AbstractIt was investigated the bioleaching of uranyl ions from uranium ores, in aquatic medium with algae: Scenedesmus quadricauda and Nostoc linkia under different experimental conditions. The oxidation of U(IV) to U(VI) species, like uranyl ions was done by means of the atomic oxygen generated through photosynthesis by the aquatic medium from solution above of uranium ores.After almost 10 days of direct contact with the given microorganisms, it was observed a bioleaching degree between 10% an...
Autori: Alexandru Cecal, Rodica Calmoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25107

<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

Iinclude urmatoarele articole:� Process water of papermaking: model building and characterization� Landfill inventory in the Republic of Moldova: problems and solutions� Floodplain revegetation and river basin restoration� Environmental problems of copper complex in Bor area� Researches on air micro flora determination from public indoor spaces and hospital wards in an urban area� Current practice of solid waste management in Malaysia and its disposal� An assessment of potential he...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25199

In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

AbstractThe textile industry is a large water consumer. Stringent regulations of wastewater characteristics require the use of membrane processes for the removal of persistent organic pollutants (POPs) from textile wastewater prior to discharge or recycling of these effluents.This paper presents an overview of research related to the removal of persistent organic pollutants from textile industry by membrane processes, discussing also the correlations with actual pre-treatment and removal rates. ...
Autori: , Corina - Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25127

AbstractThe corrosion behaviour of three commercial nickel-chromium based dental materials was investigated by electrochemical methods in a corroding mixture of sodium chloride, oxalic acid and lactic acid. In order to establish electrochemical parameters of the corrosion process, linear and cyclic polarization curves were plotted. The samples performances in the corroding system were investigated by weight loss, pH and electrical conductivity measurements. The quantitative analysis related with...
Autori: , Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25132

AbsractThe paper highlights the inventory of landfill, focusing on the feasibility study of solid waste disposal sites inventory in the Republic of Moldova and existing situation in waste management, including landfills analysis. The paper contains relevant information on landfills characteristics, their location and description of disposed waste. Technical assistance for the study was provided by the regional project Capacity building for improving the quality of greenhouse gas inventories (Eur...
Autori: Tatiana Tugui
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25135

AbstractE-waste is a new term coined in the market of hazardous substances. It has taken a new bourgeoning route since the boom of Information Technology (IT). The problems regarding the transportation, handling and dispose have to be tackled at the earliest as it might cause detrimental effects on environment. Presently in India there is no distinct and lucid regulation(s) regarding e-waste management. There should one stop solution! In the present paper, some of the Technical and E-Management ...
Autori: Santosh M. Avvannavar, Surathkal Shrihari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25142

AbstractIn 2004, the types of shoreline were estimated on Lake Balaton, such as rip-rap covered, reedy, concrete or grit. Exact area of a specific face of a rock in the rip-rap covered parts can be determined by digital image analysis. Wetted rocky area of the shore was estimated as a function of water level in 10 cm steps of level changes. Taking into account the reproduction characteristics of the studied fish species (Cyprinidae) the potential substrates for spawning are dominantly the shallo...
Autori: Gabor Borbely, Gabor Paulovits, Laszlo G. Toth, Nora Kovats
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25204

AbstractMunicipal solid waste (MSW) management is an important and challenging issue for sustainable development. It is also one of themost controversial problems and a subject of an ongoing debate between different interested parties. A particularly controversial issue is MSW incineration (with or without energy recovery) which has in many countries become a socially unacceptable option for dealing with solid waste. On the other hand, the increasing amounts of waste each year demand immediate a...
Autori: Adisa Azapagic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25147

Experiments in a Pilot Plant (PP) are extremely important and relevant for the substantiation of research. This is the way to set up the most suitable coagulation-flocculation reagents, optimum operating conditions (injection point, reaction times, etc.),compatibility with the processes at the actual Water Works and real possibilities for further improvement.The present work aimed at verifying the previously obtained results in laboratory under PP working conditions for optimizing the coagulatio...
Autori: Adina Pacala, Alina Anghelina, Dalila Marşavina, Ilie Vlaicu, Katalin Bodor, Mihaela Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25156

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

In this work, the ability of Romanian peat for sorption of Pb (II) ions from aqueous solution has been determined using the batch experimental techniques. The sorption equilibrium has been studied at different pH values. The equilibrium adsorption level was determined to be dependent of the pH of solution and initial Pb(II) concentration.The equilibrium adsorption capacity of Romanian peat sorbent for lead has been described by seven types of mathematical model isotherms, namely: Freundlich, Lan...
Autori: Brindusa Robu, Corneliu Cojocaru, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25160

Contain all the articles from this issue Risk assessment and management - tools for sustainable developmentMaria GavrilescuSustainable alternatives for petrochemical wastewater managementCarmen Teodosiu, Lidy E. Fratila-ApachiteiThe role and the place of oxidant reagents in wastewater treatmentIoan RoscaEnvironmental Psychology, a new direction in the psychological fieldCarmen Catalina IoanChanging concepts of high performance to socially sustainable organizationCostache Rusu, Nerida DavisU...
Autori: Abdelnaser Omran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25166

Contain all the articles from this issueEnvironmental analysis by capillary electrophoresis. Atmospheric samplesCamelia Draghici, Gheorghe Coman, Mihaela Sica,Dana Perniu, Mihaela Badea   The ecological farms - A solution for sustainable agriculture. II. Position and perspectives of the ecofarms in the frame of the productive agricultural system Stela Axinte, Alina Stanciu, Lorica Axinte  The extraction and clean up of organochlorine pesticides and PCB's from water using solid phase ex...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25170

Plants as biomarkers, biosensors and biomonitorsModelling of wastewater treatment of a pulp and paper mill for monitoringCatalysts for heterogeneous photocatalysts. Part I. Possibilities to improve photoefficiency through catalysts modificationThe global assessment method of the water qualityAspects regarding the wood certification in RomaniaDecolorizing of pulping effluents by ammonium lignosulphonate oxidationPowder coatings-based organic filmsOn environmental effects of the pulp and paper mil...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25172

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueBiosorption of Cu2+ ions from aqueous solution by Enteromorpha sp.Loredana Brinza, Matthew Dring, Maria Gavrilescu  Environmental impact assessment for steel processingBrindusa Robu, Carmen Zaharia, Matei MacoveanuEnhanced primary treatment of municipal wastewater by ion exchange and membrane processesDaniela Teleman, Peter A. Wilderer, Carmen Teodosiu, Thilo K?śtzle Best practices in kraft pulping - benefits and costs Dan GavrilescuAspects of waste m...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25177

AbstractHeavy metals can be transported by rivers which flow through areas with industrial pollution, both as metal in solution and metal adsorbed to suspended solids. They can settle in lakes and accumulate in the sediment, exhibiting significant effects on wildlife and humans if they enter into the food chain.In this work, heavy metals transport and sedimentation is simulated based on an analytical model proposed in literature, considering the material balance and complementary equations, unde...
Autori: Camelia Beţianu, Florina Ungureanu, Loredana Branza, Lucian Vasile Pavel, Maria Gavrilescu, Simona Pintilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25197

Include urmatoarele articole:� Removal of persistent organic pollutants from textile wastewater by membrane processes� Sustainability evaluation of an urban residential settlement� Removal of zinc (II) from aqueous solutions by romanian sphagnum peat moss� Development trends of cold plasma reactors in the global context of carbon emission reduction� Assessing the potential of wind power in Romania within Kyoto targets� Research on the impact induced in the environment by milk process...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25198

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� "Waste not, want not" a study of household attitude toward recycling of solid wastes� A kinetic model for the crystal violet mineralization in water by the electro- fenton process� Development of a coagulation/flocculation predictive model for turbidity removal from tehran water treatment plants� Removal of cadmium (II) from aqueous solutions by sphagnum moss peat: Equilibrium study� Environmental sustainability based on fuzzy models� Impact of dust emi...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25207

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractThis paper dealt with Cr(VI) sorption on isomorphic substituted Mg/Zn-Al - type hydrotalcites under proper working conditions. The prepared samples were named Mg3Al, Mg2ZnAl, Mg1.5Zn1.5Al, MgZn2Al and Zn3Al. The experimental data concerning sorption isotherms were modelled in accordance with four equilibrium equations: Langmuir (L), Freundlich (F), Langmuir-Freundlich (L-F) and Redlich-Peterson (R-P) by using two ways: (i) estimation of qmax, K and n; and (ii) estimation of K and n, for ...
Autori: Aurel Iovi, Eveline Popovici, Laura Cocheci, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25215

AbstractThe project’s idea is really simple: using the LabView environment, we have realized a virtual instrument able to get from the GPS the information about latitude, longitude, altitude and from a prototype data acquisition board for environmental monitoring parameters the information about air pollution factors. The perfect solution regarding the costs, the covered area and the accuracy of the measured data is the use of a glider for flight, because of its characteristics: free flights (...
Autori: , Codrin Donciu, Marius Branzila, Marius Paslaru, Romeo Cristian Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25221

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractCadmium is listed by US-EPA as one of priority pollutant and as a known carcinogen, and therefore its removal from wastewaters of various industrial processes is a very important environmental problem. The paper analyzes the effectiveness of a Romanian sphagnum moss peat as available and cheaper sorbent in removal of Cd (II) from aqueous solutions. Batch sorption experiments were carried out in order to establish the influence of solution pH, peat dose, contact time and initial cadmium c...
Autori: Catalin Balan, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25231

AbstractThe paper presents new experimental results on the photodegradation of two important phenyl urea herbicides in water: Monuron and Isoproturon. The photodegradation was performed by two Advanced Oxidation Processes (AOPs): the homogeneous photo- Fenton process (, UV-H2O2 - Fe3+) and a heterogeneous photo - Fenton reaction using an iron pillared Laponide- RD catalyst (Fe-Lap-RD). The Fe-Lap-RD catalyst was prepared from iron nitrate 0.2 M solution and a suspension of Laponite - RD clay. Th...
Autori: Elsa Lundanes, Ilie Siminiceanu, Maria-Magdalena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25234

AbstractAn assessment of acide drainage forming potential for a mining waste material resulted in a former mine of nonferrous and precious metals ore has been made. The waste material has the following contents: 2,20?ˇ2,28% sulphide sulphur, 2,53?ˇ2,58% Fe, 0,07% Cu, 0,05% Zn, 0,36?ˇ0,40% Pb, 0,008?ˇ0,013% Ca and 3,85?ˇ7,97% sulphate. Bacterial leaching tests in percolating columns during 380 days have been made. The leaching liquor has been recirculated at a liquid:solid ratio of 1L:1kg. After ...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25239

AbstractLaboratory scale experiments were conducted in order to investigate the photolysis of Reactive Blue 19 (RB 19) dye using UV as the irradiation source in alkaline solution. The effects of operating parameters such as, pH, initial dye concentration, UV dosage, hydrogen peroxide and oxygen have been evaluated. The results indicate that the UV photolysis process in alkaline solution is ideal for decolorizing of RB 19 and it can be taken as a starting step to establish the economical feasibil...
Autori: Abbas Rezaee, Ebrahim Hajizadeh, Gholamreza Mosavi, Mohamadtaghi Ghaneian, Seyyed Jamalodin Hashemian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25245

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractThe effective mass transfer area of a Mellapak 750 Y structured packing was measured in a bench-scale plant with a column having an internal diameter of 100mm, and a packing height of 518 mm, using a broad range of gas and liquid flow rates. The absorption of carbon dioxide into natrium hydroxide aqueous solutions of 0.5 and 1.0 mol/L has been employed as test reaction. The validity of data obtained was tested by checking the two conditions of fast pseudo first order irreversible reactio...
Autori: Anton Friedl, Ilie Siminiceanu, Michael Harasek, Mihaela Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25264

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractSoil pollution causes significant damage to the environment and human health as a result of their mobilities and solubilities.Significant progress has been made in regulating soil pollution, with a parallel development of methodologies for soil assessmentand remediation. The selection of the most appropriate soil and sediment remediation method depend on site characteristics, concentration, type of pollutants to be removed, and the end use of the contaminated medium. The approach include...
Autori: Attar Singh Sheoran, Poonia Poonam, Vimla Sheoran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25291

AbstractThe paper proposes a suitable solution for a one step treatment process of the wastewaters resulted from the textile industry, using a mixture of anatase and modified fly ash. The dyes photo-degradation on TiO2 anatase is well known. The use of fly ash in advanced wastewater treatment, for heavy metal adsorption, represents an environmental friendly process, efficient if the fly ash surface charge is controlled by solubilisation/reprecipitation. The first step in implementing the single ...
Autori: Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25292

AbstractBiosorption an alternative process is the uptake of heavy metals from aqueous solutions by biological materials. The biosorption of nickel ions from aqueous solution was investigated by Nordmann fir (Abies nordmanniana (Stev.) Spach. subsp. nordmanniana) in a batch adsorption system as a function of pH, initial metal concentration, biomass dosage, contact time. The data showed that the maximum pH for efficient sorption of Ni(II) was 6.5. At the optimal conditions, Ni(II) ion biosorption ...
Autori: Handan Ucun, Ozkan Aksakal, Yusuf Kaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25295

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractThe development of technologies for waste treatment, simultaneously with minimizing greenhouse gas emissions, has become a matter of great concern at global level. Biogas systems can help in the fight against global warming by avoiding to escape methane from organic waste, into the atmosphere. Biogas technology is of great benefit to the end-users and the environment by energy, compost and nutrient recovery. Romania is a country with a huge biomass potential. Implementing of biogas techn...
Autori: , Corina Alice Babutanu, Gheorghe Băran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25300

AbstractAt the beginning of 3rd century the humankind finds at a crossroads. Daily, people assist at miracles, live in a time of change, both in economical and rational areas. Energy demand is expected to increase steadily over the next couple of decades, as income levels and economic output expand, especially in the new democratic states after ’90th.Renewable energy resources represent a new opportunity in Romania, with less participation in the market than those forums outside of the country...
Autori: Camelia Ciubota-Rosie, Maria Gavrilescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25305

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

AbstractThe sorption of Pb(II) and Hg(II) ions from aqueous solutions by moss peat (from Poiana Stampei, Romania) was studied in a batch system. The data obtained from experiments of a single-component sorption were analyzed using Langmuir and Freundlich models. The Langmuir equation describe sorption isotherm of Pb(II) and Hg(II) with high correlation coefficients, and better than Freundlich model. According to the Langmuir model, the maximum uptake capacities of moss peat for Pb(II) and Hg(II)...
Autori: Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu, Mioara Răţoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25311

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractThe paper proposes a solution for life quality improvement by changing the individual’s mentality and creating a sustainable behavior. The solution consists of the development of a psycho-behavioral pattern starting from the Gorgon experiences. The latter are hurtful experiences in the individual’s life the effect of which is a complete or partial emotional components blockage. The hindrance of these components performance affects the individual’s behavior, placing him or her in a ...
Autori: Brindusa Robu, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25323

AbstractSince public concerns about the environmental issues have increased, several universities all over the world have been establishing environmental engineering programs. Environmental engineering programs in Iran at graduate level have been developed since 1990. At the present time, there are ten universities are presenting environmental engineering programs at graduate levels. The environmental engineering education systems of almost all Iran universities are quite traditional. As the env...
Autori: Ahmad Tahershamsi, , Reza Maknoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25324

AbstractThe electrochemical behaviour of Ti6Al4V and Ti6Al4Zr alloys has been evaluated in Ringer's solution at 250C. The effect of the substitution of vanadium in Ti6Al4V alloy has been specifically addressed. The evaluation of the corrosion resistance was carried out through the analysis of the open circuit potential variation with time, potentiodynamic polarization curves, and electrochemical impedance spectroscopy (EIS) tests. Very low current densities were obtained (order of nA/cm2) from t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25334

AbstractThe removal of Acid Red 398 (AR398) dye from dye-containing solution using coagulation/flocculation process with polyaluminum chloride (PAC) and Alum was investigated. The effect of different parameters involving pH, dosage of coagulant, initial dye concentration, and bentonite as a natural coagulant aid was examined. According to the obtained results, the optimum pH, at which the maximum removal occurred, was about 4 and 5 for PAC and Alum, respectively. However, PAC performed efficient...
Autori: Maryam Hasani Zonoozi, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25335

AbstractNatural hemp fibers have been evaluated for Zn (II) ions sorption from diluted aqueous solutions. In order to establish the optimum conditions, the effect of initial pH of solution, hemp dose, Zn (II) concentration, temperature and contact time of phases on the Zn (II) sorption by natural hemp has been studied. To model the Zn (II) sorption at three different temperatures the Langmuir and Freundlich isotherms have been used. The Langmuir maximum sorption capacities were determined as bei...
Autori: Carmen Paduraru, Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25336

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

Abstract        The sorption of metal ions from aqueous solution plays an important role in water pollution control and in recent years there has been considerable interest in the use of low-cost adsorbents. Many researchers have tried to exploit naturally occurring materials as low-cost adsorbents, for removing of heavy metals. In this article the removal performance of various low-cost adsorbents derived from agricultural waste or natural material is evaluate...
Autori: Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25379

AbstractThe present work carries out a parallel analysis between the performances and, on the other hand, of the restrictions of two different model systems designed to assess the nearshore circulation. These are SHORECIRC, which is a widely known general prediction system for nearshore circulation and ISSM (the Interface for SWAN and SURF Models). SHORECIRC is a quasi-3D model that combines a numerical solution for the depth-integrated 2D horizontal momentum balance equations with an analytical...
Autori: Eugen Rusu, Silviu Macuţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25345

