The models describing the flow or the heat and mass transfer in stirred bioreactors can be easily adapted for the continuous phase from the stirred bed bioreactors. But, for the immobilized biocatalyst phase, new models have to be established. Therefore, in this paper the influences of the main factors on mixing for a bioreactor with stirred bed of S. cerevisiae immobilized cells in alginate have been analyzed.. The mixing efficiency continuously increases with rotation speed acceleration for th...
Autori: Anca-Irina Galaction, Anca-Marcela Lupasteanu, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25116

AbstractDuring the modern history the ability of plant roots to consolidate and strengthen the soil was exploited twice in France: once in1867 by Joseph Monier who created the reinforced concrete, and then in 1962 by Henry Vidal who created structured soils.The paper presents the some results obtained on the ecological protection of floodplain in major riverbeds. The aerodynamic modeling represents an efficient, economic and easy way to work with. The main condition of successful experiments is ...
Autori: Ana Virsta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25136

AbstractFlocculation performance of three chitosan samples with different viscosities (?§ = 400, 800 and 1000 mPas) and two strong synthetic polycations of integral type (PDADMAC and PCA5) on two model aqueous suspensions (kaolin and bentonite) was investigated. The flocculation results indicated that all the polycation samples were efficient in the kaolin flocculation, the turbidity being completely removed at approximately the same polycation dose; the flocculation window ranged between 2.7 an...
Autori: Ecaterina Stela Dragan, Luminita Ghimici, Marcela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25201

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractAluminum and ferric salts are widely used as coagulants in water and wastewater treatment. They are effective in removing a broad range of impurities from water, including colloidal particles and dissolved organic substances. As well as traditional additives, such as aluminum sulphate ("alum") and ferric chloride, other products containing prehydrolized metal ions such as polyaluminum chlorides are now commonly used. The aim of this study was to develop a model for coagulation/flocculati...
Autori: Avid Banihashemi, Manouchehr Nikazar, , Reza Maknoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25230

AbstractThe removal of formasine fines particles from water by precipitation with polyelectrolyte and surfactant complex of Polyacrylamide (industrial product Praestol 611 made by Degussa) and Sodium Lauryl Sulphate (SLS) was experimentally studied. Calcium oxide was added to initiate precipitation of the polyelectrolyte complex together with the fines particles. The experiments were carried out with complexes having the surfactants concentration higher then the critical aggregation concentratio...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25238

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractAdvanced closing of paper machine circuits results in the accumulation of the dissolved and colloidal substances (DCS) in the process water. At a critical concentration, the DCS are destabilizing even by small variations in paper machine parameters, producing operational and product quality problems. This article presents results of lab experiments simulating the process water recycling in short circuit of paper machine, without and with addition of fixing agents. Tests were performing w...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25261

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

AbstractConsidering that three-phase dispersions are common in chemical engineering and biotechnology, and with increasing airlift reactor applications to chemical and biotechnological processes, a experimental study was undertaken in order to investigate the liquid phase hydrodynamics and dispersion in an external-loop airlift reactor on laboratory scale. Experiments were conducted in order to find a relationship between relevant hydrodynamic and mixing parameters of a solidsuspended exter...
Autori: Florina Ungureanu, Maria Gavrilescu, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25268

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract The synergistic combination of polymers and inorganic compounds via sol-gel process has attracted great attention, by manipulating structure at molecular level, for developing new materials with desired properties. These new hybrid materials could have a controllable combination of the benefits of polymers (flexibility, toughness, ease of processing) and those of ceramics or glasses (hardness, durability, thermal stability). The microstructures and the properties of hybrid materials...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25446

Abstract This paper presents an experimentally study of the anionic iodide separation from a mixture with immobilized liquid membrane. The experiments were carried out in a double jet installation. In order to intensify the transfer of iodide ions from the source phase to the receiving phase, the both phases are dispersed as droplets in the membrane and the hydrodynamic parameters of the dispersed phases are measured with the photographic method. The photos of the droplets were taken with a C...
Autori: Mihaela Emanuela Craciun, Mihaela Mihai, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25476

Abstract Highly dispersed nanoparticles of transition and noble metals are utilized for hydrocarbon reactions and rearrangements important to the chemical industry. The need to obtain 1 to 3 nm particles with narrow size distributions has prompted the development of alternative processing methods. Due to widespread speculation concerning the enhanced properties of nanoparticles over their bulk and atomic material equivalents, nanoparticle synthesis has become an active field of research withi...
Autori: , Irina Dumitriu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25482

Abstract Nanotechnologies may have properties of self-assembly, stability, specificity, drug encapsulation and biocompatibility as a result of their material composition. Nano-particles are being actively developed for tumour imaging in vivo, bio-molecular profiling of cancer biomarkers, and targeted drug delivery. These particles are stable, environmentally benign, and their chemical properties can be easily tailored by chemically modifying their surfaces. Conjugated with pharmacological a...
Autori: Simona-Florentina Pop, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25484

Abstract Various specialists draw attention on the conflict between the industrial civilization and the environment and mention two aspects: 1. The tendency of depletion of natural energy resources, raw materials and food, or consumption of renewable into a rhythm superior to their capacity of regeneration 2. Physical damage and pollution of the environment: water, air and land. It can be said that a sustainable society is the one that shapes its economic and social system so that natural ...
Autori: Dan Duran, Irina Duran, Ciprian Costescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25485

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract Tartrazine, (CI 19140) is an azo dye widely used in pharmaceuticals, cosmetics and foodstuff, as well as for coloring the textiles, hence it can be easily found in municipal wastewaters or wastewaters originating from textile, food, drugs and cosmetic industry. In this work, the capacity of a Romanian soil to retain Tartrazine from aqueous solution by sorption onto soil particles of different size has been investigated. The sorption kinetics was studied by applying five kinetic model...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25534

Abstract The constructed wetlands are considered as a low-cost alternative system for nitrogen removal. Shale was selected as a media in constructed wetlands, on the basis of adsorption capacity and suitability for plant growth. The specific objective of this study was to evaluate nitrogen adsorption capacity for using as a media in constructed wetlands. Shale was sieved into 5 particle sizes Shale A-E. The physical and chemical characteristics of shale showed that it is suitable to be use as...
Autori: Amara Daothaisong, Jareeya Yimrattanabovorn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25535

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract The paper presents the surfactant-assisted solvo-thermal route to synthesize nanoparticles of cerium oxide with different shape and morphology. The precursor was calcined at 400°C for 4 h in order to obtain CeO2 nanoparticles. The obtained samples were characterized by means of thermal analysis and FTIR spectroscopy. The UV-Vis analysis was used to study the optical properties. The morphologies and nano-structures were characterized by scanning electron microscopy (SEM) and XRD. It...
Autori: Nicolae Apostolescu, Gabriela Carja, Gabriela Apostolescu, Elena Husanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25541

Abstract University campuses can be seen as â€?small cities’ due to their high population (students, professors, employees) and corresponding high traffic flow, which may have a significant impact on both environment and people health. The objective of this work was to analyze particulate matter seasonal trends in the university area of Cosenza (University of Calabria). The relationship between sources emission, meteorological parameters and particle properties was defined. Sampling was co...
Autori: Monica Filice, Pierantonio De Luca, Giuseppe Piero Guido
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25564

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract In this paper, the capacity of a soil to retain the dye Erythrosine B from aqueous solution by sorption has been studied. Batch adsorption experiments were conducted to investigate the sorption of the dye from aqueous solutions onto soil with particles of different size. Different models were used to describe the kinetic data, to calculate the corresponding rate constants and to predict the theoretical capacities of soil for dye sorption. ...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25573

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract As a result of the global climatic changes generated by the alteration of the environment through polution, the ecosystems' natural ressources are incontrollably distributed, generating unforseeable effects at the level of the subsequent evolution of the natural balance factors. One of the greatest challenges of the science concerned with environment protection, is that of real time monitoring of the biochemical constitution. The real time monitoring of a great number of biochemical ...
Autori: Andrada Pretorian, Bojin Dionezie, Gabriel Epure, Ion Savu, Lucia Mutihac, Mihaela Muresan, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Rodica Lungu, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25583

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract Characterization of soil permeability is of great importance for several geotechnical analyses. In common practice, because of the difficulty in sampling of granular material, constant head permeability tests are usually employed on specimens having similar relative densities to those in the field. An alternative approach to permeability tests for granular soils is the prediction of permeability levels by means of empirical equations depending on several particle size distribution an...
Autori: Alper Sezer, Burak A. Goktepe, Selim Altun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25609

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

The combustion process plays the important role to improve performance and emission of diesel engine. To improve the rate of combustion process, the fuel-air mixing process should be accelerated. In this paper, based on the Double Swirl combustion chamber, from the macroscopic characteristics and simulation analysis, the effect of the incylinder forced swirls on performance and emission of diesel engine was studied. The results indicated that due to the incylinder forced swirls, the distribution...
Autori: Chang-Yuan Wang, Fu-Shui Liu, Xiang-Rong Lihttp://www.ecozone.ro/reviste.php?RID=25673

The main phenomenon of coagulation is that particles aggregate to form floc. The formation of floc and cluster was simulated with computer in two-dimensional space using particle-cluster aggregation model and the properties of floc were analyzed using fractal theory. The effect of sticking probabilities on floc structure, density and porosity were analyzed. With the sticking probability increases, the simulated floc structure is gradually loose, floc density is gradually lower, the porosity is g...
Autori: Wanchun Tan, Yunbo Wang, Changbo Jiang, Shiquan Sun, Hong Chen, Xiaobao Niehttp://www.ecozone.ro/reviste.php?RID=25675

