AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

Include urmatoarele articole� Degradation of alcian blue 8 gx by heterogeneous and homogeneous photocatalytic processes� Evaluating the performance of solid waste management models� Bioreactors with stirred bed of immobilized cells 1. Studies on mixing efficiency� Fugitive emissions estimation from petroleum storage tanks� New Ni(II) coordination polymers with insulating and anticorrosive properties� Determination of water quality deterioration at pilgrimage centre along river netrav...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25196

AbstractThe objective of the paper is to present sustainability indicators for municipal solid waste management (MSWM). Sustainability implies environmental, economic and social acceptance. The complexity of the system-in-focus requires the employment of a systems (or cybernetic) approach: Acceptance implies clear objectives, from a specific point of view (here, the viewpoint of the municipal administration is taken), over a time horizon covering at least two generations, a life-cycle considerat...
Autori: Demetrios Panagiotakopoulos, Konstantinia Tsilemou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25112

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

The use of gasoline oxygenated with MTBE (methyl tert-butyl ether) reduced significantly air pollution (16 - 23% lower emissions of CO and 18% lower emissions of unburned hydrocarbons) but increased water pollution. There is no European or national regulations for MTBE in drinking water except for Denmark, which has set a limit value of 30 Âľg/ L for MTBE. USEPA proposed a maximum concentration of 20- 40 Âľg/L. This paper is a review with 70 references on the MTBE production, use, properties and...
Autori: Camelia Beţianu, Florina Ungureanu, Loredana Branza, Lucian Vasile Pavel, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25122

AbstractThe corrosion behaviour of three commercial nickel-chromium based dental materials was investigated by electrochemical methods in a corroding mixture of sodium chloride, oxalic acid and lactic acid. In order to establish electrochemical parameters of the corrosion process, linear and cyclic polarization curves were plotted. The samples performances in the corroding system were investigated by weight loss, pH and electrical conductivity measurements. The quantitative analysis related with...
Autori: , Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25132

AbstractCatalysts having mobile electrons in bulk such as metals and semiconductors are good solid materials for red/ox type of reaction (oxidation) and can be effectively used in gas sensing devices as well. The aims of this work were: (i) to investigate the surface behavior of Pt(0.28%)/Al2O3 and SnO2(2.94%)-Pt(0.28%)/Al2O3 samples in inert atmosphere (He) and in reducing atmosphere containing helium-cyclopropane gas mixture under ambient condition (i.e., room temperature, atmospheric pressure...
Autori: , Cornel Munteanu, Jozsef Kovacs, Mariana Scurtu, Monica Caldararu, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25146

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

Contain all the articles from this issueICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Treatment Technologies for Gaseous Fluxes"Surface chemistry studies on molybdena–alumina catalystTatiana Yuzhakova, ?kos R?Šdey, Endre Domokos, J??zsef Kov??cs, Monica Caldararu, Cristian Hornoiu, Mariana Carata, G.Postole, Cornel Munteanu, Larisa Strukova, Jozse FazakasHebicidal behaviour of a new N,N'- biquaternary salt of 4,4'- bipyridineServilia Oancea, Marinela Irimia, Gabriela Carja, Anton Airinei, Nicu...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25189

Include urmatoarele articole:� Removal of persistent organic pollutants from textile wastewater by membrane processes� Sustainability evaluation of an urban residential settlement� Removal of zinc (II) from aqueous solutions by romanian sphagnum peat moss� Development trends of cold plasma reactors in the global context of carbon emission reduction� Assessing the potential of wind power in Romania within Kyoto targets� Research on the impact induced in the environment by milk process...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25198

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Include urmatoarele articole:� "Waste not, want not" a study of household attitude toward recycling of solid wastes� A kinetic model for the crystal violet mineralization in water by the electro- fenton process� Development of a coagulation/flocculation predictive model for turbidity removal from tehran water treatment plants� Removal of cadmium (II) from aqueous solutions by sphagnum moss peat: Equilibrium study� Environmental sustainability based on fuzzy models� Impact of dust emi...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25207

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractAn assessment of acide drainage forming potential for a mining waste material resulted in a former mine of nonferrous and precious metals ore has been made. The waste material has the following contents: 2,20?ˇ2,28% sulphide sulphur, 2,53?ˇ2,58% Fe, 0,07% Cu, 0,05% Zn, 0,36?ˇ0,40% Pb, 0,008?ˇ0,013% Ca and 3,85?ˇ7,97% sulphate. Bacterial leaching tests in percolating columns during 380 days have been made. The leaching liquor has been recirculated at a liquid:solid ratio of 1L:1kg. After ...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25239

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractThe comparative study on reactive extraction of p-hydroxybenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar s...
Autori: Anca-Irina Galaction, Dan Caşcaval, Maria Cămăruţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25250

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

AbstractIn this work it had been tested the recovery of some compounds like: Fe2O3, TiO2, PO4 3- ions, Al2O3 from the sludges, which result in the industrial facilities for output of pure uranium dioxide. Solubilization of the chemical compounds from the uraniumwastes was performed in strong acidic media, using adequate methods....
Autori: Alexandru Cecal, Doina Humelnicu, Romeo Iulian Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25288

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractDark fermentation hydrogen production from a mixture of food components using two different methods of methanogenic inhibition (autoclaving and BES) and three different temperatures (37, 60, and 70 Â?C) was examined in batch assays for two different mixed anaerobic cultures - one suspended sludge (S) obtained from an anaerobic digester and one granular sludge (G) obtained from a brewery wastewater treatment plant. In general, BES-inhibition of sludge was more robust when compared against...
Autori: Angela A. Abreu, Anthony S. Danko, Francisco Pinheiro, Maria Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25308

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractThe removal of Acid Red 398 (AR398) dye from dye-containing solution using coagulation/flocculation process with polyaluminum chloride (PAC) and Alum was investigated. The effect of different parameters involving pH, dosage of coagulant, initial dye concentration, and bentonite as a natural coagulant aid was examined. According to the obtained results, the optimum pH, at which the maximum removal occurred, was about 4 and 5 for PAC and Alum, respectively. However, PAC performed efficient...
Autori: Maryam Hasani Zonoozi, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25335

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractHigh proton conductivity of CsHSO4 opened new opportunities for applications as electrolyte in solid acid fuel cells (SAFC). Relatively recent, it was proved that the accommodation of this solid electrolyte by silica supports improves its proton conductivity. During this work, solid acid CsHSO4 and its composites with mesoporous silica of SBA-15 and MCF-types as host materials were synthesized and studied for the first time. Studies were mainly focused on the influence of mesoporous supp...
Autori: Adrian Ungureanu, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25366

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

AbstractThe study presents the processing possibilities for marc resulted as still residue from the distillation of fermented fruits in view to obtain a compacted solid fuel. Initial marc composition (carbon, hydrogen, nitrogen, sulphur and oxygen contents) determined by elemental analysis is evidenced, as well as technical characterisation (ash and moisture contents) and ash's qualitative composition, chemical characterisation of the liquid phase (pH, total phosphorus, acidity and conductivity)...
Autori: Daniela Simina Stefan, Anca-Ileana Penu, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25391

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract The etching of iron materials in sulphuric acid solutions allows the dissolution of the iron oxides with formation of iron sulphates. The relatively low solubility of the formed sulphates imposes their separation for avoiding the contamination of the etching bath, as well as for preventing the environmental pollution through the wastewater. Within the flow sheet of the processing of the hot or cold rolled steel, a stage of separation by crystallization of iron sulphate is foreseen. T...
Autori: Liliana Lazar, Ion Balasanian, Florin Bandrabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25415

Abstract The aim of this study is to investigate the electrochemical behavior of a three casting non-precious dental alloys: Vera PDI (Co-Cr based), Heraenium (Ni-Cr based) and NPG+2 (Cu-Al based) three test solutions: artificial saliva (AFNOR, pH = 8), acidified saliva (pH = 2.5) and fluoridated acidified saliva (1000 ppm F-, pH = 2.5). Open circuit potential (EOC) measurement; potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) are the electrochemical proce...
Autori: Daniel Mareci, Daniel Sutiman, Adrian Cailean, Julia Claudia Mirza Rosca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25435

Abstract The analysis over the underground water monitoring system and the collected data from survey drilling show that the underground water has an unsatisfactory quality due to some physical and chemical characteristics. Along with these, factors like the surface water pollution, the hydrodynamic exchange between surface and underground waters and the reintroduction in the agricultural activities of nitrates and phosphorus based fertilizers lowers, as well, the quality that it has been tal...
Autori: Ioan Crăciun, Catrinel-Raluca Giurma-Handley, Ion Giurma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25436

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract Wood has been used as an engineering material because it is low in cost, renewable and strong and it requires low processing energy. Wood has many excellent properties that result from its exceptional combination of microstructural, ultrastructural and molecular features. The main drawback is its dimensional instability in the presence of moisture, which can affects also the biological stability. Wood is susceptible to degradation in a number of ways, including rot or decay, insect a...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25473

Abstract Herbs have been used as food and for medicinal purposes for centuries. In recent years, natural compounds such as phenolic acids, phenolic diterpenes and triterpenes, present in various plants, have been the subject of intense research due to their potential benefits for human health. It has been demonstrated that the antioxidant and radical scavenge activities are the main properties of these compounds. The main difficulties in using natural products as a source for pharmaceutical ...
Autori: Ruxanda Bodirlau, Iuliana Spiridon, Carmen Alice Teaca, Narcis Anghel, Maria Ichim, Svetlana Colceru , Alice Armatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25474

Abstract A crucial stage which makes the other directions of development of membrane processes is getting new membrane materials, to meet increasingly stringent of selectivity and productivity. Polyetheretherketone shows high stability against chemical and physical agents but is poorly soluble in most common solvents. Present studies on obtaining the support of the polyetheretherketone membranes were limited by: solubility of polyetheretherketone in concentrated sulfuric acid and fast speed a...
Autori: Mihaela Emanuela Craciun, Aurelia Cristina Nechifor, Florin Aldea, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25475

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract Biofuels represent a possibility for renewable resources conversion, storage and distribution. Today, diesel oil is commercialized only blended with biodiesel, and according to the 30/2003 Directive of the EU, 5.75% of the total fuels used in the transportation sector must be represented by biofuels by the end of 2010. Biodiesel can be produced from vegetable oils, animal fats and used oils. Viscosity is one of the most important characteristics of liquid fuels. The viscosity of liqu...
Autori: Irina Nita, Dan Mandalopol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25499

Abstract The paper presents the results obtained when using thin films (doctor blade) of titanium oxide powder (Degussa P25) and fly ashactivated with NaOH, for advanced treatment of complex waters resulted in the textile industry. There are studied the heavy metal(cadmium, copper) adsorption and the dyes (methyl orange and methylene blue) photo-degradation using these novel substrates.The thin films crystallinity (XRD), morphology and roughness (AFM) were evaluated and no significant changes...
Autori: Anca Duta, Luminita Andronic, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25500

Abstract It is known that carbonhydrates are precursors of all bioactive substances we tried in thes paper work to do some investigation on these substances in the environmental area of Iasi. To observe the influence of some chemical mutagens substances on carbohydrates biosynthesis we conducted investigations on plant material (leaves) taken from the Calendula officinalis L species. We used this assay to examine the effects of the herbicide 2,4- dichlorophenoxyacetic acid (2,4-D), etidium br...
Autori: Constantin Leonte, Roxana Vatavu, Teodor Robu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25502

Abstract This paper presents preliminary results of a batch-scale study assessing the contribution of the multiple phenomena involved in siloxane removal in three-phase biomatrices. Batch scale experiments were undertaken in shaken flasks containing acclimatised culture medium, solid media and siloxane vapours (octamethylcylotetrasiloxane and decamethylcyclopentasiloxane, respectively) under anaerobic gas-phase conditions. Abiotic and biotic phenomena, considered to be possible siloxane remov...
Autori: Gabriela Soreanu, Patricia Falletta, Michel Beland, Kara Edmonson, Peter Seto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25510

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract This paper is the investigation concerning the removal, from surface water, of humic acids and of some cations (Cu2+, Al3+) on activated carbons AG-3, BAU, CASO-16 from individual solutions as well as from their mixtures both in static and dynamic conditions. The conclusions of the paper are that, when humic acids are adsorbed from micellar solutions, semiassociates are formed on the surface of activated carbon BAU (in its porous structure), while humic acids adsorption on activated ...
Autori: Tudor Lupascu, Mihail Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25539

Abstract White mustard (Sinapis white) is an annual plant of the Cruciferae family originating from the Mediterranean region and is cultivated in Europe and Asia, mainly for its seeds, but also for animal feed or crop rotation. White mustard seed is also an important source of vegetable oil that can be used as fuel. The chemical composition of mustard seed (Sinapis alba) includes glucosinolate (sinalbozida, sinapina free), essential oils, fatty oils (glycerides of oleic acid, linoleic, linole...
Autori: Camelia Ciubota-Rosie, Rodica Diaconescu, Irina Volf, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25561

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract Withania frutescens plant from the south-western Morocco was used as an environmentally friendly material for the removal of As(V) ions from aqueous solutions. This work presents the characteristics of the adsorption and the desorption processes of As(V) using the dried W. frutescens plant as an environmentally friendly adsorbent. The mass of the adsorbent, the As(V) concentration, the contact time and the pH of the tested aqueous solutions were used as controlled variable parameters...
Autori: Mohamed Chiban, Gabriela Lehutu, Fouad Sinan, Gabriela Carja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25568

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Commercial pure titanium (Cp-Ti) and titanium alloys are used on large scale in restorative dentistry due to their advantages as compared with other similar materials: chemical inertia, low density, high strength, high corrosion resistance in biological media and increased biocompatibility.The effect of fluoride and pH on the corrosion behaviour of Cp-Ti and a new Ti50Ta alloy were examined by open circuit potential (EOC) measurement, linear polarization, potentiodynamic polarization...
Autori: Daniel Mareci, Daniel Sutiman, Georgiana Ciurescu, Igor Creţescu, Romeo Chelariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25591

Abstract In the last decades there has been a rapid evolution of techniques for production of bleached pulp. Much of these processes have been environmentally driven. New techniques have been developed in order to replace chlorine-based reagents in producing bleached pulp. Reducing the environmental impact of pulp production can be attain by using non-pollutant bleaching reagents like oxygen and related compounds. This paper deals with present findings and general trends in environmentally-s...
Autori: Adrian Catalin Puitel, Alexandru Botar, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25592

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract In this work the method for the treatment of industrial waste waters effluents containing hexavalent chromium in three companies during process of treating metal surface with chromic acid is described. Industrial water polluted with hexavalent chromium is collected in separate sewage system. Polluted water is collected in precipitation tanks which are directly connected with neutralization reservoirs. The treatment process includes pre-neutralization by lime-milk, sedimentation, floc...
Autori: Igor Creţescu, Mirjana Cvijovic, Predrag Djurdjevic, Slavica Cvetkovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25596

