AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

Include urmatoarele articole� Degradation of alcian blue 8 gx by heterogeneous and homogeneous photocatalytic processes� Evaluating the performance of solid waste management models� Bioreactors with stirred bed of immobilized cells 1. Studies on mixing efficiency� Fugitive emissions estimation from petroleum storage tanks� New Ni(II) coordination polymers with insulating and anticorrosive properties� Determination of water quality deterioration at pilgrimage centre along river netrav...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25196

Abstract Hydrogen could be considered a synthetic secondary power carrier fuel in the years to come, subsequent to the fossil fuels economy. Thus the concept 'hydrogen economy' shall be defined, and it will also have a great influence in the future years.The field of power generation (producing electric power), transports, (electric cars), chemistry (hydrogen is a major raw material) are potential users of hydrogen.The experts support, by means of a series of economical and strategic analysis ma...
Autori: Corina Rădulescu, Elisabeta Păsculete, Florentina Condrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25111

AbstractThe objective of the paper is to present sustainability indicators for municipal solid waste management (MSWM). Sustainability implies environmental, economic and social acceptance. The complexity of the system-in-focus requires the employment of a systems (or cybernetic) approach: Acceptance implies clear objectives, from a specific point of view (here, the viewpoint of the municipal administration is taken), over a time horizon covering at least two generations, a life-cycle considerat...
Autori: Demetrios Panagiotakopoulos, Konstantinia Tsilemou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25112

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

The present paper examined the photocatalytic degradation (PCD) of gas-phase trichloroethylene (TCE) over thin-film TiO2. A large-scale treatment of TCE was carried out using scale-up continuous flow photo-reactor that nine reactors were arranged in parallel and serial. The parallel or serial arrangement is a significant factor to determine the special arrangement of whole reactor module as well as to compact the multi-modules in a continuous flow reactor. The conversion of TCE according to the ...
Autori: Gyung Soo Kim, Sang Bum Kim, Sung Chang Hong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25121

The use of gasoline oxygenated with MTBE (methyl tert-butyl ether) reduced significantly air pollution (16 - 23% lower emissions of CO and 18% lower emissions of unburned hydrocarbons) but increased water pollution. There is no European or national regulations for MTBE in drinking water except for Denmark, which has set a limit value of 30 Âľg/ L for MTBE. USEPA proposed a maximum concentration of 20- 40 Âľg/L. This paper is a review with 70 references on the MTBE production, use, properties and...
Autori: Camelia Beţianu, Florina Ungureanu, Loredana Branza, Lucian Vasile Pavel, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25122

AbstractThe corrosion behaviour of three commercial nickel-chromium based dental materials was investigated by electrochemical methods in a corroding mixture of sodium chloride, oxalic acid and lactic acid. In order to establish electrochemical parameters of the corrosion process, linear and cyclic polarization curves were plotted. The samples performances in the corroding system were investigated by weight loss, pH and electrical conductivity measurements. The quantitative analysis related with...
Autori: , Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25132

AbstractThis paper reviews some practical aspects of the application of algal biomass for the biosorption of heavy metals from wastewater. The ability of different algal species to remove metals varies with algal group and morphology, with the speciation of specific metals and their competition with others in wastewater, and with environmental or process factors. The scattered literature on the uptake of heavy metals by both living and dead algal biomass - both macroalgae and immobilized microal...
Autori: Loredana Branza, Maria Gavrilescu, Matthew J. Dring
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25133

AbsractThe paper highlights the inventory of landfill, focusing on the feasibility study of solid waste disposal sites inventory in the Republic of Moldova and existing situation in waste management, including landfills analysis. The paper contains relevant information on landfills characteristics, their location and description of disposed waste. Technical assistance for the study was provided by the regional project Capacity building for improving the quality of greenhouse gas inventories (Eur...
Autori: Tatiana Tugui
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25135

AbstractCatalysts having mobile electrons in bulk such as metals and semiconductors are good solid materials for red/ox type of reaction (oxidation) and can be effectively used in gas sensing devices as well. The aims of this work were: (i) to investigate the surface behavior of Pt(0.28%)/Al2O3 and SnO2(2.94%)-Pt(0.28%)/Al2O3 samples in inert atmosphere (He) and in reducing atmosphere containing helium-cyclopropane gas mixture under ambient condition (i.e., room temperature, atmospheric pressure...
Autori: , Cornel Munteanu, Jozsef Kovacs, Mariana Scurtu, Monica Caldararu, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25146

AbstractMunicipal solid waste (MSW) management is an important and challenging issue for sustainable development. It is also one of themost controversial problems and a subject of an ongoing debate between different interested parties. A particularly controversial issue is MSW incineration (with or without energy recovery) which has in many countries become a socially unacceptable option for dealing with solid waste. On the other hand, the increasing amounts of waste each year demand immediate a...
Autori: Adisa Azapagic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25147

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

In recent years, the release of volatile organic compounds (VOCs) has received much attention. Catalytic oxidation of VOCs, found in small concentration in industrial gas emissions constitutes an alternative for environmental pollution reduction.In this paper, a comparative study regarding the non-catalytic and catalytic oxidative destruction of non-halogenated or halogenated C6 hydrocarbons (C6H14, C6H12, C6H6, Cl-C6H5, Br-C6H5), is presented. Catalytic oxidation was studied in the presence of ...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25162

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Contain all the articles from this issueEnvironmental analysis by capillary electrophoresis. Atmospheric samplesCamelia Draghici, Gheorghe Coman, Mihaela Sica,Dana Perniu, Mihaela Badea   The ecological farms - A solution for sustainable agriculture. II. Position and perspectives of the ecofarms in the frame of the productive agricultural system Stela Axinte, Alina Stanciu, Lorica Axinte  The extraction and clean up of organochlorine pesticides and PCB's from water using solid phase ex...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25170

Contain all the articles from this issueEditorialEstablishing effluent discharge limits - have we got it right?Yusuf Chisti Full papersSurvey on the treatment of gaseous streams containing volatile organic compoundsOana Penciu, Maria GavrilescuEU environmental policy for industrial pollution control. IPPC DirectiveElena Bobu Environmental monitoring Antonius A.F. KettrupProcess The sonochemical degradationof cyanide ions using atmospheric oxygen as oxidizing agentIoan Iordache, Mircea Teodor Nec...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25171

Contain all the articles from this issueDestruction of Volatile Organic Compounds by catalytic oxidationAlice Oana Rusu, Emil DumitriuRisk assessment for a shipyard from Romanian Black Sea CoastAnca Florentina Caliman, Ion Balasanian Monitoring the behavior of the restoration interventions of the Probota Monastery’s indoor frescoes under the influence of the environmental factors. II. Modifications of the physical-structural and chemical characteristicsIon Sandu, Adrian Dima, Ioan Gabriel Sand...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25173

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei, Gabriela Apostolescu, Ioan Rosca Studies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monit...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25175

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

Contain all the articles from this issueLignin in crop cultivations and bioremediationAlfred Abaecherli, Valentin I. PopaMaterials for intermediate-temperature solid oxide fuel cells and for proton exchange membrane fuel cellsAnnemarie Huijser, Joop SchoonmanAre interfacial biocatalysts important tools for nonpolluting technologies? 2. Immobilization of lipases and their  representative applications Brindusa Dragoi, Emil DumitriuUASB treatment of fruit canning wastewater: pilot-scale invest...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25180

Contain all the articles from this issueICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Treatment Technologies for Gaseous Fluxes"Surface chemistry studies on molybdena–alumina catalystTatiana Yuzhakova, ?kos R?Šdey, Endre Domokos, J??zsef Kov??cs, Monica Caldararu, Cristian Hornoiu, Mariana Carata, G.Postole, Cornel Munteanu, Larisa Strukova, Jozse FazakasHebicidal behaviour of a new N,N'- biquaternary salt of 4,4'- bipyridineServilia Oancea, Marinela Irimia, Gabriela Carja, Anton Airinei, Nicu...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25189

Include urmatoarele articole:� Removal of persistent organic pollutants from textile wastewater by membrane processes� Sustainability evaluation of an urban residential settlement� Removal of zinc (II) from aqueous solutions by romanian sphagnum peat moss� Development trends of cold plasma reactors in the global context of carbon emission reduction� Assessing the potential of wind power in Romania within Kyoto targets� Research on the impact induced in the environment by milk process...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25198

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� "Waste not, want not" a study of household attitude toward recycling of solid wastes� A kinetic model for the crystal violet mineralization in water by the electro- fenton process� Development of a coagulation/flocculation predictive model for turbidity removal from tehran water treatment plants� Removal of cadmium (II) from aqueous solutions by sphagnum moss peat: Equilibrium study� Environmental sustainability based on fuzzy models� Impact of dust emi...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25207

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractThe paper presents original results concerning concentrations of eight heavy metals in soils adjacent to two improperly built municipal waste deposits located in Eforie Sud and Techirghiol, Constanta County, Romania. Measurements have been done on surface and depth soils, during April-October 2006. The applied analytical technique for metal determination was flame atomic absorption spectrometry (FAAS). The mean measured values ranged as follows (in mg/kg dry weight): Cd: 0.09 - 0.15; Co:...
Autori: , Elisabeta Chirilă, Narcisa Elena Ilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25213

AbstractVolatile organic compounds (VOCs) constitutes an important class of environmental pollutants, which, together with other contaminants as NOx, SOx, CO, NH3, CO2 etc. participate in degradation of atmosphere and exhibit a potential risk for human health. VOC emissions may be generated in more than 25 percentages through the use of solvents in different industrial or house holding activities. For applying a certain plan concerning the pollution reduction, any user of organic solvents contai...
Autori: Florin Bandrabur, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25218

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractPolycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector ...
Autori: Alina Soceanu, , Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25237

AbstractAn assessment of acide drainage forming potential for a mining waste material resulted in a former mine of nonferrous and precious metals ore has been made. The waste material has the following contents: 2,20?ˇ2,28% sulphide sulphur, 2,53?ˇ2,58% Fe, 0,07% Cu, 0,05% Zn, 0,36?ˇ0,40% Pb, 0,008?ˇ0,013% Ca and 3,85?ˇ7,97% sulphate. Bacterial leaching tests in percolating columns during 380 days have been made. The leaching liquor has been recirculated at a liquid:solid ratio of 1L:1kg. After ...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25239

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractDespite its well known toxic effects, lead continues to be a part of modern life. Lead concentrations in the environment have increased steadily throughout history, with a huge increase when lead became a common additive to paint and gasoline. Although the use of lead in gasoline and most paint has been banned in many countries, there are still many ways for lead to be released on the environment. The effects of lead on human health have been the subject of significant international exam...
Autori: Alina Murariu, Aurelia Meghea, Ioana Lacatusu, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25244