Acidithiobacillus ferrooxidans plays an important role in the pyrite oxidation process and has been widely studied in order to determine the kinetics of the reactions, but the details of the oxidation processes on the surface of pyrite keeps poorly known. In this study, the bio-oxidation process of pyrite by Acidithiobacillus ferrooxidans was studied by comparing with abiotic oxidation by Fe3+. The attachment of Acidithiobacillus ferrooxidans on pyrite surface was found by using Scanning Electro...
Autori: Lei Jiang, Huiqun Yang, Yuruo Tao, Jinyan Yanghttp://www.ecozone.ro/reviste.php?RID=25686

Calcium zincate as an active material in Zn/Ni secondary battery has been successfully synthesized by microwave method. The sample was characterized by X-ray diffraction (XRD), thermogravimetric analysis, scanning electron microscope (SEM), chargedischarge test (CT) and cyclic voltammetry (CV) analysis. The results show that the chemical composition of sample is Ca(OH)2¡2Zn(OH)2¡2H2O with regular spherical shapes. The results from CV and CT measurement indicate that the battery has very high d...
Autori: Mengliang Tong, Xuanyan Liuhttp://www.ecozone.ro/reviste.php?RID=25700

Fuel injection system, intake system and the geometric shape of combustion chamber are the three key factors to the fuel-air mixture and combustion process for diesel engine. long with the need of high power density in diesel engine, the pressure of intake is higher increasingly. Together with the effect of high pressure fuel injection, the fuel-air mixture and combustion process is hard to spread as usual. In this circumstance, the performance of power, heat efficiency and emission in diesel en...
Autori: Shang Yong, Liu Fu-Shui, Li Xiang-Ronghttp://www.ecozone.ro/reviste.php?RID=25704

For a better evaluation of the impact of road traffic about air quality, this paper considers the development of a new evaluation index system and methods. They address the assessment of the air quality around the areas with an intense road traffic, according to Chinese standards considering sulfur dioxide index (SO2), total suspended particles index (TSP), floating dust index (PM10), nitrogen oxides index (NOX) and carbon monoxide index (CO). A systematic air quality evaluation model was establ...
Autori: Zhao-hui Liu, Zhi-bin Qinhttp://www.ecozone.ro/reviste.php?RID=25714

Abstract:In spite of the large use of batteries throughout the years, both in photovoltaic systems and in other uses, there are still nocomprehensive analyses in ageing studies and, when they exist, statistics turn out to be limited. In this sense, this macro-grid is aunique experience, since the experiment is already composed of 1600 identical stand-alone photovoltaic systems and almost 10years of data taking on 10 minute interval for the main magnitudes.In this paper, it is proposed a method f...
Autori: Angeles López Agüera, Daniel Rey Rey, Iago Rodriguez Cabo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25718

Abstract:In this paper the study on the possibilities of converting chopped reed stalk biomass into briquettes is described, in the conditions of harvesting water reed plant from Danube Delta region in winter time and based on briquetting technology used for wood waste from production. The water reed tested in the research has been harvested from Tulcea reed bed, one of the largest in Romania, chopped in a veneer drum chipper and compacted into the hydraulic briquette machine. The paper focuses ...
Autori: Aurel Lunguleasa, Camelia Coşereanu, Constantin - Radu Gheorghiu, Dumitru Lica, Gavril Budău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25734

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:The aim of this work is to obtain sintered porous membranes with graded structure for microfiltration by sedimentation andsintering of metallic powders. Our previous studies have demonstrated the possibility of obtaining sintered porous materials withgraded structure by sedimentation. In this paper, spherical nickel particles were used having a grain size in the 2-90 Âľm rangemeasured by the laser scattering particle size analyzer. The powders were sedimented into a sintering die in a s...
Autori: Gyorgy Thalmaier, Ioan Vida-Simiti, Nicolaie Jumate, Niculina Sechel, Valentin Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25775

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:Experimental research evaluated the possibilities of air treatment efficiency of a cylindrically shaped bio-charge, namely straw, toremove volatile organic compounds from the air. As determined during experiments, the air treatment efficiency of the straw biochargefor acetone removal reached 97.3%, while for butanol removal the efficiency was 86.0%. It has been determined that, withvolatile organic compound concentrations increasing biological air treatment efficiency is decreasing as h...
Autori: Alvydas Zagorskis, Petras Vaitiekunas, Pranas Baltrenas, Raimondas Leopoldas Idzelis,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25790

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Coconut coir pith, an agricultural solid waste was used for the sorption of Cd (II) from aqueous solution in batch mode. Parameters like contact time, adsorbent dosage and pH effect were studied. Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data and the system followed both the isotherms. Cd (II) adsorption capacity of coir pith was found to be 18.72 mg/g. Kinetic parameters of adsorption such as the Langergren pseudo-first-order, pseudo second order r...
Autori: Nagendra Badabhagni, Puthiya Veetil Nidheesh, Rajan Gandhimathi, Srikrishnaperumal Thanga Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25800

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

Abstract:Energy Efficiency is a topical concept managed by a wide variety of individuals and institutions from very different areas, bothacademic and professional. Economists, Engineers, Environmentalists, Lawyers and other specialists show, each one of them, anspecific dimension of this so relevant concept, not only for its implications on global evolution of Earth but for its impact onbenefit functions of enterprises.What this paper proposes is to shape a theoretical framework in which, firstl...
Autori: Jesus Rivas, Marta Magadán
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25819

An iron(Fe+3) oxide/hydroxide nanoparticles-based agglomerates (AggFe) suspension adsorbent was synthesized for efficient, cost-effective phosphate removal. A strong effect of AggFe concentration and pH level of water containing phosphate on removal efficiency was shown. It was found that phosphate adsorption onto the AggFe suspension may be described by pseudo-secondorder reaction kinetics and the Langmuir isotherm model. The unique adsorption properties of synthesized AggFe adsorbent are demon...
Autori: Grigori Zelmanov, Raphael Semiat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25829

� SUSTAINABILITY IN ENVIRONMENTAL REMEDIATION � EVALUATING THE CLIMATIC CHANGES IN THE HYDROLOGICAL FLOW REGIME OF THE MOLDAVIAN AREAS � ENSURING ECONOMICAL AND FINANCIAL SUSTAINABILITY: STATE FISCAL CONTROL - A WAY TO PREVENT AND REDUCE TAX AVOIDANCE � COMBINED OXIDATION AND ULTRAFILTRATION PROCESSES FOR THE REMOVAL OF PRIORITY ORGANIC POLLUTANTS FROM WASTEWATERS � THE FREE LEVEL UNIFORM POST-DARCY FILTRATION THROUGH A SPHERE-MADE HOMOGENOUS MEDIUM � HSLA ST...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25838

The aim of this work is the study of activated sludge floc samples stained with different dyes and imaged by Confocal Laser Scanning Microscopy (CLSM). Activated sludge flocs were stained for lipids, sugars and esterase enzyme producing bacteria. Images were acquired for different samples to analyze the structural characteristics of the bioaggregates. The analysis of the CLSM images allowed for the localization and estimation of the quantity of different build-up materials. The 3-D reconstructio...
Autori: Bela Abraham, Botond Raduly, Dan Niculae Robescu, Szabolcs Lanyi, Szabolcs Szilveszter, Szilard Bucs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25937

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

AbstractThe detection of environmental pollutants has challenged conventional chemical analysis for the rapid estimation of thebioavailability and toxicity of the contamination impact on human health and ecosystems. Magnetic nanoparticles (MNPs)functionalization as bioreporters can enhance the ability for biosensing in complex contaminated samples such as soils, and theimmobilization of bioreporters will promote the detection of gas and online monitoring. In this study, Acinetobacter baylyi ADP1...
Autori: Aizhong Ding, Cheng Chen, Dayi Zhang, Musen Duan, Steven F. Thornton, Wei E. Huang, Yanjun Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25952

AbstractThe paper outlines a technique to mitigate the power frequency magnetic field produced in its vicinity by the transport anddistribution power lines. The technique consists in introduction below the line conductors of a passive loop of rectangular shape.Due to the induced currents in the rectangular frame, the total magnetic field below this structure is significantly reduced. Themethod’s efficiency depends by the line conductor’s configuration and also by the dimensions of the frame. The...
Autori: Călin Munteanu, Emil Merdan, Ioan T. Pop, Sorin Deleanu, Vasile Topa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25994

AbstractThe aim of this work is to characterize the flocculation process of a bentonite synthetic suspension with characteristics close toBega River from Timisoara, Romania. The time stability of the synthetic suspension was firstly investigated. After a few days ofcontinuous mixing a stable suspension was reached, stability being confirmed by monitoring the main physicochemicalparameters (pH, temperature, turbidity, dissolved organic carbon and initial particle size). In order to determine the ...
Autori: Alain Liné, Cosmina-Mariana Militaru, Ligia Barna, Teodor Todinca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26027

AbstractA comparative study regarding the shape, dimension and bactericidal activity of the undoped and Ag-doped TiO2 nanocrystalswas achieved. In this way, two hydrothermal methods, classical hydrothermal and microwave-assisted hydrothermal, was usedfor nanoparticles synthesis. The obtained materials were investigated by X-ray diffraction, DRUV-VIS spectroscopy, BET andSEM/EDX analysis. Antibacterial activity of undoped and Ag-doped TiO2 materials was tested on real water from Bega River.The be...
Autori: Carmen Lazau, Corina Misca, Corina Orha, Cornelia Bandas, Sorin Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26034

AbstractWater quality is an inportant concern for the ecosystem state from a particular region. Since the continuous urban and economicdevelopment induces a negative impact on entire hydrological cycle, this study investigates the water quality of a Romanian lake,located in the Surduc area - Timis County. This perimeter has undergone significant economic development in the past twodecades due to increased tourism potential and the number of holiday residences.We proposed hybrid materias for the ...
Autori: Adina-Elena Segneanu, Cornelia Bandas, Florentina Cziple, Ioan Grozescu, Paula Sfîrloagă, Titus Slavici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26040