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The former Arad Chemical Fertilizer Plant had an important polluting effect on environment and, although it was shut down in 1990, its environmental heritage still exists. The paper contains a short description of the former plant and its impact on the environment, mainly on the quality of water and soil and emphasizes the effects of polluting heritage that still exists. Today, one of the major problems on the platform of the former Fertilizer Plant is the existence of all concrete b...
Autori: Aurica Grec, Florin Dumescu, Ladislau Klein
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25599

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract Anaerobic digestion (AD) is a complex biological system which can be affected by several operational problems. Among them, biological foaming is one of the most difficult to deal with. It has many effects, such as causing gas pipe clogging and probe failures, and it can affect mixing devices, etc. Since the mechanisms involved in biological foaming development are not fully understood, it is not included in standard anaerobic digestion models. For this reason, a knowledge-based risk ...
Autori: Eric Latrille, Ignasi Rodriguez-Roda, Jean-Philippe Steyer, Joaquim Comas, Jordi Dalmau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25610

Abstract The Schiff base N,N??(salicylidene)-methylenediamine, known as Salmen in combination with Cr(III) forms at pH = 4.5 a greenish precipitate, which is stable at room temperature but decomposed on heating. The study of the Infrared spectra, Electron Spin Resonance (ESR), X-ray diffraction and thermogravimetry has pointed out that the precipitation form is a complex, while the molar ratio showed that the combination rate of Cr(III): N,N?-bis(salicylidene)-methylenediamine is 1:1. The new...
Autori: Doina Sibiescu, Ioan Roşca, Irina Spatarescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25619

Abstract The aim of this study was to evaluate the capacity of certain bacterial and fungal strains - isolated from the dairy industry wastewater - to biodegrade the organic compounds such as casein, lactose and lactic acid similarly to those which determine the organic pollution. The strains able to rapidly biodegrade organic compounds were identified and screened for the inoculum preparation which is afterward tested for the aerobic biological treatment of the simulated dairy-processing was...
Autori: Gabriela Bahrim, George Ifrim, Marian Barbu, Mihaela Palela, Sergiu Caraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25625

? RESEARCH ON NaCl SALINE AEROSOLS I. NATURAL AND ARTIFICIAL SOURCES AND THEIR IMPLICATIONS ? DECISION SUPPORT MODELS FOR SOLID WASTE MANAGEMENT ? AN OVERVIEW ? POLICY AND STRATEGY FOR IMPROVING SUSTAINABLE SOCIAL DEVELOPMENT PROGRAMMES ? APPLICATION OF SHALLOW POND SYSTEM USING WATER HYACINTH FOR DOMESTIC WASTEWATER TREATMENT IN THE PRESENCE OF HIGH TOTAL DISSOLVED SOLIDS (TDS) AND HEAVY METAL SALTS ? TRENDS OF THE COMMUNITARIAN COHESION POLICIES AND ADVERTISING FOR EC...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25658

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

The variation of acidity and the wet deposition fluxes of rainwater in Nanning City were analyzed based on the local acid rain monitoring data provided by environmental protection authorities from 1991 to 2004. The result shows that the annual value of pH is less than 5.6 in the past 14 years and the wet deposition has been getting more and more severe in Nanning. The ratio of SO42-/NO3 - has decreased. NO3 - has played an increasingly large role in acidity, though SO4 2- remains a key player. T...
Autori: Feng-qin Zheng, Guo-liang Liao, Hai-hong Huang, Yu-chun Mo, Shen-xian Wuhttp://www.ecozone.ro/reviste.php?RID=25678

A chlorpyrifos-degrading strain of Stenotrophomonas acidaminiphila, lux-β was chosen for research object, and the survival and chlorpyrifos-degrading activity of strain lux-β in the soil with different treatments have been investigated in this study, so as to provide technique support for monitoring the colonization and degrading activity of chlorpyrifos-degrading bacteria in natural environment. The result indicated that the quantity of lux-β in the soil rose first and decreased ...
Autori: Dao-Sheng Wang, Ri-Mao Hua, Xin-Yun Tang, Rui-Xue Li, Jun Zhang, Yun-Lu Wanghttp://www.ecozone.ro/reviste.php?RID=25684

Acidithiobacillus ferrooxidans plays an important role in the pyrite oxidation process and has been widely studied in order to determine the kinetics of the reactions, but the details of the oxidation processes on the surface of pyrite keeps poorly known. In this study, the bio-oxidation process of pyrite by Acidithiobacillus ferrooxidans was studied by comparing with abiotic oxidation by Fe3+. The attachment of Acidithiobacillus ferrooxidans on pyrite surface was found by using Scanning Electro...
Autori: Lei Jiang, Huiqun Yang, Yuruo Tao, Jinyan Yanghttp://www.ecozone.ro/reviste.php?RID=25686

An increasing recognition of tillage erosion processes has shown that soil redistribution by tillage directly contributes to soil loss in mechanically and nonmechanically agricultural areas worldwide. Soil translocation by tillage is normally measured by means of tracers, with which a volume of soil is labeled, and therefore yielding tillage erosion rates in a field. Two tracer methods for estimating tillage erosion rates were appraised to understand the adaptability to local conditions in the h...
Autori: Jianhui Zhang, Fucheng Lihttp://www.ecozone.ro/reviste.php?RID=25687

The solubility and sorption behavior of naphthalene in the presence of dissolved organic acid was studied. The presence of dissolved organic acids at lower concentrations had only a little effect on naphthalene sorption. However, when the concentration exceeds a certain concentration, a significant inhibition was observed. Moreover, the inhibition enhanced with the increasing concentrations of dissolved organic acids. The change trend on solubility is similar to the sorption of naphthalene, that...
Autori: Jin hua Li, Bao xue Zhou, Qing Zheng, Wei min Caihttp://www.ecozone.ro/reviste.php?RID=25698

The paper analyses the removal efficiency and fluorescence spectroscopic characterization of landfill leachate dissolved organic matter (DOM) fractions in the combined stripping, fenton oxidation, sequence batch reactor, and coagulation process. The high contents of DOM of landfill leachate in each process unit were fractionated into HA, FA, and HyI. The result was the combined process availability for effective removal of DOM fractions. The removal rates for DOM, HA, FA and HyI were 91.9%, 97.1...
Autori: Zhiping Liu, Jin-song Guo, Fang Fanghttp://www.ecozone.ro/reviste.php?RID=25702

Because the green building industry starts late in China, both the government and developers have a vague view on incremental cost conception, component and algorithm of water-saving projects for green building. According to the comparative analysis of the project and economic efficiency between green building and traditional building in water-saving and water resource utilization aspect, this material presents the conception, component, algorithm and calculating method of the incremental cost i...
Autori: Qiang He, You-Zhi Hao, Fang Zhao, Hong Xiang Chaihttp://www.ecozone.ro/reviste.php?RID=25703

This paper presents a study of the numerical simulation applied for unsymmetrical dimethylhrazine (UDMH) gas dispersion. This study considers an assumed UDMH store conditions and provides important data regarding the relation between the concentration distribution of UDMH and dispersion distance from the source based on the computation fluid dynamic (CFD) software FLUENT. The simulation results show that the ventilation vent and distance of dispersion play an important role in the concentration ...
Autori: Zhiyong Huang, Guofeng Jin, Xuanjun Wanghttp://www.ecozone.ro/reviste.php?RID=25712

Abstract:In spite of the large use of batteries throughout the years, both in photovoltaic systems and in other uses, there are still nocomprehensive analyses in ageing studies and, when they exist, statistics turn out to be limited. In this sense, this macro-grid is aunique experience, since the experiment is already composed of 1600 identical stand-alone photovoltaic systems and almost 10years of data taking on 10 minute interval for the main magnitudes.In this paper, it is proposed a method f...
Autori: Angeles López Agüera, Daniel Rey Rey, Iago Rodriguez Cabo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25718

Abstract:The textile industry uses high quantities of water which in many cases are disposed to the environment with inadequate treatment.In this work the effluents from the polyamide textile industry containing Bemacid Gelb, Bemacid Rot and Bemacid Blau weretreated by heterogeneous photodegradation. Treatment performances have been evaluated in terms of conductivity, turbidity, totaldissolved solids (TSD), chemical oxygen demand (COD), total organic carbon (TOC), biochemical oxygen demand (BOD5...
Autori: Luminita Andronic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25720

Abstract:This technical paper presents some aspects concerning the static finite element analysis of a wind turbine blade. For themanufacturing of the blades for a 10 kW wind turbine elaborated at the Technical University of Moldova composite materialsmade up of polyester matrix reinforced with fiber glass are being used. In order to determine the mechanical properties of theproposed composite materials 10 different samples of laminated composite plates were numerically simulated in ANSYS 11....
Autori: Marin Guţu, Viorel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25747

Abstract:Methyl orange and methylen blue are two dyes resulted from the textile industry. They are not raising just esthetical problems, butthey are toxic and hence harmful to aquatic animals. The aim of this study is to test the capacity of three types of sawdust (oak,willow and white poplar) and mixed substrates, sawdust: fly ash (FA), to remove the methyl orange (MO) and methylen blue(MB) from wastewater. The influence of contact time, solution pH and initial concentration of dyes on the blea...
Autori: Anca Duta, Dora Lucaci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25752

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:Ash is a waste that can be an efficient substrate in wastewater treatment for the immobilization of heavy metals and for dyesremoval. For an up-scalable wastewater treatment process, efficient substrates, with relatively constant behavior are needed andmodifying the adsorbent surface can be a feasible solution. Fly ash, resulted from coal burning, and wood ash are mixtures mainlycontaining metal oxides and carbon in various proportion, depending on the initial raw material.The paper pre...
Autori: Maria Visa, Mihaela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25771

Abstract:Our research was focused on developing some new procedures to reduce the biodegradable wastes by composting. The aim of thisstudy was to obtain and asses at laboratory scale the maturity of three compost samples of different proportion of vegetable waste,beech sawdust and sewage sludge by analyzing their FT-IR spectra and C/N ratio. The composting process was monitored by testsperformed weekly on the three samples in order to investigate the physical parameters (pH and electroconductivi...
Autori: Anca Sauciuc, Claudia Zaha, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25772

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Titanium metal and its alloys have been widely used as implants under load-bearing conditions due to their biocompatibility, excellent corrosion resistance and lightness, but their inability to bond to living bone is a setback. The experiments outlined here investigated hydroxyapatite (HA) coating on Ti metal implants, used to enhance their bioactive properties. In this study, specimens of commercially pure titanium (c.p. Ti) and Ti-6Al-4V were etched in either H3PO4 or HCl, and subsequ...
Autori: Chao-Lun Fu, Hsueh-Chuan Hsu, Shih-Ching Wu, Shih-Kuang Hsu, Wen-Fu Ho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25795

Abstract: In this study, decolorization and degradation of aqueous nickel phthalocyanine reactive dye solutions was comparatively studied by electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton processes. In the electrocoagulation process with aluminum electrodes the colored aqueous solutions containing 100 mg/L nickel phthalocyanine and 6 g/L NaCl were treated at initial pH 7.5 and applied current densities of 5, 10 and 20 mA/cm2, where fast and 100% decolori...
Autori: Achilleas Christoforidis, Dimitrios Marmanis, Evgenia Valsamidou, Konstantinos Dermentzis, Konstantinos Ouzounis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25804

The aim of this work is the study of activated sludge floc samples stained with different dyes and imaged by Confocal Laser Scanning Microscopy (CLSM). Activated sludge flocs were stained for lipids, sugars and esterase enzyme producing bacteria. Images were acquired for different samples to analyze the structural characteristics of the bioaggregates. The analysis of the CLSM images allowed for the localization and estimation of the quantity of different build-up materials. The 3-D reconstructio...
Autori: Bela Abraham, Botond Raduly, Dan Niculae Robescu, Szabolcs Lanyi, Szabolcs Szilveszter, Szilard Bucs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25937

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

The most important argument of this experiment was to demonstrate an increased content of active principles under the influence of some substances (considered in the literature as mutagene), when used in low concentration, do not affect the environment. The purpose of this study was the selection of some treatment variants, which, during the experimentations show the same biosynthetic potential, stabilized or increased. The substances used in the experiment were ethidium bromide at the concentra...
Autori: Constantin Leonte, Marius Zaharia, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25867

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

2This study shows the dyeing behaviour and impact over the wastewaters quality resulted from dyeing wool fibres, of a new synthesized premetalated dyes, derived from new acid dye, sodium(E)-2 –((1-amino-4-sulphonatonaphthalen-2-yl)diazenyl)-6- methoxybenzo[d]thiazole- 5 or 7 –sulphonate, as a result of interaction with Ni(II) and Zn(II) ions. In order to characterize the complexed dyes they were studied in both phase: solution and solid phase. The dyeing performances assessment and the envir...
Autori: Ion Sandu, Laura Chirila, Maria Marcela Tarlea, Romen Butnaru, Viorica Vasilache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25886

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

Two experimental periods have been undertaken to investigate the biodegradability of sewage streams (mainly regarding the organic substances) produced by a gas cartridge production, filling and distribution company. A sequencing batch reactor (SBR) was used for the laboratory examinations launched with municipal sewage sludge with a concentration of approx. 3 g MLSS/L. The various conditions in the reactors followed each other cyclically (fill, anoxic, aerobic, settle, draw) three times a day. T...
Autori: Bence Fazekas, Karoly Reich, Krisztian Varga, Viktoria Pitas, Viola Somogyi, Zsuzsanna Banyai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25902

AbstractThe adsorption of hexachlorocyclohexane (HCH) by modified meerschaum was studied. The comparison of the meerschaummodified by anion and cation surfactant was conducted to explore their effect on HCH adsorption. The results showed that theabsorbability of HCH by the CTMAB-M (cetyltrimethylammonium bromide-modified) is better than that of SAS-M (sodiumdodecyl sulphonate-modified) because the CTMAB-M has fluffier fibers structure. The addition of amount of adsorbents shouldimprove the adsor...
Autori: Chanjuan Gao, Shengke Yang, Wenke Wang, Yaqian Zhao, Yue Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25948

AbstractWastewater from butyl rubber production is causing an increasing environmental problem due to its large quantity and complexquality. In this paper, two types of wastewaters generated from rubber synthesis, i.e. alkaline wastewater (AW) and cleaning andflushing wastewater (CFW), were investigated. Coagulation and flocculation were firstly applied to remove suspended solids(SS) from the AW. By single factor experiment, the optimum operational conditions were obtained as pH 8, PAC dosage 40...
Autori: Lujun Chen, Rui Liu, Wei Li, Wei Zheng, Yan Zhang, Ying Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25950