AbstractPaint sludge of automotive industry contains heavy metals and other toxic substances. Due to this matter, it has a high pollution potential. Incorrect disposal of paint sludge led to kinds of environmental pollution. Recycling and reusing of wastes can be one of the best solutions for decreasing of pollutant entrance to environment. The purpose of this study was to present a new method of extracting the main components of paint sludge, for determining concentration of elements in paint s...
Autori: Azadeh Akhavan Bloorchian, Seyed Mostafa Khezri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25346

AbstractSolid waste management problems proved to be complex in origin and in solution. The rapid economic development and population growth experienced by the State of Penang, Malaysia have resulted in a tremendous increase in the quantities and types of solid wastes generated. Domestic solid waste is the most visible consequence of this economic development. However, considerable amounts of this waste could be recycled and reutilized if separated. This paper reviews the current status of solid...
Autori: Abdelnaser Omran, Abdelsalam O. El-Amrouni, Abdul Hamid Pakir, , Latifa K. Suliman, Mahyuddin Ramli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25353

AbstractThe paper presents an original method, as well as a calculus mode of the main hydraulic parameters, for the transfer of the aeolian power from the nacelle of the tower to its base. The system proposes the existence in the nacelle of a two-, three- or poly- phased sonic generator, from which the obtained energy is transferred by some pipes to the base of the tower, where this can be easily  transformed in electric energy. The paper treats the two-phase variant. An important consequen...
Autori: Ioan I. Pop, Ioana Denes-Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25356

AbstractTitanium alloys show attractive properties for biomedical applications where the most important factors are biocompatibility, corrosion resistance, low modulus of elasticity, very good strength-to-weight ratio, reasonable formability and osseointegration. The aim of present study was to evaluate the electrochemical behaviour of Ti6Al7Nb alloy in Ringer’s solution of different pH. This evaluation was carried out through the analysis of the potentiodynamic polarization curves, and electr...
Autori: Daniel Mareci, Julia Claudia Mirza Rosca, Marina Garcia Falcon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25363

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

AbstractThe paper proposes a simple and less expensive gas chromatographic method for analyzing acrylamide in food and reveals comparative results regarding the acrylamide content in commercial and home toasted bread. Validation of the method has been achieved by establishing parameters linearity, limit of detection (LOD = 0.1 mg/L), limit of quantization (LOQ = 0.5 mg/L), precision, stability. Run-to-run precision was determined by carrying out five replicate determinations for three acrylamide...
Autori: Anca Irina Burlacu, Rodica Cuciureanu, Patricia Fitterman, Michel Larroque
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25385

AbstractThe purpose of this study is to analyze the recycling potential of printing papers, which are obtained by two different filler loading processes: conventional loading by direct addition of calcium carbonate to cellulose fiber suspension and in-situ loading by precipitating calcium carbonate within cell wall and lumen of pulp fibres. In order to evidence the influences of the both filler content and loading method, a reference sample for recycling was obtained without filler, but using th...
Autori: Maria Ciobanu, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25386

AbstractThe lead(II) ions sorption from aqueous solutions on three types of peat from Poiana Stampei (Romania) was studied. The peat was drawing from different deeps, such as 5-10 cm deep (peat 1), 0.5-1.0 m deep (peat 2) and from > 1.5 m deep (peat 3). The influence of several experimental parameters (initial lead concentration, contact time) was studied in batch experiments. The kinetics of sorption was followed based on the amount of lead(II) ions retained at various time intervals. The re...
Autori: Laura Bulgariu, Mioara Răţoi, Dumitru Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25389

AbstractEquilibrium data of water vapor adsorption from wet air on several materials were experimentally determined at temperature values of 313 and 333 K and air relative humidity values ranged between 30 and 90 %. Experimental data were correlated with Langmuir and Freundlich models. The obtained results emphasize the significant difference between the water retained on the adsorbent materials impregnated with various salt solutions, and on classic adsorbents....
Autori: Ioan Mămăligă, Constantin Baciu, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25394

Abstract The efficiency of Cd (II) removal from aqueous solutions was investigated using Sphagnum moss peat as sorbent. A 23 orthogonal central composite design was successfully employed for experimental design and analysis of results. The combined effect of the initial solution pH, peat dosage and initial Cd (II) concentration was studied and optimized using Response Surface Methodology (RSM). The optimum values of these variables were found to be pH = 4.72, 14.7 g peat /L and 13.64 mg Cd /L, ...
Autori: Catalin Balan, Corneliu Cojocaru, Petru Bulai, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25399

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract The potential of using ultrasonic irradiation and microbiological treatment for the removal bis(1-chloro-2-propyl) ether from aqueous solutions has been investigated. Experiments were performed in a continuous bioreactor, 3500 mL volume, and in an ultrasonic bath respectively, using frequencies of 38+1kHz and applying a power of 30 W. Under these conditions, the sonochemical conversion of ether was found to be superior to the biological one. The ultrasound method was improved by air ...
Autori: Mihaela Iordache, Vasile Lucian Pavel, Lim Myunghee, Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25403

Abstract Taking into account the statistical data gathered in two previously published papers concerning the pollution sources in the production sector, namely Finishing section, various solutions are proposed for wastewater treatment. Bearing in mind the results obtained through the sampling method on different types of water in the urban sanitary sewer system, the conclusion was that the most convenient alternative, besides the source control is the treatment in wastewater treatment plants...
Autori: Irina-Isabella Savin, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25408

Abstract The etching of iron materials in sulphuric acid solutions allows the dissolution of the iron oxides with formation of iron sulphates. The relatively low solubility of the formed sulphates imposes their separation for avoiding the contamination of the etching bath, as well as for preventing the environmental pollution through the wastewater. Within the flow sheet of the processing of the hot or cold rolled steel, a stage of separation by crystallization of iron sulphate is foreseen. T...
Autori: Liliana Lazar, Ion Balasanian, Florin Bandrabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25415

Abstract Phytoremediation is an eco-friendly, cost effective, in situ treatment technology. In the present research study, phytoremediation technology has been employed for remediation of radionuclides namely 137Cs and 90Sr by using living green plant Catharanthus roseus. C. roseus plants were exposed to different activity levels of 137Cs and 90Sr in aquatic condition to assess the efficiency of plants for remediation of radionuclides. C. roseus plants have been found to remediate 70%, 52% an...
Autori: Singh Anamika, Susan Eapen, Madhusudan H. Fulekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25417

Abstract Up to the present days, the bioprocesses were designed and operated with the aim at achieving some economic, environmental, and social criteria. Sustainability based optimization has to be the next step towards the improvement of the economical, environmental and social parameters of bioprocesses. In this work, sustainability will be treated as an optimization task where the objective function(s) is/are either a performance index or a set of performance indices, subject to economic, ...
Autori: Alexandru Woinaroschy, Dana Irina Ofiteru, Vasile Lavric
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25418

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract Strategic Environmental Assessment (SEA) represents one of the most important instruments for implementation of the sustainable development strategy in planning. The paper presents methodological framework and method used for SEA impact evaluation of the Waste Management Regional plan for Kolubara region in Serbia. The methodological approach and method are based on planer’s approach that has results in practice. The method is found after the multicriterion evaluation of the plan s...
Autori: Bosko Josimovic, Tijana Crnčević
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25427

Abstract The photocatalytic degradation of sulfamethazine, a sulfonamide drug, has been investigated experimentally, in aqueous heterogeneous solutions containing n-type oxide semiconductors as photocatalysts, and by simulation, using neural network modeling. Through direct neural network modeling, the evolution of the photocatalytic oxidation process is evaluated as function of illumination time and type of catalyst. Inverse neural network modeling is a particular optimization that gives inf...
Autori: Ciprian George Piuleac, Ioannis Poulios, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25430

Abstract The aim of this study is to investigate the electrochemical behavior of a three casting non-precious dental alloys: Vera PDI (Co-Cr based), Heraenium (Ni-Cr based) and NPG+2 (Cu-Al based) three test solutions: artificial saliva (AFNOR, pH = 8), acidified saliva (pH = 2.5) and fluoridated acidified saliva (1000 ppm F-, pH = 2.5). Open circuit potential (EOC) measurement; potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) are the electrochemical proce...
Autori: Daniel Mareci, Daniel Sutiman, Adrian Cailean, Julia Claudia Mirza Rosca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25435

Abstract The analysis over the underground water monitoring system and the collected data from survey drilling show that the underground water has an unsatisfactory quality due to some physical and chemical characteristics. Along with these, factors like the surface water pollution, the hydrodynamic exchange between surface and underground waters and the reintroduction in the agricultural activities of nitrates and phosphorus based fertilizers lowers, as well, the quality that it has been tal...
Autori: Ioan Crăciun, Catrinel-Raluca Giurma-Handley, Ion Giurma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25436

Abstract This paper aims to propose a new solution for rational valorization of the secondary powder materials from steel makingin electric arc furnaces. The elaborated steel quality as well as the economical advantages represented by secondary powdermaterials recirculation were studied. A good correlation between the proportion of brickets loaded into the melt and the melting ofcarbon has been found. The proportion of the EAF dust brickets can grow even at 5-7%. Zinc presence could havenegat...
Autori: Mirela Gabriela Sohaciu, Avram Nicolae, Cristian Predescu, Stefan Velicu, Gheorghe Gh. Calea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25438

Abstract Using slag in steel making represents a challenge for road construction industry and decreasing environment interactions also.Steel making slag wit granulations of < 10 mm, which today have not a sure solution, represents the research object. The technological research solutions have aimed reducing CaO free content in these slugs, and reducing slug fraction with granulationof ...
Autori: Florian Zaman, Mirela Gabriela Sohaciu, Ecaterina Matei, Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25439

Abstract Arsenic (As)-contaminated drinking water is a major problem around the world. The removal efficiency depends strongly on the size of Fe3O4 sorbents.Fe3O4 prepared in laboratory is more efficient in the removal of As and is also more easily recovered from column of magnetic separator than the commercial materials. This would be beneficial in a water treatment system because the As-contaminated Fe3O4 could be flushed from the column permitting reuse of the separator system. The dispers...
Autori: Ionel Balcu, Adina Segneanu, Marius Mirica, Mirela Iorga, Catalin Badea, Iuliana Firuta Fitigau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25456

Abstract Electroflotocoagulation is used for the treatment of liquid wastes of various origins, containing suspended matter. The metal hydroxide formed by electrochemical metallic ions generation acts to aggregate the colloidal impurities, and the hydrogen bubbles evolved at the cathode allow flotation of foam containing the impurities. The aggregates formed (containing the impurities) and lifted above the solution can then be removed. Electroflotocoagulation (simultaneous electrocoagulation ...
Autori: Marius Constantin Mirica, Mirela Ioana Iorga, Adina Segneanu, Ionel Balcu, Doru Buzatu, Cristian Vaszilcsin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25457

Abstract This paper presents the corrosion processes of steel samples with different composition, in aggressive corrosion solutions containing chloride ions. The inhibition capacity of two new Mannich basis: 2-aceto-4-morpholylmetyl-1-naphtol (BM1) and 1- (2'-hydroxynaphtyl)-3-(4-morpholyl)-1-propanone (BM2) was tested and compared. The corrosion tests were done in a potentiostatic installation and, based on the polarization curves, the Tafel plots were obtained. The kinetic and thermodynamic...
Autori: Ileana Manciulea, Cristina Bogatu, Eugenia Comanita, Anca Duta, Lucia Dumitrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25459

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract The development of energy from renewable resources is a very important action in the reduction of CO2 emissions. Hydropower is a renewable source able to reduce the CO2 emissions by more than 67 million tons / year. The paper analyzes a small hydropower plant to be implemented in Brasov region, from the environmental point of view. The reduction in the CO2 emissions brought by the small hydro is estimated by taking into account an ex-ante emission factor, based on validated and regis...
Autori: Codruta Jaliu, Dorin Diaconescu, Mircea Neagoe, Radu Saulescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25466

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract A crucial stage which makes the other directions of development of membrane processes is getting new membrane materials, to meet increasingly stringent of selectivity and productivity. Polyetheretherketone shows high stability against chemical and physical agents but is poorly soluble in most common solvents. Present studies on obtaining the support of the polyetheretherketone membranes were limited by: solubility of polyetheretherketone in concentrated sulfuric acid and fast speed a...
Autori: Mihaela Emanuela Craciun, Aurelia Cristina Nechifor, Florin Aldea, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25475

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract Application of ozone is known to yield favorable results in purification of phosphate plant water from elemental phosphorus, in treatment of water of alkali aluminate solutions of aluminum plants, in decontamination of cyanide-containing waste water of enrichment plants, and so on. It has been proved that halogen-containing compounds, most of which have mutagenic properties, and some of which are carcinogenic to humans, are formed when water is treated with chlorine. Conclusions made...
Autori: Irina Dumitriu, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25483

Abstract Nanotechnologies may have properties of self-assembly, stability, specificity, drug encapsulation and biocompatibility as a result of their material composition. Nano-particles are being actively developed for tumour imaging in vivo, bio-molecular profiling of cancer biomarkers, and targeted drug delivery. These particles are stable, environmentally benign, and their chemical properties can be easily tailored by chemically modifying their surfaces. Conjugated with pharmacological a...
Autori: Simona-Florentina Pop, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25484

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract The paper presents the results obtained when using thin films (doctor blade) of titanium oxide powder (Degussa P25) and fly ashactivated with NaOH, for advanced treatment of complex waters resulted in the textile industry. There are studied the heavy metal(cadmium, copper) adsorption and the dyes (methyl orange and methylene blue) photo-degradation using these novel substrates.The thin films crystallinity (XRD), morphology and roughness (AFM) were evaluated and no significant changes...
Autori: Anca Duta, Luminita Andronic, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25500

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract This paperwork tried to simulate the combustion inside the naval engines using the newest computer methods and technologies with the result of a diverse and rich palette of solutions, extremely useful for the study and prediction of complex phenomena of the fuel combustion. The paperwork is contributing to the theoretical systematization of the area of interest bringing into attention a thoroughly inventory of the thermodynamic description of the phenomena which take place in the co...
Autori: Nicolae Buzbuchi, Liviu Constantin Stan, Daniela-Elena Mitu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25514

Abstract This paper is a study about the symbiosis between the environmental aspects – innovation and competitive character of an industrial organization in our modern and sophisticated world. In actually global market and in conditions of world sever recession, for any organization or economic sector, the chance for surviving and development is given by adopting an innovative culture. This work contains case studies about the necessary steps for developing an innovative organization, a deb...
Autori: Florin Negoescu, Eugen Axinte, Gheorghe Nagit, Adrian Iosub
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25517

Abstract Waste management hierarchy has as priorities waste recycling and energy recovery. Unfortunately, Romania is in the situation so as the waste landfilling is still considered as a suitable solution for waste management. European Union imposed a number of regulations and programs in the field of waste treatment and management that Romania must comply. The paper describes some aspects regarding characterization of the leachate originating from the Tomesti landfill (situated in Iasi County...
Autori: Ana-Maria Schiopu, Brindusa Mihaela Robu, Ion Apostol, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25523

Abstract The work studies the orientations regarding the recycling of the products from the industry of auto-vehicles parts and components, orientations that can provide solutions which permit to the enterprises producing auto components the efficient management of the related products and services during the whole life cycle of the products, from the conception phase to that of recycling. The new way of approaching the development of metallic auto products promoted in Romania will contribut...
Autori: Petrica Corabieru, Stefan Velicu, Dumitru Zait, Anisoara Corabieru, Dan Dragos Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25524

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract Peat moss has been widely used as low-cost adsorbent to remove a variety of pollutants, including organic compounds and metal ions from aqueous effluents. Various functional groups allow such compounds to bind on active sites of peat moss. The adsorbent used in this study was Romanian peat moss sampled from Poiana Stampei (Romania). The adsorption of Co(II) ions from aqueous solutions on Romanian peat moss was studied in batch experiments, in order to establish the influence of initi...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25533

Abstract Tartrazine, (CI 19140) is an azo dye widely used in pharmaceuticals, cosmetics and foodstuff, as well as for coloring the textiles, hence it can be easily found in municipal wastewaters or wastewaters originating from textile, food, drugs and cosmetic industry. In this work, the capacity of a Romanian soil to retain Tartrazine from aqueous solution by sorption onto soil particles of different size has been investigated. The sorption kinetics was studied by applying five kinetic model...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25534

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract This paper is the investigation concerning the removal, from surface water, of humic acids and of some cations (Cu2+, Al3+) on activated carbons AG-3, BAU, CASO-16 from individual solutions as well as from their mixtures both in static and dynamic conditions. The conclusions of the paper are that, when humic acids are adsorbed from micellar solutions, semiassociates are formed on the surface of activated carbon BAU (in its porous structure), while humic acids adsorption on activated ...
Autori: Tudor Lupascu, Mihail Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25539

Abstract Geopolymerization is a continuous developing field of research for utilizing solid waste and by-products. It provides a solution to many problems where hazardous residue has to be treated and stored under critical environmental conditions. Consumption of fly ash in the manufacture of geopolymer is an important strategy in making materials more environmentally friendly. Fly ash has been chosen as a base material in order to utilize this industrial waste. Previous researches have show...
Autori: Maria Harja, Marinela Bărbuţă, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25542

Abstract Plasma is often called the fourth state of matter. It is distinct from other lower-energy states of matter, most commonly solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. Plasma technique may use any gas or gas mixture, within equipment limitations. Each gas or mixture of gases produces distinctive plasma, making possible a very diverse range of chemical environments. Besides the recombination mechanisms developed...
Autori: Marian I. Totolin, Ghiocel E. Ioanid, Iordana Neamtu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25550