AbstractAs a member of the European Union, and as part of the Kyoto Protocol, Romania has the obligation to implement environmental legislation regarding greenhouse gases (GHG) and to take appropiate actions for emissions reduction. The paper deals with Romanian GHG legislation and with its requirements concerning monitoring, reporting and reduction of GHG emissions, within the field of pulp and paper manufacturing....
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25246

AbstractThe health effects caused by air pollutants may range from slight biochemical and physiological changes to difficulty breathing, wheezing, coughing and aggravation of existing respiratory and cardiac conditions. This paper presents an experimental study of air quality in the city of Tg. Jiu, Gorj County, by evaluating the air-floated powders of the PM10 fraction and lead from air. The analysis was performed by measurements in sampling points using the method presented in the European Nor...
Autori: Camelia Capatana, Claudia Maria Simonescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25247

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractThe comparative study on reactive extraction of p-hydroxybenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar s...
Autori: Anca-Irina Galaction, Dan Caşcaval, Maria Cămăruţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25250

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractA comprehensive characterization of fly ash from Iasi, Romania has been carried out in order to set up the utilization potential of fly ash resulting in appreciable amounts from thermal power plants as a waste, which leads to soil and groundwater contamination, as well as atmospheric pollution. This fly ash can be classified on the base chemical and technological properties in F class. Having in mind the assignment of the processing conditions, the fly ash can be used as sorbent for poll...
Autori: , Maria Harja, Marinela Bărbuţă, Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25259

AbstractThe effective mass transfer area of a Mellapak 750 Y structured packing was measured in a bench-scale plant with a column having an internal diameter of 100mm, and a packing height of 518 mm, using a broad range of gas and liquid flow rates. The absorption of carbon dioxide into natrium hydroxide aqueous solutions of 0.5 and 1.0 mol/L has been employed as test reaction. The validity of data obtained was tested by checking the two conditions of fast pseudo first order irreversible reactio...
Autori: Anton Friedl, Ilie Siminiceanu, Michael Harasek, Mihaela Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25264

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractConsidering that three-phase dispersions are common in chemical engineering and biotechnology, and with increasing airlift reactor applications to chemical and biotechnological processes, a experimental study was undertaken in order to investigate the liquid phase hydrodynamics and dispersion in an external-loop airlift reactor on laboratory scale. Experiments were conducted in order to find a relationship between relevant hydrodynamic and mixing parameters of a solidsuspended exter...
Autori: Florina Ungureanu, Maria Gavrilescu, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25268

AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

AbstractTheoretical and experimental studies of gas drying processes by adsorption in fixed bed of grains are presented in this paper. Based on an extensive literature study, some of the most representative mathematical models describing gas adsorption in fixed bed and consequently gas drying processes by adsorption in fixed bed are also presented. Using a mathematical model from those mentioned describing adsorption under isotherm regime, the temperature and gas flow velocity effects over the d...
Autori: Marius Sebastian Secula, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25272

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

AbstractIn this work it had been tested the recovery of some compounds like: Fe2O3, TiO2, PO4 3- ions, Al2O3 from the sludges, which result in the industrial facilities for output of pure uranium dioxide. Solubilization of the chemical compounds from the uraniumwastes was performed in strong acidic media, using adequate methods....
Autori: Alexandru Cecal, Doina Humelnicu, Romeo Iulian Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25288

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractThe development of technologies for waste treatment, simultaneously with minimizing greenhouse gas emissions, has become a matter of great concern at global level. Biogas systems can help in the fight against global warming by avoiding to escape methane from organic waste, into the atmosphere. Biogas technology is of great benefit to the end-users and the environment by energy, compost and nutrient recovery. Romania is a country with a huge biomass potential. Implementing of biogas techn...
Autori: , Corina Alice Babutanu, Gheorghe Băran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25300

AbstractPulp and paper mills generate various quantities of energy-rich biomass as wastes, depending on technological level, pulp and paper grades and wood quality. These wastes are produced in all stages of the process: wood preparation, pulp and paper manufacture, chemical recovery, recycled paper processing, waste water treatment. Energy recovery from wastes of different origin has become a generally accepted alternative to their disposal. Pulp and paper industry expresses an interest in adap...
Autori: Dan Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25307

AbstractNowadays, energetic utilization of biomass, biotechnology attracts a big attention not only from the environmental point of view but also have a social, political and economical impact. According to the Directive 2003/30/EC of the European Parliament and the European Council the emission of greenhouse gases can be reduced by 49% using bioethanol produced by a manufacturing process based on corn, instead of crude oil based fuels. Moreover in Hungary from 1st of July 2007 only gasoline wit...
Autori: , , Gyula Marton, , Jenő Hancsók, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25312

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractThe paper presents the main causes of the sea accidents and disasters, which call for the implementation of a sea pollution and safety management system (SMS) in the navigation companies, for certification purposes, in compliance with the International Management Code for the safe vessel operation and pollution prevention (ISM). For this purpose the objectives of the ISM codes are presented and which are to be found in the implemented Management System.From the main causes of the safety ...
Autori: Carmen Gasparotti, Lucian Georgescu, Mirela Voiculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25330

AbstractThe removal of Acid Red 398 (AR398) dye from dye-containing solution using coagulation/flocculation process with polyaluminum chloride (PAC) and Alum was investigated. The effect of different parameters involving pH, dosage of coagulant, initial dye concentration, and bentonite as a natural coagulant aid was examined. According to the obtained results, the optimum pH, at which the maximum removal occurred, was about 4 and 5 for PAC and Alum, respectively. However, PAC performed efficient...
Autori: Maryam Hasani Zonoozi, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25335

AbstractIn the present work, composite membranes were developed for separation of hydrogen from its mixtures with other gases. The composite membranes were characterized by single gas permeation and scanning electron microscopy. Gas transport properties have been determined for four gases (H2, CH4, N2, CO2). The influence of cross-linking on transport was measured. H2/CH4 selectivity values up to 115 were obtained. The resulting membranes have a selectivity of H2/CH4 close to intrinsic selectivi...
Autori: Carmen Nistor, Marcel Popa, Sergey Shishatskiy, Suzana Pereira Nunes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25339

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

AbstractThe technological process of basic chemical organic compounds synthesis is included among the economic activities that can affect the environment quality. The environmental impact of chemical organic synthesis is evaluated using the alternative method of global pollution index that considers the concentric circles graphical methodology proposing a scale of the arithmetic mean values for the evaluation scores of each environmental components (e.g. water resources, gaseous emission, soil a...
Autori: Carmen Zaharia, Ilie Murăraşu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25352

AbstractA present challenge for research is to determine how to use the combination of oil, gas and coal most efficiently with the minimum environmental damage. In this paper the authors have compared technologies to produce the electricity using natural gas and coal. The objective of this paper consists in evaluation of the life cycle assessment of the natural gas and coal in order to compare their greenhouse gases (GHG) emissions. In this way, three systems with and without CCS were examined: ...
Autori: Adrian-Alexandru Badea, Cristian Dincă, Gheorghe Lăzăroiu, Tiberiu Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25355

AbstractA study was fulfilled concerning the source and the distribution of PAHs in the effluent proceeding from an oil refinery. The monitoring of the PAHs concentration in the refinery’s effluent also was performed during a year long. The practical goal of the work was to observe the complying with the limits imposed by the current legislation and to identify the potential risks of exceeding these limits in the future. For this study, gas chromatographic and HPLC methods were used. The metho...
Autori: Anca Iuliana Birladeanu, Claudia Irina Koncsag, Mariana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25357

AbstractPolycyclic aromatic hydrocarbons (PAHs) are included in the European Community (EC) and in the Environmental Protection Agency (EPA) priority pollutant list due to their mutagenic and carcinogenic properties. PAHs emissions from automobile traffic and industry activities were shown to influence the PAHs levels and profiles in vegetables grown nearby. The levels of 15 PAHs were determinate in samples of pepper (Capsicum Annuum) and tomato (SolanumLlycopersicum) in different stages of plan...
Autori: Alina Soceanu, Dan Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25360

AbstractPulsed high voltage discharge technology is a newly developed method for knock out viruses in blood with various electrohydraulic discharge reactors. The aim of this study is to investigate the effect of an electrohydraulic discharge treatment system on Hepatitis C virus (HCV) behaviour. The electrohydraulic discharge (EHD) reactor consist of high voltage point discharge electrode above blood surface and cylindrical ground copper electrode containing the blood (in the same time act as th...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25362

AbstractThe main goal of this study is to determine the trend in exhaust concentrations during the last 12 years. Accordingly, a nondisperse infrared gas analyzer was used to measure the concentrations of carbon monoxide (CO) and hydrocarbons (HC) emitted from vehicle exhaust. A total of 449 vehicles distributed across model years ranging between 1968 and 2005 were tested under idling conditions. The results indicated that there is a strong relationship between the age of the vehicle and the con...
Autori: Kamel Al Zboon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25365

AbstractHigh proton conductivity of CsHSO4 opened new opportunities for applications as electrolyte in solid acid fuel cells (SAFC). Relatively recent, it was proved that the accommodation of this solid electrolyte by silica supports improves its proton conductivity. During this work, solid acid CsHSO4 and its composites with mesoporous silica of SBA-15 and MCF-types as host materials were synthesized and studied for the first time. Studies were mainly focused on the influence of mesoporous supp...
Autori: Adrian Ungureanu, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25366

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

AbstractThis paper presents an analysis of the levels of electromagnetic fields caused by cellular base stations or mobile phones, measured in some residential areas. A statistical processing of the data has also been done in order to estimate both the short-term and the long-term variability of the fields caused by cellular base stations in some apartments and on the terraces of the apartment buildings at tens or hundreds of meters distance from the antenna systems. In some places, comparative ...
Autori: Alexandru Salceanu, Ionut Nica, Valeriu David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25381

AbstractThis paper analyses a new technology for minimizing the use of metalworking fluids (MWF) during the machining process. Despite the fact that near dry machining (NDM) produces almost similar cutting performance to conventional flood supply machining while using much less MWF, for being fully utilized in industry is necessary to research ecological impact of these machining techniques. To take full advantage of minimal quantity lubrication (MQL) technique and expand its applicability, an u...
Autori: Domnita Florina Fratila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25382

AbstractThe paper proposes a simple and less expensive gas chromatographic method for analyzing acrylamide in food and reveals comparative results regarding the acrylamide content in commercial and home toasted bread. Validation of the method has been achieved by establishing parameters linearity, limit of detection (LOD = 0.1 mg/L), limit of quantization (LOQ = 0.5 mg/L), precision, stability. Run-to-run precision was determined by carrying out five replicate determinations for three acrylamide...
Autori: Anca Irina Burlacu, Rodica Cuciureanu, Patricia Fitterman, Michel Larroque
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25385

