? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� "Waste not, want not" a study of household attitude toward recycling of solid wastes� A kinetic model for the crystal violet mineralization in water by the electro- fenton process� Development of a coagulation/flocculation predictive model for turbidity removal from tehran water treatment plants� Removal of cadmium (II) from aqueous solutions by sphagnum moss peat: Equilibrium study� Environmental sustainability based on fuzzy models� Impact of dust emi...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25207

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractThe removal of formasine fines particles from water by precipitation with polyelectrolyte and surfactant complex of Polyacrylamide (industrial product Praestol 611 made by Degussa) and Sodium Lauryl Sulphate (SLS) was experimentally studied. Calcium oxide was added to initiate precipitation of the polyelectrolyte complex together with the fines particles. The experiments were carried out with complexes having the surfactants concentration higher then the critical aggregation concentratio...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25238

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

Many industrial complexes in Korea have produced a variety of potential toxic chemicals during manufacturing processes and activities by air emissions, effluents, or solid wastes over the past few decades. In this study, arsenic levels in air, soil, and water near an industrial complex were determined. Human health risk assessment for arsenic was conducted based on the levels and potential exposure pathways in a multimedia environment (air, soil, and water). The point estimate of incremental can...
Autori: Yong-Chul Jang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27249

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

Continuously increasing energy prices, as well as the increasing number of legal stipulations, bring to the attention of scientists the necessity of finding solutions for energy saving by using different heat sources. According to the EU Action Plan, the highest potential of energy savings (27-30% until 2020) will be applied to the existing buildings. Under the circumstances of environmental issues, research on the use of secondary energy resources is of great interest, being a concern in the...
Autori: Timea Gabor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27395

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

Two sets of simulated landfill reactors, namely conventional landfill (CL) and leachate recirculated landfill (RL) were operated to investigate the effect of leachate recirculation on the fractionation of Zn in municipal solid waste (MSW) landfill leachate. Zn in landfill leachate was fractionated into three fractionations: particulate and colloidal matter >0.45 μm, non-labile complexes <0.45 μm and free cations/labile complexes <0.45 μm. The result showed that the recirculatio...
Autori: Jun Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27648

This work seeks to develop a suitable heavy metals precipitation modeling approach that could give reasonable results in mainstream use with industrial wastewater treatment. This paper is devoted to the thermodynamic analysis of the degree of precipitation of slightly soluble hydroxides and salts in industrial wastewaters in order to optimize the technological schemes of extraction and reuse of heavy metals from industrial waste. Based on the notion of the solubility product, the equations desc...
Autori: Igor Povar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28156