Abstract Starting from the disadvantages of the polystyrene system – the most important being that they are not biodegradable and their life cycle is relatively small, up to fifteen years – there were conceived several structures for outside walls made of perforated bricks vertically disposed and filled with granular materials. In this manner the thermal resistance is improved knowing that in gaps bigger than twenty millimeters there appear convective streams which substantially decrease ...
Autori: Răzvan Giuşcă, Vladimir Corobceanu, Raluca Giusca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25551

Abstract The efficient understanding and application of mathematical models in the study of environmental phenomena keep up with the latest results in the mathematical domain which could provide solutions for controlling, analyzing, predicting and study of risk phenomena. This paper presents a browsing through some mathematical categories of interpreting statistical data, examples and their analysis in connection with the degree of polluting the water down the Danube River with the help of qu...
Autori: Valerian Antohe, Constantin Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25562

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract Withania frutescens plant from the south-western Morocco was used as an environmentally friendly material for the removal of As(V) ions from aqueous solutions. This work presents the characteristics of the adsorption and the desorption processes of As(V) using the dried W. frutescens plant as an environmentally friendly adsorbent. The mass of the adsorbent, the As(V) concentration, the contact time and the pH of the tested aqueous solutions were used as controlled variable parameters...
Autori: Mohamed Chiban, Gabriela Lehutu, Fouad Sinan, Gabriela Carja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25568

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract This work describes the preparation of a hydroxyapatite/polyurethane composite membrane and their characteristics. The porous hydroxyapatite/polyurethane composite membranes were made via solvent casting process. The deposited hydroxyapatite layers were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The data suggest that the method utilized in this work can be applied to obtain deposition of coating of crystalline hydroxyapatite on porous polyurethane...
Autori: Gabriela Ciobanu, Dorina Ignat, Gabriela Carja, Constantin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25572

Abstract In this paper, the capacity of a soil to retain the dye Erythrosine B from aqueous solution by sorption has been studied. Batch adsorption experiments were conducted to investigate the sorption of the dye from aqueous solutions onto soil with particles of different size. Different models were used to describe the kinetic data, to calculate the corresponding rate constants and to predict the theoretical capacities of soil for dye sorption. ...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25573

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

Abstract The present paper proposes an integrated-treatment process of leachate from a municipal landfill, which involves two treatment steps. The first step consists in diminishing the organic content through an advanced oxidation process using ozone and hydrogen peroxide. The second step is performed in order to diminish the content of heavy metals through a sorption process on a natural low-cost biosorbent, thus the traces of organic substances remained after oxidative degradation or oxida...
Autori: Carmen Paduraru, Corneliu Pohontu, Igor Creţescu, Lavinia Tofan, Marius Sebastian Secula, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25589

Abstract Commercial pure titanium (Cp-Ti) and titanium alloys are used on large scale in restorative dentistry due to their advantages as compared with other similar materials: chemical inertia, low density, high strength, high corrosion resistance in biological media and increased biocompatibility.The effect of fluoride and pH on the corrosion behaviour of Cp-Ti and a new Ti50Ta alloy were examined by open circuit potential (EOC) measurement, linear polarization, potentiodynamic polarization...
Autori: Daniel Mareci, Daniel Sutiman, Georgiana Ciurescu, Igor Creţescu, Romeo Chelariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25591

Abstract The use of biomaterials as biosorbents for treatment of wastewaters will provide as a potential alternate to the conventional treatment methods. The main advantages of biosorption are high selectivity , cost effectiveness and good removal performance. World wide numerous low cost bio materials have tried for biosorption of dyes. In this present investigation, the dead biomass of Penicillium sp. fungus and wood sawdust was used as biosorbents and their capacity to removed malachite gr...
Autori: Cornel Pohontu, Florin Luca, Igor Creţescu, Manea Liliana, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25593

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The aim of this study is the evaluation of photo-Fenton as a suitable advanced oxidation process to degrade ampicillin and streptomycin antibiotics. The degradation was studied by monitoring the organic substrate concentration changes in aqueous solution as a function of reaction time using COD analysis. The oxidation process follows two successive stages. In the first stage (I) the oxidation of the antibiotics takes place with high reaction rate, leading to intermediate oxidation pr...
Autori: Cristina Orbeci, Daniela Simina Stefan, Ion Untea, Madelene Dancila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25602

Abstract Despite their success, the so-called Italian Industrial Districts (IIDs) have to face the crisis caused by the phenomenon of globalization. The paper presents the interventions carried out in two industrial districts, tannery district of Arzignano and artistic glass district of Murano, in order to help the public administrations to improve the environmental situation. Introducing strategic and social considerations in environmental initiatives and implementing ?radical? environmenta...
Autori: Flaviano D'Amico, Giulio D'Amico, Ion Tanase, Marian Mihai Buleandra, Mihaela Buleandra
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25603

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

Abstract A method based on measuring substrate depletion rate was developed to evaluate the denitrifying activity of activated sludge in suspension and in biofilm form in anoxic serum flasks. The adapted activated sludge inoculum was grown as biofilm in an anoxic rotating biological contactor (RBC). Acetate was used as external carbon source to obtain a carbon to nitrogen ratio (C/N) of 2. The results showed that the specific activity of cells in biofilm form was higher than in planktonic for...
Autori: Elba Vivanco, Juan Carlos Ruiz, Paola Poirrier, Rolando Chamy, Yves Lesty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25617

Abstract The aim of this study was to assess nitrate removal using impregnated activated carbon (AC) with MgCl2. After impregnating of AC using heat treatment, the MgCl2 is converted to efficient MgO. The denitrification was conducted at pH 6.2, 25?C, and initial concentrations of 20 mg/L nitrate-N. The effects of the operating parameters including AC dosage, pH, and contact time have been investigated. Experimental data show that AC modified by MgCl2 was more effective than virgin AC for nit...
Autori: Abbas Rezaee, Hatam Godini, Sahand Jorfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25618

Abstract The adsorption behavior of bael tree (BT) leaf powder for cadmium ions from aqueous solutions has been investigated as a function of appropriate equilibrium time, adsorbent dose, adsorbate concentrations and pH using a batch system. Studies showed that the pH of aqueous solutions affected cadmium removal as a result of the fact that removal efficiency increased with increasing solution pH. The maximum adsorption was 93.56% at solution pH equal to 6.0, contact time of 30 min and initi...
Autori: Ponnusamy Senthilkumar, Rangasamy Gayathri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25621

Abstract This paper presents an integrated system of management and control for water resources, designated to improve the process of finding sustainable solutions for the problems of water pollution according to EU regulations. It is known that, regardless of the type of the source of pollution, punctual or diffuse, the water quality for both surface and underground waters can be severely damaged. Consequently, measures have to be taken in order to reduce/suppress the water pollution. In ord...
Autori: Aurelia Caldararu, Lucian P. Georgescu, Mirela Voiculescu, Virgil Olaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25622

Abstract Finding solutions to the waste problems generated by human activity represents a high concern of authorities and environment specialists for many years. Furthermore, energy conservation and reduction of the dependency from fossil fuels represents a top priority of governmental organizations at world level. The developments in alcohol industry have resulted in the increase of wastewaters which are highly polluted with organic substances, causing environmental pollution hazards. A wide...
Autori: Carmen Mateescu, Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25626

Abstract Equilibrium and kinetics of sorption of Zn (II) ions from aqueous solutions of pH 5 on indigene (Romanian) peat moss were investigated in batch system. The experimental equilibrium sorption data at three temperatures were analysed by Freundlich, Langmuir, Tempkin and Dubinin-Radushkevich sorption isotherm models. Results indicate the following order in to fit the isotherm equations: Langmuir > Tempkin > Dubinin-Radushkevich > Freundlich. The equilibrium sorption capacity determine...
Autori: Angelica Kicsi, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25632

Abstract Two different inocula - acclimated and non-acclimated to fat- were used to evaluate the methane production of cow manure, food waste and oily waste in batch assays. The inoculum adapted to fat had a better performance in the methanisation of substrates with significant lipids content. Furthermore, it is demonstrated that an increase in the ratio inoculum/substrate can enhance the initial methane production rate of oily waste when using a non-adapted inoculum, improving also the ultim...
Autori: Lucia Neves, Maria Madalena Alves, Raquel Ferreira, Rosario Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25634

Abstract The structural modification of external surface of NaY was investigated in order to enhance efficient biosorption systems consisting of a bacterial biofilm, Arthrobacter viscosus, supported on that zeolite, for removing hexavalent chromium from aqueous solutions. The supported bacterial biofilm reduces Cr(VI) to Cr(III) and this cation is then retained in the zeolite by ion exchange. NaY zeolite was modified by alkali-treatments using NaOH 2.0 M, with two different contact periods of...
Autori: Bruna Silva, Cristina Quintelas, Hugo Figueiredo, Isabel C. Neves, Manuel F.R. Pereira, Teresa Tavares
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25637

Abstract The aim of this work was the evaluation of the denitrification potential of a consortium of activated sludge adapted to anoxic conditions. As the carbon source is the main parameter influencing the denitrification process, in the first stage three carbon sources (acetate, citrate and glucose) were assayed in batch activity tests. The highest denitrification efficiency was ttained with acetate, being nitrate and nitrite completely reduced. The adapted sludge was then used as a potent...
Autori: Joana Azeredo, Pilar Teixeira, Rosario Oliveira, Zelia Fernandes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25638

Abstract A method based on measuring substrate depletion rate was developed to evaluate the denitrifying activity of activated sludge in suspension and in biofilm form in anoxic serum flasks. The adapted activated sludge inoculum was grown as biofilm in an anoxic rotating biological contactor (RBC). Acetate was used as external carbon source to obtain a carbon to nitrogen ratio (C/N) of 2. The results showed that the specific activity of cells in biofilm form was higher than in planktonic for...
Autori: Manuel Mota, Pilar Teixeira, Rosario Oliveira, Susana Cortez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25639

? SUSTAINABLE CONCRETE HARDENING PROCESSES IN NORMAL CLIMATIC AND THERMAL TREATMENT CONDITIONS ? THE ENVIRONMENTAL DIMENSION ? AN INTERDISCIPLINARY RESEARCH AREA ? MENU PLANNING STRATEGY BASED ON ECOLOGICAL FOOTPRINT ? EVALUATING ENVIRONMENTAL IMPACT OF NIGERIAN COMPOSTED WASTES USING LABORATORY EXTRACTION TEST ? IN SITU RADIOFREQUENCY FIELD LEVEL ASSESSMENT IN TWO URBAN AREAS IN ROMANIA: OPEN QUESTIONS TO ELECTROMAGNETIC POLLUTION ? INNOVATIVE SOLUTION FOR WARNING ON HI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25657

? POLLUTION PREVENTION, A KEY TO ECONOMIC AND ENVIRONMENTAL SUSTAINABILITY ? A COMPARISON BETWEEN DIFFERENT SCENARIOS OF ROMANIAN MUNICIPAL SOLID WASTE TREATMENT BEFORE LANDFILLING ? A STUDY ON ENERGY CONSUMPTION IN ROMANIA ? ENVIRONMENTAL INFLUENCES ON STRESSED METALLIC SURFACES ? ASPECTS OF HYDRODYNAMICS AND MASS TRANSFER IN DIFFUSED AERATION SYSTEMS ? THE STATUS OF SOME SELECTED HEAVY METALS IN ROADSIDE SOILS OF BURSA PROVINCE, TURKEY ? PREPARATION AND CHARACTERI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25656

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

? COMPARATIVE CONSIDERATIONS ON THE STRUCTURE OF SOME MOLYBDENUM/NIOBIUM DOUBLE PEROVSKITES OXIDES ? THE INFLUENCE OF THE STORAGE TIME ON THE STABILITY OF BUTTER ? CaCO3 CONTROLLABLE SYNTHESIS BY DOUBLE EXCHANGE METHOD USING CaCl2 RESIDUAL SOLUTIONS ? OPTIMIZATION OF COAGULATION-FLOCCULATION IN THE TREATMENT OF CANAL WATER ? ANODIC DETERMINATION OF PENTACHLOROPHENOL FROM WATER USING CARBON NANOFIBER-BASED COMPOSITE ELECTRODE ? STUDY OF PRECIPITATES GROWTH IN COAGULATION ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25663

? POST-DARCY FILTRATION THROUGH RIGID PERMEABLE MEDIA ? BIOSORPTION OF Cr(VI) FROM AQUEOUS SOLUTIONS ONTO Hydrilla verticillata WEED: EQUILIBRIUM, KINETICS AND THERMODYNAMIC STUDIES ? IMPACT OF BUILDING A TIDAL GATE ON THE YONGJIANG RIVER IN CHINA ? MONITORING OF THE HYDROTECHNICAL TORRENT CONTROL STRUCTURES: A STATISTICAL APPROACH ? RESEARCH ON SOIL PROPERTIES CONSERVATION DURING THE PREPARATION OF GERMINATION BEDS IN GREENHOUSES ? MANAGEMENT OF THE POTATO CROPS FOR MIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25664

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

? ADSORPTION OF DYE FROM AQUEOUS SOLUTION USING SILVER WOOD SAWDUST CARBON ? TIME SERIES ANALYSIS OF THE HEAVY METALS LOADED WASTEWATERS RESULTED FROM CHROMIUM ELECTROPLATING PROCESS ? WATER QUALITY CHARACTERIZATION OF THE PRUT RIVER ? ETHICAL AND SUSTAINABLE EDUCATION OF ENVIRONMENTAL ENGINEERS - BETWEEN REALITY AND HOPE ? INTERACTIONS AMONG CLIMATE, VEGETATION AND SOILS IN RADUCANENI ? IASI AREA ? DISTRIBUTION OF MIXING INTENSITY OF OXYGEN-VECTOR DISPERSIONS IN AERATED...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25669

Biosorption of lead (II) onto the biosorbent, represented by untreated S. cerevisiae and NaOH-treated S. cerevisiae was examined and the effects of contact time were investigated. The lead (II) biosorption was fast and equilibrium was attained within 90 mins. The maximum removal ratios of lead (II) for untreated S. cerevisiae and NaOH-treated S. cerevisiae after 3 h were 48.6% and 92.5%, respectively, with initial lead (II) concentration of 40 mg/L and optimum pH of 5.0. Data obtained from batch...
Autori: Ying Zhang, Yingjie Dai, Baiyin Liu, Fang Ma, Ru Zheng, Limin Donghttp://www.ecozone.ro/reviste.php?RID=25670

As one of the very few countries using coal as its dominant energy resources, China has the coal production exceeding one thirds of in the world, added to it are the problems of environmental damages and soil resource destructions result from the solid waste, such as mining waste discharged in the process of coal production and fly ash deserted from the electric power plant etc. In this paper, the mineral ingredient of waste and fly ash was tested by X-ray Diffraction. Meanwhile, the deformation...
Autori: Yanli Huang, Jixiong Zhang, Qiang Zhang, Shoujiang Niehttp://www.ecozone.ro/reviste.php?RID=25677

The abundant and inexhaustible solar energy has been widely considered a viable solution to the energy-shortage problem as well as the pollution of the environment. Therefore, it is an urgent need to perform detailed and reliable estimation of available solar resource in order to shift from traditional fossil fuels to the rich solar energy. However, such a scientific action has been often taken simply from the theoretical reserves, with few regards for the specific using scenarios. This paper in...
Autori: Guangxu Liu, Wenxiang Wu, Quansheng Ge, Erfu Dai, Zhiwei Wan, Yang Zhouhttp://www.ecozone.ro/reviste.php?RID=25690

The solubility and sorption behavior of naphthalene in the presence of dissolved organic acid was studied. The presence of dissolved organic acids at lower concentrations had only a little effect on naphthalene sorption. However, when the concentration exceeds a certain concentration, a significant inhibition was observed. Moreover, the inhibition enhanced with the increasing concentrations of dissolved organic acids. The change trend on solubility is similar to the sorption of naphthalene, that...
Autori: Jin hua Li, Bao xue Zhou, Qing Zheng, Wei min Caihttp://www.ecozone.ro/reviste.php?RID=25698

Abstract:Drying wood requires a significant amount of thermal energy, in order to heat-up wood and evaporate the water inside it.Therefore, solutions to minimize this consumption are a topic of maximum interest for wood-processing industries. Employingsolar power for drying wood is not a novelty, considering that this possibility was already acknowledged at the end of the 17thcentury, but since then, kiln design was significantly improved, once with the progress of knowledge regarding the mechan...
Autori: Ion Marinescu, Mihaela Câmpean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25727

Abstract:Point of zero charge (PZC) is defined as the condition at which the surface charge density of a material equals to zero and, formost of the solids it is strongly pH dependent. The PZC can be controlled by tuning the solid surface properties (crystallinestructure, morphology) and by a proper environment control, thus it is important to evaluate the PZC for a certain type of material,in given working conditions, for enhancing the efficiency in the targeted application (e.g. layer by layer...
Autori: Laura Maria Bertus, Radu Adrian Carcel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25721

Abstract:Under the circumstances of the total energetic recourses deficit in the Republic of Moldova appears the problem of non-traditionalsources utilization. An important source of renewable energy is the wind energy. This paper deals with two new concepts ofvertical axis wind turbine (VAWT) with helical blades, elaborated by the authors.The main element of the wind turbine is, certainly, the rotor. It is directly subdued to the action of the air flow and transforms thekinetic energy of the ai...
Autori: Ion Bostan, Ion Vişa, Rodion Ciupercă, Valeriu Dulgheru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25722

Abstract:In order to comply with the 20-20-20 Directive, by which every EU member state has pledged to produce 20% of the energy byusing renewable sources, solar energy for heating became a much addressed to topic, as a viable and up-scalable option. Researchis devoted to increasing the efficiency while reducing the production costs and the development of novel solar thermal systemswith dish collectors can contribute with innovative solutions. Thus, the first step in the development process, the...
Autori: Daniela Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25730

