol, a by-product of the biodiesel manufacturing process was studied on copper chromite catalysts with different chemical composition. The obtaining of propylene glycol was studied under mild reaction conditions (180- 240oC temperature range, 8 hours reaction time and moderate pressures). These important parameters have significant effects on the glycerol conversion and that is way the actual study was concerned to the obtaining of a superior selectivity t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27892

Biosorption of copper(II) by lyophilized and thermally treated bacterial biomass of Pseudomonas aeruginosa PAO1 and Pseudomonas fluorescens BME in aqueous suspension was studied. The cell surface properties were characterized and the experimental conditions, e.g., pH, adsorption time, and initial metal concentration were optimized for efficient biosorption. The surface charge was negative at pH above 2.5 for P. aeruginosa, and above pH 4 for P. fluorescens. The highest copper(II) uptake was ...
Autori: Anikó Kőnig-Péter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27917

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

This study evaluates the environmental impacts of four types of frozen food packages throughout their lifecycle and suggests strategies for reducing their related environmental impacts. The four most widely used frozen food packaging materials were chosen for this study: (1) pouches composed of low-density polyethylene (LDPE) film; (2) pouches composed of polyethylene terephthalate (PET) and LDPE film laminate; (3) cardboard boxes coated with LDPE; and (4) multipackage composed of cardboard boxe...
Autori: Daina Kliaugaite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27979

Chlortetracycline (CTC) and copper (Cu) are simultaneously used as feed additives to improve the growth performance and to prevent infection in pig farming. After ingestion by animals, most of these compounds are excreted and coexist in swine manure. They might have an influence on anaerobic digestion when the swine manure is used as substrate in a biogas plant. The purpose of this study was to investigate the effects of both CTC and Cu on batch swine manure anaerobic digestion in order to bette...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27983

In this paper, several image analysis techniques have been applied aiming to obtain useful information regarding the processing of municipal solid waste polymers. An automated color extraction method has been applied in order to quantize the color distribution in the polymer wastes aiming their resource and time-efficient separation according to their color. Also, by processing different density fractions from the polymer waste the color of the final material has been predicted, as well as th...
Autori: Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27994

This paper analyzes the fundamental principles of the substitution of strip coal pillars with coal refuse through the combination of theoretical analysis, physical simulation and numerical calculation with engineering practice. We propose to lay out roadways through strip coal pillars in a reasonable manner so as to produce a “coal-rock bearing mass” consisting of stowboards (i.e., roadways backfilled with coal refuse) and coal pillars that substitute the original strip coal pilla...
Autori: Qiang-ling Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28014

The coal gas is a potential risk for the safety production in coalmines. The practical experiences in coalmine show that the gas may suffer massive desorption and migration after coal seam mining and deformation of overlying strata. Therefore, gas extraction in mines focuses on mining ground pressure relief gas extraction. In this paper, the study is carried out on gas permeability and migration pathway based on movements of overlying strata over the working face and the spatial location of t...
Autori: Jianwei Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28019

Trace elements (TEs) in contaminated soils are considered as primary jeopardy issues in developing countries which can cause major concerns for this industry and also menace the surrounding ecosystems, human health and wildlife, so urgent reclamation methods are required. The present research aims to evaluate potential phytoremediation capability of selected plant species Tamarix Spp., Haloxylon Spp. and Malcolmia Africana to grow in TE contaminated soils. Muteh Gold mine, a widespread mountaino...
Autori: Ali Daryabeigi Zand
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28056

Extracts of Bifurcaria bifurcata seaweed were obtained by diverse conditions. Different extraction techniques, such as hydrothermal and ultrasounds, and three different solvents (water, ethanol and water/ethanol (50:50)) depending on technique were used. Moreover, supercritical CO2 (SC-CO2) with 10% of ethanol as co-solvent using different extraction times (30, 45 and 60 min) was also used as extraction technique. Extraction yield, phenolic content and antioxidant activity were measured for e...
Autori: Rubén Agregán
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28039

The activities connected with the construction sector are responsible for several environmental impacts, both in the construction sector, and in the many manufacturing sectors involved in the supply chain of materials and products (mining sector, manufacturing sector, waste treatment etc.). The building products have a marked cross-sectorial connotation, according to the ANCE 2016 report, 31 economic sectors out of 36 are suppliers in the construction sector. One of the possibilities to reduce t...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28090