AbstractThe use of adhesives for floor covering have been deeply modified for longtime, by formulations of polymer-based products in aqueous dispersion as an alternative to organic solvents. These advances envisaged ways for obtaining nonpolluting products. Developing these adhesives required the parallel development of methods for monitoring and analyzing the emissions over time. This paper shows the results of some research devoted to identify the indoor presence of volatile organic compounds ...
Autori: Irina Ioniţă, Domnica Ciobanu, Monica Tulbure, Iulian Tanţoş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25388

AbstractThe study presents the processing possibilities for marc resulted as still residue from the distillation of fermented fruits in view to obtain a compacted solid fuel. Initial marc composition (carbon, hydrogen, nitrogen, sulphur and oxygen contents) determined by elemental analysis is evidenced, as well as technical characterisation (ash and moisture contents) and ash's qualitative composition, chemical characterisation of the liquid phase (pH, total phosphorus, acidity and conductivity)...
Autori: Daniela Simina Stefan, Anca-Ileana Penu, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25391

AbstractThe adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated. The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed at 30, 40 and 50 ?C. Thermodynamic potentials ?H, ?S, and ?G and isosteric heats of adsorption were calculated from experiment performed at different temperatures (30-50?C...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25393

Abstract Human exposure to heavy metals requires special surveillance measures on these elements in human body in order to detect a relation between heavy metal exposure and adverse health effects. The aim of this paper is focused on biomonitoring contamination with heavy metals in fish foodstuffs and in blood, and corroboration of contaminant levels with immunotoxicological effects on target groups of consumers. The final goal is to establish some recommendations on human diet with fish food...
Autori: Aurelia Meghea, Alina Murariu, Cristina Tanase, Eleonora Codorean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25398

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract Green buildings are considered a quick and effective approach to protect the environment by slowing down the consumption rate of primary energy resources and by reducing greenhouse gas emissions. In Europe, appraisals of properties should take into consideration this new feature of buildings by implementing data from Energy Performance Certificates (EPC) into real estate assessment. With this respect, a methodology is proposed and analyzed to be considered in the sales comparison rea...
Autori: Daniela Popescu, Emilia Cerna Mladin, Rodica Boazu, Sven Bienert
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25406

Abstract Fine particulate matter and ground-level ozone are now generally recognized as the most significant in terms of health impacts. This study shows that concentrations of particulate matter up to 10 microns in diameter (PM10) in Suceava city exceeded EU limits set to protect human health during 2004-2007. In order to design effective PM10 air quality management programmes, it is essential to identify the sources affecting PM10 background levels. For this, PM10 data series were analyzed ...
Autori: Lacramioara Gina Ursul, , Doina Carmen Manciuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25409

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract The etching of iron materials in sulphuric acid solutions allows the dissolution of the iron oxides with formation of iron sulphates. The relatively low solubility of the formed sulphates imposes their separation for avoiding the contamination of the etching bath, as well as for preventing the environmental pollution through the wastewater. Within the flow sheet of the processing of the hot or cold rolled steel, a stage of separation by crystallization of iron sulphate is foreseen. T...
Autori: Liliana Lazar, Ion Balasanian, Florin Bandrabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25415

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract The aim of this study is to investigate the electrochemical behavior of a three casting non-precious dental alloys: Vera PDI (Co-Cr based), Heraenium (Ni-Cr based) and NPG+2 (Cu-Al based) three test solutions: artificial saliva (AFNOR, pH = 8), acidified saliva (pH = 2.5) and fluoridated acidified saliva (1000 ppm F-, pH = 2.5). Open circuit potential (EOC) measurement; potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) are the electrochemical proce...
Autori: Daniel Mareci, Daniel Sutiman, Adrian Cailean, Julia Claudia Mirza Rosca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25435

Abstract The analysis over the underground water monitoring system and the collected data from survey drilling show that the underground water has an unsatisfactory quality due to some physical and chemical characteristics. Along with these, factors like the surface water pollution, the hydrodynamic exchange between surface and underground waters and the reintroduction in the agricultural activities of nitrates and phosphorus based fertilizers lowers, as well, the quality that it has been tal...
Autori: Ioan Crăciun, Catrinel-Raluca Giurma-Handley, Ion Giurma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25436

Abstract This study examined the effect of hexane concentration in the inlet gas stream on the treatment performance of a concentric tube internal loop airlift bioreactor with a 7 L capacity, inoculated with a strain of Pseudomonas aeruginosa. The experiments were conducted employing hexane-contaminated air, in 0.62, 1.26, 2.15 and 4.5 g/m3 concentrations at 29 ¹ 1°C. The 100% hydrocarbon removal was verified when effluents containing 0.62 and 1.26 g/m3 of hexane were employed. Under contin...
Autori: Fernando Jorge Santos Oliveira, Leonardo Vazquez, Francisca Pessoa de Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25437

Abstract Spent hydroprocessing catalysts from petroleum refining industries have been classified as hazardous wastes due to their content in heavy metal and persistent organic pollutants (POPs). The aim of our paper determine the polycyclic aromatic hydrocarbons (PAHs) residues contents in spent catalysts samples from four different units of the Romanian refinery Rompetrol Rafinare,Constanta: Hydrogen (H), Gas Desulfurization Sulfur Recovery (GDSR), Hydrofining Turbojet Kerosene (HTK) and Pet...
Autori: Camelia Draghici, , , Gabriela Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25449

Abstract Arsenic (As)-contaminated drinking water is a major problem around the world. The removal efficiency depends strongly on the size of Fe3O4 sorbents.Fe3O4 prepared in laboratory is more efficient in the removal of As and is also more easily recovered from column of magnetic separator than the commercial materials. This would be beneficial in a water treatment system because the As-contaminated Fe3O4 could be flushed from the column permitting reuse of the separator system. The dispers...
Autori: Ionel Balcu, Adina Segneanu, Marius Mirica, Mirela Iorga, Catalin Badea, Iuliana Firuta Fitigau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25456

Abstract In designing an efficient photovoltaic system, the meteorological data of the system location must be considered. Field data registered over years prove the importance of the implementation site characteristics in the design and optimal exploitation of a PV system, because wetting and atmospheric gaseous and particulate pollution can strongly distort the incident solar radiation. Thus, in addition to the efficiency of the solar module, the tracking efficiency, the clouds crossing fac...
Autori: Dorin Valentin Diaconescu, , Ioana Sinziana Hermenean, Maria Monica Vatasescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25464

Abstract The development of energy from renewable resources is a very important action in the reduction of CO2 emissions. Hydropower is a renewable source able to reduce the CO2 emissions by more than 67 million tons / year. The paper analyzes a small hydropower plant to be implemented in Brasov region, from the environmental point of view. The reduction in the CO2 emissions brought by the small hydro is estimated by taking into account an ex-ante emission factor, based on validated and regis...
Autori: Codruta Jaliu, Dorin Diaconescu, Mircea Neagoe, Radu Saulescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25466

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract Wood has been used as an engineering material because it is low in cost, renewable and strong and it requires low processing energy. Wood has many excellent properties that result from its exceptional combination of microstructural, ultrastructural and molecular features. The main drawback is its dimensional instability in the presence of moisture, which can affects also the biological stability. Wood is susceptible to degradation in a number of ways, including rot or decay, insect a...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25473

Abstract Herbs have been used as food and for medicinal purposes for centuries. In recent years, natural compounds such as phenolic acids, phenolic diterpenes and triterpenes, present in various plants, have been the subject of intense research due to their potential benefits for human health. It has been demonstrated that the antioxidant and radical scavenge activities are the main properties of these compounds. The main difficulties in using natural products as a source for pharmaceutical ...
Autori: Ruxanda Bodirlau, Iuliana Spiridon, Carmen Alice Teaca, Narcis Anghel, Maria Ichim, Svetlana Colceru , Alice Armatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25474

Abstract A crucial stage which makes the other directions of development of membrane processes is getting new membrane materials, to meet increasingly stringent of selectivity and productivity. Polyetheretherketone shows high stability against chemical and physical agents but is poorly soluble in most common solvents. Present studies on obtaining the support of the polyetheretherketone membranes were limited by: solubility of polyetheretherketone in concentrated sulfuric acid and fast speed a...
Autori: Mihaela Emanuela Craciun, Aurelia Cristina Nechifor, Florin Aldea, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25475

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract Biofuels represent a possibility for renewable resources conversion, storage and distribution. Today, diesel oil is commercialized only blended with biodiesel, and according to the 30/2003 Directive of the EU, 5.75% of the total fuels used in the transportation sector must be represented by biofuels by the end of 2010. Biodiesel can be produced from vegetable oils, animal fats and used oils. Viscosity is one of the most important characteristics of liquid fuels. The viscosity of liqu...
Autori: Irina Nita, Dan Mandalopol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25499

Abstract It is known that carbonhydrates are precursors of all bioactive substances we tried in thes paper work to do some investigation on these substances in the environmental area of Iasi. To observe the influence of some chemical mutagens substances on carbohydrates biosynthesis we conducted investigations on plant material (leaves) taken from the Calendula officinalis L species. We used this assay to examine the effects of the herbicide 2,4- dichlorophenoxyacetic acid (2,4-D), etidium br...
Autori: Constantin Leonte, Roxana Vatavu, Teodor Robu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25502

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract This paper presents preliminary results of a batch-scale study assessing the contribution of the multiple phenomena involved in siloxane removal in three-phase biomatrices. Batch scale experiments were undertaken in shaken flasks containing acclimatised culture medium, solid media and siloxane vapours (octamethylcylotetrasiloxane and decamethylcyclopentasiloxane, respectively) under anaerobic gas-phase conditions. Abiotic and biotic phenomena, considered to be possible siloxane remov...
Autori: Gabriela Soreanu, Patricia Falletta, Michel Beland, Kara Edmonson, Peter Seto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25510

Abstract Alignment of the manufacture technologies to the environment European directives requirements represents a modern approach of the environment issues considered as integrant part of the lasting development which will represent one of the connecting ways of the Romanian economy to the globalization process. In the present work a pertinent study is made regarding the harmonizing into the limits imposed by the environment European directives (Dir. 99/13/CE, Dir. 76/464/CEE and Dir. 2000/...
Autori: Stefan Velicu, Petrica Corabieru, Dumitru Zait, Anisoara Corabieru, Dan Dragos Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25518