Abstract:The operation of solar air heat collectors consists in a sequence of transient regimes, being conditioned by the availability in timeof the solar resource. This paper presents the results of an experimental research on transient regimes of two types of solar air heatcollectors. The absorbers of the collectors have different configurations and are made of different materials. One collector is acommercial passage air collector with the absorber made of aluminum. The other collector is an ...
Autori: Adrian Ciocănea, Andrei Dragomirescu, Sanda Budea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25731

Abstract:A specific topical issue both for small hydropower plants and wind turbines refers to the discrepancy between the relatively lowspeed of the water turbine/wind rotor and relatively high speed of the electric generator: the turbine/rotor has higher performancesat lower speeds, while the generator performances are increasing with the speed. Usually, this problem can be solved connecting aproper speed increaser between the turbine (increaser input) and generator (increaser output). Besides...
Autori: Codruta Jaliu, Oliver Climescu, Radu Saulescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25732

Abstract:The demand for new and high performance products in the automotive industry is increasing exponentially and this trend imposesinnovative concepts for cars. The future solutions for the automotive industry may find their answer in the fabricationtechnologies and also in alternative propulsion and energy production.The car design field cannot ignore the global economic crisis, imposing new approaches in terms of materials and cost effectivetechnologies and by the means of environmental pr...
Autori: Mihai Comşiţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25733

Abstract:The drying of biological materials plays an important role in influencing energy savings, quality of end-products and alsoenvironmental issues. Several new approaches in application of solar dryers and a great number of biological materials have beendeveloped. In the paper the background of solar drying, current solar drying arrangements, and some of the recently focusedbiological products such as grain, fruit, vegetable etc. are selected and discussed. Additionally an integrated energy...
Autori: Istvan Farkas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25745

Abstract:The paper aims to present the new pattern of modular agriculture, as evolution of agri-food production in the coming decades aswell as to highlight the direct relation between this pattern and the massive energy support it requires.The paper basically deals with reactions to climate change, reductions of carbon emission, in addition to high quality and safetyrequirements for food production. The author envisages the PAC measures called for in order to ensure a sustainable developmentof ...
Autori: Romulus Gruia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25746

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

Abstract:Methyl orange and methylen blue are two dyes resulted from the textile industry. They are not raising just esthetical problems, butthey are toxic and hence harmful to aquatic animals. The aim of this study is to test the capacity of three types of sawdust (oak,willow and white poplar) and mixed substrates, sawdust: fly ash (FA), to remove the methyl orange (MO) and methylen blue(MB) from wastewater. The influence of contact time, solution pH and initial concentration of dyes on the blea...
Autori: Anca Duta, Dora Lucaci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25752

Abstract:This paper aims to analyze two types of wooden briquettes made from different raw material, in order to determine thecompactness of the wood used, namely their compaction coefficient. This factor is a new feature of briquettes that defines moreprecisely the quality of them. The density of raw material and briquettes causes the compaction coefficient, namely the ratiobetween them. Relevance of research and scientific innovation results from the fact that European standard of wooden briqu...
Autori: Aurel Lunguleasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25753

Abstract:Energy mix used in "Solar House" is currently composed of about 50% renewable energy sources (geothermal energy) and 50%conventional sources of energy (mainly electricity from national grid and less than 10% natural gas). The geothermal energy isextracted by the mean of a ground coupled heat pump which assures the heating load of the "Solar House" and the preparation ofdomestic hot water. The peak load in heating period is covered by a natural gas boiler and the electricity to drive the...
Autori: Bogdan Burduhos, Ion Vişa, Macedon Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25756

Abstract:It is of major importance that the mechanical structures and components of a photovoltaic (PV) system to have the same durabilityas the PV modules. The embodiment design process of the mechanical structure becomes significant as the results provide anoverall view of the PV system durability. The performance of the mechanical system must be attained based on functional andoperational requirements of the PV system. Therefore, the modelling and theoretical analysis of the mechanical behavi...
Autori: Bianca Butuc, Gheorghe Moldovean, Radu Velicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25757

Abstract:Hydropower exploitation has become a multifaceted task due to continuously increasing interest in all parts of the world but alsodue to inhomogeneity of framework conditions in the social, the political, the regulatory and the economic view. The final successof a plant is not only ensured by a good technical concept or design but additionally by a suitably model of financing, by selectingthe most reliable partners, by evaluating the environmental restrictions or the political stability ...
Autori: Bernhard Pelikan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25761

Abstract:The paper presents a method to improve the efficiency of a photovoltaic (PV) string by employing a mono-axis trackingmechanism. The tracking system was optimized so that it has minimum energy consumption during tracking. The PV stringsimultaneously changes the daily position using a linear actuator which transmits the motion to all modules by a rack-pinion gearmechanism. The system is designed in virtual prototyping concept with the following software solutions: for the solid modeling -...
Autori: Cătălin Alexandru, Nicoleta-Irina Tatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25766

Abstract:The present study proposes a comparative analysis on the clean electric energy response given by two types of PV (photovoltaic)tracking systems implemented on the same location: the azimuth and the pseudo-equatorial. The analysis is done based on analgorithm applied on the two-axes and one-axis systems. The tracking is done according to various laws, obtained by combiningdaily, seasonal and annual tracking programs. The algorithm and the comparative analysis are exemplified, by numerica...
Autori: Dorin Diaconescu, Maria Monica Vatasescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25770

Abstract:Ash is a waste that can be an efficient substrate in wastewater treatment for the immobilization of heavy metals and for dyesremoval. For an up-scalable wastewater treatment process, efficient substrates, with relatively constant behavior are needed andmodifying the adsorbent surface can be a feasible solution. Fly ash, resulted from coal burning, and wood ash are mixtures mainlycontaining metal oxides and carbon in various proportion, depending on the initial raw material.The paper pre...
Autori: Maria Visa, Mihaela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25771

Abstract:The oxidation of low grade complex concentrates (Cu, Pb and Zn) in aqueous media (weak alkaline) oxidized nonferrous metalsconcentrates is carried out at high pressure. Leaching is the subsequent processing step in metal extraction. The paper studies theinfluence of some parameters (temperature, time, L:S ratio, excess) on the leaching efficiency of nonferrous metals from oxidizedconcentrate. The optimum parameters determined are: S/L ratio of 10/1, 25% reactive excess, leaching tempera...
Autori: Cornelia Lupu, Dragoş Taloi, Liliana Gherghe, Luminita Mara, Teodor Velea, Vasile Predica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25774

Abstract:In this paper, photo-catalytic process for treatment of phenolic wastewater by TiO2 nano powder immobilized on concrete surfacein a recirculation hydraulic flow was investigated. The process affected by different operational conditions that the optimum onescould be obtained from variables interchange. Taguchi method as a proper method for design of experiments and optimizationwas used to find optimum conditions. Selected five parameters at four levels were consists of initial phenol con...
Autori: Bita Ayati, Hossein Ganjidoust, Mohammad Delnavaz, Sohrab Sanjabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25778

Abstract:Lightweight materials are more viable for use in invariably hot or cold climates than in temperate climates. However, it is possibleto use lightweight construction systems and specifically membranes even in housing buildings in temperate climate areas, if theirproperties are well explored, allowing better environmental performance and cost effectiveness than conventional solutions. In theouter skin and in dividing elements, architectural membranes can be used as thermal regulators, for ...
Autori: António Pedro Reis, Joăo Pedro Couto, Paulo Mendonça
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25781

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:The present paper presents an enhanced Activated Sludge Model No. 1 in which nitrification and denitrification are modelled astwo-step processes. The nitrification process is considered as a sequence of two steps carried out by two distinct genera ofbacteria, with nitrite as an intermediate product. For the denitrification process a parallel approach was used that considers nitrateand nitrite to be directly reduced to molecular nitrogen. The new model is compared to the original Activat...
Autori: George Simion Ostace, Paul Şerban Agachi, Vasile Mircea Cristea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25786

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:This investigation focused on the adsorption of Pb (II) onto Lewatit FO 36 resin from aqueous solutions. The effects of initialmetal concentration, contact time, pH of solution were factors that affected the adsorption of Pb (II). Adsorption kinetic was betterexplained by the pseudo second order type 1 kinetic model that was confirmed by the values (R2>0.986). The Langmuir,Freundlich, Temkin and BET adsorption models were used for the equilibrium studies and Freundlich isotherm bette...
Autori: Alireza Asgari, Azra Setodeh, Mehdi Ahmadi, Mohamad Sedigh Mortazavi, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25791

Abstract:There is a growing concern that the Earth’s atmospheric composition is being altered by human activities which can lead toclimate change. Policy measures to reduce carbon dioxide emissions are on the agenda of the International Maritime Organization(IMO) and the European Union (EU). Climate Change is an environmental problem and answers have to be sought among robustenvironmental policies that are often classified in market-based, command-and-control and voluntary instruments. Althoug...
Autori: Christos A. Kontovas, Harilaos N. Psaraftis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25792

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Titanium metal and its alloys have been widely used as implants under load-bearing conditions due to their biocompatibility, excellent corrosion resistance and lightness, but their inability to bond to living bone is a setback. The experiments outlined here investigated hydroxyapatite (HA) coating on Ti metal implants, used to enhance their bioactive properties. In this study, specimens of commercially pure titanium (c.p. Ti) and Ti-6Al-4V were etched in either H3PO4 or HCl, and subsequ...
Autori: Chao-Lun Fu, Hsueh-Chuan Hsu, Shih-Ching Wu, Shih-Kuang Hsu, Wen-Fu Ho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25795

Abstract:Coconut coir pith, an agricultural solid waste was used for the sorption of Cd (II) from aqueous solution in batch mode. Parameters like contact time, adsorbent dosage and pH effect were studied. Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data and the system followed both the isotherms. Cd (II) adsorption capacity of coir pith was found to be 18.72 mg/g. Kinetic parameters of adsorption such as the Langergren pseudo-first-order, pseudo second order r...
Autori: Nagendra Badabhagni, Puthiya Veetil Nidheesh, Rajan Gandhimathi, Srikrishnaperumal Thanga Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25800

Abstract: In this study, decolorization and degradation of aqueous nickel phthalocyanine reactive dye solutions was comparatively studied by electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton processes. In the electrocoagulation process with aluminum electrodes the colored aqueous solutions containing 100 mg/L nickel phthalocyanine and 6 g/L NaCl were treated at initial pH 7.5 and applied current densities of 5, 10 and 20 mA/cm2, where fast and 100% decolori...
Autori: Achilleas Christoforidis, Dimitrios Marmanis, Evgenia Valsamidou, Konstantinos Dermentzis, Konstantinos Ouzounis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25804

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

An iron(Fe+3) oxide/hydroxide nanoparticles-based agglomerates (AggFe) suspension adsorbent was synthesized for efficient, cost-effective phosphate removal. A strong effect of AggFe concentration and pH level of water containing phosphate on removal efficiency was shown. It was found that phosphate adsorption onto the AggFe suspension may be described by pseudo-secondorder reaction kinetics and the Langmuir isotherm model. The unique adsorption properties of synthesized AggFe adsorbent are demon...
Autori: Grigori Zelmanov, Raphael Semiat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25829

The corrosion products of high strength low-alloyed steel and of cast iron, maintained a prolonged period in natural seawater, were analyzed. A part of the corrosion products are soluble compounds of divalent and trivalent iron, the iron dissolution being accelerated when divalent ions are formed and in the case of the aerated seawater. The solid corrosion product formed during corrosion in seawater is principally oxy-hydroxide (FeOOH), but were identified small quantities of Fe2O3, Fe3O4 and so...
Autori: Daniel Mareci, Maria Lungu, Nicanor Cimpoeşu, Nicolae Aelenei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25832

This paper presents a mathematical model for the prediction of pollutant transport in rivers. The model has been developed and calibrated using the Matlab software and relying on field data from Romanian Someş River (collected in case of accidental cyanide release). Field data has been used to estimate model parameters (e.g. dispersion coefficient, velocity) as variable in time and space in order account for river features non-uniformity in time and also in space. These initial parameter va...
Autori: Elisabeta-Cristina Ani, Vasile Mircea Cristea, Paul Serban Agachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25848

The removal of Cr (VI) from aqueous solutions by sphagnum peat moss was investigated in batch experiments as a function of solution pH and initial Cr (VI) concentration. The highest removal percentage (R=99%) was obtained at pH = 1, in solutions of 20.8 mg Cr (VI)/L. In order to establish the mechanism of the removal process, Cr (VI) and total Cr (Cr (VI) + Cr (III)) in residual solutions was analyzed. The Cr (VI) removal by the peat moss at low pH is governed by two processes – electrostatic ...
Autori: Catalin Balan, Doina Bilba, Irina Volf, Matei Macoveanu, Petru Bulai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25849

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

The first part of this work presents the development and implementation in the Benchmark Simulation Model No 1 (BSM1) of a modified Activated Sludge Model No 3 (ASM3). The enhanced ASM3 presented in this study has three modifications compared to the original ASM3. The first modification is the representation of the simultaneous heterotrophic biomass growth on the primary substrate and on the internal storage products. Second, nitrification is modeled as a two-step process with nitrite as an inte...
Autori: George Simion Ostace, Paul Şerban Agachi, Vasile Mircea Cristea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25865

Chromium and cadmium are heavy metals that occur naturally in the environment and especially in soils. Their toxic effect is more pronounced at high concentrations and it depends on the oxidation states. While Cr (III) is considered an essential trace element for the metabolism of living organisms, Cr (VI) has a higher mobility and is easily soluble in soils and can be leached into surface water or groundwater, and taken up by plants. That leads to a toxic and carcinogenic effect to humans via i...
Autori: Dumitru Bulgariu, Florian Statescu, Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25866

Among the different types of waste products tested, the bark of different Pinus species have been identified as a promising class of low- cost sorbents for heavy metal binding. In this context, the potential of Romanian pine bark wastes as green and economical sorbent for cadmium (II) ions removal from aqueous solutions has been tested in batch conditions as function of initial pH, contact time, sorbent dose, metal ion concentration and temperature. The equilibrium data at three different temper...
Autori: Anca Miron, Brindusa Robu, Carmen Paduraru, Lavinia Tofan, Roxana Laura Mihailescu Amalinei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25871

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

Newly prepared SnO2-CeO2 catalyst samples used as depollution catalysts were characterized applying low-temperature nitrogen adsorption (BET), X-ray diffraction (XRD), thermo-gravimetry (TG-dTG) and temperature-programmed reduction (TPR) methods. Pure SnO2 has higher surface area (17 m2/g) than the pure CeO2 (8 m2/g). Addition of organic tin oxide precursor to ceria in amount of 5 wt% slightly decreases the surface area of CeO2 (SSn5-Ce= 7 m2/g). The increase of tin oxide content to 10 and 20 wt...
Autori: , Anca Vasile, , Cristian Hornoiu, Jozsef Kovacs, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25875

2This study shows the dyeing behaviour and impact over the wastewaters quality resulted from dyeing wool fibres, of a new synthesized premetalated dyes, derived from new acid dye, sodium(E)-2 –((1-amino-4-sulphonatonaphthalen-2-yl)diazenyl)-6- methoxybenzo[d]thiazole- 5 or 7 –sulphonate, as a result of interaction with Ni(II) and Zn(II) ions. In order to characterize the complexed dyes they were studied in both phase: solution and solid phase. The dyeing performances assessment and the envir...
Autori: Ion Sandu, Laura Chirila, Maria Marcela Tarlea, Romen Butnaru, Viorica Vasilache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25886

This research investigates the influence of certain vitamins (A and D2) on the possibility of hydroxyapatite formation on polymer surfaces. A coating method based on biomimetic techniques was used to form a crystalline hydroxyapatite thin layer on porous polyurethane matrix. The method is based on a wet process of hydroxyapatite formation that involves porous polyurethane film soaking in a modified synthetic Simulated Body Fluid (SBF) solution. This modified SBF solution contains vitamin A and v...
Autori: Alina Costina Luca, Constantin Luca, Gabriela Ciobanu, Simona Ilisei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25884

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

AbstractIn this study, palygorskite clay calcinated at different temperatures from 200 to 900 °C was used as adsorbent to removephosphate from aqueous solutions. The crystal structure and the surface property of the thermally modified material wasinvestigated to determinate the relationship between the adsorption capacity of the adsorbent and the changes of the crystalstructure and surface property. The results indicate that palygorskite clay calcinated at 700 °C had the highest adsorptioncapaci...
Autori: Chengsong Qing, Chengzhu Zhu, Dong Chen, Jiayuan Wang, Jingjing Xie, Tianhuhu Chen, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25949

AbstractVegetable waste was used as the fuel of a two-chamber microbial fuel cell (MFC) for simultaneous power recovery and wastedegradation. Effects of ultrasonic pretreatment, organic loadings, anolyte pH adjustment on the MFC performance wereinvestigated. Results showed that higher power generation and organic compounds removal efficiency were achieved in theMFCs with the vegetable waste pretreated with ultrasonication at >1.0W/mL compared to the un-pretreated control. A maximumvoltage of ...
Autori: Kun Tao, Xiangchun Quan, Yanping Quan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25953

AbstractGroundwater hydrochemical evolution has influences on the rational use and conservation of water resources. This paper whichtakes MapGIS as the platform is aimed at demonstrating the evolution of shallow groundwater hydrochemistry in Guanzhongbasin (China) by adopting mathematical statistics, ratios of ion pair equivalents, geochemical simulation. The direction ofevolution is dependent on the geological, geomorphological, and hydrogeological conditions of the study area. The spatialdistr...
Autori: Hua Tian, Lei Duan, Wenke Wang, Xiaoting Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25956