AbstractA simplified numerical model of the water distribution network of a medium sized town (with 30,000 inhabitants), of elongatedshape, was implemented in EPANET. The decay of chlorine residual concentration in the above mentioned network was studied,using the extended time analysis capabilities of EPANET, for a 3 days period. The water supply system, composed of one tank, 86pipes and 52 nodes is driven by gravity. The chlorine is injected at the tank with a constant concentration amount. Th...
Autori: Andrei-Mugur Georgescu, Sanda-Carmen Georgescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26054

AbstractThe paper presents the application of cross-spectrum analysis (CSA) to air pollution and meteorological time series collected fromseven air quality monitoring stations located in three urban agglomerations of Romania, affected by industrial and trafficpollution: Braşov, Ploieşti and Târgovişte. Data have been collected from November 2011 till March 2012, at one hour samplingrate. The purpose of the analysis was to reveal the correlations between two series at different fre...
Autori: Ştefania Iordache, Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26057

AbstractThe global diming means a gradual reduction on the earth's surface of global direct irradiance. The global dimming blocks thesunlight that would otherwise cause evaporation, thereby interacting with the global warming. In order to determine somecharacteristics confirming the global dimming were conducted a series of measurements of temperature and luminosity in Iasi.The purpose of the study was to link the urban pollution to the decrease in the solar luminosity during the time of a month...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26065

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

Abstract The Black Sea is seriously affected by a large range of pollutants, despite severe laws regarding the protection of sea ecosystems. Heavy metals are among the most important xenobiotics from the environment, presenting also toxicity for humans. The studies upon heavy metals have proven that the sediments have the highest concentrations and they can release metals back to water and this fact represents a risk for the humans and aquatic ecosystem life. The use of aquatic ...
Autori: Oana Jitar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26112

Abstract In many industrial applications most of the solid particles are separated by size and for this purpose there are used the oscillating sieves. The separation process based on sieves is a complex one and it depends on several factors, such as the properties of solid particles submitted to the separation process and on the operating regimes of the separating equipment. We have studied the separation process of the behaviour of solid particles on a flat oscillating surface...
Autori: Ovidiu Bontas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26134

Abstract In order to accomplish the water quality standards required for a specific use, the continental surface water is treated through a sequence of operations and unit processes. The treatment technological flowsheets carry out, partially or totally, the removal of various pollutants, every treatment step being used for improving one or more qualitative parameter. The treatment scheme is specific to water source type and water use. One of the basic operations for water treatmen...
Autori: Oana Tirtoacă Irimia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26136

Abstract Our researches have focused primarily on variations of different biophysical and biochemical effects on vegetal and animal material at macro, micro, and ultra-micro scale resulted from changes in environmental condition. Growth and spectral parameters of rapeseed seedlings from seeds exposed to UVA-VIS radiation with a high pressure lamp which emits incoherent continuously radiation for different time periods were examined 14 days after germination. These studied parameter...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26138

AbstractBased on the method of images, the three-dimensional soil additive load formula caused by pipe jacking soil loss was derived byusing non-uniform soil displacement mode. Combining the formulas of additive load induced both by bulkhead additive thrust,force of friction between shield and soil, force of friction between follow-up pipes, which are based on the Mindlin solution, theformulas of total soil additive load were obtained. The distribution regularity of total additive load on adjace...
Autori: Gang Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26166

AbstractWith global climate change, flood disasters occur frequently and detention basins are facing greater flooding risk. The flood riskassessment of detention basins becomes an important content for the management of detention basins.In this study, the index system of flood risk assessment of detention basins in Huaihe River Basin is established according to thenatural and social properties of detention basins flood disasters. The flood risk assessment methods are proposed based on support ve...
Autori: Junfei Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26172

AbstractAs a new type of photoelectrocatalytic materials, the TiO2 nanotube arrays have drawn a lot of attention for efficientlyphotoelectrocatalytic organic pollutants degradation due to their highly photoelectrocatalytic properties. Yet, the performance ofphotoelectrocatalytic organics degradation using TiO2 nanotube arrays electrode is influenced by Cl-, a kind of typical reducingmaterial. This paper focuses on the effect of Cl- on the different photoelectrocatalytic performance of TiO2 nanot...
Autori: Jialing Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26177

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractGallinaceous feathers are an abundant solid waste from the poultry processing industries, which poses disposal problems. Akinetic study dealing with the adsorption process of wool reactive dye, Yellow Lanasol 4G (CI Reactive Yellow 39), ongallinaceous (Gallus gallus, Cobb 500) feathers was carried out. The main research goals of this work were to evaluate theviability of using this waste as adsorbent and to study the kinetics of the adsorption process, using a synthetic effluent. Thechar...
Autori: Sónia Adriana Figueiredo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26203

AbstractIn an urban environment, visibility strongly reflects human safety and welfare. Generally, visibility is dependent on particlescattering and absorption. The former is influenced by light wavelength, atmospheric gaseous species and particle characteristics,especially number and size distribution. Therefore, it is necessary to establish the relationship between visibility and particlecharacteristics. Furthermore, it is important to understand the formation mechanism of secondary aerosols. ...
Autori: Chih-Ming Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26221

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractBased on principles of feeding solid waste into vertical boreholes in fully mechanized coal mining and backfilling technology,the literature established a trajectory model of particles in gas-solid two-phase flow for the sake of reducing the damage tostorage silo underground done by enormous impulsive force generated by falling solid waste. In addition, dynamical analysismethod in gas-solid two-phase flow field was adopted herein to study the solid particles’ force characteristics and th...
Autori: Nan Zhou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26271

AbstractThe extent of the problem of the excessive fluoride in drinking water remains an important health issue. In the present work,strong-base anion resins were investigated to assess their sorptive removal capacity of fluoride from water. It was found that theremoval of fluoride was high at natural pH (7) and was improved for increasing contact time and adsorbent dosage. Themaximum sorption of the resin was 13.7 mg/g according to the Langmuir model, namely higher than the values reported in t...
Autori: Mohammad Taghi Samadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26273

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractThe removal of phosphorus by strongly basic anion exchanger was investigated. Removal efficiency increased with contact time,resin mass and initial solute concentration, while temperature showed a reverse effect. Equilibrium data were best fitted ontoLangmuir isotherm model (R2>0.99). Maximum sorption capacity of the resin was 66.22 mg/g, namely significantly higher thevalues reported in the literature. The Freundlich parameter (n = 4.3) and the Langmuir separation factor (RL = 0.067-...
Autori: Abdeltif Amrane, Hamid Reza Ghaffari, Mansur Zarrabi, Mohammad Mahdi Soori, Mohammad Noori Sepehr, Saied Borji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26343

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractIn industrial plants many types of combustible dusts are generated, processed, handled and stored. When ignited, they can burnrapidly and with a considerable explosion force, when mixed with air in proper proportions. This is the reason why adequateprecautions have to be adopted, to ensure all equipment is appropriately protected so that the ignition likelihood of the explosiveatmosphere is diminished.Explosion preventing and protection precautions aim to stop explosion occurrence, by el...
Autori: Adrian Jurca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26406

AbstractResearches aim to develop new knowledge in the metal cutting field, using a relatively new technique with a low number ofapplications nationwide, namely the flexible explosive charge with cumulative effect for fast and precise cutting of metals. Theprocedure of cutting with explosives is a process that involves using and handling materials in their solid phase.This procedure isespecially applied in cases where materials are mostly metals and it uses a directed and controlled cumulative e...
Autori: Ilie Ciprian Jitea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26410

AbstractThe problem the paper deals with is the determination of ground heat distribution on different distances inside a cylindrical minework. Both interior radius and the exterior radii of the cylinder are known. The use of the range of temperatures is useful for thecalculation of the heat exchange rock - air. Results dissemination allow the development of a mathematical, model which may be applied to a seriesof natural conditions as well as to different geometrical shapes closer or not to the...
Autori: Dan Codruț Petrilean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26417

AbstractThe process of semi-volatile aerosol particle evaporation was studied with respect to both computational and experimentalapproaches. A Sinclair-La Mer type aerosol generator was used to produce monodisperse particles from four n-alkanes(tetradecane, hexadecane, octadecane, eicosane) while particle sizing and FID measurements were applied to quantify particleandvapor mass and their subsequent phase distribution. Aerosol dilution and later stationary analyses in a flow tube at two timeinte...
Autori: George C. Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26448

AbstractThe washing method for uranium contaminated soils using three different reagents was investigated. Experimental data havebeen obtained for four types of soils, which have been characterized in terms of particle size distribution, as well as structure andchemical composition. Thus, the decontamination degree for each type of soil and reagent respectively has been measured.Subsequently, the decontamination process has been simulated using an artificial neural network. Based on this neural ...
Autori: Alexandru Woinaroschy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26451

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractPathogenic bacteria are fetal to human health, requiring cost-effective and safe approaches to be removed from drinking watersource. With poly-allylamine-hydrochloride (PAAH) stabilization, magnetic nanoparticles (MNPs) were introduced in this studyto remove pathogenic bacteria by electrostatic interaction and magnet capture. High removal efficiency was achieved for fourmain pathogenic species, as Escherichia, Acinetobacter, Pseudomonas and Bacillus, and over 99.5% of the pathogens can b...
Autori: Yunfeng Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26475

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

AbstractThe conducted research has proved the dependence of gas flow rate in the separate channels of the two-level multichannel cycloneat a different inflow velocity and the number of channels. The carried out investigation demonstrates the dependence of changesin velocity in the channels under varying relations between peripheral and transitional flows. The work of a cyclone of the channelis based on centrifugal forces and an additionally occurring filtration process caused by the interaction ...
Autori: Pranas Baltrėnas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26488

AbstractFluorescence spectroscopy and parallel factor (PARAFAC) form a powerful tool in separating different fluorophores and maybe useful in detecting the fluorescent signature of dissolved organic matter (DOM). Despite the large number of studies onfluorescence and PARAFAC it is still uncertain if this combination is capable to separate DOM from different water types byanalyzing the presence of specific components and their spectral shape. This paper presents a preliminary study on thefluoresc...
Autori: Elfrida M. Carstea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26495