Abstract A friendly technology with the environment which consists of the elaboration of carbon steels through specific proceedings to powder metallurgy has in view the contribution of methane gas in iron powders at the same time with sintering. This technology is advantageous from various points of view: the final product is a part which does not need afterward processing with solid waste result and therefore the specific energy consume is lower, the wear and corrosion behavior is similar to...
Autori: Olimpia Ghermec, Cristian Ghermec, Traian Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25526

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract This paper is the investigation concerning the removal, from surface water, of humic acids and of some cations (Cu2+, Al3+) on activated carbons AG-3, BAU, CASO-16 from individual solutions as well as from their mixtures both in static and dynamic conditions. The conclusions of the paper are that, when humic acids are adsorbed from micellar solutions, semiassociates are formed on the surface of activated carbon BAU (in its porous structure), while humic acids adsorption on activated ...
Autori: Tudor Lupascu, Mihail Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25539

Abstract Nowadays the global climate change is one of the most significant questions from environmental, social, political and economic point of views. Global warming caused by green house gases emitted into the air is a result of the human activities (Energy Revolution, 2005-2007). The majority of the industrial processes has significant impact to human life and deteriorates the natural environment. In this paper different technologies (three industrial technologies) will be dealt with spec...
Autori: Zsofia Kovacs, Orsolya Kakucs, Janos Lako, , Tamas Fulop, Tatiana Yuzhakova, , Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25545

Abstract Plasma is often called the fourth state of matter. It is distinct from other lower-energy states of matter, most commonly solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. Plasma technique may use any gas or gas mixture, within equipment limitations. Each gas or mixture of gases produces distinctive plasma, making possible a very diverse range of chemical environments. Besides the recombination mechanisms developed...
Autori: Marian I. Totolin, Ghiocel E. Ioanid, Iordana Neamtu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25550

Abstract Starting from the disadvantages of the polystyrene system – the most important being that they are not biodegradable and their life cycle is relatively small, up to fifteen years – there were conceived several structures for outside walls made of perforated bricks vertically disposed and filled with granular materials. In this manner the thermal resistance is improved knowing that in gaps bigger than twenty millimeters there appear convective streams which substantially decrease ...
Autori: Răzvan Giuşcă, Vladimir Corobceanu, Raluca Giusca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25551

Abstract White mustard (Sinapis white) is an annual plant of the Cruciferae family originating from the Mediterranean region and is cultivated in Europe and Asia, mainly for its seeds, but also for animal feed or crop rotation. White mustard seed is also an important source of vegetable oil that can be used as fuel. The chemical composition of mustard seed (Sinapis alba) includes glucosinolate (sinalbozida, sinapina free), essential oils, fatty oils (glycerides of oleic acid, linoleic, linole...
Autori: Camelia Ciubota-Rosie, Rodica Diaconescu, Irina Volf, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25561

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract When plants are exposed to heavy metals influence, the processes of growth inhibition, ion leakage of all membrane, distribution of pigment and even more death of plants are produced. The physiological and biochemical changes in germinating seedling and cultivation in plastic pots experiments of different plant species (maize, bean, oat, and spinach) were investigated under the influence of copper ions as stress agent. Differences between tolerances against copper excess in the case ...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25578

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract In this work, the behavior of n-hexane vapors in the adsorption-desorption cycles of non-functionalized polymeric adsorbents (MN 202 and MN 250) and granular activated carbon (AC 20) was studied. The adsorption experiments were performed in a fixed bed column, under dynamic conditions, at 30?C and atmospheric pressure. The inlet concentration of n-hexane in the air streams was 0.115 mg/cm3 (32500 ppm) and the space velocity was 2.75 s-1. Also, desorption experiments were performed in...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25584

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Commercial pure titanium (Cp-Ti) and titanium alloys are used on large scale in restorative dentistry due to their advantages as compared with other similar materials: chemical inertia, low density, high strength, high corrosion resistance in biological media and increased biocompatibility.The effect of fluoride and pH on the corrosion behaviour of Cp-Ti and a new Ti50Ta alloy were examined by open circuit potential (EOC) measurement, linear polarization, potentiodynamic polarization...
Autori: Daniel Mareci, Daniel Sutiman, Georgiana Ciurescu, Igor Creţescu, Romeo Chelariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25591

Abstract In the last decades there has been a rapid evolution of techniques for production of bleached pulp. Much of these processes have been environmentally driven. New techniques have been developed in order to replace chlorine-based reagents in producing bleached pulp. Reducing the environmental impact of pulp production can be attain by using non-pollutant bleaching reagents like oxygen and related compounds. This paper deals with present findings and general trends in environmentally-s...
Autori: Adrian Catalin Puitel, Alexandru Botar, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25592

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract In this work the method for the treatment of industrial waste waters effluents containing hexavalent chromium in three companies during process of treating metal surface with chromic acid is described. Industrial water polluted with hexavalent chromium is collected in separate sewage system. Polluted water is collected in precipitation tanks which are directly connected with neutralization reservoirs. The treatment process includes pre-neutralization by lime-milk, sedimentation, floc...
Autori: Igor Creţescu, Mirjana Cvijovic, Predrag Djurdjevic, Slavica Cvetkovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25596

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The former Arad Chemical Fertilizer Plant had an important polluting effect on environment and, although it was shut down in 1990, its environmental heritage still exists. The paper contains a short description of the former plant and its impact on the environment, mainly on the quality of water and soil and emphasizes the effects of polluting heritage that still exists. Today, one of the major problems on the platform of the former Fertilizer Plant is the existence of all concrete b...
Autori: Aurica Grec, Florin Dumescu, Ladislau Klein
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25599

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

Abstract Anaerobic digestion (AD) is a complex biological system which can be affected by several operational problems. Among them, biological foaming is one of the most difficult to deal with. It has many effects, such as causing gas pipe clogging and probe failures, and it can affect mixing devices, etc. Since the mechanisms involved in biological foaming development are not fully understood, it is not included in standard anaerobic digestion models. For this reason, a knowledge-based risk ...
Autori: Eric Latrille, Ignasi Rodriguez-Roda, Jean-Philippe Steyer, Joaquim Comas, Jordi Dalmau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25610

Abstract A method based on measuring substrate depletion rate was developed to evaluate the denitrifying activity of activated sludge in suspension and in biofilm form in anoxic serum flasks. The adapted activated sludge inoculum was grown as biofilm in an anoxic rotating biological contactor (RBC). Acetate was used as external carbon source to obtain a carbon to nitrogen ratio (C/N) of 2. The results showed that the specific activity of cells in biofilm form was higher than in planktonic for...
Autori: Elba Vivanco, Juan Carlos Ruiz, Paola Poirrier, Rolando Chamy, Yves Lesty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25617

Abstract The adsorption behavior of bael tree (BT) leaf powder for cadmium ions from aqueous solutions has been investigated as a function of appropriate equilibrium time, adsorbent dose, adsorbate concentrations and pH using a batch system. Studies showed that the pH of aqueous solutions affected cadmium removal as a result of the fact that removal efficiency increased with increasing solution pH. The maximum adsorption was 93.56% at solution pH equal to 6.0, contact time of 30 min and initi...
Autori: Ponnusamy Senthilkumar, Rangasamy Gayathri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25621

Abstract The aim of this study was to evaluate the capacity of certain bacterial and fungal strains - isolated from the dairy industry wastewater - to biodegrade the organic compounds such as casein, lactose and lactic acid similarly to those which determine the organic pollution. The strains able to rapidly biodegrade organic compounds were identified and screened for the inoculum preparation which is afterward tested for the aerobic biological treatment of the simulated dairy-processing was...
Autori: Gabriela Bahrim, George Ifrim, Marian Barbu, Mihaela Palela, Sergiu Caraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25625

Abstract Finding solutions to the waste problems generated by human activity represents a high concern of authorities and environment specialists for many years. Furthermore, energy conservation and reduction of the dependency from fossil fuels represents a top priority of governmental organizations at world level. The developments in alcohol industry have resulted in the increase of wastewaters which are highly polluted with organic substances, causing environmental pollution hazards. A wide...
Autori: Carmen Mateescu, Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25626

Abstract The olive mill wastewater (OMW) is a stable emulsion composed by water, olive pulp and residual oil. An approach for using this waste as a renewable resource is of greater interest. Several authors have been studding physicochemical treatment methods. However, the biological treatments allow not only the treatment, but also the effluent valorization, by producing several valuable products. This effluent is also a source of natural antioxidants and its extraction is economically attra...
Autori: Carina Pereira, Cristiana Goncalves, Isabel Belo, Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25635

? RESEARCH ON NaCl SALINE AEROSOLS I. NATURAL AND ARTIFICIAL SOURCES AND THEIR IMPLICATIONS ? DECISION SUPPORT MODELS FOR SOLID WASTE MANAGEMENT ? AN OVERVIEW ? POLICY AND STRATEGY FOR IMPROVING SUSTAINABLE SOCIAL DEVELOPMENT PROGRAMMES ? APPLICATION OF SHALLOW POND SYSTEM USING WATER HYACINTH FOR DOMESTIC WASTEWATER TREATMENT IN THE PRESENCE OF HIGH TOTAL DISSOLVED SOLIDS (TDS) AND HEAVY METAL SALTS ? TRENDS OF THE COMMUNITARIAN COHESION POLICIES AND ADVERTISING FOR EC...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25658

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

The removal efficiency of p-xylene from gas stream was experimentally investigated in a dielectric barrier discharge (DBD) reactor, which was combined with catalyst, MnO2/Al2O3 pellets, in the discharging and the afterglow area, respectively. The CO2 selectivity of the two kinds of structure was also discussed. The results showed that in both the situation, the synergetic removal efficiency of p-xylene by the DBD-catalyst hybrid system increased with increasing the discharge power and decreasing...
Autori: Hongxia Liu, Yun Liuhttp://www.ecozone.ro/reviste.php?RID=25674

The variation of acidity and the wet deposition fluxes of rainwater in Nanning City were analyzed based on the local acid rain monitoring data provided by environmental protection authorities from 1991 to 2004. The result shows that the annual value of pH is less than 5.6 in the past 14 years and the wet deposition has been getting more and more severe in Nanning. The ratio of SO42-/NO3 - has decreased. NO3 - has played an increasingly large role in acidity, though SO4 2- remains a key player. T...
Autori: Feng-qin Zheng, Guo-liang Liao, Hai-hong Huang, Yu-chun Mo, Shen-xian Wuhttp://www.ecozone.ro/reviste.php?RID=25678