Geochemical cycling of reduced inorganic sulfur in sediments may affect water quality. This study investigated the reducedinorganic sulfur distribution and environmental behaviour in superficial sediments in different watersheds and coastal zones inBohai Bay, China. Acid volatile sulfur (AVS), chromium (II)-reducible sulfur (CRS) and elemental sulfur (ES) distributed insurface sediment were quantified. Total organic carbon and total nitrogen were presented in higher concentrations in the fluvial...
Autori: Robert Mortimer, Simon Bottrell, Wenjing Shi, Yanqing Sheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25959

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractIn this paper integrated network of continuous reactors for the decontamination of gaseous flows in heterogeneouscatalytic gas-liquid-solid – also applicable for bioremediation systems is investigated. For this purpose, duringprocess integration we have identified strategies to develop an optimal system for a variety of well-definedrequirements and to discover ways to ensure cost efficiency to achieve the requirements of sustainable industry in theframe of knowledge-based sustainable eco...
Autori: Maria Gavrilescu, Oana Marlena Penciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25977

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

AbstractThe stability of soil aggregates is an indicator of soil structure. Soil acidity affects soil structure stability. Soil acidity has twocomponents: active acidity and exchangeable acidity. In natural conditions, each soil type has a certain level of acidity, which isgiven by its composition, natural vegetation, the chemical composition of precipitations and other factors that cause changes overtime in soil pH. Acidic soils are characterized by physical, chemical and biological properties ...
Autori: Dorin Cotiusca Zauca, , Lucian Vasile Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26064

AbstractCombined electrocoagulation (EC) and homogeneous phase TiO2 photo-assisted system were applied to methyl orange (MO)wastewater treatment. Optimum including current density, initial concentration of MO, TiO2 concentration, pH, solutionconductivity and electrode distance were investigated. 98% decolorization (initial concentration = 500 mg/L) was achieved in 30min with a current density of 125 A/m2, electrode distance of 2.5 cm, electrolyte KCl concentration of 0.5 g/L, initial pH of 6.86,...
Autori: Yi Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26090

Mother Earth Investments AG, is actively working onthe development 2nd generation bioenergy feedstocks.In this book, Mr. Jansen generously shares hisknowledge in the field, in particular, regarding thechallenges and opportunities in development ofbiomass-derived fuels. This essential guide toinvesting in bioenergy commodities details secondgeneration biofuels from a scientific, technical andeconomic perspective, and discusses their globalenvironmental, political and financial impact.The book is ...
Autori: Roland A. Jansen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26100

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Poly(hydroxybutyrate) (PHB) is a biodegradable thermoplastic polyester with very high potential for industrial applications. The properties could be improved by mixing with another polymer, natural or synthetic, such as poly(vinyl alcohol) (PVA). The resulting polymer blends are potentially able to achieve the desired performance for different applications. Biodegradation modifies mechanical, physical and chemical properties of a given material. PHB are degraded by diverse...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26111

Abstract This study focuses on the local scale behavior of SO2 emissions resulting from lignite-combustion thermal power plants. The investigations aimed at monitoring the SO2 emissions and imissions over a two week period in September 2010. One of the largest power plants from Eastern Europe was chosen for monitoring using different optoelectronic techniques. Rovinari power plant (44o54’45”N – 23o09’44”E) is one of the largest electricity suppliers of Romania, having 4 groups of 3...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26113

Abstract Nowadays, all over the world, the car transport sector is one of the main factors responsible for the Greenhouse Gas Emissions. The current systems of emission taxation do not take into consideration the distance travelled by cars; therefore, they are not fully compliant with the “polluter pays” principle. In addition to the produced inequality, these systems do not encourage the reduction of the distances travelled annually (with possible favorable effects on pollution an...
Autori: Cristian-Mihai Dragos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26120

Abstract Agriculture is an axis of socio-economic development of the area of Denguele, Cote d’Ivoire. The evaluation of a project carried out as part of an agricultural campaign requires the handling of large amounts of heterogeneous data for effective monitoring. The design of an appropriate management tool is needed to organize and communicate information useful for decision making. The aim of this work is to provide a useful tool for a better management of information related to...
Autori: Arthur Brice Konan-Waidhet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26137

Abstract Our researches have focused primarily on variations of different biophysical and biochemical effects on vegetal and animal material at macro, micro, and ultra-micro scale resulted from changes in environmental condition. Growth and spectral parameters of rapeseed seedlings from seeds exposed to UVA-VIS radiation with a high pressure lamp which emits incoherent continuously radiation for different time periods were examined 14 days after germination. These studied parameter...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26138

Abstract Pesticides can be considered useful to eliminate pests, but can also induce negative effects to the processes of germination, growth and development of plants or disrupt some physiological and metabolic processes. By studying the effect of pesticides on treated seeds germination, and determination of growth indices, it was possible to evaluate the positive or negative influence or toxicity of the chemical compounds. The aim of this research is to highlight the effects of d...
Autori: Daniela Nicuţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26142

Abstract Avocado post-harvest losses and cultivar-oriented trade are relevant issues in Cameroon that affect producers and retailers incomes. Identifying specific chemical characteristics of avocado oils would give an added value to underutilized species. Five avocado varieties, Booth 7, Booth 8, Collinson, Hickson and Lula, were subjected to aqueous extraction and the Attenuated Total Reflectance-Fourier Transformed Infrared spectrometry coupled with chemometrics (ATR-FTIR) profil...
Autori: Brice Ulrich Saha Foudjo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26143

AbstractTo understand the typical organic pollutant contamination status of the main source water in Yellow River basin, samples werecollected from fifty source water points (including reservoir and river) in Yellow River basin. The samples were analyzed for therepresentative organic pollutants, including benzene homologous, chlorobenzene compounds, organophosphorous pesticides, and nitrobenzene compounds, total of 17 compounds. It was observed that all concentrations of the 17 compounds in the ...
Autori: Jijun Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26155

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractAccommodation profoundly affects energy use and carbon dioxide emissions in the tourism sector. This paper focuses on starratedhotels in China, and applies a bottom-up approach to estimate the amount of carbon dioxide emissions from tourismaccommodation in 1998–2009. The results show that carbon dioxide emission of star-rated hotels increased from 4.37 million tonin 1998 to 16.82 million ton in 2009 (an increase of 3.84 times). Although the amount of carbon emissions is increasing, the r...
Autori: Zi Tang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26185

AbstractThe dominant litter samples Pinus sylvestris L. needle litter and Acer platanoides L. leaf litter were collected in the coniferousmixed forest located at 54ş43‘ N 25ş19‘ E (Vilnius, Lithuania) in April 2010. Different heating temperatures (150, 250, 350, 450and 550şC) and 2 hour heating duration were used to produce ashes. The selected heating temperatures affected mass loss, colour, pH, electrical conductivity (EC), C/N ratio, nutrient concentrations of the ash. The darkness of Munsell ...
Autori: Jolita Dūdaitė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26208

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractIn this study, as part of developing a green recycling process of spent lead-acid battery that can avoid both smelting and electrowinning, leaching agent citric acid and other additives (such as sodium citrate and hydrogen peroxide) in aqueous media were reacted with spent lead-acid battery paste. PbO, PbO2 and PbSO4, which are the three main components in a spent lead-acid battery paste, were leached to form lead citrate precursor which was crystallized and then separated from the solut...
Autori: Xinfeng Zhu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26215

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractGlobal warming is happening due to increasing level of carbon dioxide and other greenhouse gases into the atmosphere. In orderto reduce this rising level of CO2 emitted by human activities, carbon capture and storage technologies are being developed.The present paper investigates and compares, from a techno-economical point of view, two of the most used conceptual methods(post- and pre- combustion) for CO2 capture generated from the fossil fuel power generation sector. For post-combustio...
Autori: Anamaria Padurean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26217

AbstractDespite the Moderate Resolution Imaging Spectrometer (MODIS/Aqua) presently collects data on operational basis, evaluationof its biogeochemical products from standard bio-optical algorithms is scare especially in Arctic waters. The present study isaimed to evaluate several MODIS/Aqua bio-optical algorithms and MODIS/Aqua remote sensing reflectance (Rrs) products inKongsfjorden waters on the western side of Svalbard, Arctic. Data sets consisting of in-situ measurements of radiometric quan...
Autori: Palanisamy Shanmugam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26220

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractThe aim of this study is to evaluate the treatment performance of mono azo dye Methyl Orange (MO)-containing wastewater byrecirculated up-flow constructed wetland (UFCW) with and without supplementary aeration. The successive anaerobic andaerobic treatment of the UFCW reactors could effectively remove color, organic matters and intermediate aromatic aminessimultaneously in a single reactor. With influent 50 mg/L of MO, the removal efficiencies of COD and MO were 91 and 75 %,respectively,...
Autori: Soon-An Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26254

AbstractThis study is focused on simulating and optimizing design and configuration of anaerobic baffled reactor (ABR) by means ofartificial neural network (ANN). This approach is aimed to assess an efficient ABR performance in various operational conditionstreating municipal wastewater. For this purpose, to analyze comprehensively on a base of experimental data, the system isoperated in two pilots of 48 liters net volume made of 8 compartments. In 7 months, more than 130 sets of data are obtain...
Autori: Gagik Badalians Gholikandi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26260

AbstractA novel RHA/PFA/CFA sorbent was developed by sol-gel method using three types of ashes, i.e. rice husk ash (RHA), palm oilfuel ash (PFA) and coal fly ash. From surface analysis of selected RHA/PFA/CFA sorbents, the spent sorbent had more compactstructures covered by irregular rough surface and the specific structure of raw RHA, PFA, and CFA were no longer visible. Inaddition, lower specific surface area was obtained for spent RHA/PFA/CFA sorbent. Batch studies were performed to evaluatet...
Autori: Irvan Dahlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26272

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe paper compares the electrocoagulation performance during the removal of Acid Brown 14, Acid Yellow 17, Acid Blue 113and Acid Black 172 dyes from aqueous solutions. For this purpose, pH changes and effectiveness of main parameters includinginitial dye concentrations and current densities for the selected dyes were examined. In addition, effluent turbidity, energyconsumption and amounts of released aluminum were also investigated. The present work shows that Acid Yellow 17 removaleffic...
Autori: Mahsa Taheri, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26310

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractThe environmental pressure brought by foreign direct investment (FDI) to China has been an increasingly common topic. It is thecurrent and later policy tropism to protect environment all-sided and keep the environmental elements continual use in making useof FDI in China. Environmental effect of FDI is a "double blade sword". This paper first analyzes the environmental effects ofFDI and the terms of its positive effect, and then analyzes the negative environmental impacts of FDI in China...
Autori: Hong-Min Qu, Lu Yang, Yan-Bo Zhang, Ye Liu, Ze-Shen Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26372

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

EVENT...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26453

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

AbstractThe purpose of the present study is the comparative investigation of the calcium cations removal from aqueous solutions usingtwo strong acid cationic resins recommended during the last years for water softening. The performances of the two resins wereevaluated by the means of the cationic exchange capacity and the retention degree of the calcium cations. The evaluation of thetwo resins behaviour in the ion exchange process was performed by the means of the FTIR spectra recorded on the re...
Autori: Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26489

AbstractEnhanced nitrogen inputs to both terrestrial and aquatic ecosystems affects biodiversity at all its levels. Grasslands provide acomplex range of functions, due to their wide representation throughout terrestrial ecosystems. Numerous studies demonstratesoil acidification, eutrophication and species richness reduction as a result of elevated reactive nitrogen availability. The presentstudy aims to assess soil nitrogen stocks and transformations for two Romanian grasslands during November 2...
Autori: Carmen Postolache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26497

AbstractAs air quality becomes increasingly deteriorated in world-wide cities, air quality monitoring has extended beyond the criteriapollutants (CO, SO2, NOx, O3 and PM) in order to include several toxic air pollutants such as volatile organic compounds(VOCs). In the present study it was investigated the presence of 29 VOCs and PM including PM2.5, PM2.5-10 and PM>10 fractions,in an urban area from Romania. The total VOCs was higher in the urban area (176.72 - 192.54 μg/m3) than in the r...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26504

AbstractThe mining waste facilities in the Baia Mare region, Romania, resulted from the extraction of poly-metallic ores (including Au,Ag). Metal sulphide minerals from the mining waste facilities have a potential to produce acid rock drainage (ARD) and togenerate risk for the environment, including for the water resources. Some of the mining waste deposits from the region arelocated near the town of Baia Mare, close to the residential areas, the agricultural lands and the surface water. The sho...
Autori: Oana-Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26512

AbstractThe alkylation of light hydrocarbons leads to produce the high octane number gasoline blending components. The homogeneouscatalytic alkylation reaction is usually carried out at low temperature in the presence of H2SO4 and HF. The use of heterogeneouscatalysis for this reaction is a promising solution for the replacement of hazardous acids to environmentally friendly zeolitecatalyst. The alkylation reaction of isobutane with 1-butene was studied on selected zeolite catalysts. The objecti...
Autori: Tatjána Juzsakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26514

AbstractPetroleum tanker trucks are integral vehicles for delivering fuel and other petrochemical products from place to place and must becleaned regularly. Pressure washing with hot or cold water serving to remove oil and filth from the tanker truck container,produces oily waste water with an oil concentration of about 300-500 mg L-1 which, according to environmental standards andregulations worldwide, must be disposed of and treated properly. In the present paper an integrated electrochemical ...
Autori: Konstantinos Dermentzis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26520

AbstractThe primary objectives of this study were to identify the ecotypes of the ‘longicaulis’ giant reed (Arundo donax L.) that arewinter-frost and cold tolerant in temperate climates on marginal lands and to perform biotechnological research on theseecotypes. We searched for large ‘longicaulis’ giant reed ecotypes, which wintered successfully in spite of the 2012/2013 winterfrosts and sprouted from stem nodes in the spring of 2013 in three locations of the Balaton basin. Starting in vitro cul...
Autori: Gabriella Antal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26527

AbstractIn our study, we examined the annual carbon footprint and energy balance of a Hungarian biogas power plant with a poweroutput of 0.637 MW in 2013, with reference to the complete life cycle of the biogas production. The life cycle analysis (LCA)considered the emissions of greenhouse gases (GHG) during the production of feedstock and its transportation into the powerplant, during the operation of the factory and during the process of rendering the discarded waste materials harmless. Weesta...
Autori: György Szabó
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26548