AbstractDue to rapid growth in both population and economic development in China, water demand is increasing dramatically andChina is facing more and more severe water scarcity problems. Thus competitions for water (between uses, users and regions) areincreasing which make water use efficiency an important issue in China, together with the uneven spatial and temporaldistribution of water, all of which drive the Chinese government and water planners to find the optimal water resource allocationpl...
Autori: Adrian T. McDonald, Linda See, Martin Clarke, Yanan Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25961

A fast economic development in China over thelast three decades has lifted hundreds of millions ofpeople out of poverty. However, an annual GDPincrease of over 10% due to the large scale industrialactivities and fast urbanization has released substantialamounts of pollutants into the environment and exertedtremendous pressure on local ecosystems. Although alarge amount of investment has been made by theChinese government and a series of efforts have beenmade by the environmental regulators, scie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25965

AbstractChina has experienced enormously rapid development since the open door policy introduced in 1979. Population has increasedby 30% to 1.3 billion, and the annual GDP growth rate was 9.8 % in the last few years. However, frequent water disasters inrecent years have caused significant damages to China’s regional growth and societies. There are huge contemporary challengesfor Chinese water resource management. In this paper, we examine three major challenges for China’s water resourcemanageme...
Autori: Dabo Guan, Faith Ka Shun Chan, Joseph Holden, Yanan Jiang, Yaqian Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25966

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

“The Exploratory Workshop „Progress inEnvironmental Engineering, Biotechnology andManagement in The Frame of Knowledge-BasedSustainable Economy” took place in the contextwhen worldwide research shows that the currentindustrial system supports a population that useresources and generates waste, consuming the Earth'ssupply, but who’s biocapacity is far outweighed bythe increased demand of products for a developmentsystem that often works on unsustainable bases.Today’s challenge is the integration ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25969

AbstractWastewater streams and particularly industrial effluents tend to increase in volumes and to get more complex in terms ofpollution. Nevertheless, nowadays the focus is directed towards recycling or reuse of treated wastewater so as to close the wateruse loop. Advanced wastewater treatment allows these possible applications by achieving good quality effluent to suit the newpurposes, but the implementation of this treatment stage is a difficult task. This study gives an example on how to ap...
Autori: , Daniela Cailean, Florina Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25971

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractThe huge emission of greenhouse gases from fossil-fuelled power plants is emphasizing the need for efficient Carbon Captureand Storage (CCS) technologies. The biomimetic CO2 absorption in aqueous solutions has been recently investigated as apromising innovative alternative for post-combustion CCS. The carbonic anhydrase (CA) - a broad group of ubiquitous enzymes– may catalyse the CO2 hydration reaction and then to promote CO2 absorption rate into aqueous solutions. Nevertheless theresear...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Maria Elena Russo, Piero Salatino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25976

AbstractIn this paper integrated network of continuous reactors for the decontamination of gaseous flows in heterogeneouscatalytic gas-liquid-solid – also applicable for bioremediation systems is investigated. For this purpose, duringprocess integration we have identified strategies to develop an optimal system for a variety of well-definedrequirements and to discover ways to ensure cost efficiency to achieve the requirements of sustainable industry in theframe of knowledge-based sustainable eco...
Autori: Maria Gavrilescu, Oana Marlena Penciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25977

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractThis study presents the development and use of a hydraulic-coupled water quality model for the simulation of BiochemicalOxygen Demand (BOD) concentrations in the Bahlui River, a small river located in northeastern Romania. This river experiencesthe typical pollution problems for many Romanian water bodies: heavy pollution from both diffuse and point sources, lowconnectivity to wastewater systems in rural areas and moderate removal of pollutants in municipal wastewater treatment plants.Th...
Autori: , Claudia Cojocariu, Denie C.M. Augustijn, George Bârjoveanu, Ioan Crăciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25985

AbstractThe transmission line pulse (TLP) method it is one of the most advantageous electrostatic discharge (ESD) testing method forsemiconductor devices. A new factual approach is developed in this paper which is based on TLP method. The new method isnamed “very-fast transmission line pulse” (VF-TLP), having as principal characteristics the very short pulse width and small risetime. The appropriate device under test (DUT) is a gate-grounded (GG) NMOS transistor. The testing signal was applied o...
Autori: Alexandru Salceanu, Ana-Maria Nicuta, Paul Bicleanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25992

AbstractThis paper presents the most recent developments regarding the square spiral inductors inductance evaluation. The study wasperformed in order to develop, implement and validate powerful software, CIBSOC able to determine the inductances of spiralinductors and also to optimize the spiral inductors layouts.We have studied the inductance variation of square spiral inductors. The four modules of the CIBSOC software were described,applied for the computation of inductance and the optimization...
Autori: Adina Racasan, Calin Munteanu, Claudia Hebedean, Claudia Pacurar, Vasile Topa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25997

AbstractDuring the last decade, European methodologies on electromagnetic field measurement and human exposure assessment havebeen extensively developed and improved. At present, there is a large number of complex technical standards dedicated to variousexposure situations. The implementation of the new methodology in the national practice might be difficult, expensive and timeconsuming. Taking into account the methodological change, we analyzed some practical difficulties that might occur and w...
Autori: Cristian Goiceanu, Eugenia Dănulescu, Răzvan Dănulescu, Raluca Dănulescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25999

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractDue to high energy costs and the rising consciousness of energy issues in the textile industry, saving energy became a significantproblem. Since a large amount of the energy required in textile finishing is needed in the form of steam for various processes,recovering wastewater heat has great potential for cost reduction. In this research, it was studied the heat recovery from cellulosictextiles finishing wastewater, based on a case study in a textile company. After examining the wastewa...
Autori: Armand F. Bertea, Gheorghe Condurache, Răzvan Berariu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26013

• STUDIES ON HEAT RECOVERY FROM CELLULOSIC TEXTILES FINISHING WASTEWATER    • ASSESSMENT OF SYNERGIC REGULATORY ACTIONS OF SPRUCE BARK EXTRACT AND DEUTERIUM DEPLETED WATER ON MAIZE (Zea mays L.) CROPS    • LUNG CANCER RISK INDUCED BY RESIDENTIAL RADON IN CLUJ AND ALBA COUNTIES, ROMANIA    • A CLEAR SKY IRRADIATION ASSESSMENT USING THE ESRA MODEL AND SRTM DATABASE    • ENVIRONMENTAL FACTORS ASSOCIATED WITH DYSPHONIA IN PROFESSIONAL VOICE USERS    ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26014

The first edition of the International Conference„ECOIMPULS 2012- Environmental Research andTechnology” plans to open a conference seriesdedicated exclusively environmental issues. Thescientific topics are devoted to the on-going research onenvironmental topics regarding: „Environment – apolitical, economic and social responsibility”,„Water in a changing world”, „ZERO – waste cities”and „ Energy – beyond the conventional”.This scientific event aims to bring togetherprofessionals, academics, scie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26015

AbstractWater distribution networks are complex systems that require innovative technological solutions enabling an integrated andrational water resource management. This paper presents the application of data analytics approaches on flow and pressure data,continuously measured at crucial points of the network, for improving efficiency of leak localization. The general goal is toreduce time and costs for physical check and consequent rehabilitation activities.Although the general benefits provid...
Autori: Antonio Candelieri, Enza Messina, Francesco Archetti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26018

AbstractThe developing of the infrastructure for wastewater collection and treatment in Romania is leading more and more to theproduction of huge quantities of activated sludge, as direct result of the application of state of wastewater treatment. The rapidand rational development of a national policy for management of activated on short, medium and long term has emerged as anecessity, and must be implemented urgently.The EU 27 countries consider environmental management of activated sludge as a...
Autori: Ilie Vlaicu, Ioan Neamt, Ioana Ionel, Mihail Reinhold Wächter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26019

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractThis paper deals with the experimental investigation related to removal of hydrogen sulfide from simulated groundwater byadsorption/oxidation on activated carbons. Carbonaceous adsorbents were synthesized from peach stones by physical-chemicalactivation method and modified by oxidation following impregnation with Cu2+ by ion-exchange method. Obtained carbonaceousadsorbents were characterized by specific surface area and micropore volume. Surface chemistry properties were evaluated usingB...
Autori: , , Vasile Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26026

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe hydrodynamics of two equipments from a surface water treatment pilot plant has been investigated through residence timedistribution (RTD) experiments using brine solution as tracer. Computational Fluid Dynamics (CFD) procedure, which isincreasingly utilized to study a wide variety of complex environmental fluid mechanics processes, was used to predict the flowpatterns and other properties of flowing fluids (e.g. velocity, concentration of species etc.). In this work, ANSYS Fluent 14....
Autori: Adina Pacala, Alain Liné, Alexandru-Dan Filep, Cosmina-Mariana Militaru, Teodor Todinca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26030

AbstractThe performance of two cation exchanger resins, Amberjet UP1400 and Amberlite IR120 in the process of Cs(I) ions removalfrom aqueous solutions was examined. Batch experiments were carried out to determine the influence of several parameters(resin dosage, contact time, temperature and initial concentration of Cs(I) ions) on the removal process. The equilibrium wasreached after 60 min for Amberlite IR120 and after 120 min for Amberjet UP1400, with an overall adsorption performance of~97% f...
Autori: Adina Negrea, Cornelia Muntean, Corneliu Mircea Davidescu, , Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26032

AbstractIn this work, cyclic voltammetry (CV) and differential-pulsed voltammetry (DPV) were used to detect pentachlorophenol (PCP)at two types of multi-walled carbon nanotubes (CNT)-based composite electrode, i.e., TiO2-modified-CNT-Epoxy (TiO2-CNTEpoxy)and CNT-Epoxy in 0.1 M sodium sulphate solution supporting electrolyte. The electrochemical behaviour of theelectrodes was investigated in the absence and presence of UV irradiation. A single oxidation peak at a potential value of about+1 V vers...
Autori: , Ágnes Jakab, Aniela Pop, Cornelia Bandas, Florica Manea, Joop Schoonman, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26033

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

AbstractZinc is an important metal for humans and the environment. Its intensive application in industry has led to water and soilcontamination. A lot of microorganisms both unicellular and multicellular can be applied for removal of metals from theenvironment. The process of zinc adsorption by cyanobacteria Spirulina platensis biomass was investigated. The concentrationsof 0.34 mM and 3.4 mM of ZnSO4ˇ7H2O were used. The process of biosorption of zinc was studied during 1-hour experiment.To dete...
Autori: Gheorghe Duca, Inga Zinicovscaia, Liliana Cepoi, Marina V. Frontasyeva, Sergey S. Pavlov, Svetlana F. Gundorina, Tatiana Chiriac, Valeriu Rudic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26041

AbstractBasic principles for assessing phytotoxicity are the same whether the test compound is a heavy metal, herbicide, fungicide,insecticide or other toxic compounds. The difference lies not in the method of evaluation, but in the experimental program andworking methodology.In this paper the phytotoxic effects of heavy metals, Cr (VI) and Cd (II) on plants germination and growth were studied. Stocksolutions of the two heavy metals were prepared at a concentration of 1000 mg/L, in distilled wat...
Autori: Dana Luminiţa Sobariu, , Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26062

AbstractThe role of human resources in agricultural exploitations proved to be an essential matter due to the decisive influence on theagricultural crop efficiency and production results. There exist particularities regarding the calculation of the human resourcesnecessary in vegetal crop production, animal husbandry and other activities connected with agriculture. From an economicalfinancialpoint of view, the analysis of human resources efficiency is based on two indicators, as follows: labour ...
Autori: Carmen Olguta Brezuleanu, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26068

AbstractConsidering the decrease water resources in the past decade, research for rational solutions on water use has become a worldwideconcern. Agriculture is the largest consumer of water, and when the soil moisture level is not assured of precipitation, it issupplemented by irrigation. In the current context of climate change, and consequently the arid territories growth, the researchersare looking for solutions to rational water consumption, and equally to cover the deficit of water in agric...
Autori: Cristina Elena Iurciuc,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26072

AbstractAtmospheric emission inventories are useful tools to support informed decision making in air quality management. In theframework of Apulia Region emission inventory, a tool for the industrial atmospheric emission management called TerritorialEmissions Cadastre (CET) was developed. CET is a Web-based system able to store all data related to the industrial plants and toperform spatial queries; its components are used for synchronizing, exporting and querying the underlined database. CET al...
Autori: Eleonora Andriani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26079

AbstractThe present study reports the efficiency of almond shell as a cheap and available material for the removal of Cu (II) fromcontaminated aqueous solutions. The equilibrium experiments indicated that Cu (II) sorption obeyed the Langmuir isotherm at26, 40 and 55oC. The highest value of the maximum uptake (Qo) from the Langmuir equation was found 6.783 mg g-1 at 40oC.The various thermodynamic parameters such as ΔGo, ΔHo and ΔSo were also calculated. The values of ΔGo varie...
Autori: Soheil Aber
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26080

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractA study on the electrochemical decolourisation, aromatic ring degradation and mineralization of Reactive Red 147 (RR) syntheticsolutions using boron-doped diamond (BDD) electrodes is presented. Electrolyses were carried out under galvanostaticconditions in 0.1 M Na2SO4 supporting electrolyte using undivided electrolytic cell. Prior to electrolysis application, theelectrochemical behaviour of BDD electrode was characterized in the presence of RR dye by cyclic voltammetry in order toestabl...
Autori: Sorina Moţoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26089

AbstractCombined electrocoagulation (EC) and homogeneous phase TiO2 photo-assisted system were applied to methyl orange (MO)wastewater treatment. Optimum including current density, initial concentration of MO, TiO2 concentration, pH, solutionconductivity and electrode distance were investigated. 98% decolorization (initial concentration = 500 mg/L) was achieved in 30min with a current density of 125 A/m2, electrode distance of 2.5 cm, electrolyte KCl concentration of 0.5 g/L, initial pH of 6.86,...
Autori: Yi Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26090

AbstractThe evaluation of the environmental impact of transport infrastructure entails a complex characterization of factors, attitudes andconsequences. In the frame of an ecologically friendly approach, sustainable alternatives and solutions for road asphaltpavements production and exploitation must be identified. A comparative evaluation of the environmental impact for recycledand traditional road pavements asphalt mixtures, expressed as the amount of equivalent carbon dioxide, per ton of mixt...
Autori: Alina Mihaela Nicuţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26096

AbstractA new approach to environmental protection management is the aerobic microbial digestion of food industry wastewaters byusing those waters as substrate, while the pollutants contained work also as oxygen-vectors. In biotechnology, oxygen masstransfer is a key parameter involved in the design and operation of mixing–sparging bioreactors and it can be analyzed by meansof the oxygen mass transfer coefficient (kLa). The influence of a second liquid phase with higher oxygen affinity (in this ...
Autori: Elena Folescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26097

AbstractThis paper presents the results of the research analyses and laboratory studies, aiming to develop design guidelines and suitabletechnologies for the construction of durable and environmental friendly rigid pavements by using recycled cement concrete,resulted from various demolition works. Various recycling principles and technologies, specific laboratory methods of improvedtechnical solutions to enhance wear coefficients, density homogeneity, mixture contamination and water absorption o...
Autori: Marius Muscalu
ISSN: 1843 - 3707Abstract This paper presents the results of the research analyses and laboratory studies, aiming to develop design guidelines and suitable technologies for the construction of durable and environmental friendly rigid pavements by using recycled
http://www.ecozone.ro/reviste.php?RID=26098

AbstractThere are a quite large number of studies published in the last decade, dealing with the possible pass of the human society to thehydrogen-based energy. The efforts made by researchers all around the world, in order to bring technical solutions, seemremarkable, but at global level only minor progresses were made toward this major change. Furthermore, most of studiespredicted a fuel crisis, but not a possible economical crisis with significant effects on the developing renewable energytec...
Autori: Ştefan Stanciugelu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26099

Mother Earth Investments AG, is actively working onthe development 2nd generation bioenergy feedstocks.In this book, Mr. Jansen generously shares hisknowledge in the field, in particular, regarding thechallenges and opportunities in development ofbiomass-derived fuels. This essential guide toinvesting in bioenergy commodities details secondgeneration biofuels from a scientific, technical andeconomic perspective, and discusses their globalenvironmental, political and financial impact.The book is ...
Autori: Roland A. Jansen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26100

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract The cultivation of Miscanthus sinensis x giganteus on a polluted soil near Copsa Mica – Romania has started in 2008. Since then every March and August the roots and stems have been analyzed, showing a very low amount of heavy metals in the aerial parts in February, when the harvesting takes place. The combustion properties of the material are similar to those of lignite, but without sulphur and with low ash amount. Because cultivation of edible plants poses the risk of hea...
Autori: Constantin Horia Barbu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26106

Abstract Recently, a new failure probability index was introduced that characterizes the operation of highly sensitive chemical reactors (i.e. when highly exothermic / hazardous reactions are conducted). Based on this, the current paper exemplifies the application of the risk analysis methodology proposed to generate the Pareto optimal operating solutions accounting for reactor productivity maximization (product yield) and probabilistic risk minimization. The multi-objective optimi...
Autori: Anca Dan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26108

Abstract Environmental degradation is today one of the great problems of mankind. Not only the need to exploit, but also the necessity to protect and preserve the natural environment have led to the adoption of specific rules for the prevention and remediation of environmental damages, according to EU standards. Taking into account that any human intervention on the natural and anthropogenic environment can lead to ecological risk diversification, occurrence of accidental pollut...
Autori: Aurica Grec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26130

Abstract Agriculture is an axis of socio-economic development of the area of Denguele, Cote d’Ivoire. The evaluation of a project carried out as part of an agricultural campaign requires the handling of large amounts of heterogeneous data for effective monitoring. The design of an appropriate management tool is needed to organize and communicate information useful for decision making. The aim of this work is to provide a useful tool for a better management of information related to...
Autori: Arthur Brice Konan-Waidhet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26137