A chlorpyrifos-degrading strain of Stenotrophomonas acidaminiphila, lux-β was chosen for research object, and the survival and chlorpyrifos-degrading activity of strain lux-β in the soil with different treatments have been investigated in this study, so as to provide technique support for monitoring the colonization and degrading activity of chlorpyrifos-degrading bacteria in natural environment. The result indicated that the quantity of lux-β in the soil rose first and decreased ...
Autori: Dao-Sheng Wang, Ri-Mao Hua, Xin-Yun Tang, Rui-Xue Li, Jun Zhang, Yun-Lu Wanghttp://www.ecozone.ro/reviste.php?RID=25684

Acidithiobacillus ferrooxidans plays an important role in the pyrite oxidation process and has been widely studied in order to determine the kinetics of the reactions, but the details of the oxidation processes on the surface of pyrite keeps poorly known. In this study, the bio-oxidation process of pyrite by Acidithiobacillus ferrooxidans was studied by comparing with abiotic oxidation by Fe3+. The attachment of Acidithiobacillus ferrooxidans on pyrite surface was found by using Scanning Electro...
Autori: Lei Jiang, Huiqun Yang, Yuruo Tao, Jinyan Yanghttp://www.ecozone.ro/reviste.php?RID=25686

Mass and energy balance calculation is the premise and key of the SCR (Selective Catalyst Reduction) DeNOx system design. However, the traditional calculation method is too complicated. In this paper, the author designed E-R data model for DeNOx system, simulated mass and energy transfer process, and developed visual calculation software based on VCL (visual component library) after studying the principle of SCR and data structure of DeNOx system. Comparing the ammonia demand and flue gas volume...
Autori: Yungui Du, Qirong Wu, Xiu Yang, Yu Yuhttp://www.ecozone.ro/reviste.php?RID=25688

It is a promising way for CO2 capture and sequestration by hydrates crystallization. In this study, the characteristics of CO2 hydrate formation are investigated in a small scale dynamic reactor under pressure conditions from 2.0-3.5 MPa and temperature varied between 0.5-4.0Â?C. The effects of supercooling degree and pressure on hydrates formation were discussed. Hydrates formation can be completely finished within 150 min and the final pressure-temperature points of system are just located on ...
Autori: Ni Liu, Xiaobo Xuan, Daoping Liu, Yingming Xiehttp://www.ecozone.ro/reviste.php?RID=25689

Hydrogen production via biomass steam gasification and partial oxidation is analyzed from exergy aspect. Based on cypress sawdust gasified from 800°C to 1200°C, the exergy value of H2 from steam gasification rises from 1410.80 kJ kg-1 to 7922.89 kJ kg-1, while that from partial oxidation increases from 988.30 kJ kg-1 to 3097.81 kJ kg-1. The exergy efficiency of H2 from biomass also increases for both steam gasification (6.42–36.08%) and partial oxidation (4.50–14.11%). However, the exergy ...
Autori: Yaning Zhang, Bingxi Li, Hongtao Li, Bo Zhang, Hui Liuhttp://www.ecozone.ro/reviste.php?RID=25693

The solubility and sorption behavior of naphthalene in the presence of dissolved organic acid was studied. The presence of dissolved organic acids at lower concentrations had only a little effect on naphthalene sorption. However, when the concentration exceeds a certain concentration, a significant inhibition was observed. Moreover, the inhibition enhanced with the increasing concentrations of dissolved organic acids. The change trend on solubility is similar to the sorption of naphthalene, that...
Autori: Jin hua Li, Bao xue Zhou, Qing Zheng, Wei min Caihttp://www.ecozone.ro/reviste.php?RID=25698

The paper analyses the removal efficiency and fluorescence spectroscopic characterization of landfill leachate dissolved organic matter (DOM) fractions in the combined stripping, fenton oxidation, sequence batch reactor, and coagulation process. The high contents of DOM of landfill leachate in each process unit were fractionated into HA, FA, and HyI. The result was the combined process availability for effective removal of DOM fractions. The removal rates for DOM, HA, FA and HyI were 91.9%, 97.1...
Autori: Zhiping Liu, Jin-song Guo, Fang Fanghttp://www.ecozone.ro/reviste.php?RID=25702

This paper presents a study of the numerical simulation applied for unsymmetrical dimethylhrazine (UDMH) gas dispersion. This study considers an assumed UDMH store conditions and provides important data regarding the relation between the concentration distribution of UDMH and dispersion distance from the source based on the computation fluid dynamic (CFD) software FLUENT. The simulation results show that the ventilation vent and distance of dispersion play an important role in the concentration ...
Autori: Zhiyong Huang, Guofeng Jin, Xuanjun Wanghttp://www.ecozone.ro/reviste.php?RID=25712

Semi-dry FGD with fabric filter has been extensively studied in recent years. After a series of industrial tests on 300MW boiler with semi-dry FGD and fabric filter, some operation notes were obtained. The test results show that CFB-FGD with fabric filter can be run longer and stable, and its actual performance is even higher than the design parameters. Moreover, the pressure drop of fabric filter after CFB-FGD is 600~800Pa (higher than normal). The fabric filter, which contributes to the desulf...
Autori: Tong Li, Han Yi, Han Xu, Reti Hai, Wang Wenxinghttp://www.ecozone.ro/reviste.php?RID=25716

Abstract:In spite of the large use of batteries throughout the years, both in photovoltaic systems and in other uses, there are still nocomprehensive analyses in ageing studies and, when they exist, statistics turn out to be limited. In this sense, this macro-grid is aunique experience, since the experiment is already composed of 1600 identical stand-alone photovoltaic systems and almost 10years of data taking on 10 minute interval for the main magnitudes.In this paper, it is proposed a method f...
Autori: Angeles López Agüera, Daniel Rey Rey, Iago Rodriguez Cabo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25718

Abstract:The textile industry uses high quantities of water which in many cases are disposed to the environment with inadequate treatment.In this work the effluents from the polyamide textile industry containing Bemacid Gelb, Bemacid Rot and Bemacid Blau weretreated by heterogeneous photodegradation. Treatment performances have been evaluated in terms of conductivity, turbidity, totaldissolved solids (TSD), chemical oxygen demand (COD), total organic carbon (TOC), biochemical oxygen demand (BOD5...
Autori: Luminita Andronic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25720

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:Energy mix used in "Solar House" is currently composed of about 50% renewable energy sources (geothermal energy) and 50%conventional sources of energy (mainly electricity from national grid and less than 10% natural gas). The geothermal energy isextracted by the mean of a ground coupled heat pump which assures the heating load of the "Solar House" and the preparation ofdomestic hot water. The peak load in heating period is covered by a natural gas boiler and the electricity to drive the...
Autori: Bogdan Burduhos, Ion Vişa, Macedon Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25756

Abstract:The increasing of energy consumption and fossil fuel emissions (especially CO2, SO2 and NOx) and the limitation of crude oilreserves, determined a growing trend toward renewable energy technologies, like solar, wind, geo-thermal energy and biomass forbiofuels.From all the renewable energies sources, biomass attracts more and more interest being a renewable resource with economicpotential, which can be found all over the world, with positive environmental properties due to neutral emissi...
Autori: Anca Sauciuc, Angela Potetz, Georg Schlaub, Gerald Weber, Hermann Hofbauer, Lucia Dumitrescu, Reinhard Rauch, Ziad Abosteif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25762

Abstract:A thermodynamic model for studying the overall efficiency and power output of a solar assembly using a Stirling engine ispresented. It is based on the application of the energy and exergy balance equations to the system components. The results of theproposed model are generated as a function of solar incident radiation whose analytical estimation is presented. The numericalapplication is set for a solar assembly operating in Bucharest, composed by a parabolic dish mirror, a plane receiv...
Autori: Adina Gheorghian, Alexandru Dobrovicescu, Camelia Stanciu, Dorin Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25764

Abstract:Our research was focused on developing some new procedures to reduce the biodegradable wastes by composting. The aim of thisstudy was to obtain and asses at laboratory scale the maturity of three compost samples of different proportion of vegetable waste,beech sawdust and sewage sludge by analyzing their FT-IR spectra and C/N ratio. The composting process was monitored by testsperformed weekly on the three samples in order to investigate the physical parameters (pH and electroconductivi...
Autori: Anca Sauciuc, Claudia Zaha, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25772

Abnstract:In recent years, solar receivers have been employed in several applications where high temperature fluids are involved, such aspower plants and solar thermal reactor. The possible presence of high temperature gradients could determine reduced receiverefficiency and a short life of the material. Thermal and fluid dynamic analysis of the receiver allows to highlight possible presenceof temperature gradients and to evaluate their values and the more critical zone of the material. Compress...
Autori: Alina Adriana Minea, Oronzio Manca, Salvatore Tamburrino, Sergio Nardini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25779

Abstract:One of the basic conditions for the operation of nuclear installations is security operation. The complexity of the phenomena inheavy water detritiation plants, determine the use of advanced equipment for technological processes involved. Pilot Plant forTritium and Deuterium Separation developed the cryogenic technology of tritium separation from tritiated heavy water. Theprocess is based on an catalyzed isotopic exchange module, where the tritium is extracted from tritiated heavy water...
Autori: Sorin Gherghinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25787

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Titanium metal and its alloys have been widely used as implants under load-bearing conditions due to their biocompatibility, excellent corrosion resistance and lightness, but their inability to bond to living bone is a setback. The experiments outlined here investigated hydroxyapatite (HA) coating on Ti metal implants, used to enhance their bioactive properties. In this study, specimens of commercially pure titanium (c.p. Ti) and Ti-6Al-4V were etched in either H3PO4 or HCl, and subsequ...
Autori: Chao-Lun Fu, Hsueh-Chuan Hsu, Shih-Ching Wu, Shih-Kuang Hsu, Wen-Fu Ho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25795

Abstract: In this study, decolorization and degradation of aqueous nickel phthalocyanine reactive dye solutions was comparatively studied by electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton processes. In the electrocoagulation process with aluminum electrodes the colored aqueous solutions containing 100 mg/L nickel phthalocyanine and 6 g/L NaCl were treated at initial pH 7.5 and applied current densities of 5, 10 and 20 mA/cm2, where fast and 100% decolori...
Autori: Achilleas Christoforidis, Dimitrios Marmanis, Evgenia Valsamidou, Konstantinos Dermentzis, Konstantinos Ouzounis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25804

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

The relationships between economic growth, environmental sustainability and energy are of great interest among researchers and policy makers. One of the theoretical conclusions that have received most attention is the convergence of the per capita carbon emission levels. But empirical results of theoretical growth models that include the environmental variable or estimated Environmental Kuznets Curve are not conclusive. This paper uses a multivariate state-space model to examine the process of c...
Autori: Gema Fernández-Avilés, Jose Mondejar-Jimenez, Josep Illa, Manuel Vargas-Vargas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25823