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractThis study aims to understand the acid-leaching behavior of metals from 2 to 4 mm waste printed circuit boards (WPCBs)containing 22.0% ą 1.1 Cu, 6.7% ą 0.2 Ca, 0.68% ą 0.02 Sn, 0.59 ą 0.01 % Pb, 2.71% ą 0.08 Al, 0.22% ą 0.01 Fe, etc..Copper leaching was increased for sulfuric acid concentrations up to 1.2 mol/L and hydrogen peroxide concentrations of 10.0vol% for a pulp density of 100 g/L at 50°C over 4 h, whereas for the same concentrations of sulfuric acid and hydrogen peroxidecopper l...
Autori: Manoj Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26566

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract The feasibility of catholyte-conditioning to enhance the electrokinetic (EK) remediation of cobalt and lead polluted soil has been investigated in this study. Electrokinetic experiments were conducted using an EK cell 10 cm in width, 10 cm in height, and 50 cm in length. Plate type electrode of graphite was used as electrode material. Two experiments were conducted under constant voltage condition (2 V/cm). The pH values of the soil significantly affect the removal of Co and Pb ions...
Autori: Mahdi Bahemmat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26623

Abstract Malathion is a toxic, wide-spectrum organophosphorus pesticide. The removal of this pesticide from water is one of the major environmental concerns. In this study, the biodegradation of malathion using batch activated sludge was studied. The effect of initial malathion concentration (5 to 140 mg/L) on the degradation process was investigated. The biokinetic parameters (rs max, Ks and Ki) were estimated. Identification of dominant bacterial flora was also achieved. In addition, two k...
Autori: Djaber Tazdaďt
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26625

Abstract The degradation of polycyclic aromatic hydrocarbons (PAHs) including fluorene, phenanthrene, anthracene, fluoranthene and pyrene were investigated under thermophilic and mesophilic anaerobic-methanogenic conditions. By using central composite design, the impact of PAH concentration and soil to inocula ratio were systematically studied for their influence on PAH removal and biogas production. During the first 30 days, PAH concentration decreased in all samples indicating that the ino...
Autori: Tahseen Sayara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26629

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract Anaerobic digestion was analyzed as the biological process that converts the organic matter present in various types of wastes, activated sludge from the wastewater treatment facilities respectively, into biogas. Latest advancements in the mathematical modeling, simulation and control practices have helped in gaining a better insight of the process. In this paper, an energy efficiency and techno-economical investigation of anaerobic digestion technology for the CHP cogeneration unit...
Autori: Alexandrina Zuza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26648

Abstract Hydrogel membranes obtained by neat polyvinyl alcohol (PVA) or PVA with various bio insertions like: Scleroglucan (Scl), Zein (Zein) or Cellulose (Cel), were subjected to diffusion and sorption/desorption experiments using different type of dyes such as: Crystal Violet (CV), Methylene Blue (MB), Congo Red (CR). If the sorption, desorption or diffusion of a dye in/from/through a hydrogel is usually monitored by the dye solution analysis, in this case the transport phenomena are follo...
Autori: Adina Papancea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26649

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract Succinic acid is widely used in different industries, its demand increasing each year. Therefore, efficiently producing it (especially from bio-regenerable sources) is an aspect that researchers try to solve thorough different methods, one of the approaches consisting in using process models for generating predictions and improving production by process optimization. In this work, a combination of two bio-inspired algorithms represented by Artificial Neural Networks and Clonal Selec...
Autori: Elena-Niculina Drăgoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26669

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract The performance of electrocoagulation (EC) process, a non-specific electrochemical technology, was investigated for the removal of carbamazepine (CBZ), an antiepileptic drug, from water. Experiments were carried out in synthetic wastewater in a batch cell. The respective influences of some key process parameters were studied, such as mixing conditions, initial pH, and current on aluminium electrodes. Experimental results showed that a CBZ removal efficiency of 62% was observed under...
Autori: Tania Yehya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26683

Abstract The present study explores the potential of Streptococcus epidermis, an indigenous isolate for biotransformation of phenol and phenol derivatives. Different phenolic derivatives such as 4-methylphenol, methylbenzene, 2,4-dichlorophenol, 2,6- dichlorophenol and 4-nitrophenol were attempted for biotransformation study. The results have shown that 4-nitrophenol was best transformed. The effect of degradation parameters like pH and temperature was studied, showing the value of 7.0 as o...
Autori: Bhavana V. Mohite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26705

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract The paper investigates the role of the Common Agriculture Policy support in the economic sustainability of sheep breeding farms from North-Western Romania (Transylvania), focusing particularly on the Agri-Environment Schemes (AES). The region has important High Natural Value (HNV) grassland areas significant for bio-conservation. To analyze their importance in the overall economic viability, individual data was collected from 207 farms using a stratified sample. A principal componen...
Autori: Mugurel I. Jitea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26716

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract Large quantities of snail and clam shells are left as waste material when their meat is used as food for people. It has been a big problem that how to treat these wastes and usually these are land filled as wastes. In the present paper, these shells are studied as recycling resource for phosphate removal from solutions. Laboratory-scale batch experiments were conducted to evaluate the efficiency of snail and clam shells in removing phosphate from aqueous solutions. Major factors inv...
Autori: Ji Bing Xiong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26727

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

`Abstract End of life tires require sound accounting of environmental performances to design sustainable procedures for material recovery. Their use in rubber modified asphalt provides could lead to the improvement of technical and environmental performances of asphalt roads, but the effectiveness of simplified procedures is to be proved. During LIFE+ project ROADTIRE, a rubber modified asphalt road prototype, with the upper surface layer containing 10% crumb rubber in the bituminous binder,...
Autori: Irene Bartolozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26741

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract In order to verify the possibility of agricultural drought forecasting and prediction of agricultural yields in a given region, two climatic indices were used to monitor drought: Standardized Precipitation Index (SPI) and Bhalme - Mooley Drought Index (BMDI). For the case study were taken into account conditions in Oradea, from Crişurilor Plain, which is located in the Western Romania. Evolution of dry periods determined by the two indices is similar but there are differences i...
Autori: Nicu Cornel Sabău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26766

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract Energy costs not included in consumer utility invoices include human health problems triggered by air pollution from burning fossil fuels, and environmental degradation caused by global warming, acid rain, and water pollution. Such costs, peripheral to energy pricing, are called externalities because electricity producers and users do not pay for them directly. Society as a whole must pay. This pricing system masks the true costs of fossil-based electricity generation plants, result...
Autori: Hasan Karimzadegan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26862

Abstract To assess the pollutants input of acid mine drainage (AMD) and domestic activities in Aries River, the water was monitored monthly, during one year, in 15 sampling points along the River. The dissolved metals (Ca, Mg, Na, K, Fe, Cu, Zn, Mn), anions (SO42-, NO3- and Cl-), pH and electrical conductivity were analyzed. The obtained data were assessed against the water quality standards, Principal Component Analysis (PCA) and Hierarchical Cluster Analysis. The results revealed the water...
Autori: Erika Andrea Levei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26881

Abstract The general goal of the research was to integrate organic food consumer behavior into the topic of the management of environmental security. The detailed objectives were to determine Romanian consumers’ beliefs about organic food and its role for environmental security, to identify consumers’ judgement of environmental problems, to establish the influence that demographic and social variables have on consumers’ beliefs and to emphasize the relationship between thes...
Autori: Dacinia Crina Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26886

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The results of batch tests of anaerobic dechlorination on groundwater samples collected downgradient from an industrial site in Northern Italy are presented and discussed. The experiments were carried out using sucrose as electron donor at equimolar concentration and at selected excess with respect to the total reducible species. The purpose of the study was to investigate the effectiveness of sucrose to achieve a complete chlorinated solvents degradations at the specific site, and ...
Autori: Luca Di Palma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26895

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

Abstract Trace metal elements commonly exist in drinking water. Excessive exposing on them may result in lots of health problems. This paper mainly focuses on the accumulations of Cu2+, Cd2+, and Pb2+ in drinking water supply networks with amorphous Al(OH)3 formation. The effects of pH, water flow rate, and metal element contents were investigated at laboratory bench scale. It was found that chemical adsorption mainly occurred at pH > 7.0. Suspended Al(OH)3 showed a strong adsorption capa...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26906

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Abstract The present study was designed to determine the sound effects of ultrasonic treatment and the biologically mediated extraction of uranium from low grade black shale. Low grade uranium was subjected to fungal treatments assisted by sonication by conventional methods. In situ fungal leaching of black shale with different fungal strains in the presence of molasses as growth substrate resulted in highest leaching yield of uranium by Phoma tropica (57.73%) compared to Penicillium chrysog...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26919

Abstract A new assessment method of groundwater vulnerability was done using multilayer data analysis through GIS Spatial Analyst Tools. The method presented here refers at Beliș district territory and describes two tasks: (1) groundwater vulnerability determination from Water Surplus, Ecosystem Services, Aquifers map, and Infiltration map; (2) the future vulnerability assessment for 2050, considering four scenarios of land cover and climate data changes. First results, carried out by p...
Autori: Mărgărit-Mircea Nistor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26921

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

The pickling liquor used in the stainless steel manufacturing process is a mixture of nitric and hydrofluoric acid which generates wastewater with nitrate concentrations ranging between 500 and 6000 mgNO3--N/L. In the present study, laboratory-scale anoxic Sequencing Batch Reactors (SBRs) were used to treat high nitrate wastewaters. Two different sludge inocula were tested: one from a Municipal Solid Waste Leachate Treatment Plant (LTP), and the other from a Sewage Treatment Plant (STP). Meth...
Autori: Ana Isabel Pelaez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26933

The influence of key process parameters of homogenous catalytic ozonation using ferrous or manganese catalysts on the mineralization rate of salicylic acid (SA), model pharmaceutical pollutant, in water was investigated. In order to assess the combined influence and interactions of studied process parameters as well, the empirical/statistical approach applying Box- Behnken experimental design (BBD) combined with response surface methodology (RSM) was applied. Three numerical and one categori...
Autori: Kresimir Koricic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26939

In this work biodegradation of basic fuchsin and methyl red by the blue green algae Hydrocoleum oligotrichum and Oscillatoria limnetica was investigated. The degradation of basic fuschin after 7 days by H. oligotrichum and O. limnetica was 92.44% and 90.23%, respectively. On the other hand, the degradation of methyl red by H. oligotrichum and O. limnetica after 7 days was 53.23% and 50.18%, respectively. The degradation of these dyes by algae seems to be related to the molecular structures of...
Autori: Ghada W. Abou-El-Souod
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26949

Various plants were investigated here as bioindicators for control of the environment. Grass, moss and leaves of maple, birch and oak from different locations, i.e., mining, chemical industrial sites and open green area in a small industrial town in the southwestern Poland (Zloty Stok) were examined. Concentrations of As, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Se, Sr, Ti, V and Zn were measured by the ICP-OES and CVG-ICP-OES techniques. Infrared spectroscopy (FT-IR) was used to inves...
Autori: Lukasz Zarebski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26951

Treatment of agrochemical industry wastewater is difficult to carry out unless integration with some advanced oxidation process (AOP) is used. The present study deals with treatment of an agrochemical industry wastewater, first using activated sludge and then with sulfuric acid treated activated carbon (SAAC) in presence of Fenton reagent. During the activated sludge treatment the food-to-microorganisms (F/M) ratio is varied from 0.1 to 0.2 mg chemical oxygen demand (COD) per mg mixed liquor ...
Autori: Makarand Vasant Karkare
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26957

Ranunculus rionii and Ceratophyllum demersum develop aquatic dense stands, which lately started to represent a major ecological concern for all the ponds and/or lakes in Romania. The potential relationships between the phytochemical compounds detected in these plant extracts (acids, phenols, heterocycles, alcohols, hydrocarbures) and the allelopathic properties against Gram positive and Gram negative bacterial strains and microalgal cultures were investigated and discussed in the current stud...
Autori: Mariana Lupoae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26971

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

Biomass is a very important source for the production of biofuels. During the hydrolysis step of the process for obtaining biofuels the rate of decomposition of biomass is strictly related to its organic matter content and the operating mode of the facilities. This paper highlights the effect of different pretreatments on the composition of biomass at the molecular level using Fourier Transform Infrared Spectroscopy (FTIR) and Principal Component Analysis (PCA). For this experiment, a mixture...
Autori: Andreea Cocarcea Rusei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26986

In this study, Sick Building Syndrome (SBS) is surveyed in the residential buildings of Ekbatan, a district in the Western part of Tehran. A number of 330 individuals were selected randomly. It was investigated whether factors such as the physical conditions of the sampled buildings, occupation and lifestyle-related behavior such as smoking were associated with the intensification of irritation and mental symptoms. The symptoms of SBS were observed positive in 56.4% of the cases. The worst sy...
Autori: Amir Sheikhmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26998

Adsorption studies of cadmium(II) were conducted on 623oK or 723oK carbonized banana peels named as BP623 and respectively BP723 as well as on the dried ones (BP). Carbonization enhances the quality of organic by-product used as adsorbent, reduces the equilibrium time and improves the quality of the final product (water). Evaluation of the effects of pH, contact time and solution temperature showed that the uptake of cadmium(II) ions was highly dependent on these factors, and increased with ...
Autori: Josiane Ponou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27009

The diversity of life cycle impact assessment (LCIA) methods may create barriers to life cycle assessment (LCA) since the focus and outcomes generated could be quite different. Furthermore, these could lead to different interpretations and hence affect the robustness of LCA. While previous studies have attempted to compare various LCIA methods, their results are limited to the cases that were used in their respective studies. To assist LCA participants in selecting a suitable LCIA method to a...
Autori: Ya Hong Dong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27012

Maghemite nanoparticles (γ-Fe2O3) were synthesized in order to be used as magnetic adsorbent for two heavy metals, Pb(II) and Zn(II), from aqueous solutions. γ-Fe2O3 was prepared from magnetite nanoparticles and was tested for single and binary aqueous solutions. Efficiency removal (%) for single solutions appears only after 10 minutes and was higher than 80%. In case of binary solutions, same results regarding efficiency removal were registered after 60 minutes, being almost 90% ...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27029

An environmental axis consists of elements, and the way they behave reflects the conditions in which they work. Romania, for example, is a country located at the crossroads of the most important environmental axes of the continent, namely the West-East axis: Western Europe - the ex-Soviet space; the North-West - South-East axis: Central Europe - Asia Minor and the Middle East; the axis of the seas: the Caspian Sea - the Black Sea - the Mediterranean; the axis of rivers and canals: Rhine - Mai...
Autori: Călin-Cornel Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27044

This study highlights the potential use of yellow Zea mays seed chaff (YZMSC) biomass as a biosorbent for the removal of Cr3+, Cd2+ and Pb2+ ions from aqueous solutions. Fourier transformed Infrared analysis of the biomass suggests that YZMSC biomass is basically composed of cellulose and methyl cellulose. The biosorption capacities, qmax, of YZMSC biomass for Cr3+, Cd2+ and Pb2+ are 14.68, 121.95 and 384.62 mg/g respectively. Biosorption equilibrium was achieved at 20, 30 and 60 min for Cr3+...
Autori: Jonathan Oyebamiji Babalola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27083