AbstractA soot transducer based on the measurement of the electrical resistance value of the soot layer deposited on a finger structure wastested at different thermophoretic potentials. The soot, similar to that issued from the Diesel engines, in terms of particle numberand size distribution, was obtained by the incomplete burning of propane and subsequent dilution. The decrease of the resistancevalue in time was directly proportional with the temperature gradient. Thus a soot transducer is aime...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26503

AbstractAs air quality becomes increasingly deteriorated in world-wide cities, air quality monitoring has extended beyond the criteriapollutants (CO, SO2, NOx, O3 and PM) in order to include several toxic air pollutants such as volatile organic compounds(VOCs). In the present study it was investigated the presence of 29 VOCs and PM including PM2.5, PM2.5-10 and PM>10 fractions,in an urban area from Romania. The total VOCs was higher in the urban area (176.72 - 192.54 μg/m3) than in the r...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26504

AbstractTwo types of nanofiltration membranes had been used to study the influence of cross flow velocity on the membrane filtration ofdenitrification effluent (NF270 and NF90). Filtration had been conducted at constant transmembrane pressure of 5 bar andvariable cross flow velocity (0.03, 0.06, 0.15 and 0.39 ms-1). The obtained normal flux was 0.47, 0.58, 0.59 and 0.77for NF270membranes and 0.35, 0.38, 0.41 and 0.39 for NF90 membranes, the increase in cross flow velocity had enhanced fluxperfor...
Autori: Abdel Halim Fuqaha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26523

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract Some of the major stressors of air quality in the urban areas are nitrogen oxides, ozone and suspended particles. The effect of air pollution on respiratory diseases can increase considerably at high levels of pollution and might trigger asthma symptoms. Longterm exposure can increase the rate of respiratory infections and symptoms at population level, but particularly in children. The goal was to analyze with statistical techniques the pollutant concentrations (NO, NO2, and SO2) re...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26605

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract Adsorption equilibrium and effective diffusion coefficients of water vapor, in cylindrical particles of activated alumina (A) and activated alumina impregnated with calcium chloride (MCA), are experimentally determined. The experiments were conducted at 303 K and 323 K using cylindrical particles with 2.5 mm in both length and diameter. Diffusion coefficients were determined from the kinetics of water sorption. The measurements were conducted in a constant pressure unit based on a m...
Autori: Eugenia Teodora Iacob Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26665

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract β-galactosidase from Aspergillus oryzae was strongly immobilized on magnetic particles functionalized with amino groups. By simple incubation without any activating agents, electrostatic interactions between amino groups and enzymes allowed obtaining a strong linkage. The immobilization efficiency was studied with the quantification of amino groups of the particles and of immobilized β-galactosidase. Kinetic parameters, especially the maximal velocity Vmax and the affinity...
Autori: Kalim Belhacene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26682

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract The Southeastern Black Sea coastal region in Turkey and Georgia is under threat of severe coastal erosion and shoreline recession. The main reason for this problem is the response of the coast to human activities. While water discharge rates were reduced by dams by approximately 7% only, about 98% of the suspended sediment is being captured by the dams, leading to reservoir siltation over time in the southern Black Sea Region Rivers in Turkey. About 83% of the total suspended sedime...
Autori: Mehmet Berkun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26698

Abstract Individual exposure to particulate matter (PM) fractions is mainly determined by indoor source characteristics and personal activity patterns. This paper discusses experimental results obtained through the analysis of individual exposure of women to PM10 and PM2.5. To this purpose, 15 volunteers of different ages and lifestyles living/working in Ceccano (Italy) were selected and their exposures to PM10 and PM2.5 were measured through a handheld photometer. They also filled out a tim...
Autori: Giorgio Buonanno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26703

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Maximum removal (94±1.2%) of 2, 4 dichlorophenol (50 mg.dm-3) was achieved on silica with agitation of 4 hours, at pH 8 and 42°C. The positive enthalpy (ΔH) and negative free energy values (ΔG315K) suggested the endothermic and a spontaneous nature of sorption. The free energy of the process at all temperature was negative and increased with the increase in temperature. The values of free energy suggested a spontaneous process where the spontaneity decreased w...
Autori: Abdul Ghaffar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26718

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract Impact damage is considered the primary cause of in-service delamination in composite materials and promotes significant reduction in residual strength. Non-destructive techniques (NDT) include several methods able to detect the shape and the size of the interior damages without destruction of the structure or component, which is economically advantageous. The aim of this paper is to evaluate the properties after low velocity impacts using an experimental-numerical procedure based o...
Autori: Ana Martins Amaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26726

Abstract This paper aims to analyze the characteristic of Road deposited sediment (RDS) using West Chang Tan highway, Hunan, China as a study site. RDS samples were collected at five representative highway sites and the particle size distribution was generally less than 150μm. Particles with the grain size (<150μm) had high metal concentrations among all sampling sites (unit: mg/kg): Cu 74-178, Zn 309-2737, Pb 601-1160, Cd 9.8-44.5. There is significant spatial variability between t...
Autori: Yunbo Zhai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26728

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Particle size distribution is one of the most influential factors of most soil physical and even some soil chemical characteristics. As modern measurement techniques are being introduced, the need for comparing new methods with older methodologies arises because comparability means data continuity. Here, three institutes conducted a comparison of particle size measurement among the laser, areometer and pipette techniques. The purpose of the comparison was to a) discover any differen...
Autori: Csaba Centeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26733

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract Extensive use of plastics leads to the increase of non biodegradable wastes that have to be recycled due to both dramatically decrease of natural resources to producing them and to their increasing need as well as due to environmental issues. Most of goods made by materials based on wastes have to be commonly used by people. Antibacterial character of those is necessary to avoid epidemics. This paper deals with determination of antimicrobial character of materials based on polymeric...
Autori: Florica Silvia Cristina Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26751

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract The wide spread traffic congestion witnessed in urban transportation network, especially during rush hours, aggravates vehicle exhaust emissions. Previous studies reveal that congestion not only slows down the traffic flow but also significantly increases emissions. This highlights the need of accounting for congestion-related emissions in transportation planning. In this paper, congestion-related emission is incorporated into a transit bus scheduling problem by a nonlinear programm...
Autori: Yan Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26806

Abstract In citizen observatories, the observations, insights and involvement of 'ordinary' citizens - alongside those of scientists and professionals - can be included in earth observation, environmental conservation as well as decision making. Facilitated by information and communication technologies (ICTs), such ICT-enabled citizen observatories have the potential to generate fundamental changes to existing governance structures. Based on an action research approach in three Europ...
Autori: Uta Wehn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26831

Abstract Environmental research has been significantly enriched by genomic and proteomic methodologies. Particularly in the atmospheric pollution studies, where a variety of environmental hazards act simultaneously and frequently in close interrelationship, only such integrative methods can provide a comprehensive analysis. Nanoparticles are a heterogeneous class of particles, but their health effects have also common aspects. The scope of the article is to present the contribution of genomi...
Autori: Marina Otelea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26852

Abstract The adsorption of phosphorus (P) on sediment plays a significant role in phosphorus transport in aquatic systems. This research examined the effect of the main components of sediments (including iron (Fe), manganese (Mn) oxides and organic matter (OM)) on P adsorption and to evaluate their relative contribution with different sediment particle sizes. The sediments were separated into four particle-size fractions: 0-30 μm, 30-62 μm, 62-90 μm, and 90-125 μm, and then selec...
Autori: Yang Xiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26873

Abstract In this paper we present results from the first European (EUR) and North Atlantic (NAT) volcanic ash exercise (VOLCEX) which includes all the warning phases associated as alerting, reactive and proactive phases. Because volcanic ash represents one of the most serious natural hazards that could affect aviation safety, the measurement campaign was focused on improving the reaction of relevant authorities in case of airspace contamination with volcanic ash and, particularly, to assess ...
Autori: Livio Belegante
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26874

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Abstract This paper is an environmental approach of land cover in rural areas, based on a case study of Eastern Romania: Studineţ catchment (9669 hectares). The information necessary to shape the profile of the research area is obtained through diachronic and comparative analysis of different land cover categories. For this purpose, three distinct aspects were analyzed: weight and fragmentation of arable land; evolution and current weight of forests; expansion of xerotermophilous shrubs...
Autori: Iulian Cătălin Stângă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26924

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

Adsorptive removal of dibutyl phthalate (DBP) by bamboo biochar (BC) was investigated under various experimental conditions. BC demonstrated excellent sorptive ability to remove DBP from the aqueous solutions. The removal of DBP by BC increased as the contacting time increased and reached an equilibrium value after 240 min. The presence of natural organic matter decreased the removal efficiency while increased the time to reach sorption equilibrium. The adsorption of DBP on BC could be well ...
Autori: Junliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26934

Water scarcity, the degradation of freshwater resources, and wastewater pollution are reaching crisis levels, especially in arid regions of the world. The reuse of wastewater was investigated by using intermittent media infiltration (IMI) to evaluate fecal coliform (FC) removal efficiency. Twelve IMI columns were packed with soil and natural filtering materials (sand, zeolite, vermicompost and charcoal) at percentages of 25, 50 and 75. The municipal wastewater was treated for the FC analysis ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26935

One way to improve the performance of non-thermal plasma (NTP) reactor for volatile organic compound decomposition is by the introduction of ferroelectric materials into the discharge zone of NTP. This paper is a review of the breakthroughs and the current status of the applications of this technology for the abatement of volatile organic compounds (VOCs). It covers the process of energy generation in NTP, VOCs decomposition processes and the effects of critical factors such as type of packed...
Autori: Abdullahi Mohammed Evuti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26948

This paper studies, in lab scale, the possibility of removing a rich-in-pollutant soil fraction using flotation, with the clean fraction been restored to its natural condition. The tests were carried out in a conventional flotation cell with mechanical agitation. Artificially polluted soil was used throughout this study by mixing soil with diesel fuel. The effect of the following flotation factors was studied: pulp pH, collector type and quantity, conditioning and flotation time, initial soil...
Autori: Nickolaos Georgiou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26960