Abstract One of the causes of climate change is the accumulation of greenhouse gases (GHGs). Methane (CH4) is one of the greenhouse gases, with an ability to trap heat in Earth's atmosphere 21 times greater than carbon dioxide (CO2) per unit mass and in the same period of time. Because the lifetime of methane in the atmosphere is relatively short, it could be kept under control. Wastewater treatment plants (WWTPs) are anthropogenic sources of CH4 emissions. Anaerobic digestion of t...
Autori: Doru Lucian Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26139

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

Abstract The reason for carrying out this research is related to the significant risk of heavy metals present in wastewater on the environment and human health. The removal of heavy metal ions from aqueous solutions was performed in a batch system, using peat (from Poiana Stampei, Romania) as adsorbent. The efficiency of the process was predicted with high accuracy (correlation with experimental data more than 0.99) based on a feed-forward neural network with two hidden layers. The...
Autori: Gabriel Dan Suditu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26150

Abstract The biosorption of Pb(II) and Cd(II) ions from aqueous solution on marine green algae biomass (Ulva lactuca sp.) was studied in batch systems, at initial solution pH of 5.0 and biomass dose of 8.0 g/L, considered as optimum experimental conditions. The obtained results from experiments of a single-component biosorption were analyzed using Langmuir, Freundlich and Dubinin- Radushkevich isotherm models. The Langmuir equation describe the biosorption isotherm of Pb(II) and Cd...
Autori: Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26152

AbstractBased on the method of images, the three-dimensional soil additive load formula caused by pipe jacking soil loss was derived byusing non-uniform soil displacement mode. Combining the formulas of additive load induced both by bulkhead additive thrust,force of friction between shield and soil, force of friction between follow-up pipes, which are based on the Mindlin solution, theformulas of total soil additive load were obtained. The distribution regularity of total additive load on adjace...
Autori: Gang Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26166

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractThough at a first sight the potential of tourism was advocated, without any doubt, as an routine tool for improving the welfare ofthe population, in recent years several works have appeared that criticize the universal validity of tourism as a development tool,whose premise is that the relationship is not automatic between the two dimensions, but instead a country must meet certaincharacteristics in order for this link to occur and, therefore, calls into question the solution implemented...
Autori: Juan Ignacio Pulido-Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26197

AbstractThe transport of hazardous substances is an essential economic activity because it represents a quite relevant percentage of thetotal goods transportation. The risk associated to such an activity is fundamentally related to the possibility of an accidenttriggering that may cause negative environmental and public health consequences. A recent example is the Viareggio accident(2009), which involved the blast of tank wagons containing liquefied petroleum gas (LPG) and caused more than thirt...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26200

AbstractPotential of unmodified Wheat Straw as an adsorbent for the removal of lead and copper was studied. Effect of pH, adsorbentdose, contact time and initial metal concentration on the removal of the metal ions were also investigated. Maximum removal oflead was found to be 43.55% by wheat straw under optimum conditions (pH=5, adsorbent dose=16g/L, contact time= 240minutes, metal concentration=100 mg/L). Unmodified Wheat straw removed 0.381 mg/g of lead. While 56.36% copper removalwas achieve...
Autori: Mehwish Anis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26209

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractIn this study, as part of developing a green recycling process of spent lead-acid battery that can avoid both smelting and electrowinning, leaching agent citric acid and other additives (such as sodium citrate and hydrogen peroxide) in aqueous media were reacted with spent lead-acid battery paste. PbO, PbO2 and PbSO4, which are the three main components in a spent lead-acid battery paste, were leached to form lead citrate precursor which was crystallized and then separated from the solut...
Autori: Xinfeng Zhu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26215

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractGlobal warming is happening due to increasing level of carbon dioxide and other greenhouse gases into the atmosphere. In orderto reduce this rising level of CO2 emitted by human activities, carbon capture and storage technologies are being developed.The present paper investigates and compares, from a techno-economical point of view, two of the most used conceptual methods(post- and pre- combustion) for CO2 capture generated from the fossil fuel power generation sector. For post-combustio...
Autori: Anamaria Padurean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26217

AbstractDespite the Moderate Resolution Imaging Spectrometer (MODIS/Aqua) presently collects data on operational basis, evaluationof its biogeochemical products from standard bio-optical algorithms is scare especially in Arctic waters. The present study isaimed to evaluate several MODIS/Aqua bio-optical algorithms and MODIS/Aqua remote sensing reflectance (Rrs) products inKongsfjorden waters on the western side of Svalbard, Arctic. Data sets consisting of in-situ measurements of radiometric quan...
Autori: Palanisamy Shanmugam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26220

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractCd (II) removal efficiency of free and immobilized fungal consortia of 48-h-old Mucor sp. HI33 + 72-h-old Gliocladium virideAI003 + 72-h-old Aspergillus niger AH09 from aqueous solutions were tested under different aeration systems. Cd (II) removalby free cells under air bubble system aeration was higher (99.91%) than under shaker system aeration. Cd (II) removal byimmobilized fungal consortia was higher (83.18 %) under shaker system aeration and lower in air bubble system aerationrespec...
Autori: Arifa Tahir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26232

AbstractFor the purpose of coping with oil spills successfully, it is important to establish effective response and preparedness plans. Inprevious study, we proposed the use of Case-Based Reasoning (CBR) technology to develop environmental emergency responseand preparedness plans. In this paper, we present how to develop a CBR-Oil Spill Response and Preparedness System (CBROSRPS). In particular, the Frame method is employed to do case representation, the modified Heterogeneous Euclidean-Overlap ...
Autori: Zhenliang Liao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26247

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractHealthcare waste management is one of the most important environmental problems in the world and particularly in Tunisia,because of the potential environmental hazards and public health risks. The collection of infectious healthcare waste is a highlyvisible and important service that involves large expenditures. This study discusses the off-site transport problem of infectioushealthcare waste from the 12 hospitals in the governorate of Sfax (Tunisia) to a planned steam sterilization disp...
Autori: Wafik Hachicha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26252

AbstractThe purpose of the undertaken research work is to degrade the biopolymeric pigments present in the distillery spentwash. This isdone by direct electro-oxidation using iridium oxide coated titanium mesh as catalytic anode. The effects of current intensity,dilution, pH and time of electro-oxidation were studied. The combined effects were analyzed using Box-Behnken design foroptimization and statistical analysis. The rate constant for first order electrochemical kinetics relating the rate c...
Autori: R. Krishna Prasad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26253

AbstractEnergy efficiency in buildings is a key issue in achieving sustainable development. Many decision support methodologies andtools have been developed, mainly based on energy consumption measurements or simulations and rules designed by experts toconstruct Building Energy Management Systems. An extension of this information from raw consumptions to energy efficiency isrequired. In addition, a visual depiction of this information with temporal and spatial resolution, applied to the differen...
Autori: Mark Richard Wilby
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26259

AbstractThe construction industry is one of the main sectors of energy consumption and carbon emissions in China. The new-types ofbuilding materials can be produced by recycling industrial solid wastes which is an effective solution to development of greenbuilding materials and abatement of environmental emissions. In this paper, new-types of bricks made of fly ash (residuesgenerated in coal combustion) and coal gangue (a kind of solid wastes generated in coal mining and coal production) and the...
Autori: Haitao Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26265

AbstractA novel RHA/PFA/CFA sorbent was developed by sol-gel method using three types of ashes, i.e. rice husk ash (RHA), palm oilfuel ash (PFA) and coal fly ash. From surface analysis of selected RHA/PFA/CFA sorbents, the spent sorbent had more compactstructures covered by irregular rough surface and the specific structure of raw RHA, PFA, and CFA were no longer visible. Inaddition, lower specific surface area was obtained for spent RHA/PFA/CFA sorbent. Batch studies were performed to evaluatet...
Autori: Irvan Dahlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26272

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractThe present work is focused on the importance of the resolution and accuracy of the wind fields in modeling waves in the Black Sea. Two different wind fields are considered for forcing the third generation spectral wave model SWAN. The wind data wave model results are compared against ‘in situ’ measurements performed at the Gloria drilling unit and also against satellite data for a two-month period of wintertime at the beginning of 2002. Subsequently, the model simulations were extended ...
Autori: Dorin Butunoiu, Liliana Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26283

AbstractThe objectives of this study were to investigate of cadmium and chromium adsorption from aqueous solutions by using orange (Citrus sinensis var Tampson) and sour orange (Citrus aurantium) mesocarp. The chemometric approach was applied for the optimization of removal percent of Cd2+ and Cr6+. To optimize Cd2+ and Cr6+ removal percent, the effect of four experimental parameters on removal percent was investigated by means of multivariate analysis. The considered factors were Cd2+ and Cr6+ ...
Autori: Maryam Bagheri Ardebilian, Mohammad Ali Zazouli, Pouneh Ebrahimi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26287

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractAerobic granulation is a novel biotechnique for the treatment of coloured wastewater containing toxic xenobiotics in sequencingbatch reactor (SBR). The aerobic granules were investigated as a potential biomaterial for biodegradation of p-nitrophenol. Theremoval efficiency of p-nitrophenol was 93 % after 65 days of operation at 8 hr hydraulic retention time (HRT). The aerobicgranules were cultivated at a p-nitrophenol loading rate of 0.9 kg m-3 day-1, with sodium acetate as co-substrate t...
Autori: Pijush Kanti Mondal, Rais Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26302

AbstractA new cell design which makes an efficient use of the cathodically evolved H2 to improve the mixing efficiency and thefloatation ability during electrocoagulation was used to remove dyes from waste solution. In this study, the decolorization andCOD reduction of colored solutions containing reactive and basic dyes by electrocoagulation was investigated using aluminumelectrodes in a batch mode. The effect of operating parameters such as current density, initial dye concentration, NaClconce...
Autori: El Sayed Zakaria El Ashtoukhy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26303

AbstractThis investigation compared the performance of Fenton and photo-Fenton oxidation processes in the treatment of sulfidic spentcaustic wastewater. Response surface methodology, particularly central composite design was used to investigate the effect ofFe/H2O2 and H2O2/COD in assessing treatment process efficiency. Empirical models were developed to describe the relationshipbetween the factors and responses. The models were validated through analysis of variance and were further used in pro...
Autori: Azmi Aris, Mohd Ariffin Abu Hassan, Sharifah Hanis Yasmin Sayid Abdullah, Siti Fadilah Md Noor, Zainura Zainon Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26307

AbstractIn this study, a fuzzy-Markov-based interval stochastic dynamic (FM-ISDP) analysis method is developed for reservoir operationmanagement (ROM). In ROM, uncertainties could be represented as discrete intervals, fuzzy sets, and fuzzy-stochastic forms.FM-ISDP is framed on the integration of interval analysis, fuzzy vertex analysis, stochastic dynamic optimization approaches andthe fuzzy-Markov chain. The developed model is applied to a case of ROM within a multi-user, multi-uncertainty and ...
Autori: Dianzheng Fu, Guohe Huang, Ying Zhu, Yongping Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26306

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe paper compares the electrocoagulation performance during the removal of Acid Brown 14, Acid Yellow 17, Acid Blue 113and Acid Black 172 dyes from aqueous solutions. For this purpose, pH changes and effectiveness of main parameters includinginitial dye concentrations and current densities for the selected dyes were examined. In addition, effluent turbidity, energyconsumption and amounts of released aluminum were also investigated. The present work shows that Acid Yellow 17 removaleffic...
Autori: Mahsa Taheri, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26310

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractThis research introduces a new Robust Interval Type-2 Fuzzy Set Linear Programming (R-IT2FSLP) model to manage irrigationwater resources. This method improves upon previous interval fuzzy bound models by allowing uncertainties presented asmultiple fuzzy boundaries. It creates additional degrees of freedom and enable direct modeling of uncertainties within anoptimization framework. It more explicitly reflects the system’s uncertainties under the fuzzy membership function. The more ofR-IT2...
Autori: Guohe Huang, Lei Jin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26324

AbstractDue to its toxicity, persistence in the environment and specific properties, 1,2-dichlorobenzene (DCB) has been listed as apriority pollutant by the European Agency. In this study, the oxidation with ozone alone as well as in combination withultraviolet irradiation was applied for the degradation of DCB. This article presents the abatements obtained, after the varioustreatments proposed, in the levels of chemical pollution as monitored by chromatographic techniques (GC/ECD, GC/MS andHPLC...
Autori: Bertrand Sancey, Corina Bradu, Grégorio Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26328

AbstractThe biosorption characteristics of Cd(II) ions using the NaCl-treated Ceratophyllum demersum were studied. The effect ofaltering the conditions, such as solution pH, the biosorbent dosage and contact time for the biosorption of Cd(II), and thebiosorption/desorption studies, were investigated. Langmuir, Freundlich, Dubinin-Radushkevich and Redlich–Peterson modelswere applied to describe the biosorption isotherms. Langmuir model fitted the equilibrium data better than the other isotherms(R...
Autori: Ali Akbar Babaei, Mehdi Ahmadi, Nadali Alavi, Nemat Jaafarzadeh, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26331

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractLead (II) can bind with papain at its active site, destroying the enzymatic activity. Papain a sulfhydryl protease has beenimmobilized in calcium alginate bead for the purpose of removal of lead (II) from industrial waste water. Effect of lead (II) onthe enzyme activity of immobilized papain, has been observed. A detailed kinetic study has been carried out and the data arefitted to different kinetic models. EDS (Energy Dispersive X-Ray Spectrometry) and desorption study suggest that meta...
Autori: Aparupa Bhattacharyya, Parameswar De, Soumasree Chatterjee, Srabanti Basu, Susmita Dutta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26338

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractA pilot scale Upflow Anaerobic Filter (UAF) treating tannery wastewaters was operated for 160 days. The UAF was fed with lowCOD/SO42- ratio (SO42- = 1810 mg L-1, CODtotal = 2530 mg L-1) for the investigation of sulphate and COD removal as a functionof substrates limitation and ammonia and sulphide inhibition. Sulphate-reducing bacteria (SRB) out-competed methanogenicbacteria due to the low influent COD/SO42- ratio, the high concentration of sulphide and the presence of inhibiting compoun...
Autori: Alberto Mannucci, Claudio Lubello, Giulio Munz, Gualtiero Mori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26353

AbstractEmployers notified about working places under special conditions are required to develop Preventive and Protective RevisedPlan, in order to ensure the improvement of workers safety and health protection, including specific measures and actions, so thatthose working places comply with the norms and operate under normal conditions by the late 31 December 2013.This paper considers some outcomes of the Nucleu Program PN 07450226 funded by Romanian National Authority for Research(ANCS) and de...
Autori: Marius Kovacs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26404

AbstractThis paper describes the model for forecasting the exposure risk of workers to global occupational vibrations. The research hasbeen achieved within the PN 07 45 01 18 Project in the framework of the NUCLEU/2012-2013 Program. This project has anational and European interest, entailing the increase of occupational health and safety level and ensuring sustainableenvironmental quality and comfort at workplaces.The scientific novelty is given by the complex and interdisciplinary aspect of the...
Autori: Gabriel Dragoş Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26409

AbstractMunicipal wastewater, characterized by temperatures of 14-22°C in the inflow of Wastewater Treatment Plants and above 35-40°C in domestic outflows, represents a relevant thermal energy source. A feasibility study of the implementation of heatrecovery from a specific sewer system should take into account several aspects: potential heat capacity (depending on wastewatertemperature and flow rate in the considered area and climate conditions, and on the sewer characteristics), users that cou...
Autori: Silvia Fiore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26427

AbstractNowadays, when the problem of environmental protection is quite stringent, the producers are concerned to bring on the marketproducts, which have reduced environmental impact. In their turn, the consumers have become more aware and selective inpurchasing products or services. Due to the financial crisis, consumers buy less but they are asking for quality and environmentalfriendly products. Under these circumstances the producers must find solutions in order to satisfy the consumers’ requ...
Autori: Mirela Panainte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26433

AbstractThe right individuation of the more convenient solution for final treatment and destination of sewage sludge deriving fromwastewater plants, normally after anaerobic digestion process, is a very interesting problem, in accounting of urgent needs foracceptable solutions. The produced sludge, primarily after thermal drying, can be sent to energetic valorization processes as, forexample, incineration, gasification and also pyrolysis. In this work we examined the thermal solutions (both dire...
Autori: Deborah Panepinto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26435

AbstractIn order to diminish the climat changes due to greenhouse gases, the capture from the source, transport and storage of carbondioxide is one of the environmental priorities of the EU until 2050. Transportation of this gas through pipelines (one of thesolutions with most advantages in transport) can be done at ambient temperature only at high pressures, so the carbon dioxide toremain in the supercritical state. In case of underground pipelines, there is a risk of cracking at the wall of th...
Autori: Valentin Zichil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26447

AbstractAdaptive water resources management recognizes the centrality of learning to its effective implementation. However, theliterature on learning in Adaptive Management (AM) is disjointed and lacks rigorous treatment. The purpose of this paper is toclarify how learning associated with AM is distinctive and to explain the importance of successfully integrating it into policydesign. Because adaptive learning holds a unique position within the adaptive management and assessment process, it shou...
Autori: Wietske Medema
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26450

AbstractThis research aims to investigate the level of cluster approach adoption to support the environmental management of small andmedium enterprises and reduce their environmental impact. The research identifies the main phases of cluster approachmethodology and assesses the level of its adoption in 28 international case studies included in 5 different categories of cluster.Our study carried out a comparative analysis between the experiences of each cluster category and the level of implement...
Autori: Sara Tessitore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26452