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

Wastewater generated from industrial activities has delivered elevated heavy metal concentrations into fresh and salted aqueous systems. Herein, the migrated trace metals were studied from their initial location through a coastal aquifer up to the seawater. The experiments were carried out at lab scale using a sandbox with glass beads and two attached chambers containing natural groundwater and seawater. The study focused on the transport behaviour of heavy metals such as copper, zinc and lead i...
Autori: Abdelkader Tawfeek Ahmed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28111

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

This work seeks to develop a suitable heavy metals precipitation modeling approach that could give reasonable results in mainstream use with industrial wastewater treatment. This paper is devoted to the thermodynamic analysis of the degree of precipitation of slightly soluble hydroxides and salts in industrial wastewaters in order to optimize the technological schemes of extraction and reuse of heavy metals from industrial waste. Based on the notion of the solubility product, the equations desc...
Autori: Igor Povar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28156

The recovery of nutrients from sewage sludge ash, especial phosphorus, is one of the most important alternative in sewage sludge management. Phosphorus is an essential element for all living organisms and very important for agriculture and industry, as well as. Because the phosphorus is a non-regenerative resource, its recovery plays an important role for society. Phosphorus capitalization as struvite (NH4MgPO4.6H2O) from sewage sludge has attracted considerable attention due to its potential to...
Autori: Bogdan Adrian Militaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28158

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Silk sericin is a water-soluble macromolecular protein obtained from the raw cocoons of silkworm, Bombyx mori. It comprises of about 25% of the total cocoon shell weight and is categorized as a waste by-product in textile and silk industries after the extraction of silk fibers. This study emphasizes on the extraction of sericin from B. mori by a conventional salt alkaline method and characterized their physico-chemical properties, thermal stability, anti-bacterial and anti-oxidant activities. T...
Autori: Inderchand Manjubala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28213

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

The olive oil extraction industry is one of the most polluting wastewaters from the food industry, which is considered an important economic activity in the world. The environmental effects of olive wastewater are related to chemical and organic loading, which is resistant to biodegradation processes. The purpose of this study was to determine the efficiency of combined electrocoagulation, catalytic ozonation, to reduce organic load and improve the biodegradability of olive oil sewage. The pres...
Autori: Mohammad Reza Khani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28261

Growth of city population and migration of communities lead to higher accumulation of heavy metals in coastal areas of the Caspian Sea suburbs. In the present study there are represented geographical and ecological locations and environmental monitoring results of the Caspian Sea offshore and coastal area near Akshukyr (Aktau suburbs). The shallow offshore near Aktau city and adjacent areas were monitored in cooperation with the Institute of Ocean Sciences. Sea water analysis carried out specia...
Autori: Nurgul Janaliyeva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28263

The treatment of acidic wastewater of copper sulfide produces a huge amount of sediment, which can be processed into the planting matrix for ecological restoration of mines. This paper attempts to screen out the plants suitable for the acidic wastewater sediment, laying the basis for ecological restoration of mines. Therefore, 14 plant species were selected for preliminary tests on survival rate and growth tests in sediment pond. The survival rates and growth conditions of each plant species in...
Autori: Jinchun Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28268

The concentrations of Copper (Cu), cadmium (Cd), manganese (Mn) and lead (Pb) in liver, kidneys and red meat of cattle slaughtered in selected abattoirs in Owerri metropolis, Nigeria were studied using atomic absorption spectroscopy (AAS). This was performed in relation to their concentrations in a forage grass, Panicum maximum randomly harvested from roadsides of Owerri- Onitsha and Owerri-Aba expressways. Results obtained showed that cattle meat samples contained all heavy metals studied. Thei...
Autori: Henry Uzoma Anuforo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28320

The study presents the experimental testing of a heat exchanger with uniform thermal flux (HEUTF), used as a cold source in HVAC systems with heat pumps. A water-water heat exchanger is tested, having a special geometry, with uniform thermal flux along the system. The heat exchanger proposed consists of a distributor and a collector, connected to each other by means of 20 staggered copper pipes, being suitable for serving low or medium geothermal sources. The innovation consists in the uniformit...
Autori: Sebastian Valeriu Hudișteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28340