Waste recycling in steel industry by turning grain-size and powdery waste into pellets is a must now more than ever for economical motivation, in order to save raw materials and also for ecological reasons, as it leads to a cut down in the quantity of dumped waste. Industrial practice offers processors various technologies of waste recycling (agglomeration, briquetting, pelleting, mechanical mixture). The optimal variant should be chosen according to waste type, its content of useful elements...
Autori: Ana Virgina Socalici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26968

The flocculation process is applied in wastewater treatment to separate the destabilized colloid particles (or the particles formed during the coagulation phase) by forming flocs. The scope of this research was to identify the predictability of the synthetic organic flocculants use for industrial wastewater treatment. The research was performed at small scale, in laboratory, but also at industrial scale, by applying the synthetic organic flocculants in a real industrial wastewater treatment p...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26975

Air pollution has a significant impact on human health and natural ecosystems. The principal gaseous pollutants compounds result from different types of combustion processes. In this category there are included carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), dust and hydrocarbons. Nitrogen oxides are a group of highly reactive gases, which contain nitrogen and oxygen in varying amounts. Most of the nitrogen oxides are colorless and odorless gas. This paper highlights the c...
Autori: Doina Capşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26988

The adsorption characteristics of nitrate ions from aqueous solution using Lewatit FO 36 was investigated as a function of pH, biomass dosage and contact time. Results showed that optimum conditions were obtained at pH 8, adsorbent dosage of 160 mg/L and contact time of 60 min. At the optimized experimental parameters, the maximum nitrate adsorption capacity of Lewatit FO 36 was 200 mg/g and nitrate adsorption followed Freundlich model. Among seven kinetic models used in this study, the adso...
Autori: Mehdi Ahmadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26996

The densities and distributions of airborne fungal spores known to cause respiratory tract disorders were monitored in three educational buildings located in different boroughs in Iaşi. Air samples from all locations were collected monthly over a period of 3 months (March-May 2011), using the Petri plate gravitational settling (passive) method. Petri plates containing nutrient media were exposed to room air for a 15-minute period, face upwards, to collect particles settling by gravity. A...
Autori: Florin Daniel Lipşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27003

Production and utilization of engineered nanoparticles (ENPs), which are smart materials with ability of sensing and destroying chemical contaminants, is growing rapidly. However, these materials seem to have some ecological and health adverse effects. Hence, the main goal of this review study is to give a brief description about the recent developments of the commercial available engineered nano particles in the environmental remediation and also to note the current state of findings about t...
Autori: Mohammadreza Kamali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27017

Over the past three decades, nickel–titanium engine-driven files have become instruments “sine qua non” for root canal treatment. They are increasingly used by dentists to facilitate the cleaning and shaping of root canals, during the mechanical treatment phase in endodontic therapy, increasing not only the speed of the treatment but also assuring a proper shape of the canal preparation. During the repeated use of these instruments, separation of the file occurs. It has been...
Autori: Teodora Stefanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27024

This paper aims to establish the capacity removal of hexavalent chromium [Cr(VI)] from wastewaters using a TiO2 – Fe3O4 based nanocomposite. Latest researches in the field point adsorption as a better option for removal of heavy metal ions from waters, this method being more efficient and cost effective, in comparison with other advanced methods like reverse osmosis, ion exchange, nanofiltration, etc. Based on this information, the goal of this work had as purpose the obtaining, charact...
Autori: Andra Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27025

Maghemite nanoparticles (γ-Fe2O3) were synthesized in order to be used as magnetic adsorbent for two heavy metals, Pb(II) and Zn(II), from aqueous solutions. γ-Fe2O3 was prepared from magnetite nanoparticles and was tested for single and binary aqueous solutions. Efficiency removal (%) for single solutions appears only after 10 minutes and was higher than 80%. In case of binary solutions, same results regarding efficiency removal were registered after 60 minutes, being almost 90% ...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27029

An environmental axis consists of elements, and the way they behave reflects the conditions in which they work. Romania, for example, is a country located at the crossroads of the most important environmental axes of the continent, namely the West-East axis: Western Europe - the ex-Soviet space; the North-West - South-East axis: Central Europe - Asia Minor and the Middle East; the axis of the seas: the Caspian Sea - the Black Sea - the Mediterranean; the axis of rivers and canals: Rhine - Mai...
Autori: Călin-Cornel Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27044

The investigation of bottom sediments in oxbow lakes was conducted in the free-flowing, meandering section of the Łyna River in N Poland. Seven oxbow lakes, differed by a degree of hydrological connectivity with the river channel, were chosen for the present study. In samples taken from 21 sediment profiles, particle size distribution, pH, bulk density, CaCO3, organic matter, total organic carbon as well as total forms of N, P, K, Ca, Na, Mg, Mn and Fe were determined. The gradient of de...
Autori: Szymon Kobus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27052

Hospitality is the main industry in the service sector in Spain, contributing to more than 10% of the gross domestic product and approximately 12% of all employees. Firms in this industry are beginning to adopt eco-innovations to reduce their environmental impact and optimize the use of natural resources. However, most companies do not have the necessary resources to tackle ecoinnovation on their own and need to cooperate with different agents. The purpose of this paper is to examine how open...
Autori: Francisco José Sáez-Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27073

This work evaluates the potential of Phyllanthus debilis for the adsorption of Zn2+ and Ni2+ ions using synthetic solutions. Adsorption experiments were performed in order to examine the effect of pH, contact time, biomass concentration and initial metal ion concentration in the removal process, in a batch mode. The results revealed that the adsorption is highly pH dependent. The adsorption of Zn2+ and Ni2+ ions were concentration dependent and increased from 2.446 to 8.688 mg/g for Zn2+ and ...
Autori: Mohammad Aslam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27084

Triton X-100 (TX100) and Tween 80 (TW80) were used to study the decontamination of polycyclic aromatic hydrocarbons (PAHs) in the bulk and different size fractions of soil samples from a former coke oven plant. The effects of PAH ring number, initial concentration and soil total organic carbon (TOC)/black carbon (BC) contents on PAH removal efficiencies were analyzed. Surfactant washing for the bulk sample showed clear relation between the removal efficiency and PAH ring number. When the sur...
Autori: Helian Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27093

We computed the Product Environmental Footprint (PEF) to identify the environmental performance of recycled wool by means of data belonging to a real case study in Italy. First, we analyzed inventory data quality by computing the data quality rating (DQR) index, according to the criteria provided by the PEF protocol. Quality of specific and generic data (selected from the Ecoinvent database) was evaluated as excellent and good, respectively. We then quantified the impacts related to each rele...
Autori: Silvia Bamonti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27121

The aim of the present study was to prepare environmentally friendly silver-based materials using Cornus mas L. fruits extract. For this purpose, silver nanoparticles (Cornus mas-AgNPs) were green synthesized using this plant extract. The bioreduction of silver ions was analyzed by UV–VIS and ATR-FTIR spectroscopic studies. Scanning Electron Microscopy (SEM) analysis revealed the formation of spherical phyto-nanosilver particles with size ranging between 12 and 40 nm. Different amounts ...
Autori: Ioana-Raluca Suica-Bunghez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27139

The removal of quinoline from synthetic wastewater by heterogeneous photo-Fenton in a novel internal circulating fluidized-bed reactor was investigated systematically. The flow field in the reactor was simulated by FLUENT software conjoined with tracer particles experiment, and the influence of reaction parameters such as initial quinoline concentration, catalysts dosage and H2O2 dosage were evaluated. Results indicated that the designed reactor was suitable for the heterogeneous photo-Fenton...
Autori: Ran Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27142

In this study, a mathematical model was introduced to calculate the collection efficiency of dust particles in a wire-pipe single-stage electrostatic precipitator (ESP). The aerodynamic diameters of these particles are less than 10 μm (PM10). The mathematical model, using combined Deutsch-Anderson Equation, considers coupling effects among gas flow field, electric field and particle field. A simplified 2-D ESP model was established using GAMBIT and a software application (FLUENT) was used to ...
Autori: Jian-Ping Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27172

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

As part of the 2012 Land Use/Land Cover Area Frame Survey (LUCAS), topsoil samples were collected in Bulgaria and Romania using the same methodology as for other EU Member States in an equivalent survey carried out in 2009. In total, 664 Bulgarian and 1384 Romanian samples were collected which enabled a comparative assessment of topsoil properties under different land covers within, and between, these countries, as well as in a broader European context. The samples were analysed for basic soil p...
Autori: Gergely Tóth
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27205

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

The present study was aimed at examining the ability of the natural zeolitic tuff from the Zlatokop deposit in Serbia to remove Pb(II) ions from aqueous solutions under various conditions. It has been found that the adsorption proceeds via an ion-exchange reaction in which the Na+ ions from the clinoptilolite phase of the tuff are replaced to a high degree by aqueous Pb(II) ions. The removal capacity of the clinoptilolite at 298 K varies from 78 mg Pb g–1 (for C0 = 100 mg Pb dm–3) to...
Autori: Djordje Stojakovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27234

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

The effect of ceria content on the physicochemical properties and catalytic performance of nanostructured CeO2/Al2O3 for removal of toluene from waste gas stream was studied. The properties of the catalysts were addressed using XRD, FESEM, BET, TPR-H2 and FTIR techniques. XRD patterns confirmed the formation of CeO2 with average crystallite size of 7.8-8.7 nm. FESEM images confirmed the presence of fine particles between 25.2-189.1 nm. BET results showed that nanostructured CeO2/Al2O3 had high s...
Autori: Saeed Saedy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27245

The capability of ornamental rocks solid waste (ORSW) as a low-cost sorbent was investigated in order to remove As(V) and Mn(II) from aqueous solution. Physical-chemical characterization analyses of the raw material presented albite and quartz as the main minerals. The solid waste presents low surface area (209.70 m2/g). The Langmuir, Freundlich, Sips (Langmuir-Freundlich), Redlich-Petersen and Tóth models were used to analyze sorption phenomena. The maximum sorption capability from the e...
Autori: Fernando Jorge Santos Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27246