Freshwater is a fundamental natural resource. It is essential for sustaining life, supports the development of ecosystems and economies and is also used as a recreational resource. Therefore, its appropriate management is critical if we want to guarantee the long-term sustainability of the supply. The aim of this paper is to analyze the main aspects influencing water saving in Spanish households. To accomplish this goal, we start by developing a theoretical analysis of those aspects that affect ...
Autori: Juan Carlos Gázquez-Abad, Juan-Antonio Mondejar-Jimenez, Manuel Vargas-Vargas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25824

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

This paper presents original studies about the influence of mineral and/or organic fertilization on the minerals contents (P, Na, K, Ca, Mg, Fe, Mn, Zn, Cu, Ni and Pb) in leguminous plants from permanent grassland situated in a hill area of Banat County. Determination of minerals in grassland is very important both for the nutritional or toxic effects of these elements and their compounds, in the plants, animals and environment. Phosphorous was analyzed colorimetric and all the others metals hav...
Autori: Alexandru Moisuc, Iosif Gergen, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25858

This paper is part of LCA studies performed in the frame of FP7 project �Recovered Paper Sorting by Innovative Technologies - SORT IT�. It analysis the results obtained by Life Cycle Impact Assessment (LCIA) of the reference case for recycled packaging paper manufacturing (current sorting technology), which will constitute a comparison base for new sorting technology developed in SORT IT project. The main stages considered in the life cycle were: recovered paper (RP) transport from collectio...
Autori: Alina Iosip, Antonio Dobon, Elena Bobu, Mercedes Hortal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25860

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

Marine species (n=36) available in a supermarket of Cluj-Napoca city, Romania were collected and analyzed for the levels of heavy metals (Cr, Cu, Zn, Cd, Pb, Hg) and As, polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and analogous, hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB). The collection included samples from twelve fish groups (sardine, tuna, herring, pangasius, marbled rockcod, hake, shrimp, pink shrimp, lo...
Autori: Adriana Gog, Claudiu Tanaselia, Ioan Ştefan Groza, Marin Senila, Mirela Miclean, Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25863

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

The most important argument of this experiment was to demonstrate an increased content of active principles under the influence of some substances (considered in the literature as mutagene), when used in low concentration, do not affect the environment. The purpose of this study was the selection of some treatment variants, which, during the experimentations show the same biosynthetic potential, stabilized or increased. The substances used in the experiment were ethidium bromide at the concentra...
Autori: Constantin Leonte, Marius Zaharia, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25867

In this study, we have tested the possibility of utilization of three types of natural low-cost sorbents: (Sphagnum moss peat, natural moss peat and alkaline treated moss peat) for the active biomonitoring of air quality from Căliman National Park area (Dorna Basin), during of two months (September – October 2010). The concentrations of some heavy metals (Pb, Cd, Cu, Mn and Fe) in the sorbent samples were used as an indicator of the level of air pollution in the studied region. After expo...
Autori: Iulian-Ovidiu Sandu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25868

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

Herbicides industry is a large consumer of water, as well as a major wastewater generator, its effluents contain priority organic pollutants in very high concentrations which have severe effects on human health and on the environment due to their toxicity and bio-recalcitrant nature, persistence in the environment and bioaccumulation. A vast number of herbicides and other priority organic pollutants have been found in wastewater effluents, surface water, and drinking water around the world. The ...
Autori: Bianca Weinberg,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25874

Fluorescence spectroscopy is a promising approach to the characterization of natural aquatic components and organic pollutants, due to its rapid analysis and high sensitivity. Petroleum products had been studied, using fluorescence technique, in numerous occasions, as seawater and soil contaminant or as raw sample. Nevertheless, no complex assessment has been made on fluorescence real–time spectra of freshwater diesel oil contamination. This study reports a 5–days experiment on an urban rive...
Autori: Elfrida M. Carstea, Gabriela Pavelescu, Luminita Ghervase, Marina Tautan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25882

2This study shows the dyeing behaviour and impact over the wastewaters quality resulted from dyeing wool fibres, of a new synthesized premetalated dyes, derived from new acid dye, sodium(E)-2 –((1-amino-4-sulphonatonaphthalen-2-yl)diazenyl)-6- methoxybenzo[d]thiazole- 5 or 7 –sulphonate, as a result of interaction with Ni(II) and Zn(II) ions. In order to characterize the complexed dyes they were studied in both phase: solution and solid phase. The dyeing performances assessment and the envir...
Autori: Ion Sandu, Laura Chirila, Maria Marcela Tarlea, Romen Butnaru, Viorica Vasilache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25886

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

Two experimental periods have been undertaken to investigate the biodegradability of sewage streams (mainly regarding the organic substances) produced by a gas cartridge production, filling and distribution company. A sequencing batch reactor (SBR) was used for the laboratory examinations launched with municipal sewage sludge with a concentration of approx. 3 g MLSS/L. The various conditions in the reactors followed each other cyclically (fill, anoxic, aerobic, settle, draw) three times a day. T...
Autori: Bence Fazekas, Karoly Reich, Krisztian Varga, Viktoria Pitas, Viola Somogyi, Zsuzsanna Banyai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25902

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

AbstractWastewater from butyl rubber production is causing an increasing environmental problem due to its large quantity and complexquality. In this paper, two types of wastewaters generated from rubber synthesis, i.e. alkaline wastewater (AW) and cleaning andflushing wastewater (CFW), were investigated. Coagulation and flocculation were firstly applied to remove suspended solids(SS) from the AW. By single factor experiment, the optimum operational conditions were obtained as pH 8, PAC dosage 40...
Autori: Lujun Chen, Rui Liu, Wei Li, Wei Zheng, Yan Zhang, Ying Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25950

AbstractThe detection of environmental pollutants has challenged conventional chemical analysis for the rapid estimation of thebioavailability and toxicity of the contamination impact on human health and ecosystems. Magnetic nanoparticles (MNPs)functionalization as bioreporters can enhance the ability for biosensing in complex contaminated samples such as soils, and theimmobilization of bioreporters will promote the detection of gas and online monitoring. In this study, Acinetobacter baylyi ADP1...
Autori: Aizhong Ding, Cheng Chen, Dayi Zhang, Musen Duan, Steven F. Thornton, Wei E. Huang, Yanjun Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25952

Geochemical cycling of reduced inorganic sulfur in sediments may affect water quality. This study investigated the reducedinorganic sulfur distribution and environmental behaviour in superficial sediments in different watersheds and coastal zones inBohai Bay, China. Acid volatile sulfur (AVS), chromium (II)-reducible sulfur (CRS) and elemental sulfur (ES) distributed insurface sediment were quantified. Total organic carbon and total nitrogen were presented in higher concentrations in the fluvial...
Autori: Robert Mortimer, Simon Bottrell, Wenjing Shi, Yanqing Sheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25959

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

“The Exploratory Workshop „Progress inEnvironmental Engineering, Biotechnology andManagement in The Frame of Knowledge-BasedSustainable Economy” took place in the contextwhen worldwide research shows that the currentindustrial system supports a population that useresources and generates waste, consuming the Earth'ssupply, but who’s biocapacity is far outweighed bythe increased demand of products for a developmentsystem that often works on unsustainable bases.Today’s challenge is the integration ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25969

AbstractIn this paper, the background of bioethanol as an alternative fuel to conventional one is analyzed with the aim of examining theefficiency of biomass-to-fuel conversion by poly-generation taking into account the energy integration approach for a completerecovery of the process’ exergy potential.Based on literature data it is underlined that exergy analysis represents a primary tool to analyze the ethanol production processfrom an integrated point of view....
Autori: Anton Friedl, Maria Gavrilescu, Petronela Cozma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25974

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractThe huge emission of greenhouse gases from fossil-fuelled power plants is emphasizing the need for efficient Carbon Captureand Storage (CCS) technologies. The biomimetic CO2 absorption in aqueous solutions has been recently investigated as apromising innovative alternative for post-combustion CCS. The carbonic anhydrase (CA) - a broad group of ubiquitous enzymes– may catalyse the CO2 hydration reaction and then to promote CO2 absorption rate into aqueous solutions. Nevertheless theresear...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Maria Elena Russo, Piero Salatino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25976

AbstractIn this paper integrated network of continuous reactors for the decontamination of gaseous flows in heterogeneouscatalytic gas-liquid-solid – also applicable for bioremediation systems is investigated. For this purpose, duringprocess integration we have identified strategies to develop an optimal system for a variety of well-definedrequirements and to discover ways to ensure cost efficiency to achieve the requirements of sustainable industry in theframe of knowledge-based sustainable eco...
Autori: Maria Gavrilescu, Oana Marlena Penciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25977

AbstractMethane landfill emissions are a general concern and should be estimated for taking the proper measures for global warmingmitigation. The European legislation is supporting all techniques that avoid, reduce or treat CH4 emissions. One of the maindirections is reducing the quantities of biodegradable waste disposed in landfills. The efforts for GHG emissions reduction andalso compliance with European legislation in the field of waste management does not mean only putting in place some sta...
Autori: Liliana Bobirica, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25984

AbstractEU policy on waste management stresses the importance of an integrated approach to waste management, which includesconstruction of waste disposal facilities with prevention of waste generation and recycling, in line with management hierarchy:prevention of waste and its negative impacts; recovery of waste through recycling, reuse, safe final disposal of waste where thereis no possibility of recovery.This paper address the issue of municipal waste management and the impacts generated into ...
Autori: Ana-Maria Şchiopu, Cristina Ghinea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25987

AbstractIn this paper we describe a wireless system, including smart sensing nodes for indoor air quality and unobtrusive cardiorespiratorymonitoring. The sensing nodes include a set of solid state gas sensors, sensors for temperature and relative humidity, amicrowave Doppler radar sensor for cardio-respiratory function, and appropriate conditioning circuits expressed by active filtersand amplifiers. The analog signals provided by the signal conditioning circuits is applied to a data acquisition...
Autori: Gabriela Postolache, Octavian Postolache, Pedro Silva Girăo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26007

AbstractGastro-Esophageal Reflux Disease (GERD) seems to be frequently associated with laryngeal lesions and the occurrence ofdisphonia. The aim of the study was to evaluate the environmental factors associated with dysphonia in professional voice users.We prospective studied 50 intense voice users’ subjects (actors, singers, teachers, priests) with dysphonia in order to identify theenvironmental factors which may be involved in the alteration of voice. We demonstrated the importance of the risk...
Autori: Anca Ciubotaru, Bogdan Mihail Cobzeanu, Mihail Dan Cobzeanu, Monica Voineag, Octavian Dragos Palade, Vasile Liviu Drug
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26009