AbstractIn the present work, the kinetics of amaranth dye biosorption onto the roots, stems, leaves and the whole plant of water hyacinth(Eichhornia crassipes) were studied for differential evaluation of the plant’s biosorptive potential to remove the toxic dye fromaqueous solutions. E. crassipes´ leaves showed the highest level of amaranth dye biosorption (43.1 mg/g), followed by the entireplant (31.18 mg/g), the roots (28.51 mg/g), and finally by the stems (23.97 mg/g). The same differential t...
Autori: Imelda Guerrero-Coronilla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26463

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractThe aim of this study is to investigate new perspectives with respect to the greening of the wastewater collection, subsequentlyassessing the value of the vacuum over the conventional wastewater collecting system in rural areas. The research was framedfrom the perspective of policy makers to aid in making decisions about benefits on long term horizon in implementing ecoinnovativeinfrastructure technologies. The study postulates the hypothesis that the vacuum sewerage system is technologi...
Autori: Iulia Carmen Ciobotici Terryn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26456

AbstractThe paper analyses the hydrologic parameters of the Tarata perimeter with alluvial soils, in order to estimate the values of theTazlau River behaviour, in case of flooding. Tazlau River flow rate has an annual average value of 4.9 mł/s, with a torrentialcharacter when the level of precipitation is increasing. The analysis of this perimeter is of interest today as a result of the existingexcessive erosion. We identified a possible solution to reduce soil erosion through the exploitation o...
Autori: Stelian Cartacuzencu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26469

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractThe purpose of the present study is the comparative investigation of the calcium cations removal from aqueous solutions usingtwo strong acid cationic resins recommended during the last years for water softening. The performances of the two resins wereevaluated by the means of the cationic exchange capacity and the retention degree of the calcium cations. The evaluation of thetwo resins behaviour in the ion exchange process was performed by the means of the FTIR spectra recorded on the re...
Autori: Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26489

AbstractIn this study, TiO2-zeolite modified carbon nanotubes-epoxy (TiO2-Z-CNT-Epoxy) and TiO2-zeolite modified carbon nanofibersepoxy(TiO2-Z-CNF-Epoxy) composite electrodes were applied for pentachlorophenol (PCP) degradation and determination inaqueous solution. The morpho-structural characterization of the composite electrodes was studied by scanning electronmicroscopy. The electrochemical behaviour of the electrodes was investigated under UV irradiation presence/absence, usingcyclic voltamm...
Autori: Ágnes Jakab
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26491

AbstractAir flow measurements as well as concentration measurements within a naturally ventilated dairy barn (NVD) were carried outduring one summer season of 2012. Air flow measurements were performed using ultrasonic anemometers (UA), either as shortduration (20 min duration) measurements with a higher spatial distribution (using up to 9 UAs at the same time) or as long period(roughly 2 weeks) measurements with a lower spatial resolution (3 to 5 UAs). Measurements were conducted at two heights...
Autori: Merike Fiedler
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26496

AbstractA soot transducer based on the measurement of the electrical resistance value of the soot layer deposited on a finger structure wastested at different thermophoretic potentials. The soot, similar to that issued from the Diesel engines, in terms of particle numberand size distribution, was obtained by the incomplete burning of propane and subsequent dilution. The decrease of the resistancevalue in time was directly proportional with the temperature gradient. Thus a soot transducer is aime...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26503

AbstractNano-Ag electrodeposited on carbon nanotubes-epoxy and carbon nanofibers-epoxy composites electrode materials as Ag-CNTand Ag-CNF electrodes were tested for simultaneous detection of arsenic (III) and lead (II) from aqueous solution. Theelectrochemical behaviour of As(III) and Pb(II) on both composite electrode offered useful detection information and Ag-CNFexhibited better electroanalytical performance. The detection scheme using Ag-CNF for simultaneous detection of As(III) andPb(II) wa...
Autori: Anamaria Baciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26511

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractThe alkylation of light hydrocarbons leads to produce the high octane number gasoline blending components. The homogeneouscatalytic alkylation reaction is usually carried out at low temperature in the presence of H2SO4 and HF. The use of heterogeneouscatalysis for this reaction is a promising solution for the replacement of hazardous acids to environmentally friendly zeolitecatalyst. The alkylation reaction of isobutane with 1-butene was studied on selected zeolite catalysts. The objecti...
Autori: Tatjána Juzsakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26514

AbstractThe impact of modern structures on the environment during the building process and actual life-cycle becomes more and more ofa problem and needs to be minimized using unconventional architectural and building solutions, materials and overallacknowledgement of the whole concept.This study has the task of determining the feasibility of a modern earth sheltered house solution by comparing its thermalperformances and environmental impact to a conventional above-ground building solution. Alth...
Autori: Horia Tundrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26517

AbstractPetroleum tanker trucks are integral vehicles for delivering fuel and other petrochemical products from place to place and must becleaned regularly. Pressure washing with hot or cold water serving to remove oil and filth from the tanker truck container,produces oily waste water with an oil concentration of about 300-500 mg L-1 which, according to environmental standards andregulations worldwide, must be disposed of and treated properly. In the present paper an integrated electrochemical ...
Autori: Konstantinos Dermentzis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26520

AbstractIn this paper, we develop a rigorous theoretical framework and a practical implementation for the evaluation of the energy- andcost-saving potential of buildings. The goal is to promote sustainability in the context of building energetics by achieving themost efficient, optimal exploitation of the financial resources available for refurbishments. The practical realization of thisconcept requires the evaluation of the optimal refurbishment cost that maximizes the net energetic or financia...
Autori: Árpád Csík
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26535

AbstractThe thermal and water insulation of buildings is extremely important. Currently, the most applied insulation materials in thebuilding sector are plastic foams and fibrous materials. Different types of polystyrene materials are used as water and thermalinsulators, e.g., expanded polystyrene (EPS) and extruded polystyrene (XPS). The differences between the different polystyrenematerials is found in their manufacturing processes and thus in their microstructure. Our research focuses on the ...
Autori: Ákos Lakatos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26546

AbstractIn our study, we examined the annual carbon footprint and energy balance of a Hungarian biogas power plant with a poweroutput of 0.637 MW in 2013, with reference to the complete life cycle of the biogas production. The life cycle analysis (LCA)considered the emissions of greenhouse gases (GHG) during the production of feedstock and its transportation into the powerplant, during the operation of the factory and during the process of rendering the discarded waste materials harmless. Weesta...
Autori: György Szabó
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26548

AbstractThere are several environmental issues in urban areas that are caused by the unintentional consequences of past activities. One ofthese issues is the wide application of asbestos cement in roofing materials in the 2nd half of the 1900s. In this study, our goal wasto identify different roof types and to determine those with asbestos components using high-ground (1 m) and spectral (126bands) resolution airborne hyperspectral imagery (AISA Eagle II) and several classification approaches. In...
Autori: Szilárd Szabó
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26549

AbstractDue to the continuously increasing trend in the costs of the traditional fossil fuels, the development of residential or commercialbuildings with reduced energy needs becomes a significant and more pressing scientific challenge. At the same time, consumersare increasingly demanding more comfortable buildings, where the energy needs are addressed using locally available renewableenergy resources. Consumers also require a higher level of security, supervision, and control of the building, ...
Autori: Géza Husi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26553

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractEnvironmental and territorial compatibility of industrial activities can be evaluated by considering several criteria, usuallyformalized in the contest of a Strategic Environmental Assessment (SEA); the pipelines sector, however, is not as wellstandardized as others. In this paper, a new methodology to evaluate territorial compatibility of proposed pipelines is presented.This approach can be useful to assess proper development compatibility of oil and gas pipeline networks, and it could ...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26561

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractEnd-of-life tires are waste materials that pollute landscapes when they are disposed of in tire dumps. However, its life cycle is notfinished when they are scrapped. The rubber of end-of-life tires could be used for new purposes as construction material in roadrehabilitation. A gap-graded mix characterization was carried out in this work by means of laboratory and field performancetests. The mixture has a high content of crumb rubber (CR) by weight of bitumen. Crumb Rubber was added to t...
Autori: Victor F. Vázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26577

AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract The objective of this study is to develop a mathematical model which would confidently predict the rate of substrate degradation of an oil-water emulsion in a laboratory-scale completely-mixed continuous flow reactor using the photo-Fenton treatment process. Two models are developed from first principles and the predicted substrate removal rates for both models are compared with experimental data. The principal conclusions of the study are that both models produce good correlations ...
Autori: Maha A. Tony
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26613

Abstract The present study deals with the removal of Cr (VI) from aqueous solution by polypyrrole (PPy). Response surface methodology (RSM) was applied for the design and analysis of experiments in the optimization of pH, temperature, initial concentration, contact time and adsorbent dose during the removal of the Cr (VI). The optimum adsorbent dose, temperature, initial concentration of Cr (VI), pH and contact time were found to be 0.8 g, 46.5 oC, 187.5 mg/L, 5.3 and 15.4 min respectively. ...
Autori: Ehsan Hasani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26614

Abstract This study is focused on the dissolution kinetics of zinc oxide in ammonium acetate solutions to recover the zinc from alkaline and zinc-carbon spent battery powders. This study represents a first step for further studies in which actual waste powder is to be used. Therefore, the experiments were performed by using pure zinc oxide powder to evaluate the dissolution behavior of zinc. The effects of ammonium acetate concentration, reaction temperature, stirring speed and solid to liqu...
Autori: Nizamettin Demirkıran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26618

Abstract Malathion is a toxic, wide-spectrum organophosphorus pesticide. The removal of this pesticide from water is one of the major environmental concerns. In this study, the biodegradation of malathion using batch activated sludge was studied. The effect of initial malathion concentration (5 to 140 mg/L) on the degradation process was investigated. The biokinetic parameters (rs max, Ks and Ki) were estimated. Identification of dominant bacterial flora was also achieved. In addition, two k...
Autori: Djaber Tazdaďt
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26625

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract Remote sensing data has been broadly used in assessing and monitoring natural resources. Monitoring forest resources with Landsat Thematic Mapper (TM) and other fine resolution sensors has become a challenging work in a wide variety of forest applications. In this paper, the relationships between stand crown closure with spectral reflectance values and some vegetation indices (VIs) obtained from Landsat TM were investigated in a case study area. The Pearson correlation and multiple ...
Autori: Alkan Günlü
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26631

Abstract Soil organic carbon is one of the key substrates affecting methane emissions in paddy fields. However, not all soil organic carbon forms methane. This study therefore involved comparative analysis of the methanogenesis of different organic carbon sources (rice straw, chicken manure and pig manure) in paddy field soils. The results indicated that whereas methane emissions from the pig manure treatment (PM) were not significantly different to those associated with the application of c...
Autori: Jiamei Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26637

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract Hydrogel membranes obtained by neat polyvinyl alcohol (PVA) or PVA with various bio insertions like: Scleroglucan (Scl), Zein (Zein) or Cellulose (Cel), were subjected to diffusion and sorption/desorption experiments using different type of dyes such as: Crystal Violet (CV), Methylene Blue (MB), Congo Red (CR). If the sorption, desorption or diffusion of a dye in/from/through a hydrogel is usually monitored by the dye solution analysis, in this case the transport phenomena are follo...
Autori: Adina Papancea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26649

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract Environmental contamination by antimony has been described as a critical issue in many articles. In this study, the Sb(III) removal by two brown algae, Sargassum muticum and Aschophylum nodosum, has been tested. Algae were collected in Viana do Castelo beach (Portugal). Preliminary tests were carried out and, based on the results, Sargassum muticum was chosen for subsequent experiments. Kinetic data were described by pseudo second order model. After about four hours contact time the...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26659

Abstract The class of xanthene dyes has a complex chemical structure, which showed to be toxic for mixed culture of microorganisms (i.e. anaerobic granular sludge). Because of the unwanted effects of Erythrosin B (Ery B) on environmental components and some food confirmed previously, the dye was chosen in this study to evaluate its ecotoxicity. Also, the Ery B photocatalytic degradation products were assessed in terms of their ecotoxicity. Three-days of seed germination and root growth test...
Autori: Laura Carmen Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26660

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract The transformation of lentic ecosystems in other types of ecosystems (plain, forest) is a part of normal process of ecological succession that occurs slowly, at geological scale. The filling of cuvette with eroded material transported by precipitations, air masses or detritus produced in situ, start from the moment when the body of water lakes is formed and has different rates depending on many factors: geographical location, geological substrate type, types of existing uses in the ...
Autori: Ofelia Axinte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26672

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon material was found to adsorb vitamin B2 from aqueous solution at room temperature. The obtained ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26679

Abstract β-galactosidase from Aspergillus oryzae was strongly immobilized on magnetic particles functionalized with amino groups. By simple incubation without any activating agents, electrostatic interactions between amino groups and enzymes allowed obtaining a strong linkage. The immobilization efficiency was studied with the quantification of amino groups of the particles and of immobilized β-galactosidase. Kinetic parameters, especially the maximal velocity Vmax and the affinity...
Autori: Kalim Belhacene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26682

Abstract The adaptation of commercially available ion-selective electrodes (ISEs) for use in wastewater matrices was demonstrated using multivariate analysis and optimization with the Microsoft Excel Solver tool. The electrodes were characterized in pure analyte solutions, and their parameters were estimated using multivariate analysis and Solver optimization. The ammonium, nitrate, and nitrite ions were measured in model systems that were designed to simulate wastewater. The accuracy of the...
Autori: Natalija Koprivanac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26687

Abstract Bioplastics are biobased materials, usually easy biodegradable, derived from renewable resources. Evolution of bioplastics production is related to: bio starch and starch mixtures (74.5%); bioplastic products from fermentation (13%), bioplastic from petrochemicals materials (12.5%). They are seen as a viable solution to avoid some environmental impacts caused by the use of fossil-based conventional plastics. In this context, the general objectives of this study entail the analysis a...
Autori: Elena-Diana Comaniţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26688

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract In the process of chitin extraction, shrimp shell powder was treated by Lactobacillus plantarum culture. The efficiency of microbial demineralization (DM) under aerobic and anaerobic conditions was investigated. The shrimp shell powder was incubated at 30 °C for 6 days with L. plantarum. In order to prepare microbial culture, inoculums size was 5% for culture inoculation. Date syrup with total reduce sugar concentration of 30 g.L-1 was used. The value of pH in anaerobic conditio...
Autori: Marjan Khorrami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26692

Abstract Anaerobic processes have been successfully applied in the treatment of municipal and industrial wastewaters. Judicious use of nutrients in anaerobic treatment has not been systematically investigated. The optimal nutrient dosage for anaerobic wastewater treatment systems is largely unknown. In this paper, COD:N:P ratio used by various researchers in anaerobic wastewater treatment systems for treating different types of wastewaters are compiled and critically analyzed. In order to ha...
Autori: Athar Hussain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26697

Abstract In the present work, the removal of cadmium ions from aqueous solution using an agricultural waste as biosorbent, namely trunk palm fibers was investigated. The adsorption equilibrium and kinetics for this system were studied. Four adsorption models were applied to understand the nature of the adsorption process. Freundlich adsorption isotherm was found to best fit the experimental data. The maximum adsorption capacity was found to be 23.8 mg/g. The adsorption process was found to b...
Autori: Hosam Altaher
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26699

Abstract The main purpose of this research was to study the biodegradation ability of atrazine by using Arthrobacter sp. as free and immobilized cells of the strain DNS10, under several important environmental factors such as temperature, pH, salinity, substrate concentration. Furthermore, this paper objective was also to assess the process considering the immobilization under extreme conditions, such as high salinity and high atrazine concentration. DNS10 was immobilized on a sodium alginat...
Autori: Zhang Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26702

Abstract We started from a prey-predator model, where a periodic variation in the number of prey and predators is possible, without perturbation. We followed the line that periodically we carried out an overpopulation of prey. In general it is expected that this fact will increase the populations both of prey and of predator. We try to understand the way in which the overpopulation of prey can change the average number of prey and predators. In terms of application, such increase of the popu...
Autori: László Mátyás
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26706

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract The removal efficiency of algal biomass Chlamydomonas reinhardtii for Pb and Cu metal ions was evaluated in single and binary metal systems. Biosorption experiments were performed in solutions containing 0.2 g L-1 of algal biomass at 30oC and pH 6. Initial metal ion concentrations ranged from 10-7 M to 10-6 M. Thermal analysis of the biosorbent indicated that algal cells are composed of groups containing C, H, N, and S. The presence of ionisable functional groups responsible for bio...
Autori: Roula Flouty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26709

Abstract This research evaluated two electrokinetic remediation systems (EKR) for separating phenanthrene from bentonite and its electrochemical destruction by using a Boron Doped Diamond (BDD) electrode. The effect of the electrochemical potential for the oxidation of phenanthrene in liquid phase with Ti/BDD was analyzed by Normal Pulse Voltammetry and Hydroxyl Radical (●OH) analysis using the Spin Trapping Technique. The results showed that 70% of phenanthrene was removed from benton...
Autori: Alejandro Medel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26710

Abstract One of the changes in marketing refers to the redirection of focus from profit to sustainable development. Sustainability marketing can influence sustainable development. The key contribution of the paper is the presentation of holistic approach to sustainable development and sustainability marketing through three dimensions: goals, actors and capital. Holistic management of sustainability marketing in the process of sustainable development is focused on economic, environmental and ...
Autori: Beba Rakic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26711

Abstract Adsorption has proved to be an excellent way to treat industrial wastewater, due to its significant advantages like easy availability, inexpensive, ease of operation and highly efficient, compared to conventional expensive adsorbents like activated charcoal, alumina etc. The present investigation focused on utilization of Mangifera indica seed shell substrate for the removal of toxic heavy metals like Fe(II) and Mn(II) from wastewater. Mangifera indica seed shell substrate as an eff...
Autori: Tikaram D. Kose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26713