Analyzing and reducing the possible effects of air pollution on human health became important issues for improving the quality of life in urban areas. Particulate matters (PM) are air pollutants with a potential important impact on human health of vulnerable people (e.g., children, elderly) and non-vulnerable people as well. The level of PM air pollution is mainly influenced by the PM concentration and parameters such as meteorological conditions and synergic effects of other air pollutants. The...
Autori: Mihaela Oprea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27286

The level of dissolved oxygen (DO) in the water downstream hydro power plants is an essential parameter which allows preservation and development of the aquatic habitat. The objective of this paper is to identify a new technical solution that contributes to the increase of DO level in the water passing through the turbine. The current technical solutions improve the DO level but affect the hydraulic efficiency of the turbine. There is no general technical solution for aeration of water used by h...
Autori: Florentina Bunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27296

According to literature, aggregate stability of soils is influenced by: particle size and soil texture, soil structure, content of Ca2+ and Mg2+, mineral clay type, soil content of organic matter, soil processing degree. This paper aims to investigate the influence of some physical, microbiological and chemical properties of saline soil concerning water-stable aggregate. The hydro system stability of the aggregates appears in the specialized studies as having a positive correlation with microorg...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27300

In the current context of industrialization, chemical and radioactive pollution is a concern for environmental protection and interference with human health. Care for environmental protection also includes vegetation that grows spontaneously in potentially contaminated places, thus avoiding illness among the population if consumed. The study area is located at 4.5km SSE from downtown Bacău City, Romania and is the result of the manufacture of H3PO4 through the wet method. In this study, t...
Autori: Mioara Săndulache Rachieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27331

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

Using the panel data of 30 provinces, cities and autonomous regions in China from 1997 to 2013, and taking different finance development and financial structure indexes into consideration, the paper systematically investigate the impact of finance development and finance structure on carbon emission. The results of empirical research show: (1) The financial development efficiency at a provincial level, and in Eastern regions, has a significant effect on carbon emission, illustrating an invert...
Autori: Yu Kong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27393

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

In this work, magnetic alginate was synthesized by encapsulating of Nickel Zinc Ferrite nanoparticle within Ca-alginate. The synthesized magnetic alginate was modified by ethylenediamine using microwave radiation to remove anionic dye from wastewater. The characteristics of magnetic nanoparticle, magnetic alginate and magnetic alginate amide (MAA) were studied using Fourier transform infrared (FTIR) and Scanning electron microscope (SEM). FTIR analysis confirmed the amidation of alginate. Di...
Autori: Niyaz Mohammad Mahmoodi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27424

The efficient use of fresh water sources and proper modeling of the water quality can only be possible when flows in the dam reservoir are well defined. Therefore, in this study, a hydrodynamics model of an actual dam reservoir in three dimensions for simulating a real dam reservoir flows for summer season is created. The model is developed using nonlinear and unsteady continuity, momentum, energy and k-ε turbulence model equations. In order to include the Coriolis force effect on the...
Autori: Fatih Üneş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27430

Considering that glass containers are generally highly transparent they are good candidates for spectroscopic measurements and application of a transmittance for glass separation. The selection of glass container samples directly from municipal waste disposal bins, characterized by different colors, thicknesses, and shapes was done. Transmittance spectra of clear, green, amber and black clean glass containers were recorded, along with spectra of the usual bottled liquids. Positions of the absorp...
Autori: Dragana D. Strbac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27452

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

Chemical composition variations of aerosols during summer and winter seasons have been investigated using an Aerosol Mass Spectrometer (AMS) at Magurele, a city near Bucharest, Romania. Proportions of chemical species, concentration time series, mass range distribution and aerodynamic size distribution of aerosols have been analyzed. AMS measurements proved that the organics, nitrate, sulphate and ammonium, with small amounts of chloride were the main species at ground level during the investig...
Autori: Jeni Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27479

An experimental study of the wires-two plates is presented in this paper. The principal running of these types of electrostatic precipitators is based on the corona discharge on which depend their performances. The factors affecting corona formation on wire - to- plate gaps are investigated experimentally. There are many factors affecting such corona formation. The investigated factors were the interspace between the two wires, gap length between the wire and the plate, ambient temperature, r...
Autori: Nouri Hamou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27485

A low-cost magnetic zeolitic material was synthesized from coal fly ash by means of a new, simple method involving alkaline hydrothermal zeolitization of fly ash (FA) followed by low-intensity wet magnetic separation. Scanning electron microscopy with energy-dispersive X-ray analysis was applied to characterize the composition, microstructure, and morphology of the material. The mineral and synthetic zeolite phases were identified by powder X-ray diffraction. The obtained magnetic zeolitic m...
Autori: Annie Shoumkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27486

An apatitic calcium phosphate gel (HaG) was elaborated and used to treat municipal wastewater in a physicochemical cycle prior to the standard biological degradation process. Preliminary laboratory batch experiments outlined the kinetics of heavy metal sorption by monitoring the concentrations found in filtered fractions as a function of treatment time. On site experiments were performed in a municipal wastewater treatment plant by derivation of real wastewater into an experimental tank. In this...
Autori: Nathalie Lyczko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27488

Studying on evolution law of sediment concentration in the lower Yellow River, revealing the evolution cycle and the relationship with the grain size of sediment have an important guiding significance for the governance of sediment in the Lower Yellow River. Based on the sediment data concentration of four important hydrological stations, Huayuankou, Gaocun, Aishan and Lijin, in the lower Yellow River. The evolution of the sediment sequence cycle were studied using Morlet wavelet analysis the co...
Autori: Xianqi Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27491

Influence of process variables like pH, adsorbent dosage (D), initial dye concentration (C0), particle size (S) and temperature (T) on adsorption of a direct dye on carbon derived from mango leaf were studied using a 25 factorial design. The main effects and interaction effects were determined using statistical methods. Maximum uptake obtained was 55.7 mg/g (pH = 2, T = 40 °C, D = 0.5 g/dm³, C0= 100 mg/dm³ and S = 53 μm). It was found that the effects of process variables namely...
Autori: Varadarajan Gunasekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27506

The aim of this study was to examine the adsorption of malachite green dye from aqueous solutions on the waste foundry sand. The effects of contact time, adsorbent amount, pH and initial dye concentration were investigated. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin adsorption isotherm models. The adsorption capacity of waste foundry sand for the removal of malachite green dye was determined with the Langmuir and found to be 23.29 mg/g. The adsorption isothe...
Autori: Elif Hatice Gürkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27536

It is acknowledged that organic fertilizers and wastes, such as animal slurries/manure from intensive farm enterprise, sewage sludge, poultry litter are and will continue to be spread on agricultural land and provide beneficial nutrients to crops. However, many of these materials which are also potentially polluting if not properly managed can pose a risk to groundwater and surface water quality. Generally, their distribution on the soil is performed with specialized machines to reduce the risk...
Autori: Vasilica Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27545

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

A factorial design analysis was performed in order to determine the significant factors influencing cadmium removal from aqueous solutions by powdered marble wastes (PMW), using a continuous stirring tank reactor (CSTR) system. Investigated factors were initial cadmium aqueous concentration (5-30 mg L-1), PMW dosage (5-15 g L-1) and flow rate (20-40 mL min-1). Results showed that the cadmium aqueous concentration and PMW dosage were the most influencing factors on metal removal from synthetic aq...
Autori: Ammar Mlayah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27590

The thermal degradation of kenaf (Hibiscus cannabinus) under the effect of several variables (particle size, Ar flow rate, sample initial mass and heating rate) was investigated. From experimental data and by application of various model-free methods (Friedman, Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa), the activation energies (EA) were calculated as a function of conversion. The results obtained allowed to conclude that kenaf follows a multi-stage degradation mechanism, with EA values rang...
Autori: Silvia Román
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27617

In this paper the results of the aerosol flux measurements in near water boundary layer are presented. Measurements were conducted using two micrometeorological methods in the southern Baltic Sea region. The preliminary results of comparisons of two methods are discussed. The eddy covariance (EC) method is shown as a method for the calibration of the gradient method (GM). The reason for proceeding with such calibration is to show that the GM, which is an indirect measuring method, is comparable ...
Autori: Piotr Markuszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27630

Copper pollution is common across the world and has caused serious public health problems recently. Among the conventional methods, adsorption has proved effective, economic, versatile and simple for the removal of aqueous Cu(II) contaminants. Deposits of natural Kaolin are abundant around the world, and are regarded as valueless due to its limited usage in industry. In this study, the adsorption behavior of natural Kaolin towards Cu(II) was evaluated. According to the results, the isothermal ad...
Autori: Qiang Tang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27651

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

In this work, PM2.5 removal mechanism was explored to investigate PM2.5 collection efficiency under the influences of applied magnetic field and diffusion charging (the main charging mode for submicron particle). The proposed electrostatic precipitators (ESPs) mathematical model considered three-field interaction between fluid field, electromagnetic field and particle dynamic field. CFD software FLUENT was used to generate the simplified solid structure of the ESP. In numerical calculation, t...
Autori: Jian-Ping Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27667

The objectives of this study were to investigate: a) whether the duration of organic farming influences the dimension, shape and geometry (fractal dimension) of soil micropores (<50μm) and b) for relationships of morphometric traits with certain chemical and biochemical soil variables (microbial biomass, N- and C-mineralization rates, NH4+, NO3-, organic C and N, extractable P, Mg+2, K+, Ca+2). We compared soil micromorphometric traits (area, perimeter, compactness, solidity, eccentricity)...
Autori: Nikolaos Monokrousos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27682