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

AbstractThe stability of soil aggregates is an indicator of soil structure. Soil acidity affects soil structure stability. Soil acidity has twocomponents: active acidity and exchangeable acidity. In natural conditions, each soil type has a certain level of acidity, which isgiven by its composition, natural vegetation, the chemical composition of precipitations and other factors that cause changes overtime in soil pH. Acidic soils are characterized by physical, chemical and biological properties ...
Autori: Dorin Cotiusca Zauca, , Lucian Vasile Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26064

AbstractTraditionally, sanitary papers are obtained from virgin cellulosic fibers. Because the production of virgin fibers requires largequantity of wood it is an unsustainable process. In addition, virgin fiber pulp is expensive and deficient, being unattractive forpaper producers. Using of virgin fiber is a waste, because sanitary papers cannot be recovered. Due to the fact that the price ofsanitary papers must be as low as possible, the paper mills focused on the use of recovered fiber as raw...
Autori: Dan Gavrilescu, Iftimi Viorel, Roxana Vlase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26067

AbstractThis paper describes preliminary tests carried out in treatment plants serving two different pig farms in Northern Italy, in order toassess the feasibility of implementing biological sulphur removal from biogas produced by anaerobic digestion processes. Thisnormally consists of mixture of CH4, CO2, and other gases; in the presence of sulphur, H2S is also formed, which must beremoved prior to the gas use in thermal engines, to avoid corrosion phenomena. Sulphur removal in the plants consi...
Autori: Andrea G. Capodaglio, Arianna Callegari, Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26074

AbstractThe ozone oxidation and disinfection stages constitute important technological phases in the modern systems of water treatment,both as unitary stages as integrated ones into systems that use advanced oxidation processes (AOP). More than half of thewater/ozone contact systems used nowadays in the water treatment plants are based on systems of contact in the bubble column.This work here aims at experimentally analysing, in terms of scale, a water-ozone contact system in the bubble column a...
Autori: Sorin Claudiu Ulinici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26088

AbstractThis paper presents the results of the research analyses and laboratory studies, aiming to develop design guidelines and suitabletechnologies for the construction of durable and environmental friendly rigid pavements by using recycled cement concrete,resulted from various demolition works. Various recycling principles and technologies, specific laboratory methods of improvedtechnical solutions to enhance wear coefficients, density homogeneity, mixture contamination and water absorption o...
Autori: Marius Muscalu
ISSN: 1843 - 3707Abstract This paper presents the results of the research analyses and laboratory studies, aiming to develop design guidelines and suitable technologies for the construction of durable and environmental friendly rigid pavements by using recycled
http://www.ecozone.ro/reviste.php?RID=26098

Mother Earth Investments AG, is actively working onthe development 2nd generation bioenergy feedstocks.In this book, Mr. Jansen generously shares hisknowledge in the field, in particular, regarding thechallenges and opportunities in development ofbiomass-derived fuels. This essential guide toinvesting in bioenergy commodities details secondgeneration biofuels from a scientific, technical andeconomic perspective, and discusses their globalenvironmental, political and financial impact.The book is ...
Autori: Roland A. Jansen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26100

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Known as the most important byproducts of water disinfection with chlorigen chemicals, trihalomethanes (THMs) are incriminated in causing severe effects upon human health. The exposure pathways that can lead to potentially significant uptake of THMs include for adults ingestion of tap water and inhalation of THMs in vapor phase resulting from bathing, showering and washing. The purpose of this paper is the exposure assessment to THMs through ingestion, inhalation and derma...
Autori: Anca Elena Gurzău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26110

Abstract Poly(hydroxybutyrate) (PHB) is a biodegradable thermoplastic polyester with very high potential for industrial applications. The properties could be improved by mixing with another polymer, natural or synthetic, such as poly(vinyl alcohol) (PVA). The resulting polymer blends are potentially able to achieve the desired performance for different applications. Biodegradation modifies mechanical, physical and chemical properties of a given material. PHB are degraded by diverse...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26111

Abstract This study focuses on the local scale behavior of SO2 emissions resulting from lignite-combustion thermal power plants. The investigations aimed at monitoring the SO2 emissions and imissions over a two week period in September 2010. One of the largest power plants from Eastern Europe was chosen for monitoring using different optoelectronic techniques. Rovinari power plant (44o54’45”N – 23o09’44”E) is one of the largest electricity suppliers of Romania, having 4 groups of 3...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26113

Abstract Nowadays, all over the world, the car transport sector is one of the main factors responsible for the Greenhouse Gas Emissions. The current systems of emission taxation do not take into consideration the distance travelled by cars; therefore, they are not fully compliant with the “polluter pays” principle. In addition to the produced inequality, these systems do not encourage the reduction of the distances travelled annually (with possible favorable effects on pollution an...
Autori: Cristian-Mihai Dragos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26120

Abstract The aim of this paper is to analyze how local and atmospheric conditions influence pollutants’ distribution. Two different sites in Romania were chosen for measurement campaigns: Surlari (44° 34', 26° 19') located into a forest and near a lake, and a suburban area, Magurele (44° 21', 26° 2'), where the anthropogenic activities dominate. The same equipments for measurements of surface ozone, CO, NO2, NO and PM10 were used at the two sites. The measurements were performed in...
Autori: Sabina Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26126

Abstract This paper presents a research method for the exploratory analysis of non-compliant municipal waste landfills by determining the gas composition of emissions. The proposed method has the following stages: establishing municipal landfill surface contour by topographic measurements; setting measuring points on the deposit surface; setting the number of points needed and their spatial coordinate; field location of points for making exploratory measurements; making and recordi...
Autori: Michaela Bianca Vac Soporan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26127

Abstract This paper presents a proposal for measurements and interpretation of gaseous emissions from the municipal landfills, especially for non-compliant sites. Based on the measurements made on the Pata Rat landfill, Cluj-Napoca, a methodology for interpreting the results is presented, in order to assess current energy potential of the deposit. Measurements are the main basis for determining the energy potential of the deposit. By applying the methodology for determining the ene...
Autori: Michaela Bianca Vac Soporan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26128

Abstract Our researches have focused primarily on variations of different biophysical and biochemical effects on vegetal and animal material at macro, micro, and ultra-micro scale resulted from changes in environmental condition. Growth and spectral parameters of rapeseed seedlings from seeds exposed to UVA-VIS radiation with a high pressure lamp which emits incoherent continuously radiation for different time periods were examined 14 days after germination. These studied parameter...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26138

Abstract One of the causes of climate change is the accumulation of greenhouse gases (GHGs). Methane (CH4) is one of the greenhouse gases, with an ability to trap heat in Earth's atmosphere 21 times greater than carbon dioxide (CO2) per unit mass and in the same period of time. Because the lifetime of methane in the atmosphere is relatively short, it could be kept under control. Wastewater treatment plants (WWTPs) are anthropogenic sources of CH4 emissions. Anaerobic digestion of t...
Autori: Doru Lucian Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26139

Abstract The paper presents several aspects regarding the optimization of the operation for a mixed cycle gas turbine, Titan 130S type, installed at S.C. CET S.A. Bacau, during the warm season. The optimization entails the partial loads operation and has been done using the multicriterial analysis, taking into consideration the operation restrictions required for this type of gas turbine. The criteria that regard this analysis are: thermal energy requirements, the global efficiency...
Autori: Marius-Ion Stanila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26145

Abstract Volcanic hazard is ignored in natural hazard studies in Romania because no active volcano is known on its territory. However, the 2010 eruption of Eyjafjallajökull volcano in Iceland and its consequences on air traffic safety across Europe and the whole northern hemisphere dramatically demonstrated that volcanic hazard in a certain area, such as a country, is not necessarily related to the presence of active volcanoes in the same territory. Therefore, target-focused approa...
Autori: Alexandru Szakács
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26146

Abstract Biogas can be used as a renewable and green energy source by upgrading to natural gas. Water scrubbing, which is one of the most widely-applied upgrading technologies, involves an accurate knowledge of the solubility of the main biogas components in water, which is essential to the design and optimization of the biogas upgrading process. In this work, we use several thermodynamic models available in the Aspen Plus software modeling environment to calculate the solubilit...
Autori: Petronela Cozma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26148

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractThe solidified waste drilling mud has been landfilled into slurry ponds with impermeable layer at oil & gas field since 1990s. Thisarticle aims to elucidate the heavy metal contaminations from landfill ponds at semiarid region. The heavy metal concentration inthe waste and its potential mobility based on its binding forms was studied. Furthermore, the blocking effect of impermeable layer was used to elaborate the environmental effects of heavy metals. From the analysis, Cr was found ...
Autori: Yun Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26171

AbstractMethane production and concentration from six cells were investigated in two landfills in China. Long-term monitoring tests wereconducted to evaluate the methane recovery efficiency of active wells. Results showed that the recovery efficiency of a wellsdistribution simulation method was 75.6% to 83.5%, which was much higher than 50.1% to 53.6% when considering the EPAmethod in the EST (Ecological Sludge Evapotranspiration Technology) cover structure. The recovery efficiency of methane in...
Autori: Qiang Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26174

AbstractA wet flue gas desulfurization (WFGD) system adopting electrostatically-assited twin-fluid atomization injector was presented.Spatial distributions of the droplet sizes, velocity for different voltages were measured using limewater and SO2 removalefficiency for different voltages and Ca/S ratios were tested using limewater drops. The physical and chemical improvementmechanisms were analyzed using spray characteristics and double film theory. The analysis showed that electrostatically-ass...
Autori: Zhentao Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26175

AbstractElectrostatic Precipitator draws many researches on flue gas treatment technology and very few researches on its structural design. The conventional structural design of electrostatic precipitator casing uses stiffened flat sheet as wallboard which consumes a great amount of steel. Consequently, a new structural idea was explored to optimize the conventional design which applies profiled steel sheet and locates wall beam and wall column. Optimization codes were programmed to select the o...
Autori: Dengfeng Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26178

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractGlobal energy demand is following a strong upward trend. As highlighted by the latest analyses the overall black coal resourcesare able to satisfy human needs for more than 200 years including the particular case of intensive exploitation. According to theInternational Energy Agency (IEA) renewable energy and natural gas resources have encouraging perspectives for furtherexpansion. Even so coal will continue to cover almost a quarter of primary energy resources needs. The EU is currently...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26199

AbstractThe transport of hazardous substances is an essential economic activity because it represents a quite relevant percentage of thetotal goods transportation. The risk associated to such an activity is fundamentally related to the possibility of an accidenttriggering that may cause negative environmental and public health consequences. A recent example is the Viareggio accident(2009), which involved the blast of tank wagons containing liquefied petroleum gas (LPG) and caused more than thirt...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26200