Abstract Currently, conventional energy sources i.e. fossil fuels represent the main segment as regards electricity generation. Thus, their contribution to global CO2 emissions is considerable. This study considers carbon capture and storage (CCS) as a promising solution for the environmental problems we are now facing. Based on previous research, post-combustion capture (PCC) has been recognized as being the more appropriate technology for CO2 capturing from the existing power plants. The m...
Autori: Ales Hribernik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26714

Abstract Total anthocyanins were extracted from six sweet cherry cultivars grown in Sakarya, Turkey. In vitro inhibition effects of the extracted total anthocyanins on purified carbonic anhydrase I and II were investigated using CO2 as a substrate. All the extracted total anthocyanins inhibited the activity of the human carbonic anhydrase (hCA) I and II enzymes. Among all the cultivars, ‘Karakiraz’ was found to be the most active on both hCA I (IC50 = 30.59 μg/mL) and hCA II a...
Autori: Taki Demir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26715

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Maximum removal (94±1.2%) of 2, 4 dichlorophenol (50 mg.dm-3) was achieved on silica with agitation of 4 hours, at pH 8 and 42°C. The positive enthalpy (ΔH) and negative free energy values (ΔG315K) suggested the endothermic and a spontaneous nature of sorption. The free energy of the process at all temperature was negative and increased with the increase in temperature. The values of free energy suggested a spontaneous process where the spontaneity decreased w...
Autori: Abdul Ghaffar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26718

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract Five multiple-attribute decision-making (MADM) methods are used to rank the four most commonly used wastewater treatment technologies in India using pre-defined set of criteria and their indicators. Results show that it is difficult to get similar ranking using different MADM methods for equal set of weights. However, for varying weights all MADM methods generated similar ranking. It is found that in wastewater treatment alternative selection problem, it is essential to define set o...
Autori: Pradip P. Kalbar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26722

Abstract The objective of this study was to identify differences between three of the most conventional UV-based advanced oxidation processes, namely photolysis, UV/TiO2, and UV/ZnO for the decolorization and mineralization of reactive red 198 (RR198) model dye in saline media. The study investigated influences of solution pH levels, salt concentration, reaction time and dye concentration on the degradation of RR198. The most effective dye removal and mineralization was observed at pH levels...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26724

Abstract Large quantities of snail and clam shells are left as waste material when their meat is used as food for people. It has been a big problem that how to treat these wastes and usually these are land filled as wastes. In the present paper, these shells are studied as recycling resource for phosphate removal from solutions. Laboratory-scale batch experiments were conducted to evaluate the efficiency of snail and clam shells in removing phosphate from aqueous solutions. Major factors inv...
Autori: Ji Bing Xiong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26727

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Response surface methodology and central composite experimental design were used to model and optimize the operational parameters of the excess sludge protein extraction yield by ultrasonic wave-assisted extraction. The three variables involved in this research were the ultrasonic extraction time, pH, and temperature. In the range studied, statistical analysis of the results showed that selected variables had a significant effect on protein extraction yield. The optimized extraction...
Autori: Yulin Xiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26736

Abstract Today, a new generation of software applications can be developed, as IT services developed by software providers can be integrated by solution developers in complex control and monitoring Smart Building Management solutions. This paper introduces the concept of Virtual Smart Building Service Enterprise (SBSE) as a novel perspective to develop an innovated services ecosystem for smart buildings. The Virtual SBSE allows different stakeholder categories to interact in order to develop...
Autori: Monica Drăgoicea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26739

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract Along with nowadays growth of urban areas and population, it is more and more important to have better water resources management, especially regarding drinking water supply. Maintaining a good state of a water distribution network poses challenges that are addressed by research community. Two of the main challenges in management of water distribution systems are the reduction of energy consumption due to the high pumping requirements in some systems and/or reduction of water losses...
Autori: Mario Castro Gama
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26747

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract Natural herbicides may be more sustainable than their chemical homologues, but they are still toxic substances that can affect humans and animals. Implementation of natural herbicides may require just as many safety precautions as the application of commercial herbicides, hence the need not to confuse the term "organic" with "non toxic". Allelopathy is accomplished through chemical inhibition of species towards each other, being an antagonistic phenomenon. Respon...
Autori: Ana Maria Vîrteiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26752

Abstract The paper presents the most economical and less polluting retaining wall system, calculated for the same site, having few different common heights used in design. The paper will highlight the importance of an environmentally friendly solution, but also the most economical solution, which should be the main criteria in the design. Two of the tools used in environmental life cycle assessments (LCA) are the carbon footprint and the energy footprint. The quantification of the carbon and...
Autori: Vasile Farcas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26753

Abstract Diclofenac (DCF), which belongs to nonsteroidal anti-inflammatory drugs (NSAIDs), is a biorefractory micropollutant and its removal from wastewaters has become strongly necessary. This paper dealt with the DCF removal from aqueous solutions by electrooxidation at boron-doped diamond (BDD) electrode. In addition, the dual character of BDD electrode in electrochemical degradation processes and their control was investigated. The electrooxidation process was assessed based on ultraviol...
Autori: Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26755

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Abstract Waste management does not try to dispose waste anymore but is searching for the best solution to manage valuable and scarce resources and reduce the negative impact on the environment. Preoccupation in Germany with regard to optimization of waste recuperation and valorization increases and separate collection systems for different waste fractions are taken into consideration. Within this study a pilot project was set up and its results are presented below. The investigation evaluate...
Autori: Mihaela Berechet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26758

Abstract The research is focused on the relationship between aviation systems and extreme terrorist events, the impacts of such events, and the solutions to manage the associated risks on medium and long term. The development of predictive models for extremeasymmetric events in aviation (EAEA) still represents an emerging direction of interdisciplinary research because not all mechanisms and interactions are understood. The testing of models is difficult due to lack of data and interpretatio...
Autori: Catalin Cioaca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26762

Abstract This paper presents a toolset for the efficient control of the indoor air quality and thermal comfort in retrofitted buildings. The refurbishment of existing buildings, compliant to actual regulations, often leads to airtightness and the consequent poor conditions for the occupants that could cause low productivity and even sickness. For this reason, the CETIEB (Cost Effective Tools for Better Indoor Environment in Retrofitted Energy Efficient Buildings) project developed innovative...
Autori: Gian Marco Revel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26770

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract This study was aimed to stimulate laccase production by Trametes pubescens MUT 2400 by using a tomato-based medium. Two sequential 2x2 factorial designs were used to determine the effect of carbon (C) and nitrogen (N) source concentration on laccase activity and biomass concentration; copper was used as the sole inducer (0.75 mM). Analysis of the first factorial design showed that N had a strong positive effect on the maximum laccase activity, which occurred at day 12 of cultivation...
Autori: Federica Spina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26795

Abstract To make sustainability transitions happen, it is crucial not only to have strategic planning processes committed by the top management, but also to encourage community engagement, approaching and promoting a bottom-up process. In the specific case of a University Campus, that means the involvement of the students not only as consumers, but with a leading role in the sustainability process. DICAM department of University of Bologna has recently started the implementation of some prac...
Autori: Sara Rizzo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26798

Abstract Based on the study on the reformation of Dawsonite-bearing sandstones with CO2 fluids at different temperature (100oC 200oC and 300oC) and different CO2/H2O/sandstone systems, it is suggested that as the temperature increases, the corrosion intensity of dawsonite-bearing sandstones is gradually increased, but the stability of the sandstone is reduced. The SEM study shows that there are radiated aggregate sediments of boehmite in all samples. At 200oC, with the dissolving of dawsonit...
Autori: Xi-Yu Qu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26814

Abstract The short-term effects of plant diversity (number of plant species and species compositions) on aboveground biomass, substrate inorganic nitrogen (N) concentrations, and substrate solution “effluent” N concentrations were studied in a subsurface verticalflow constructed wetland (CW). Results showed that (1) the number of plant species increased aboveground biomass (P< 0.05) but had no effect on the overyielding index DMax; (2) the species compositions and presence of ...
Autori: Hai Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26822

Abstract The problem of monitoring and controlling the complex and heterogeneous water distribution networks in urban environments is not new. Existing solutions include high-resilience and availability of telemetry systems where a wired or less often wireless backbone is connecting heterogeneous field devices to a centralized control centre. In the control centre, the administrative personnel of the utility are offered an overview of the system status, presented with possible alarms and may...
Autori: Athanasia Tsertou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26825

Abstract Water Distribution Networks (WDN) are large-scale systems whose management is a complex task, with increasing environmental and socio-economic implications worldwide, and with a renewed considerable attention by all stakeholders: local authorities, regulators, environmental groups and the scientific community. WDM managers need to reliably estimate the water demand in the short-term (typically 1 day ahead), in order to operate their reservoirs and treatment plants appropriately to ...
Autori: Antonio Candelieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26830

Abstract Decision support systems (DSS) have been wildly developed in the recent decades, in various areas of decision making. In the 21st century, the advances in Information and Communication Technology (ICT) have brought the era of cloud computing, in which network-distributed resources (simulation and optimization models, data, etc.) are integrated in decision support applications. The aim of the present article is to present the application of web-based decision support systems (WBDSS) ...
Autori: Quan Pan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26832

Abstract Although in Lithuania artificial land drainage is a common water management practice, there are still concerns about its downstream hydrological effects. Due to the complexity of flow driving factors, the hydrological effect of drainage is very uncertain, making it difficult to determine its relative importance. Aiming to distinguish between the influence of drainage and other factors in this study, the extent of changes of twenty hydrologic variables (flow magnitude, frequency, dur...
Autori: Arvydas Povilaitis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26848

Abstract This work presents the optimization of process variables to maximize the percent of Fe (II) removal, R (%), by chelating resin Purolite S930 from 34% CaCl2 solutions. To study the combined effect of the initial solution pH, initial Fe (II) concentration and resin dosage was used a 23 orthogonal central composite design and Response Surface Methodology (RSM) for analysis of experimental data. To optimize the regression equation was used The Gradient method. The study discovered that ...
Autori: Camelia Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26856

Abstract Urban Tree Canopy (UTC) is an important asset in the urban ecological system by reducing the heat, runoff and improving air quality. Estimating the available urban tree canopy is important for decision makers for better understanding of urban ecosystems and helps to improve environmental quality and human health in urban areas and plan conservation activities. This paper reports on an object-oriented tree extraction method developed by using spectral and textural information of High...
Autori: Muneeswaran Mariappan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26858

Abstract This study concentrates on the reactive biosorption of dyes such as Reactive Red 3:1 (RR3:1), Reactive Orange 13 (RO13), Reactive Blue 13 (RB13), Reactive Blue 72 (RB72). The modified fungal biosorbent, Paecilomyces sp., had a higher dye biosorption yield in our study. 100% of biosorption yield observed on RR3:1 and RB13 and 94.09% of color removal of RO13 with the chemically modified biosorbent were great. Also, such modified biosorbent exhibited remarkable performance in simulate...
Autori: Ahmet Çabuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26860

Abstract This study investigated the use of tea waste to decolorize refractory dyestuff from textile wastewater. The influence of the solution pH and the contacting time were examined for various adsorbents, namely green tea-leaf powder (GTP), black tea-leaf powder (BTP), and powdered activated carbon (PAC). Results from batch experiments revealed that the reduction in true color (ADMI) increases with decreasing pH. The ADMI reduced from 1106 to 150 with 0.8 g/L of GTP at pH 2. The results a...
Autori: Chih-Huang Weng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26863

Abstract In this study, Moringa oleifera seed extract was applied as coagulant under different pH values (2.5 - 9.5), coagulant dosages (200-600 mg/L), initial dye concentrations (50-300 mg/L) and different settling times (0- 60 minutes) for R. Blue 19 and R. Red 120 dyes removal. Results revealed that with increase in pH (from 2.5 to 9.5), removal efficiency decreased from 95% to 87.3% for R. Blue 19 and from 97.2% to 62% for R. Red 120. By increasing coagulant dosage to 400 mg/L, removal e...
Autori: Ali Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26864

Abstract The aim of the present study was to determine the most feasible experimental conditions for the dissolution of base metals (Cu, Ni, Zn, Pb, etc.) from waste printed circuit boards (WPCBs) obtained from WMP. The leaching of WPCB samples was performed with FeCl3 in HCl solution which allowed the separation of a precious metal rich solid residue and a high base metal concentration solution adequate for base metal recovery. The most favorable conditions for the leaching process were ide...
Autori: Szabolcs Fogarasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26877

Abstract To assess the pollutants input of acid mine drainage (AMD) and domestic activities in Aries River, the water was monitored monthly, during one year, in 15 sampling points along the River. The dissolved metals (Ca, Mg, Na, K, Fe, Cu, Zn, Mn), anions (SO42-, NO3- and Cl-), pH and electrical conductivity were analyzed. The obtained data were assessed against the water quality standards, Principal Component Analysis (PCA) and Hierarchical Cluster Analysis. The results revealed the water...
Autori: Erika Andrea Levei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26881

Abstract Ash resulting from wood combustion constitutes a waste disposal problem to facility owners. The use of ash fertilizer or soil amendment could provide nutrients for agriculture if its nutrient content is adequate and it does not contain harmful amounts of heavy metals. The recycling of nutrients bound in ash would provide an inexpensive solution to waste problem. In our study, we aimed to characterize ash and clinker resulted from incineration of oak waste resulted from wood industry...
Autori: Ioan Oroian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26885

Abstract The paper presents a study on the hazards associated with solid ammonium nitrate (AN) storage and handling, in particular the hazard of explosion. Due to its flammable and explosive characteristics, AN is largely used as an explosive material in the mining industry. Some specific problems encountered in the risk estimation are related to the determination of the explosive power of the AN, which depends on several characteristics. The simulation results of AN explosion using differen...
Autori: Zoltán Török
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26891

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The CoCrMo alloys have been widely used in artificial knee or hip joints. It is well known that these materials have a good corrosion resistance and acceptable biocompatibility properties. Zirconia as a ceramic biomaterial facilitates the osteoconductivity and tissue osteogenetic capacity in new bone formation around implant. Linear polarization and electrochemical impedance spectroscopy (EIS) were employed to characterize the electrochemical behavior of plasma sprayed yttrium oxid...
Autori: Manuela Romaş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26896

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

Abstract The design, the realization of the prototype and the acoustic standardization process of a novel periodic system made up of multiphysical phenomena scatterers as a road traffic noise reducing device are reported in this work. The structure analysed here, inspired by Sonic Crystals, has been designed following the guidelines established in recent works according to the concept of tunability. Thus, the acoustic barrier proposed here includes several mechanisms of noise control, such a...
Autori: Sergio Castińeira-Ibáńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26900

Abstract Trace metal elements commonly exist in drinking water. Excessive exposing on them may result in lots of health problems. This paper mainly focuses on the accumulations of Cu2+, Cd2+, and Pb2+ in drinking water supply networks with amorphous Al(OH)3 formation. The effects of pH, water flow rate, and metal element contents were investigated at laboratory bench scale. It was found that chemical adsorption mainly occurred at pH > 7.0. Suspended Al(OH)3 showed a strong adsorption capa...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26906

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Abstract The present study was designed to determine the sound effects of ultrasonic treatment and the biologically mediated extraction of uranium from low grade black shale. Low grade uranium was subjected to fungal treatments assisted by sonication by conventional methods. In situ fungal leaching of black shale with different fungal strains in the presence of molasses as growth substrate resulted in highest leaching yield of uranium by Phoma tropica (57.73%) compared to Penicillium chrysog...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26919

Photodegradation caused by sun irradiation may be of major significance in the natural elimination process of pharmaceuticals and personal care products (PPCPs). The fate of metronidazole (MET) in surface water under solar irradiation was investigated. Several parameters affecting the photochemical degradation rate of MET were investigated, including the initial pharmaceutical concentration, continuous input and the presence of other pharmaceuticals like tinidazole (TNZ) with similar structur...
Autori: Bo Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26928

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

Adsorptive removal of dibutyl phthalate (DBP) by bamboo biochar (BC) was investigated under various experimental conditions. BC demonstrated excellent sorptive ability to remove DBP from the aqueous solutions. The removal of DBP by BC increased as the contacting time increased and reached an equilibrium value after 240 min. The presence of natural organic matter decreased the removal efficiency while increased the time to reach sorption equilibrium. The adsorption of DBP on BC could be well ...
Autori: Junliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26934

This study investigates the effects of earthworms and a variety of substrates on photosynthetic characteristics and rate of uptake of nitrogen (N) and phosphorus (P) by Iris pseudacorus L. (Iridaceae) in a constructed wetland system under greenhouse conditions. The study seeks to identify those factors that maximize the efficient removal of N and P. Four substrates were tested: pure sand, sand and soil, sand and organic matter, and a mixture of sand, soil and organic matter. The photosyntheti...
Autori: Defu Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26936

The aim of this study was to examine the pollutant removal performance of a combined process using horizontal subsurface flow constructed wetland (HFCW) and an oxidation pond (OP) in the treatment of a decentralized domestic wastewater. Waters along the water flow and at different depths of the wetland substrate were sampled and analyzed during continuous operation. It was found that the HFCW-OP combined system presented good organic matter and phosphorus removal capacity. In the first year, ...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26943

In the context of sustainable development, focus must be set on reasonable use of natural and energetic resources, which is a real must at present. Besides these, material and informational resources add up to give the full picture of sustainable development resources. The paper introduces a valid solution of powdery waste recycling into pellets for the steelmaking industry. The pellets are obtained from powdery wastes (steel plant dust, red sludge, lime dust, dolomite waste, waste limestone,...
Autori: Ana Virgina Socalici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26944