Membrane technology has become a fundamental unit operation in the industry and society of nowadays and fouling is, probably, the most important concern related with this technology. Fouling is a complex process that can limit the performances of facilities using membranes. Many research efforts have been done in order to reduce fouling tendency. Ceramic membranes can play a major role in fouling mitigation due to its high hydrophilic nature. This paper describes the characterization of a new...
Autori: Mihaela-Elena Dascalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27089

The release of low molecular weight (LMW) organic acids under lead (Pb) and zinc (Zn) stresses in Typha latifolia (T. Latifolia) and Vetiver zizanioides (V. zizanioides) were investigated. In addition, changes in antioxidative enzymes: superoxide dismutase (SOD) and peroxidase (POD) in the leaves of T. Latifolia under Pb stress were also examined. Amongst the eight types of LMW organic acids detected in the present study, oxalic acid was found to be the most dominant during Pb and Zn treatmen...
Autori: Yu Bon Man
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27092

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

Iron humate (IH) produced as a waste by-product during the industrial manufacture of humic substances from young brown coal was tested as a new cost-effective sorbent for the removal of inorganic arsenic from waters. Its removal efficiency was compared with that of two other non-conventional sorbents – magnetite and oxihumolite (weathered brown coal). Magnetite and IH have been found to be effective in removing both forms of inorganic arsenic (arsenite and arsenate) from aqueous solutio...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27098

The research presented in this paper aimed to investigate the relationship between sludge anaerobic biodegradability and degree of sludge disintegration based on COD (DDCOD) in a wide range from 0 to 66.7%. Sonication as an advanced sludge pretreatment was used to disintegrate sludge. Meanwhile, biogas production in the anaerobic digestion process was used to present the sludge biodegradability. The performances of anaerobic digestion for pretreated sludge at different degrees of disintegrati...
Autori: Shuyu Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27100

This study was carried out to monitor the presence of organophosphorus in drainage water (Kafr El-Sheikh (Kotshinar Drainage), Fowa (Fowa Drainge No.11), Metobess (El-Hokss Drainage), Beila (Karakat Drainage), Balteem (Hafeer Shihabeldeen Drainage), Nashart Drainage and El-Hamoul (El-Hamoul Drainage) in Kafr-El-Sheikh Governorate, Egypt. Furthermore, the efficacy of chemical (advanced oxidation processes) and bioremediation (effective microorganisms) for chlorpyrifos removing in drainage wat...
Autori: Aly Derbalah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27104

In order to improve the soil fertility, several eco-friendly alternatives to traditional cultivation practices have been proposed. The use of biofertilizers, such as rhizobacteria with different plant growth promoting properties is an environmentally-friendly option to achieve sustainability in agriculture. In this context, two bacterial strains (Bacillus pumilus R3 and Pseudomonas lini R7) isolated from the rhizosphere of runner bean plants were assessed for their plant growth promoting abil...
Autori: Gabriela Mihalache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27108

Intensive agriculture has become an indispensable practice because it has to meet the needs of increasingly large yields to feed the population of the planet. In recent years, tough challenges to increase the efficiency of bioconversion were performed, since the conventional system has negative impacts on the environment, especially on health products by low intake in nutrients. In this context, the aim of this study is to show the effects of fertilization measures, which improve the quality ...
Autori: Daniela Cristina Dimitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27110

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

This work focuses on treatment of lead polluted waste glass from urban collection (Pb≈5% wt) for its valorization as support in the immobilization of lipase, because soda-lime glasses are used in enzymatic catalysis. First of all, an extraction process of surface Pb was performed. The process is based on nitrilotriacetic acid (NTA) chelating agent. The operating conditions are: T=80°C, t=1h, pH 10, solid/liquid weight ratio=1/10, reagent concentration=0.1 M. Leaching tests at contr...
Autori: Luisa Barbieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27122

The selection of proper compounds to include in perfumes’ formulation is of particular interest for the perfume industry. Essential oils and perfumes are subject to quality control as well as to chemical characterization; therefore, GC/MS-O methodology can be considered a useful tool for research purposes and/or for improving industrial manufacturing processes. In this study, GC/MS-O methodology was applied to a commercial brand perfume and a natural-derived one, both characterized by ...
Autori: Antonella Amenduni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27125

Waste frying oil (WFO) is a complex and heterogeneous waste collected mainly from restaurants and, to a lesser extent, from food processors and households. In the last decades, interest for this waste has deeply grown and a strong competition in grabbing this raw material has begun. About 90% of WFOs collected in Europe is recycled for biodiesel production, being the high free fatty acids (FFAs) concentration in WFOs one of the main drawback limiting the yield of the conversion process. In th...
Autori: Cinzia Pezzella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27130

Microbial fuel cells (MFCs) are bioelectrochemical reactors that directly convert the chemical energy stored in chemical bonds of organic substrates, to electrical energy. Saccharomyces cerevisiae was implemented as biocatalyst in the anaerobic anode compartment of an MFC using glucose as carbon source and methylene blue as electron mediator. Our results showed the effect of methylene blue on the microbial metabolism and the reversibility of the redox reaction of the shuttle mediator in the p...
Autori: Ruggero Rossi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27131

In this study, the potential for biogas production from biodegradable bioplastics was evaluated. Mater-Bi® (a family of maizestarch based flexible films) and PLA (PolyLactic Acid; a rigid, polylactide-based, polymer) bioplastics were digested in laboratory batch reactors, alone or in co-digestion with pig slurry or scotta (partially deproteinized cheese whey), at 35°C or 55°C. Methane (CH4) and hydrogen (H2) production were monitored during the incubation period. Maximum CH4 (Mmax...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27134

The removal of phthalic acid diesters PAEs, specifically di-n-butyl phthalate (DBP) and di(2-ethylhexyl) phthalate (DEHP), from leachates of a municipal solid waste incineration plant treatment process was studied. The leachates originated from the adjusting unit, the biochemical unit, the ultrafiltration membrane unit, and the reverse osmosis membrane unit. The initial concentrations of DBP and DEHP were 250.5 and 332.3 μg/L, respectively, which were correspondingly reduced to 4.2 and 2.2...
Autori: Hongyuan Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27143

This study investigated the different behavioral responses of zebrafish (Danio rerio) under sudden stress from two types of chemicals (heavy metals and insecticides) and explored the correlations of behavioral responses and several well-known biomarkers. Adult zebrafish were exposed to cadmium (Cd) and deltamethrin for 5 hours. An increase in avoidance speed and turning frequency was first detected behavioral response. The duration of hyperactivity was almost 50 min in the deltamethrin expos...
Autori: Yi Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27149

A combined system of up-flow cyclic sludge bed (UCSB) and aerobic nitrification reactor (ANR) was designed for organic matter and ammonia nitrogen (NH4-N) removals of swine wastewater. The UCSB had one acidogenic zone for hydrolytic acidification to solve the problem of poor carbon source in swine wastewater, and the other zone for denitrification. Results showed that average removals of the chemical oxygen demand (COD) and NH4-N were 92% and 95%, respectively, under the following conditions...
Autori: Jie Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27160

Two 17β-Estradiol (E2) degrading strains were isolated from the activated sludge of swine wastewater bio-treatment aerobic facility and affiliated to Bacillus subtilis based on 16S rRNA gene sequencing. The degradation rates were more than 90–95% at 37 °C in 4 days when E2 was the sole carbon source. Steady and effective nutrients and estrogen removals were achieved in three parallel sequencing batch reactors (SBRs) treating real swine wastewater for 90 days, which contributed to ...
Autori: Meixue Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27162

In this paper we applied multi-criteria methods of decision in order to establish the best encapsulation material to be used in producing photovoltaic modules. The encapsulation materials play an important role in establishing the PV module performance, especially if referring to their ability to increase their life time. For our study, we have considered the most widely used encapsulation materials available on the market, such as Ethylene-Vinyl Acetate (EVA), Polyvinyl Butyral (PVB), Thermo...
Autori: Gabriela Demian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27169

In this study, chitosan-iron(III) was used as adsorbent of the dye acid red 29. The effect of pH, temperature and concentration of the dye on the adsorption capacity were evaluated. The maximum adsorption capacity was calculated from the adsorption isotherms which were well fitted by Sips isotherm model. The process followed the kinetic model of pseudo-second-order. The activation parameters showed that the adsorption process is spontaneous and favorable. A decrease in adsorption capacity was ob...
Autori: Carla Albertina Demarchi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27181

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

This study was carried out to (1) investigate the potential of in-vessel solid-state anaerobic acidogenic co-digestion of high solids containing substrates, namely organic fraction of municipal solid waste (OFMSW) and cow manure and (2) examine the feasibility of using leaching bed reactors (LBR) for hydrolysis/liquefaction and acidification of OFMSW and cow manure mixtures for maximum total volatile fatty acid (VFA) and alcohol production. Results indicated that hydrolysis efficiency of 20-25% ...
Autori: Tuba H. Erguder
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27186

In this work, the effect of cyclic anaerobic/aerobic conditions on the biodegradative capability of the mixed microbial culture for the azo dye Acid Red 18 was investigated in the sequencing batch reactors. For this purpose, five anaerobic/aerobic sequencing batch reactors were operated under the same operation conditions at different anaerobic/aerobic reaction times. The whole reaction time was 22-h with anaerobic/aerobic periods of 6/16, 10/12, 14/8, 18/4 and 22/0 (h/h) in An/ASBR1 to 5, respe...
Autori: Mohammad Hakimelahi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27191

In this study, S-TE pretreated mariculture organic waste (MOW) was used as substrate. Acid, alkaline, S-TE, sterilization and microwave pretreated waste sludge was used as inoculation respectively. The highest hydrogen yield of 22.02 ml H2/g COD (chemical oxygen demand) was obtained from MOW with sterilization pretreated inoculation at mesophilic conditions in batch reactors. The impacts of different pretreatments on the changes of soluble chemical oxygen demand (SCOD), protein, carbohydrate, pH...
Autori: Liang Guo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27193

Intensive cereal crops planted on soils from the Western part of Romania determine, annually, significant losses of essential microelements and macronutrients for plant development from the agricultural soil, which lead to the depletion of such lands. Fly ash (FA) resulted from coal combustion at the CET Timisoara power plant, can be used as supplement to an organic fertilizer, such as manure (M) to restore the balance of micro- and macronutrients, important to obtain healthy cereal crops and hi...
Autori: Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27208

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

Banana stalk (BS) waste is used to remove Pb2+ from aqueous solution. Equilibrium data were analyzed with Langmuir and Freundlich adsorption models, which fit better in the former equation. The qmax (maximum metal uptake capacity) for Pb2+ adsorption was 105.14 mg/g of BS at pH 5.0, which followed pseudo-second order kinetics model. IR spectra confirmed the participation of hydroxyl, amino, and acidic functional moieties in the removal of Pb2+. The major mechanism involved in the biosorption of ...
Autori: Kashif Iqbal Sahibzada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27214

The application of advanced oxidation processes (AOPs) emerged as an interesting topic during the last decade. Many studies have been devoted to the complexity of phenomena imposed by AOPs, and a lot of effort was made to justify the application of AOPs. However, the reliability of AOPs has not been an issue of any extensive work. In this work, failure analysis and comparative reliability study were performed for the chosen AOP system, i.e. a laboratory scale photo- and sonoreactor, during the p...
Autori: Ivana Grčić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27220

In the present study, the effect of chitosan as an eco-friendly coagulant aid was investigated for removing turbidity (bentonite) and humic acid (HA) in the coagulation process. The effects of various operational parameters such as initial pH of the solution (4-9), dosage of chitosan (1-4.5 mg/L), dosage of alum (10-40 mg/L) and initial turbidity (10-150 NTU) were investigated. An artificial neural network (ANN) model was used to predict the performance of turbidity removal efficiencies by coagu...
Autori: Abdolmotaleb Seid Mohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27223

Life Cycle Assessment (LCA) is a methodology that can be used to evaluate the environmental performance of municipal solid waste management systems (MSWMS). Despite of Waste Directive provisions, this methodology is insufficiently applied as a decision-support method able to identify the best option for the waste management in Romania. In this paper we applied LCA methodology to study of the municipal waste management system of Cluj County, supported by GaBi software. The aim of this study is to...
Autori: Gabriela-Emilia Popiţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27225

In this study, the oleaginous yeasts cultured in tomato waste hydrolysates (TWH) to produce microbial lipids that offer a suitable alternative to vegetable oils as feedstock for the biodiesel synthesis. The TWH were prepared by acid hydrolysis (2.5% H2SO4). To obtain higher growth rates, as well as higher lipid contents, Lipomyces starkeyi were cultured under original nitrogen content (TWHON), lower nitrogen content (TWHLN), attained by alkaline precipitation of TWHON followed by centrifugation ...
Autori: Abu Yousuf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27226

Composted livestock waste (CLW) was studied as one low-cost material to remove Pb(II), Cu(II), Cd(II) and Zn(II) from simulated acid mine drainage (AMD) by batch and column experiments. The adsorption isotherm data were well fitted by the Langmuir model. The maximum monolayer adsorption capacities were 0.5485 mmol/g for Pb(II), 0.4092 mmol/g for Cu(II), 0.2246 mmol/g for Cd(II), and 0.1879 mmol/g for Zn(II) at pH 4.0. Due to the competition effect, the adsorption capacity of the single metal ion...
Autori: Mingliang Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27262

Environmental issues have received ascending attention in recent years due to the increase of their negative effects. Greenhouse gas emission levels have experienced an exponential increase in the last decades mainly on account of the development of the building sector. Life cycle assessment (LCA) of buildings is a proper tool to analyse the full environmental impact during their designed lifespan. Inventory databases have a shortage of local parameters in some countries and need to be developed...
Autori: Iosif Boros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27289

This study presents the results obtained in tailoring thin films of alumina, deposited onto aluminium substrates by spray pyrolysis, at 250°C, using AlCl3 solutions (0.15M) in a water:ethanol (1:1) solvent mixture. As morphology controlling agents, acetylacetone and maleic acid based copolymers are added in the precursors’ solutions. The precursors’ systems are analyzed by FTIR spectroscopy and the surface morphology of alumina thin films is investigated by atomic force microscop...
Autori: Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27291

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

The remarkable photocatalytic properties of titanium dioxide and the high adsorption capacity of the mesoporous materials were combined to obtain active photocatalysts for the decomposition of Rhodamine 6G dye. The mesoporous TiO2 was obtained by the controlled hydrolysis-condensation of titanium isopropoxide, using hexadecyl-trimethyl-ammonium bromide as template, followed by calcination to remove the organic matter. Subsequently, this sample was doped with sodium wolframate and platinum. T...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27325