Hexavalent chromium Cr(VI), a constituent of wastewater from many industries, is regulated by the Environmental Protection Agency (EPA) as one of the priority pollutants. Adsorption is an important technique that can be used for Cr(VI) removal from wastewater. The challenge in adsorption techniques is to find a cheap, widely available adsorbent that has a high adsorption capacity to Cr(VI). Dates stones (DS) and palm fiber (PF) are two agricultural wastes that are produced from palm trees. These...
Autori: Reda Abubeah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27689

Atmospheric concentrations of PM2.5 and PM10 were measured in Beirut, Lebanon, for a period of 12 months. The daily average concentrations of PM10 and PM2.5 were found to be 51.3 ± 33.1 and 30.3 ± 9.4 μg.m−3, respectively, with corresponding maximum values of 359.7 and 208.6 μg.m−3. The annual average concentrations of PM10 and PM2.5 exceeded the World Health Organization’s standards by 150% and 200%, respectively. The mean concentration of coarse particles ...
Autori: Wehbeh Farah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27696

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27782

This paper aims to compare the adsorption performance of activated carbon and pine bark for iron and manganese removal from contaminated groundwater. Moreover, their environmental compatibility was checked for their possible use as reactive media in a permeable reactive barrier for in situ remediation. Batch tests were carried out with different iron and manganese concentrations and different particle-size distributions, in order to evaluate the effectiveness of the activated carbon and pine bar...
Autori: Silvia Sbaffoni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27779

In the present study, Dowex HCR-S/H, cationic resin was used as a resin for the removal of cadmium from aqueous solutions. The experiments were carried out in a batch vessel. Subsequent experiments were performed as a function of initial solution pH, resin dosage, agitation time, initial Cd2+ concentration, solution temperature and agitation speed. Ion exchange rate increased with the increase in initial cadmium concentration, stirring speed and temperature. The Langmuir, Freundlich, Elovich,...
Autori: Baybars Ali Fil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27777

The adsorption rate and dynamic behavior of the system are important factors as regards the process design and operational control. The aim of this study was to find a suitable kinetic model for the hexavalent chromium removal in a batch reactor. The experimental data were analyzed using four adsorption kinetic models: the pseudo- first and second order equations, the Elovich equation, and the intraparticle diffusion equation, so as to determine the best fit equation of the Cr(VI) adsorption ont...
Autori: Ankica Radjenovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27773

Geocomposite materials consisting of lightly cemented mixtures of expanded polystyrene beads (EPS) and backfill soils are commonly used as fillers and for the construction of light weight embankments. The constant normal stress (CNS) and constant volume (CV) direct shear parameters as well as the relationship between gradation properties of four residual granular backfill soils and direct shear parameters of lightly cemented mixture of EPS and backfill soils was evaluated. The maximum density an...
Autori: Felix Okonta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27771

Bare zero-valent iron nanoparticles (bare-ZVIN) have a great tendency to aggregate, which drops their reactivity with pollutants. To address this issue, polyvinylpyrrolidone stabilized-ZVIN (PVP-ZVIN) was synthesized and used for the removal of Cd2+ from aqueous solution in a batch system. The effects of operation conditions such as the pH of aqueous solution (2-8), reaction time (0-120), adsorbent concentration (1-6 g L-1) and the initial Cd2+ concentration (10-60 mg L-1) on the removal efficie...
Autori: Amirhosein Ramazanpour Esfahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27764

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27729

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27730

In this study, the removal of Cu(II) from real industrial wastewater, being taken from galvanotechnic industry, by means of manganese ferrite (MnFe2O4) nanoparticles (NPs) was investigated. The effects of pH, adsorbent dosage, and contact time on Cu(II) removal from wastewater were monitored using the real wastewater while the effect of initial concentration was studied on synthetic aqueous solutions. Optimal conditions were found for copper removal in this study. Cu(II) removal and adsorption c...
Autori: Naim Sezgin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27743

The probabilistic estimation and the risk analysis of the exposure to pesticides through the ingestion of plants and food products is an important task for ensuring informed decision making and appropriate consumer protection. Monte Carlo-based methods are powerful tools in this regard, allowing for the empirical estimation of the distribution of exposure values, as well as for carrying out a corresponding uncertainty analysis. Such findings are important for assessing the exposure risk for mult...
Autori: Petronela Cozma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27754

The research has been focused on concretes in which the continuous phase is some kind of polymeric resin and the discrete phase is some type of mineral aggregate. Such composite materials are known as Polymer concretes (PC) and boast several advantages such as lower weights, higher resistance to corrosive environments and chemical attacks, faster curing and lower permeabilities. In PC the inorganic fraction can reach up to 90% of the total and is made up of aggregates such as sand and gravel. Th...
Autori: Paolo Pozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27799

In this study, the effect of raw material formulation used in the core layer on the water resistance and mechanical properties of particleboard made from a mixture of rice husk and wood particles was investigated. For this aim, four series of particleboard core layer were produced from different proportions of rice husk/wood particles, different amounts of urea-formaldehyde (UF) adhesive, low density polyethylene (LDPE), and maleic anhydride grafted polyethylene (MAPE), respectively. The amounts...
Autori: Jin Heon Kwon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27871

Heavy metals are inorganic persistent pollutants with adverse health and environmental effects. In our study, self-synthesized iron oxide magnetic nanoparticles were encapsulated in the Phanerochaete chrysosporium (P. chrysosporium) hyphae. The prepared biosorbents possessed high efficiency for Pb(II) biosorption from single and binary metal systems. The maximum biosorption capacity was found to be 50.05 mg g–1 at pH 5.0. Environmental scanning electron microscope accompanied with energy d...
Autori: Danlian Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27864

In this paper, an improved engineering model and analysis techniques are presented of the fly ash particles coagulation with droplets in Venturi tubes of industrial scale, based on spatial variation of the collection efficiency of particles on individual droplets, accounting for spray water flow polydispersity and particle size distribution, which allows to define optimal droplets size and spray water flow rate at different modes of thermal power units operation. The model is validated with the ...
Autori: Igor Volchyn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27836

The aim of this study is to investigate a variety behaviors of two kinds of media (multiple-layer structures and multiple-layer structures combined with surface treatment, such as finer fibers) with ages using a scanning electron microscope (SEM) and to determine the effect of fabric microstructures on cake formation and pulse cleaning. The results show that fine particles are readily deposited on the surface and inside depth filter medium. The fine fibers with diameters (~0.08 microns, this val...
Autori: Yan Cuiping
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27842

The macrophyte Pistia stratiote was used as biosorbent for the removal of Black Krom KJR (BK-KJR) dye in synthetic aqueous solution. Initially, some tests were performed to verify the best operational conditions such as pH, biosorbent particle size, sorption temperature and stirring speed, which were later used in the kinetic and equilibrium tests. All tests were performed in duplicate. The highest removal rates of the pollutant were achieved at the process conditions of initial pH 2, granulo...
Autori: Aparecido Nivaldo Módenes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27843

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

In this study, Mg-doped ZnO nanoparticles with 2% Mg content were synthesized by sol-gel method. The structure and morphology of the nanoparticles were characterized by TEM, BET and UV-Vis absorbance techniques. From TEM image, it was found out that the nanoparticles had uniform size and uniform distribution. BET analysis revealed that in comparison with pure ZnO, Mg 2%/ZnO nanoparticles had a higher specific surface area. Based on UV-Vis absorbance analysis, Mg 2%/ZnO nanoparticles shifted t...
Autori: Nahide Zarei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27909

This paper presents the results of a case study conducted between 2.04 and 24.04.2013 in order to establish the most relevant indicators that characterize the influence of outdoor air pollution, with particulate matter having a nominal diameter less than 2.5μm (PM2.5), on the quality of indoor air from a new building. The tests consisted in simultaneous determination of the daily average PM2.5 concentrations at four indoor sites and at one outside, nearby the building. The average PM2.5 c...
Autori: Elena Bucur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27914

Electrically charged particles of air pollutants show the degree of atmospheric pollution they being consistent with some chemical indicators of air pollution. This study analyses these indicators of atmospheric pollution (EIAP) present in various zones around the cities of Iasi, Bacau and Piatra Neamt and correlate them with the incidence of some diseases amongst the population. The results show that certain values of electrical indicators of atmospheric pollution point to a higher incidence...
Autori: Liliana Sachelarie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27916

Agro-industrial waste are seen as potential precursors in the development of adsorbents for the removal of phenolic compounds, which exhibit a harmful effect to human health due to their high toxicity. This work evaluated the use of coal prepared from coconut tree agro-industrial waste, for the adsorption of phenol in aqueous solutions. Three coal samples were prepared as follows: carbonized only (Cb), activated with synthetic air (Cair) and activated with CO2 (CCO2). Based on the results of ...
Autori: Marta Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27937

The present study explores the potential use of plant waste i.e. spotted golden thistle (Scolymus maculatus L.) stalks, as an inexpensive sorbent for the removal of methylene blue from synthetic aqueous solutions. Firstly, the waste material was characterized using different analysis methods, then kinetics and equilibrium of dye sorption were investigated using a batch sorption technique. The influence of contact time, initial dye concentration, sorbent dose, particle size and agitation speed...
Autori: Zoubida Senouci Bereksi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27941

Analyzing and reducing the possible effects of air pollution on human health became important issues for improving the quality of life in urban areas. Particulate matters (PM) are air pollutants with a potential important impact on the health of vulnerable people (e.g., children, elderly) and non-vulnerable people as well. The level of PM air pollution is mainly influenced by the PM concentration and by parameters such as the meteorological conditions and the synergic effects of other air pol...
Autori: Adrian Florea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27951

The research carried out in the specialized Laboratory of the National Institute for Research and Development in Mine Safety and Explosion Protection - INSEMEX Petrosani has identified the causes of high pressure peaks occurrence in the case of large electric motor enclosures as: the extremely large internal volume, the geometrical shape of motor enclosures and the very intricate and complex internal arrangement of such motor enclosures, having in mind the tendency of motor manufacturers for ...
Autori: Mihai Magyari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27960

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

Nanoparticles (NPs) have recently been concerned as emerging contaminants. Determination of NPs in different environmental compartments is a revealing topic for researchers studying their impacts in nature. Various methods of analysis have been reported in literature for their measurement and recovery. However, there are difficulties in their quatification in landfill leachate. Taking into account varying landfill components and their possible interactions with NPs, different types of NPs wer...
Autori: Ceyda Senem Uyguner-Demirel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27989

Clinoptilolite (Clin), the most widely used natural zeolite in environmental applications, was used as soil additive to investigate its effectiveness in protecting and improving the quality of soils that received surface disposal of OMW, as well as in limiting nutrients leaching from the degraded soils. Clin was added in a batch experiment of 18 months, where OMW were added in evaporation ponds and on soil for a period of more than 12 years. The zeolite was added as dust (particle diameter &l...
Autori: Maria K. Doula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28018

Based on the dynamic panel data from 29 administrative regions in China over the period of 2003-2013, we applied GMM system method to the analysis of the relationship between financial development, economic growth and CO2 emissions. Empirical analysis indicates that economic growth is usually accompanied by higher CO2 emissions, while the increasing level of final development is associated with a reduction in CO2 emissions. Further analysis shows that the relationship between financial develo...
Autori: Shushu Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28023

Sustainability and renewability in constructional materials and also utilization of such materials for various engineering purpose is the need of the hour. Green retrofitting with the aid of green fibre reinforced polymer (FRP) materials, made up of natural bio fibres like sisal would contribute to sustainable development. Non fossil-fuel carbon precursor organic fibres, i.e. sisal FRP composites were used for retrofitting of reinforced concrete (RC) beams, designed to undergo shear failure. ...
Autori: Tara Sen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28025

After the recent global financial and economic crises, unemployment, especially among young people have become a particularly serious problem. Fostering young entrepreneurship represent not only a tool to combat young unemployment and social exclusion but also a way to encourage innovation and a country’s economic growth. Education and training can contribute in building an entrepreneurial society and may shape individuals attitudes versus risk-taking. Risk taken ability is an important...
Autori: Ana Iolanda Vodă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28038

Due to emissions from power station using fossil fuels, the decrease of existing pollution as well as of operational costs should be taken into consideration, when resolving environmental economic dispatch problems. In this research, we will evidence that nonlinear constraints of generating units, forbidden regions, and ramp-rate of generating units will reduce operational costs and environmental pollution, to achieve environmental economic dispatch effectiveness, by employing an improved mul...
Autori: Daqing Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28045

Dust explosions are one of the main causes of mining disasters. To avoid them, it is important to understand how they are propagated. In the study reported here, computational fluid dynamics software was used to model a 3D diagonal pipe network then simulated a dust explosion at its inlet to examine its propagation characteristics. The initial conditions, boundary conditions and parameter settings were detailed description in the simulation to analyze possible propagation characteristics, assess...
Autori: Baichao Song
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28067

In China, there exist major differences in both the energy consumption and industrial structure between provinces and cities, leading to carbon emission transfer. Based on inter-provincial trade and industrial transfer, this paper measures the carbon emission transfer of China's sub-sectors and cities in 2007 and 2010 using the inter-provincial input-output model. The results show that, carbon dioxide transfers from economically developed regions and regions with a single industrial structur...
Autori: Yawei Qi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28106

China’s tremendous economic developments are achieved at the expense of environmental deterioration. In recent years, PM2.5 pollution has become increasingly serious in China, attracting widespread attention from the citizens and the government. This study aims to investigate the temporal–spatial characteristics of PM2.5 in China in 1998–2012, fully considering the potential influencing factors of PM2.5. The satellite remote sensing data compensate for the deficiency of surface...
Autori: Wenyang Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28115

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

The booming production and application of nanoparticles have raised great concern over its effect on environment, due to their increasing release in the environmental systems via intentional or unintentional activities, where their possible physicochemical and toxicological behavior remain unknown. The nanoparticles are released into the different environmental systems like air, soils and waters. However, their interaction with air matrices has been rarely investigated. For this reason, the chan...
Autori: Asli Baysal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28124

Photocatalytic processes are among the most efficient treatment methods of waters polluted with recalcitrant organic substances. Nanotubular TiO2 arrays with photocatalytic properties were obtained in the process of titanium anodic oxidation in the fluoridecontaining electrolyte. Under the proposed conditions of electrolysis, a coherent system of tightly adjoining nanotubes was formed with the internal diameter of 60-80 nm and walls thickness up to 60-65 nm, the tubes height being dependent on p...
Autori: Gheorghe Duca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28137

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Soluble dyes are intensively used in various industrial activities. They represent an important class of water pollutants from which they are rather difficult to remove. This paper focusses on the elimination of Congo Red (CR) ionic azo dye by adsorption on a low cost material. Cherry stones were used for activated carbon preparation by carbonization method. A temperature of 600 °C and a time of 4 h were found as adequate parameters for the physical activation and led to a final white powder...
Autori: Cristina-Gabriela Grigoraș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28153

The Cellets product represents a cellulose material, which combines different properties such as the perfect sphericity, fine particle size distribution, low friability and solubility, and inertness. The experiments were carried out with Cellets 200 granulated celluloses used as a filling material for a laboratory glass column, using diluted dye solution (9-10 mg of dye /L of solution) at adequate initial pH (4.7). The effect of flow rate was investigated, and the modeling of experimental data f...
Autori: Iulia Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28155

The paper covers the results of a study, carried out during 2005 and 2018, regarding the impact of sludge dump of a wastewater treatment plant from Iasi city, Romania, on the soil characteristics. Experimental research was conducted to highlight the evolution of the heavy metal content of both the material in the storage site and the soil in its proximity. The following heavy metal concentrations were analyzed with atomic adsorption spectrometry method: Zn, Ni, Cr, Pb, Co, Cu and Cd. Research ha...
Autori: Georgiana Cezarina Bartic Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28164

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

Distribution of solid particles in the atmosphere around the pollution sources has an important role in decision making to oppose with air pollutants. This study reports the concentration and distribution of 11 heavy metals including Cu, Co, Ni, Cd, V, Ti, Mo, Cr, Pb, As, and Hg emitted from 6 incinerators (A to F) with various feeds and operating conditions to determine the extent of exposure for industrial and residential areas. These incinerators located at Petrochemical Special Economic Zone...
Autori: Akbar Pirbadali-Somarin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28166

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

A Computational Fluid Dynamics (ANSYS Fluent CFD) software was applied for the examination of a critical combined sewer section of Budapest (Hungary) sewer network. The critical part of the main branch is located at a combined sewer overflow (CSO) which is implying environmental risk for the receiving water body. The CFD simulations proved the anticipated disadvantageous hydrodynamic effects of the lateral inflow. A discrete phase model (DPM) was also applied to analyse the sediment transport...
Autori: Marcell Knolmar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28183

This study aims to evaluate the properties of different wastes obtained from four red ceramic brick industries in the northern region of Santa Catarina, Brazil. The characterization of the clay brick waste (CBW) was performed using the XRD techniques, XRF, FTIR, DTA and SEM. Techniques to determine the pozzolanic activity, particle size, B.E.T. surface area and specific mass were used. The consumption of calcium hydroxide (CH) in the cementitious pastes with the CBWs was also measured. An app...
Autori: Adilson Schackow
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28184

This study investigates the capability of furnace bottom ash (FBA) as a filter media for phosphorus removal from wastewater effluents. Lab-scale studies were conducted, in which a mass of FBA was brought into contact with the phosphate solution (a predominant form of phosphorus in wastewater) in batch experiments and lab-scale filter. Intraparticle Diffusion Model (IPD) was applied and revealed that the mechanism of phosphate adsorption onto FBA consist of three phases; film phase occurred in...
Autori: Ali Alzeyadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28191

In the present research, four meta-heuristic algorithms named Genetic Algorithm (GA), Gravitational Search Algorithm (GSA), Particle Swarm Optimization (PSO), and Artificial Bee Colony (ABC) have been used for optimal design of cascade spillway to minimize the construction cost. Usually, the traditional design methods such as Vittal and Porey (VP) method or experimental modeling are used to solve this problem leading to infeasible or near optimal solution. The main novelty of this paper is to...
Autori: Pedram Jazayeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28195

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

The migration of methanogen in coal seams have great significance to study the improvement of coal bed gas (CBM) production by injecting microorganisms.This study aims to identify the migration characteristics of methanogens in different rank coals. Methanobacteria migration test was carried out by using coal samples of different particle sizes in the different rank coals. The results show that the maximum relative bacterial absorbance of a Qianqiu mine 18-35 mesh sample was 0.68, higher than th...
Autori: Hao Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28236

Bad water quality has serious implications for human health, which may include gastrointestinal, liver, respiratory diseases and even cancer. In view of drinking water hardness in the study area, it was hypothesized that bad water quality has some association with the renal disorders. The possible association between nephrolithiasis, drinking water quality and diet in human subjects in district Abbottabad, Pakistan was investigated. Drinking water samples were collected from different areas (tot...
Autori: Suneela Jadoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28252

The solar energy received by the atmosphere of the Earth is universally distributed, which constitutes the atmospheric dynamics. The changes observed in the climate of the Earth are due to solar output variations. Some detailed reviews have accounted for the influence of solar activities on the climate using sunspot number derived from peak Sun hours, but has gaps in analyzing critical statistical background information, seasonal, latitudinal and solar activity year validation. A number of st...
Autori: Chukwuma Moses Anoruo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28260

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

This paper aims to investigate the root characteristics of three woody species (Pinus brutia, Quercus coccifera and Spartium junceum) planted on steep soil-denuded slopes, surfaced after ring-road excavation. The planted slopes were almost vertical, south faced and adding no soil. Fifteen plants per species were manually extracted for root system analysis and testing. The findings showed that the survivorship was different among the investigated species with S. junceum plants to survive better. ...
Autori: Petros Ganatsas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28329

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349