Conversion of natural ecological systems has been one of the greatest human impact on terrestrial ecosystems. The expansion of anthroposphere altered virtually all biogeochemical cycles of elements. Nitrogen holds a key place in sustaining life and presents unique traits such as broad chemical speciation and mobility within the environmental compartments. With historically adapted ecosystems to low bioavailable nitrogen, understanding the complexity of the nitrogen disruption is a continuous cha...
Autori: Andreea Csolti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27329

Inventory and monitoring of total organic carbon stock (TOC) it’s an issue of actuality in the context of breaking into the atmosphere an alarming quantity of CO2 result of human activities. Management and sustainable management of forest and agricultural ecosystems can have a positive influence on maintaining optimal stock of carbon sequestered. A case study achieved in the Humor catchment reveals that changing the land’s utility means important modifications in the quantity of the ...
Autori: Eugen Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27336

The objective of this study was to develop a naturally dyeing process of 70% wool /30% Angora mohair blended yarns by using bio-mordants as an environmentally friendly alternative for the conventional metallic salts. Bio-mordanting operation was achieved by using of condensed tannin extract from quebracho bark trees. Conventional mordanting has been performed using the conventional mordants like copper sulphate and tin chloride. Another specific objective of this study was to investigate the pos...
Autori: Ioana Stanculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27337

The objective of the paper consists in determining the level of awareness towards sustainability and ecological issues for Russian and Romanian oil and gas multinational companies (MNCs). Thus, we employed a qualitative approach on the issue, both by investigating the information disclosed in sustainability and/or CSR reports from a sample of Russian and Romanian corporations and by keeping trace of the adequacy of their reporting practice with the Global Reporting Initiative (GRI) standards. Ou...
Autori: Codruţa Badaluta Minda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27352

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

In this study, a decision support system based on a stochastic optimization model under modeling uncertainty and parameter certainty (SOMUM-DSS) is developed for petroleum-contaminated sites management. The SOMUM-DSS incorporates scenario analysis, numerical simulation, multivariate analysis, nonlinear optimization within a decision support system. It provides an effective tool for decision makers to select the optimal remediation strategy. The developed SOMUM-DSS is then applied to a petroleum-...
Autori: Qi Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27374

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

A comparative study of humic substances (HS) extracted from raw sludge and its digested product was carried out in order to analyze HS evolution during sludge anaerobic digestion. HS content, elemental composition, functional groups, infrared spectra and ultraviolet absorbances were analyzed by means of chemical and spectrographic methods. The extracted HS were also fractionated by ultrafiltration in order to obtain their molecular weight (MW) distribution. The results showed that humic acids (...
Autori: Huan Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27390

Using the panel data of 30 provinces, cities and autonomous regions in China from 1997 to 2013, and taking different finance development and financial structure indexes into consideration, the paper systematically investigate the impact of finance development and finance structure on carbon emission. The results of empirical research show: (1) The financial development efficiency at a provincial level, and in Eastern regions, has a significant effect on carbon emission, illustrating an invert...
Autori: Yu Kong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27393

In this study heavy metal (Cr, Cd and Ni) levels in muscle tissues of pelagic and benthic fish species in Persian Gulf from western and eastern sides of Bandar Abbas were determined. In western side, the mean concentrations of Cr, Cd and Ni in Aldrichetta forsteri species were 0.57, 0.33, and 0.12 mg/kg dry weight, while in Pomadasys kaadan species were 0.08, 2.18, and 1.39 mg/kg dry weight, respectively. In eastern side, the concentrations in Aldrichetta forsteri species were 0.26, 0.10, and...
Autori: Ali Koolivand
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27396

Lignocellulosic residues are relatively recalcitrant to bioconversion during anaerobic digestion (AD) for biogas production. Pre-treatments with cellulolytic enzymes or diluted alkali can facilitate biomass hydrolysis and enhance the process. Both pre-treatments require low energy and chemical inputs, without accumulation of inhibitor. Milled wheat straw was pre-treated with hydrolytic enzymes or with diluted NaOH before AD. The pre-treatments were performed on sterilized, stabilized with formic...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27420

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

Three different synthetic textile dyeing wastewaters were treated by a chemical coagulation/flocculation process, using ferric sulphate as coagulant. Polyacrylamide (Magnafloc 155) and polyamine (Superfloc C-573) based flocculants were applied. The influence of pH (between 3.5 and 10.4) and Fe3+ concentration (from 15 to 4000 mg/L) in both color and dissolved organic carbon (DOC) removal of polyester, cotton and acrylic dyeing wastewaters was assessed in the coagulation stage. As far as floc...
Autori: Carmen S.D. Rodrigues
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27427

In the present study, anaerobic treatment of food wastes from restaurants of a fermentation industry and methane gas production yields produced during the treatment were investigated. For this purpose, food wastes with a Total Solid Contents (TS) ratio of 5- 7-10% were digested in a 100l experimental reactor. Batch anaerobic digestion studies were conducted at mesophilic temperatures (36.5 oC) for 30 days and optimum Volatile Fatty Acids (VFA) and alkalinity values for methane gas production ...
Autori: Sevgi Fersiz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27429

Decolorization of C.I. Acid Orange 7 (AO7) via TiO2-assisted photocatalysis under UV illumination in the presence of H2O2 has been investigated. The effect of pH on decolorization efficiency of AO7 was investigated in TiO2/UV/H2O2 process. The performance of TiO2/UV/H2O2 system was also evaluated by using synthetic dye-bath effluent of AO7. Solar driven TiO2 photocatalysis was found significantly efficient for the decolorization and degradation of AO7. The rates of decolorization and degrada...
Autori: Ozlem Esen Kartal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27433

The research was conducted in a spruce stand with disseminated beech and larch trees from the Carpathian Mountains, where thinning operations had taken place. The CTL (Cut-To-Length) system was applied by using harvester and forwarder. The research was aimed at determining the amount of damage to trees, identifying the damage types, their frequency, extent, form and distribution at the level of trees and at the level of the entire stand. Thus, 7.5 % of remaining trees were damaged with the am...
Autori: Vasile Răzvan Câmpu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27434

Acid-base accounting was applied to evaluate the acid generating potential of waste rock dumps of different ages at a nickel mine in Zimbabwe. Metal concentrations in soils surrounding the dumps were also assessed. The net neutralising potential (NNP) of waste rock samples was derived from the maximum potential acidity (MPA) and the neutralising potential (NP). MPA and NP were determined based on total sulphur and acid consumption respectively. Waste rock dumps (WRDs) had more (p<0.05) su...
Autori: Artwell Kanda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27437

A total of 152 different actinomycetes isolates were recovered from samples that were collected from different ecosystems of Algeria. The desert soil of Bousaada gives the greatest number of actinomycetes compared to others soils. The first screening indicates that 63.15 % of the isolates were able to produce carboxymethyl cellulase enzyme. Isolates were evaluated for their cellulase activity by growing in carboxymethyl cellulose broth. B-PNG23 isolate is one of the isolates displayed a high enz...
Autori: Azzeddine Bettache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27451

The negative effects of acid mine drainage (AMD) on the natural and human environments are well understood in South Africa, yet a robust and economic AMD treatment technology has not been developed. The current study aimed at exploring the performance of synthetic zeolite F9 in AMD treatment with specific focus on iron and manganese removal. For this, batch adsorption mode was adopted for which the effects of adsorbent dosage, initial pH and temperature were investigated. As a result, it was fou...
Autori: Mike Masukume
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27454

The purpose of this paper is to present the results regarding the obtaining of reducing sugars at the enzymatic hydrolysis of the lignocellulosic material, wheat straws. For these, the lignocellulosic material was submitted to a preliminary pretreatment for destruction of the cellulose crystalline structure and to increase the material's susceptibility to the enzymatic attack. The preliminary pretreated material with diluted acid (0.5%-4%) or with water at different temperatures (120-170&ord...
Autori: Eufrozina Albu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27463

This paper reports the possibility of using zinc ash as a secondary source for zinc oxide, which can be further used as white pigment. For the extraction of zinc from zinc ash, sulphuric acid was used. The impact of different parameters (ash fraction, contact time, sulphuric acid concentration and liquid:solid (L:S) ratio) upon the extraction degree of metallic ions from zinc ash was studied. The optimum conditions for the metallic ions extraction are: 20 % H2SO4, 30 minutes contact time, 1:1 L:...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27475

Wastewater treatment using sequencing batch reactor (SBR) has certain advantages over conventional activated sludge system. The performance of sequencing batch reactor in treating high C/N ratio was investigated with suspended polyurethane and polystyrene attached growth biomass configuration. A sequence of 4 hr HRT, 0.3 month SRT and 1kg COD/m3 was employed to study treatment efficacy. Treatment performance was assessed by means of chemical oxygen demand (COD), total nitrogen (TN) and total pho...
Autori: Beenish Saba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27478

Three modified bentonites, hydroxy-aluminum pillared bentonite (Al(OH)-Bent), cetyl trimethylammonium bromide modified bentonite (CTAB-Bent), and both cetyl trimethylammonium bromide and hydroxy-aluminum modified bentonite (Al(OH)-CTAB-Bent) were prepared and characterized by Fourier transform infrared spectroscopy (FTIR) analysis. Batch experiments were conducted on the adsorption of phenol at different temperatures, pH and initial concentration. The results indicated that adsorption capacity o...
Autori: Xiping Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27481

Fungal isolate Aspergilius niger V-8 (IITB) was isolated from the sludge of anaerobic digester of distillery wastewater treatment plant and was found to be an appropriate fungal isolate for the purposes of decolourization of anaerobically digested molasses spentwash (ADMS). The study aimed at optimization of the environmental parameters for achieving maximum decolourization of ADMS using isolated fungal species. Environmental parameters like initial pH, mixing, immobilization and surfactant a...
Autori: Mrityunjay Singh Chauhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27502

This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multi-active blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than ...
Autori: Jacob Kitinya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27505

Köyceğiz-Dalyan Lagoon is situated in the southwestern region of Turkey. The area between the Köyceğiz Lake and the sea is covered with four small lakes and numerous canals. The Dalyan Channel network connects lake to the Mediterranean Sea is one of the most important reproduction areas for Mediterranean Sea turtles. The objectives of the present study are to evaluate the influence of channel traffic and Köyceğiz Lake on the water quality of Dalyan Channel by evalua...
Autori: Başak Kılıç Taşeli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27507

Papermaking tobacco sheet wastewater exhibits high content of fine suspended solids (SS), intensive color and low biodegradability. Through the process of electrocoagulation (EC) using aluminum anode and stainless steel net cathode, the performance of wastewater treatment and the evolution of the main components in wastewater were examined. Maintaining the pH of wastewater, with 40 mA/cm2 of current density, 2.5 g/L of NaCl for a reaction of 6 min duration, 66.1% of the total chemical oxygen dem...
Autori: Xiangjuan Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27509

This study undertakes to characterize through thermal analysis in dynamic conditions a wide range of building materials used for various types of insulation and presents for the first time a comparative analysis of their thermal stability. To this effect, the dynamic thermal analysis TG/DTG was applied. The results show a degradation resulting in one, two or three stages after a complex mechanism, with different mass loss, depending on the structure and atmosphere in which the thermal decomposit...
Autori: Andreea-Camelia Sprânceană
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27514

Weakly acidic Litavka and alkaline Malín soils are some of the most contaminated soils by multiple risk elements in the Czech Republic. The aim of this paper was to determine the effect of P sources (rock phosphate, superphosphate), each applied at three rates on the mobility of risk elements (Cd, Zn, Pb, As) and micronutrients (Fe, Mn) in soils and to compare their effectiveness with lime and dolomite tested in our previous study. In 7, 14, 28, and 42 days, we determined CaCl2-extractabl...
Autori: Stanislava Vondráčková
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27521

This study of the variation process of the chemical properties of eutric Cambisols on altitudinal levels, forest station subclasses and geomorphologic units, was based on soil analyses from 847 soil horizons gathered from 379 profiles. These profiles were distributed on Romania’s entire forest area. The average values of the eutric Cambisol’s chemical properties fit were within the known limits for this type of soil, but there were slight variations based on altitude, forest station ...
Autori: Gheorghe Spârchez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27522

The environment friendly development of mining applications progressed significantly due to the rapid increase in environmental awareness and requirement of available land. The reclamation studies of those lands, ruined during mining activities, should be evaluated and regained in the most effective and rational way. In recent years, especially in open pit coal mining, reclamation applications become crucial due to rapid spreading of mining companies on extensive lands. These applications were t...
Autori: Tahir Mallı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27524

An anaerobic-aerobic (An-Ox) sequencing batch reactor (SBR) was operated for the growth of phosphate accumulating organisms (PAOs), while an anaerobic-anoxic (An-Ax) SBR was used for the growth of denitrifying PAOs (dPAOs). Both reactors exhibited successful enhanced biological phosphorous removal (EBPR) performance. The sludge P contents in the two reactors increased from approximately 2% at the beginning of the operation to 9.1% (An-Ox SBR) and 7.3% (An-Ax SBR) after 140 d. The results of the...
Autori: Hansaem Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27525

Galvanocoagulation (GC) utilizing metallic iron chips and granular coke was studied as a potential technique for decolorization of dye-containing aqueous solutions. GC and chemical coagulation by inorganic metallic coagulants such as iron sulfates (Fe2+, Fe3+) were examined for the removal of individual dyes, used in the fur industry, from model aqueous solutions. The role of metal cations when progressively electrogenerated in situ was compared to when they are added simultaneously. The superio...
Autori: Marina R. Sizykh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27526

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Chemical oxidation of pyrite and chalcopyrite by ferric sulfate (Fe2(SO4)3) solution and biogenic ferric iron obtained by mixed culture of isolated thermotolerant Acidithiobacillus sp. 13Zn and Leptospirilum ferriphilum CC immobilized on natural carriers- zeolite and shungite was studied. Oxidation rate of sulfide minerals was estimated by the decrease of Fe3+ (oxidant) and increase of Fe2+ ions in the solution. It was revealed that chemical oxidation of chalcopyrite by biogenic ferric iron occu...
Autori: Arevik Vardanyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27563

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

Social upgradation results more postconsumer glass and plastic waste and continuously demands newer techniques for their management. This research proposes a new waste-to-waste management strategy by using waste glass for polyolefin degradation. For this purpose, waste glass is activated by mechanochemical treatment and resultant material is used for the thermal pyrolysis of polyolefin. Certain improvement in the product quality is achieved by selectivity towards more alkane fraction. ...
Autori: Pooja Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27586

Phenolic compounds are known as recalcitrant pollutants in many industrial wastewaters, e.g. olive mill wastewater. An efficient treatment is therefore needed before the discharge of phenol-containing wastewaters into the environment. The possibility of removing some natural occurring phenolics, namely tyrosol, p-coumaric acid and vanillic acid, by micellar-enhanced ultrafiltration (MEUF) using a cationic surfactant, cetylpyridinium chloride (CPC), and polyethersulfone membranes of 20 and 50 kDa...
Autori: Abdelilah El-Abbassi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27607

The aim of this study is the treatment of Chlorothiazide in an aqueous medium by Electro-Fenton process using a Platinum anode. This pharmaceutical product is used to treat hypertension. Removal rates and mineralization efficiency have been analyzed under different operational conditions. Degradation kinetics well fitted to a pseudo–first–order reaction. Apparent rate constant of the oxidation of Chlorothiazide by electrochemically generated hydroxyl radicals was determined to be 9.4...
Autori: Saied Taieb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27616

Tobacco is one of the most important agricultural products in the Republic of Macedonia. Elemental composition of tobacco and soil from different agricultural areas was studied for monitoring purposes. The main purpose was to determine the intensity of accumulation of various elements in tobacco plants and to determine possible relationships between certain chemical and physical properties of soils (pH, clay, cation exchange capacity - CEC, organic matters - OM and total organic carbon - TOC). T...
Autori: Biljana Jordanoska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27625

This study was conducted on samples taken from the “Fagul Cetății – Iazul nr. 4” tailings pond in the Eastern Carpathians, Romania and is focused on exploring the way in which heavy metals from sulphide rich material are spatially distributed in relation to the geochemical conditions. For comparison, concentrated ore samples from the same area, genetically linked to the Tulgheș lithogroup were also analysed. The mineralogical and chemical composition of the sampl...
Autori: Sorin-Ionuț Balaban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27626

FLUCTUATION OF RIVER NETWORK WATER ENVIRONMENTAL CARRYING CAPACITY IN A COMPLICATED RIVER-LAKE SYSTEM    • MINERALOGY AND GEOCHEMICAL DISTRIBUTION OF HEAVY METALS FOR THE FAGUL CETĂȚII TAILINGS, ROMANIA    • ACCUMULATION AND AVAILABILITY OF TRACE ELEMENTS FROM SOIL INTO ORIENTAL TOBACCO GROWN IN MACEDONIA    • OLFACTORY EFFECT ON LANDSCAPE PREFERENCE    • EFFECT OF MOLASSES ADDITION AS BIODEGRADABLE MATERIAL ON PHENOL REMO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27628

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

The enzyme-based biosensor stability and its analytical performance depend on both the immobilization process and the matrix used for immobilization of the enzyme into a stable layer. In this paper, the development and evaluation of an optimal enzymatic layer for stable encapsulation of the acetylcholinesterase enzyme (AChE) through the sol-gel method onto mediated carbon-ink screen-printed electrodes was performed, obtaining electrochemical enzyme-based biosensors. The enzyme was immobilized on...
Autori: Melinda David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27636

Pyrometallurgical recycling of lead from spent batteries entails secondary waste fractions generated in the blast furnace as iron stone and lead slags. For further purification of both fractions, hydrometallurgic processing is proposed. This paper focuses on purification of iron stone, in view of recovering metals (mainly lead) and of producing decontaminated iron stone fit for further recycling. The results demonstrate that iron stone is mainly composed of iron and lead; copper, zinc and antimo...
Autori: Bart Van der Bruggen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27642

Five indigenous soil microbes were isolated from chickpea rhizosphere soils of different location of Jaunpur, Mirzapur, Varanasi and Azamgarh district of eastern Uttar Pradesh. The microbial strains were identified as Pseudomonas aeruginosa BHUPSB01, Pseudomonas putida BHUPSB04, Bacillus megaterium BHUPSB14, Paenibacillus polymyxa BHUPSB16 and Mesorhizobium sp. BHURC05 by biochemical and molecular characterization. The isolated strains were tested for their plant growth promoting properties....
Autori: Jay Prakash Verma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27654

Magnesium wastes are among the gradually ascending and therefore challenging metal wastes, which are produced by many industrial activities. The purpose of this study is the usage of magnesium waste, a raw material in magnesium borate production by hydrothermal synthesis. Boron sources (boric acid (H3BO3) and boron oxide (B2O3)) react with magnesium wastes in order to synthesize the magnesium borate mineral of admontite (MgO(B2O3)3ꞏ7(H2O)). In addition to the synthesis from waste magne...
Autori: Azmi Seyhun Kipcak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27657

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

In this study, the concentrations of 15 phenol derivatives were analyzed from the phreatic and groundwater wells surrounding a decommissioned chemical factory in a village from the western part of Romania. An UPLC-MS method was used to assess the concentrations of the chemical target compounds in the water samples. The most frequent compounds were 4-chlorophenol, 4-tertoctylphenol and 4-nonylphenol, being detected in 17 of the 19 sampling sites, while the least frequent compound was 2,4,6- t...
Autori: Elena Preda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27661

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

The main objective of this research was to evaluate the environmental impact generated by municipal solid waste during its collection, transportation, treatment and processing in the south-west region of the department of Norte de Santander, Colombia, by means of Life Cycle Assessment (LCA). Three strategies for waste management were considered: the current baseline situation, wherein 100% solid waste was taken to the landfill; plus, an optimistic and a pessimistic scenario in which solid was...
Autori: Oscar Orlando Ortiz-Rodriguez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27665

Organoarsenic compounds are used extensively as swine feed-additives to promote animal growth and control diseases, e.g. roxarsone (4-hydroxy-3-nitrobenzenearsonic acid) and arsanilic acid (4-aminophenylarsonic acid) are usually overused in swine industry in China. As a cost-effective technology for animal manure treatment and reuse, composting is widely used for swine manure treatment. Therefore, the purpose of this study was to investigate changes of arsenic species and fractions during a full...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27683

Unlike other vegetables, mushroom production requires several substrate ingredients, energy to sterilize the substrate, water to humidify the fruiting house and waste management of the spent substrate and used materials. This work studied the environmental impacts and eco-efficiency of sajor-caju mushroom (Pleurotus sajor-caju (Fr.) Sing.) production in terms of climate change potential, acidification potential, water depletion potential and fossil fuel depletion potential, using life cycle asse...
Autori: Siriprapa Ueawiwatsakul
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27685

Though Scirpus triqueter plays an important role in protecting the ecological functions of Yangtze River estuary wetland which is frequently contaminated by petroleum, knowledge is limited about the mechanisms involved. In this study, comparative analysis of soil properties, microbial community structure and soil enzymes in the rhizosphere of S. triqueter and bulk soil was conducted throughout one year to provide an insight into the phytoremediation mechanism in the field. The total petroleum hy...
Autori: Jing Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27697

Huge amount of red mud has been disposed for the past several decades and it is still generating all over the world. Red mud is a waste of the bauxite processing industry obtained during the alkaline extraction of alumina from bauxite ore. The red mud is a potential raw material containing several valuable components including iron, titanium and rare earth metals. The aim of the research was to develop an appropriate acid digestion technique for the red mud in order to determine the amount of...
Autori: Tatjána Juzsakova1
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27780

The quantification of heavy metals in dry and wet weather derived (runoff and snowfall) sediment from roads, under three different environmental conditions, has indeed the potential to allow improved understanding on urban diffuse pollution. With that aim, the reported study determined the concentrations of Cd, Cu, Pb, Ni, Cr and Zn in road sediment, which are reported to be found in elevated level in the road-traffic environment, and associated pollution levels at four different sites, represen...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27776

Influence of soil pH on the mechanical characteristics of glass reinforced plastic (GRP) pipes type was often investigated in different situations encountered in the field. GRP degradation is directly proportional to the exposure to soil with non-neutral reaction. The theoretical and experimental results lead during time to design standards, which allow the application of GRP pipes in water and soil, so as minimum interferences with the materials used in the manufacture of pipes would appear. Sa...
Autori: Ana Diana Ancas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27768

Evaluation of spatial/ temporal water quality data at reservoirs has shown differences after the dam construction as well as long-term changes of water chemistry. One of the most recent reservoirs created in Europe is Ilarion Reservoir in Western Macedonia – Greece (2012). In this work, the water physicochemical characteristics of this young reservoir and the spatiotemporal water quality variation of the feeding river and its main tributaries have been studied, and statistically interprete...
Autori: Elisavet Amanatidou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27737

This study investigated the spatial variability of heavy metal emission patterns and associated measures of contamination on Riccarton Campus at Heriot-Watt University in Edinburgh, Scotland. Road deposited sediments were collected from 12-different sites representing typical urban/sub-urban road layout over a 10 month period covering seasonal variations. The heavy metal concentrations of the road sediments collected from different sites of a road were determined by strong nitric acid digestion ...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27738

During the years 1965-1985, a veritable industrial platform was developed in the west part of Oradea, Bihor County, Romania. It stretches on an area of 9 sq. km. and is placed in the meadow of Crisul Repede River. Throughout that period, several industrial facilities were built that lately became sources of pollution for the environment. The purpose of the present paper is to study the influence of historical stages of industrialization and restructuring of enterprises in Western Oradea, address...
Autori: Tamara Romocea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27747

The research has been focused on concretes in which the continuous phase is some kind of polymeric resin and the discrete phase is some type of mineral aggregate. Such composite materials are known as Polymer concretes (PC) and boast several advantages such as lower weights, higher resistance to corrosive environments and chemical attacks, faster curing and lower permeabilities. In PC the inorganic fraction can reach up to 90% of the total and is made up of aggregates such as sand and gravel. Th...
Autori: Paolo Pozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27799

The corrosion inhibition of mild steel in acidic media at 303 – 333K in 0.1 - 0.5M acids (hydrochloric acid - HCl and trioxonitrate (v) acid - HNO3) and 0.01-0.03g/L Aloe Vera extract (AVE) were investigated by standard weight loss method. The corrosion rate was calculated in the absence and presence of the inhibitors. The inhibition efficiencies of AVE in both acid media increased with increase in concentration and decreased with increase in temperature and period of immersion. Results sh...
Autori: Maureen Ndibe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27870

Ti/TiO2 films were prepared by DC reactive magnetron sputtering followed by annealing in air at 400 ºC for 4 h. Structural tests have been performed to characterize the films, showing that the prepared films present 70% of anatase phase. When these results are compared with those from TiO2 films grown on glass substrates with similar deposition parameters, it can be seen that Ti substrates favour the formation of rutile phase, which is not observed on the films supported on glass, indicatin...
Autori: Susana Sério
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27868

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

This study emphasis the hydrogen fermentation from de-oiled Jatropha waste (DJW), a secondary and promising waste from biodiesel industry via influence of various combination of heat pretreatment using sewage sludge as inoculum. Batch experiments were carried out at a DJW concentration of 50 g/L, temperature of 55oC and an initial cultivation pH of 7. The peak hydrogen production rate and hydrogen yield of 16.3 mmol H2/L-d and 1.10 mmol H2/g volatile solids (VS), respectively, were obtained ...
Autori: Gopalakrishnan Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27874

In this paper a two stage bench scale leaching procedure is used to assess the heavy metals release from a wood-based fly ash of a 5.0 MWth grate-fired boiler. In the first step mostly K was leached with water. In the subsequent acid leaching step heavy metals were leached at a pH of 3. The remaining solids were agglomerated together with the bottom ash and the dried K-concentrate from the first leaching step whereas the filtrate was treated before discharge. In the agglomerates produced the ...
Autori: Christof Lanzerstorfer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27875

This study was carried out to determine the feasibility of applying a freeze-concentration technique to purify wastewater polluted with dye, such as methylene blue (MB) using a stationary wastewater vessel. In this study, we investigated the impact of freezing temperature, initial MB wastewater concentration and vessel depth upon the removal ratio of MB. Results showed that when the freezing temperature was decreased (from –5 °C to –15 °C), the freezing rate increased. The...
Autori: Yingjie Dai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27878

The effect of synthesis conditions on sorptive properties of glycerol-derived mesoporous carbon materials were studied. Sorption properties of the synthesized carbon-based materials regarding to different adsorbate molecules, as well as water vapors, phenol and methylene blue molecules were analyzed. The sorption capacity of the synthesized mesoporous carbons depends upon synthesis conditions, namely upon pyrolyzing temperature and carbon precursor to silica weight ratio, being determined by ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27880

Air cooled and water cooled slag samples were obtained from a demonstration plasma gasification / vitrification unit. The leachability of the major heavy metals present (Cr, Cu, Mn, Fe, Pb and Zn) in both the air cooled and water cooled slag when in contact with acidic solutions was investigated under different temperature, stirring and contact time conditions. Water cooled slag showed better resistance to heavy metals leaching. The vitrification process immobilised Cr and Pb. The leachabilit...
Autori: Konstantinos Moustakas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27882

The aim of this study was to determine how temperature conditions (max. 72oC, 81oC and 43.5oC) during sewage sludge composting affect the distribution of organically bound heavy metals in humic substances (HS). To accomplish this, the content of Cu, Ni, Zn and Fe was measured in the two main fractions of HS, humic acids (HAs) and the fulvic fraction (FF). In the feedstock, the FF was mainly responsible for binding all metals except Ni. During composting in the two series with thermophilic con...
Autori: Dorota Kulikowska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27894

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

The objective of this work was to evaluate the effects of six lactic acid bacterial strains originated from different natural habitats of fermented food and feedstuff on pasture grass and alfalfa laboratory scale silages. The prepared mini silos were inoculated with the following bacterial strains alone or in combination: Lactobacillus brevis LbB (2x107 cfu/mL), Enterococcus faecalis EF (3.6x108 cfu/mL), Lactobacillus plantarum subsp. plantarum LbP (2.8x108 cfu/mL), Weissella paramesenteroide...
Autori: Éva Laslo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27933

The aim of this study was to produce high quality activated carbons from Diplotaxis harra biomass by potassium hydroxide activation and their application in heavy metals removal. To reduce the number of experiments, full factorial experimental design at two levels (24) was carried out to occur optimal preparation conditions for efficient removal of cadmium and cobalt ions from aqueous solutions. Different variables influencing activation process, such as carbonization temperature (500–6...
Autori: Hanane Tounsadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27934

Removal of excessive ammonium nitrogen (NH+4-N) from aqueous solution has been of considerable concern for several decades. It can be removed by air stripping, a necessary prerequisite is adding enough alkali. This study presented the first attempt to investigate the potential use of ceramsite coated with magnesium hydroxide (CCMH) on the effectiveness of NH+4-N removal coupled with air stripping at ambient temperature without alkali addition. The results showed that the CCMH coupled with air...
Autori: Tianpeng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27940

The present study explores the potential use of plant waste i.e. spotted golden thistle (Scolymus maculatus L.) stalks, as an inexpensive sorbent for the removal of methylene blue from synthetic aqueous solutions. Firstly, the waste material was characterized using different analysis methods, then kinetics and equilibrium of dye sorption were investigated using a batch sorption technique. The influence of contact time, initial dye concentration, sorbent dose, particle size and agitation speed...
Autori: Zoubida Senouci Bereksi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27941

Livestock farming in rural areas in Jilin Province is producing a huge amount of organic pollutants like livestock and poultry manure, of which, a large portion is directly dumped into the Yitng River, bringing serious harm to the environment. Taking Soonlng Village as an example, this paper investigates the environmental pollution caused by the livestock husbandry in this village and builds a biogas heat storage greenhouse ecosystem, which, by using solar energy to heat the biogas digester, ...
Autori: Songying Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27943

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27946

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27947

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27968

A series of water quality and ecological problems are caused by algal blooms, and natural allelochemicals are considered as the source of algaecides due to their friendly advantages to environment. It has been reported that abundance of secondary metabolites are found in grape plants, and the extracts from the plant exhibit antioxidant, antibacterial and antifungal capacities. In order to reveal the anti-algal activity of grape pruning wastes and promote their usage, we analyzed the composition ...
Autori: Zhaojiang Zuo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27971

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

Nanoparticles (NPs) have recently been concerned as emerging contaminants. Determination of NPs in different environmental compartments is a revealing topic for researchers studying their impacts in nature. Various methods of analysis have been reported in literature for their measurement and recovery. However, there are difficulties in their quatification in landfill leachate. Taking into account varying landfill components and their possible interactions with NPs, different types of NPs wer...
Autori: Ceyda Senem Uyguner-Demirel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27989

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

There is a great need for an efficient geographic information system (GIS) implementation in interdisciplinary domains for providing useful information for scientific and managerial processes of further improving land-use planning and decision making in horticulture. The main goal of this study was the creation of a digital map and GIS application for the Fruit Research Station in Cluj-Napoca, North-Western Romania. The benefit of this implementation is a fully integrated land information sys...
Autori: Paul Sestraş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28015

The release of metals from many industrial processes into aquatic ecosystems is currently a major environmental threat, especially in developing and emerging countries. Most traditional treatment approaches are not efficient in terms of removal yield and cost. Plants have the ability to stabilize metals in a fast and cost-efficient way. In this context, aquatic plants are successfully applied for remediation of hazardous elements from industrial wastewater. This study demonstrates the capabil...
Autori: Hosam M. Saleh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28020

This paper presents an interdisciplinary methodology for handling the exposure of workers to lead and its compounds in a systematic way by connecting different disciplines, and thus enabling the comprehensive supervision of the workplace exposure. The exposure of workers to lead and its compounds was studied in the Republic of Slovenia. The research comprised 1079 employers being exposed to the lead concentrations between 0.01 and 0.9 mg/m3, which exceeded the limit value by 9 times. Workers ...
Autori: Lidija Korat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28032

A simultaneous hierarchical classification of groundwater in the Banat Plain-southwestern Romania and associated characteristics such as As(III), As(V), total As, trace metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn), pH and redox potential using Fuzzy Hierarchical Cross Clustering Algorithm was carried out. In samples containing more than 10 μg/Ltotal As (13.9 – 77.3 μg/L), the As(V) species represented 57±20% and 73±18% in the others. Arsenic speciation pattern was in agr...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28059

The development of green eco-friendly inhibitors for the corrosion of metallic surfaces in acid media is still considered as a major challenge and target for corrosion-mitigation engineers. We have prepared in this work 4 different extracts from the plant Ruta Chalepensis using methanol, chloroform, ethyl acetate, and aqueous ethyl acetate solvent systems. The flavonoids content, as well as the other oxygenated compounds, in the 4 extracts was carefully screened using the gas chromatographic&nda...
Autori: Meryem Amal Benghalia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28063

Common centaury, Centaurium erythraea Rafn., represent the best known and the most investigated medicinal plant species of genus Centaurium. Centaury has been used for centuries in traditional medicine. Secondary metabolites such as bitter secoiridoid glucosides (gentiopicrin, swertiamarin and sweroside), xanthones (eustomin and demethyleustomin), and phenolic acids are the main constituents responsible for the therapeutic properties of centaury. Previous investigation showed that overexpression...
Autori: Milana Trifunović-Momčilov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28068

The goal 12 of the 2030 Agenda for Sustainable Development takes into consideration the responsible consumption and production in the perspective of circular economy. The agri-food sector is more actively involved in these initiatives, because it offers the possibility to exploit waste and by-products, by adopting suitable biotechnologies. Such processes can be carried out either under aerobic conditions, for the production of compost, or anaerobically, for the production of biogas. In this work...
Autori: Veronica Novelli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28078

Digestate derived from the anaerobic digestion of biowaste is a nutrient-rich substance whose direct use on land is not permitted by the Italian Legislation. The possibility of recovering its nutrients can be given by the processes of stabilisation and sanitation required by the Italian Legislation. Among these processes, composting and calcium hydrolysis with neutralization (CHN) permit to obtain useful soil improvers like compost and defecation gypsum (DG). In this paper a gate-to-gate Life Cy...
Autori: Sofia Spagnolo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28080

In recent years, so-called emerging contaminants (ECs) have attracted growing interest as they have been detected in reservoirs and even in drinking water. The new proposal Drinking Water Directive (2018) provides for the introduction of new parameters relevant to the ECs category. As these contaminants today tend to be present in a growing number of water sources, provide treatment systems that ensure compliance with regulatory limits and the protection of public health has become essential. Th...
Autori: Sabrina Sorlini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28081

Leather processing is one of the highly polluting industries, due to generation of significant quantities of tanned and untanned wastes. Untanned wastes are less contaminated with chemicals and a better source of high value products such as collagen rather than tanned or finished leather wastes. In the present study, collagen dissolution substances (CDS) were prepared from bovine limed split wastes as value added products, by treating leather wastes with sodium hydroxide and fermented dairy b...
Autori: Gökhan Zengin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28095

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

To produce drinking water, the water treatment plants generate huge quantities of sludge, this sludge is a waste and they are evacuated to the dump. The valuation of these sludge will be benific This study focuses on the development of composite alginates beads and sludge activated chemically by sulphuric acid and thermally for the removal of dyes from aqueous solutions. Two dyes were studied; a basic cationic dye (methylene blue) and an acidic anionic dye (Congo red) to compare the adsorption m...
Autori: Hasna Elmontassir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28125

The mesoporous MCM-48 was synthesized at room temperature with different templates such as hexadecytrimethylammonium bromide (C16TABr), hexadecytrimethylammonium chloride (C16TACl) and dodecyltrimethlammonium chloride (C12TACl). The obtained materials were characterized by XRD, N2 adsorption/desorption, FTIR and SEM techniques, and their performance as uranium adsorbent were investigated. In this framework, the effect of contact time, pH of solution, initial uranium concentration and temperat...
Autori: Meriem Chabane Sari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28131

The 2030 Agenda for Sustainable Development adopted in 2015 attracted wide international attention. China’s State Council issued the Development Plan for China’s Innovation Demonstration Zone for Implementation of the 2030 Agenda for Sustainable Development in 2016, which offered a Chinese prescription for global sustainable development. Implementation of the Plan is based on National Sustainable Development Pilot Zones (NSDPZs). This gives rise to the question of what adjustments a...
Autori: Junli Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28142

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

Soluble dyes are intensively used in various industrial activities. They represent an important class of water pollutants from which they are rather difficult to remove. This paper focusses on the elimination of Congo Red (CR) ionic azo dye by adsorption on a low cost material. Cherry stones were used for activated carbon preparation by carbonization method. A temperature of 600 °C and a time of 4 h were found as adequate parameters for the physical activation and led to a final white powder...
Autori: Cristina-Gabriela Grigoraș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28153

The Cellets product represents a cellulose material, which combines different properties such as the perfect sphericity, fine particle size distribution, low friability and solubility, and inertness. The experiments were carried out with Cellets 200 granulated celluloses used as a filling material for a laboratory glass column, using diluted dye solution (9-10 mg of dye /L of solution) at adequate initial pH (4.7). The effect of flow rate was investigated, and the modeling of experimental data f...
Autori: Iulia Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28155

In this work, the removal of methyl orange (MO) and Cd2+ by simultaneous adsorption on adsorbent obtained from modified charcoal (BCBH) coated with TiO2 has been studied. The synthesized materials obtained from wood branches were characterized using atomic force microscopy (AFM) for the roughness and SEM to determine the morphology of the surface. EDX spectroscopy indicates the presence of C, N, O, Na, K, P and Ti on the surface of the adsorbent materials. The micro-porosity and BET specific sur...
Autori: Nicoleta Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28157

The recovery of nutrients from sewage sludge ash, especial phosphorus, is one of the most important alternative in sewage sludge management. Phosphorus is an essential element for all living organisms and very important for agriculture and industry, as well as. Because the phosphorus is a non-regenerative resource, its recovery plays an important role for society. Phosphorus capitalization as struvite (NH4MgPO4.6H2O) from sewage sludge has attracted considerable attention due to its potential to...
Autori: Bogdan Adrian Militaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28158

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

Since the era of the Industrial Revolution, energy consumption has considerably increased. As a consequence, a significant rise in greenhouse gas emissions has become a serious threat to environmental sustainability through climatic changes, global warming, natural disasters and pollution. In this context, increasing energy efficiency as well as the use of renewable energy can serve as important instruments for reduction of greenhouse gas emissions. The related literature has thus far generally ...
Autori: Yilmaz Bayar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28185

The western forests and rangelands of Iran in Zagros Mountain are valuable ecosystems for protecting the water and soil resources and providing the habitat for endemic fauna and flora. These ecosystems have widely destroyed by human interferences in the recent years. The land cover mapping using an accurate method is the first step to prevent the further destruction of these ecosystems. The aim of this study was to generate a land cover map of Ilam (Western Iran) using Sentinel-2A data at 10 m s...
Autori: Saeedeh Eskandari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28192

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

The study is focused on creating magnetic mesoporous materials through the insertion of a nickel ferrite into the structure of kaolintype clay. Sol-gel auto-combustion method was employed to synthesize the materials, using glycine and tartaric acid as chelating/combustion agents. This is the first study on the combined effect of different fuel agents and of clay-to-ferrite molar ratio on the structural, textural, magnetic and adsorptive properties of nanocomposites. The value of the average por...
Autori: Stefana Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28210

Silk sericin is a water-soluble macromolecular protein obtained from the raw cocoons of silkworm, Bombyx mori. It comprises of about 25% of the total cocoon shell weight and is categorized as a waste by-product in textile and silk industries after the extraction of silk fibers. This study emphasizes on the extraction of sericin from B. mori by a conventional salt alkaline method and characterized their physico-chemical properties, thermal stability, anti-bacterial and anti-oxidant activities. T...
Autori: Inderchand Manjubala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28213

In this article, issues of environmental pollution due to long-range atmospheric transport of heavy metals are considered. Researches of recent sediment cores of Lakes Liunkunlampi and Raivattalanlampi from the Republic of Karelia were carried out. The purpose of the study was to give a detailed environmental and geochemical assessment of the recent sediments in these small lakes located in the southwestern part of Karelia. The scope of the study covers the area of the southwest of Karelia (Russ...
Autori: Zakhar Slukovskii
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28229

In the current situation of increasingly urgent environmental problems, how to improve the capacity of green technology through spillover means based on the existing green knowledge and technology stock in the western region of China, so that the economy of the western region can move towards a low-carbon, coordinated and sustainable direction in a short period of time is worthy of our deep discussion. This study measured the carbon dioxide emissions and calculated the green total factor produc...
Autori: Xing Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28234

Two dairy farms (one a semi-confinement system and the other a pasture-based system) in the same region of Spain were chosen for comparison from a life cycle assessment perspective. In both cases, cattle feeding was found to be the main contributor to environmental impact in most categories. Additionally, cow emissions to air were the principal contribution to the global warming, fine particulate matter formation and terrestrial acidification categories. Although cow productivity in the pasture...
Autori: Amanda Laca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28243

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Carbendazim (CBZ, methyl 2-benzimidazolecarbamate) is used widely in agriculture against fungal diseases. We aimed to determine the effects of CBZ (0, 0.1, 0.2 and 0.4 mM) on long terminal repeat (LTR) retrotransposon polymorphism and genomic template stability (GTS), DNA damage using Äąnter-simple sequence repeats (ISSR) and inter-retrotransposon amplified polymorphisms (IRAP) marker techniques. Our results showed that all doses of CBZ compose retrotransposition polymorphism. In additional, ou...
Autori: Nalan Yildirim
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28250

Bad water quality has serious implications for human health, which may include gastrointestinal, liver, respiratory diseases and even cancer. In view of drinking water hardness in the study area, it was hypothesized that bad water quality has some association with the renal disorders. The possible association between nephrolithiasis, drinking water quality and diet in human subjects in district Abbottabad, Pakistan was investigated. Drinking water samples were collected from different areas (tot...
Autori: Suneela Jadoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28252

The treatment of acidic wastewater of copper sulfide produces a huge amount of sediment, which can be processed into the planting matrix for ecological restoration of mines. This paper attempts to screen out the plants suitable for the acidic wastewater sediment, laying the basis for ecological restoration of mines. Therefore, 14 plant species were selected for preliminary tests on survival rate and growth tests in sediment pond. The survival rates and growth conditions of each plant species in...
Autori: Jinchun Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28268

Citrus is one of the most important fruit tree crops worldwide, with respect to both total production and economic value. About 80% of the world production is destined to the fresh market, the remaining is processed to obtain various products (juices, jams, etc.). Citrus processing residues account for about 50-60% of processed fruits; their huge amounts and peculiar characteristics need a correct management that imply cost for producers and processors. If not well managed, they can represent an...
Autori: Paola Sangiorgio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28309

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

The spread of antibiotic resistant organisms and those producing extended spectrum β-lactamases (ESBL) has become a health care problem worldwide in communities and hospitals, as it leads to more complicated infections, longer duration of treatment, and increases in patient mortality. In the present study, we analyzed 226 clinical samples in order to assess the spread of ESBLproducing Enterobacteriaceae. 196 Enterobacteriaceae were identified and classified as members of the genera Pantoea...
Autori: Abdelbasset Mechai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28331

At present, the production of oily sludge is huge, and the micro-emulsion method can effectively separate crude oil and water from the oily sludge by reducing the interfacial tension between oil and cement. In this paper, the micro-emulsion was prepared by using surfactants, such as sodium dodecyl benzene sulfonate (SDBS), cetyltrimethylammonium chloride (CTAB), sodium dodecyl sulfonate (SDS), sodium cetyl sulfate (CAS), and alkylphenol polyoxyethylene ether (OP-10) as the main raw materials. T...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28344

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349