AbstractExcess biomass produced in the degradation processes of organic pollutants is creating environmental challenges for wastewatertreatment plants. The A+OSA system, a modification of the anoxic / oxic (A/O) process via insertion of a sludge holding tankinto a sludge return line, has been demonstrated to be capable of achieving simultaneous nutrient removal and sludge reduction.Here we report the results of an investigation aimed at evaluating the impact of the sludge holding tank on the bio...
Autori: Li Jia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26207

AbstractThe dominant litter samples Pinus sylvestris L. needle litter and Acer platanoides L. leaf litter were collected in the coniferousmixed forest located at 54ş43‘ N 25ş19‘ E (Vilnius, Lithuania) in April 2010. Different heating temperatures (150, 250, 350, 450and 550şC) and 2 hour heating duration were used to produce ashes. The selected heating temperatures affected mass loss, colour, pH, electrical conductivity (EC), C/N ratio, nutrient concentrations of the ash. The darkness of Munsell ...
Autori: Jolita Dūdaitė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26208

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractIn this study, as part of developing a green recycling process of spent lead-acid battery that can avoid both smelting and electrowinning, leaching agent citric acid and other additives (such as sodium citrate and hydrogen peroxide) in aqueous media were reacted with spent lead-acid battery paste. PbO, PbO2 and PbSO4, which are the three main components in a spent lead-acid battery paste, were leached to form lead citrate precursor which was crystallized and then separated from the solut...
Autori: Xinfeng Zhu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26215

AbstractGlobal warming is happening due to increasing level of carbon dioxide and other greenhouse gases into the atmosphere. In orderto reduce this rising level of CO2 emitted by human activities, carbon capture and storage technologies are being developed.The present paper investigates and compares, from a techno-economical point of view, two of the most used conceptual methods(post- and pre- combustion) for CO2 capture generated from the fossil fuel power generation sector. For post-combustio...
Autori: Anamaria Padurean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26217

AbstractDespite the Moderate Resolution Imaging Spectrometer (MODIS/Aqua) presently collects data on operational basis, evaluationof its biogeochemical products from standard bio-optical algorithms is scare especially in Arctic waters. The present study isaimed to evaluate several MODIS/Aqua bio-optical algorithms and MODIS/Aqua remote sensing reflectance (Rrs) products inKongsfjorden waters on the western side of Svalbard, Arctic. Data sets consisting of in-situ measurements of radiometric quan...
Autori: Palanisamy Shanmugam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26220

AbstractIn an urban environment, visibility strongly reflects human safety and welfare. Generally, visibility is dependent on particlescattering and absorption. The former is influenced by light wavelength, atmospheric gaseous species and particle characteristics,especially number and size distribution. Therefore, it is necessary to establish the relationship between visibility and particlecharacteristics. Furthermore, it is important to understand the formation mechanism of secondary aerosols. ...
Autori: Chih-Ming Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26221

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractIn this article, hydrodynamic parameters and overall Oxygen mass transfer coefficient of petroleum based micro-emulsions in anairlift reactor were investigated. Four different petroleum-in-water micro-emulsion systems containing kerosene, heavy naphtha,light naphtha and diesel as oil based were used with concentrations of 3% and 7 % (v/v). The experimental data were supportedby simulation results obtained from the Computational Fluid Dynamics (CFD) method. The CFD was properly able to si...
Autori: Mostafa Keshavarz Moraveji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26234

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe vortex flame concept of combustion has been well known to produce low levels of NOx. This feature qualifies it to be usedin industrial processes and in power generation to comply with the environmental regulations concerning nitrogen oxideemissions. An asymmetric vortex flame combustor has been recently proposed by the authors. The present article reports thelevels of NOx emissions of such combustor for the first time. An experimental platform designed and developed to examine theNOx...
Autori: Khalid M. Saqr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26245

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractA bench-scale anaerobic bioreactor for the anaerobic treatment of textile wastewater using anaerobic sludge was experimented.The Top and bottom of hybrid bioreactor were functioned with UAF (Up Flow Anaerobic Filter) and UASB (Up Flow AnaerobicSludge Blanket), respectively. The effect of organic loading rate (OLR) and hydraulic retention time (HRT) on treatment oforganic matters in the textile wastewater was investigated. The maximum removal of chemical oxygen demand (COD) and colorwas 9...
Autori: Reza Katal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26255

AbstractThis study is focused on simulating and optimizing design and configuration of anaerobic baffled reactor (ABR) by means ofartificial neural network (ANN). This approach is aimed to assess an efficient ABR performance in various operational conditionstreating municipal wastewater. For this purpose, to analyze comprehensively on a base of experimental data, the system isoperated in two pilots of 48 liters net volume made of 8 compartments. In 7 months, more than 130 sets of data are obtain...
Autori: Gagik Badalians Gholikandi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26260

AbstractThe inactivation of Escherichia coli was investigated with two types of underwater electrical discharge systems such as pulsedelectrical discharge (PED) and dielectric barrier discharge (DBD). The DBD system consisted of a quartz tube and a coaxialdischarging electrode, which was submerged in biologically contaminated water. In the underwater PED system, the electricaldischarge starting from the tip of submerged tubular discharging electrode propagated downward and the direction of worki...
Autori: Sang Don Kim
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26263

AbstractThe main objective of this study is to investigate the utilization potential of oil well-derived drilling waste (DW) in the firedshale-brick production. Different mixtures were suggested for the experimental work with the DW content varying from 20% to40%. The prepared briquettes from different mixture were fired at a temperature ranging from 950°C to 1050°C for 1 h, with aheating rate of 2~3°C /min. Water absorption, apparent porosity, bulk density, weight loss by ignition, firing shrin...
Autori: XiangGuo Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26269

AbstractBased on principles of feeding solid waste into vertical boreholes in fully mechanized coal mining and backfilling technology,the literature established a trajectory model of particles in gas-solid two-phase flow for the sake of reducing the damage tostorage silo underground done by enormous impulsive force generated by falling solid waste. In addition, dynamical analysismethod in gas-solid two-phase flow field was adopted herein to study the solid particles’ force characteristics and th...
Autori: Nan Zhou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26271

AbstractA novel RHA/PFA/CFA sorbent was developed by sol-gel method using three types of ashes, i.e. rice husk ash (RHA), palm oilfuel ash (PFA) and coal fly ash. From surface analysis of selected RHA/PFA/CFA sorbents, the spent sorbent had more compactstructures covered by irregular rough surface and the specific structure of raw RHA, PFA, and CFA were no longer visible. Inaddition, lower specific surface area was obtained for spent RHA/PFA/CFA sorbent. Batch studies were performed to evaluatet...
Autori: Irvan Dahlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26272

AbstractOceans have been proved to be an important resource due to their abundant reserves in oil and gas. However, because of the extent of oil exploration and development in recent years, the marine ecological environment has been increasingly affected. At present, the control and treatment of environmental pollution from offshore drilling both at home and abroad have focused on end-treatment after problems have already emerged. Nevertheless, preventative measures and appropriate control links...
Autori: Guancheng Jiang, Guangquan Liu, Hao Deng, Rongsha Wang, Shuixiang Xie, Yu Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26279

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe paper compares the electrocoagulation performance during the removal of Acid Brown 14, Acid Yellow 17, Acid Blue 113and Acid Black 172 dyes from aqueous solutions. For this purpose, pH changes and effectiveness of main parameters includinginitial dye concentrations and current densities for the selected dyes were examined. In addition, effluent turbidity, energyconsumption and amounts of released aluminum were also investigated. The present work shows that Acid Yellow 17 removaleffic...
Autori: Mahsa Taheri, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26310

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractA septic tank is an essential part of the decentralized wastewater management system. The aim of the experiment described inthis paper was to evaluate the impact of the method of sampling and hydraulic retention time (HRT) on the performance of acircular three chamber septic tank and to design a septic tank for a single household with four residents and wastewater flowrateof 0.6 m3/d. It was found out that the difference between suspended solids (SS) and chemical oxygen demand (COD) remo...
Autori: Ala Kirjanova, Mindaugas Rimeika, Regimantas Dauknys
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26329

AbstractGlobal climate change affects the temperature and precipitation. These changes have serious impacts on the availability of waterresources on regional basis. Turkey, being located in the Mediterranean Basin, is predicted to be severely affected by the adverseeffects of global climate change, particularly in terms of water resources. It is important to figure out the situation of the countryin terms of water scarcity induced by anthropogenic climate change in order to provide rational meas...
Autori: Özgür Aktaş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26342

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractThis paper discussed the potential ecological risk, homologous relativity and spatial distribution of heavy metals in the waterlevel-fluctuating zone (WLFZ) of the Xiao River, a tributary of the Yangtze River. The Cd, Cu, Pb and Zn contents in the WLFZsoil were analyzed via atomic absorption spectroscopy. The potential ecological hazards of the heavy metals were also evaluatedusing the classical Lars Hakanson potential ecological risk index method. The average Cd, Cu, Pb and Zn contents ...
Autori: Chuan Fu, Dan Liu, Junjie Lin, Zhiguo Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26346

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractThe energy and environmental regulations of thermal power plants became crucial issues in China due to the coal dependence ofelectricity generation. The regulation costs, which are distributed differently between the plants are evaluated based ondirectional distance functions approach using the input and pollution data of the main thermal power plants in 2008. The resultsof our analysis show that potential cost for complying with the regulations entailing coal consumption for power gener...
Autori: Jinyi Li, Wei Zhang, Xiaohua Xia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26376

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractThe importance of air pollution for health results from the major role the air plays in preserving life. The air pollution is one ofthe most serious problems of the current society, both temporally and spatially. The air pollution of the environment is stronglyinfluenced by meteorological factors because of a complex combination of emission processes, transport, chemicaltransformations and the removal of pollutants through wet and dry processes. This study established a database on ozone...
Autori: Gilda Rusu-Zagar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26391

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractThe naturally or industrially occurring flammable mixtures containing combustible gases or/and dusts represent a potential risk ofexplosion with major consequences on the environment and human personnel. Methane and coal dust are among the best knowncomponents able of leading to the formation of such mixtures either in coal mining activities or in different industries using coaldust as fuel. In order to assess the risk of explosion and the explosion evolution in such composite mixtures, ...
Autori: Maria Prodan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26402

AbstractThe success of rescue in toxic, flammable and explosive environments can accurately be quantified by the number of injuredcaught at the event that occurs, identified, reanimated and transported safely to the nearest hospital or point of granting the firstaid. Unfortunately, in most cases, the area where these activities are developed, research is more or less accessible due to thepresence of smoke, toxic or explosive gases or lack of visibility. For this reason, most often we are witness...
Autori: Artur Găman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26403

AbstractEmployers notified about working places under special conditions are required to develop Preventive and Protective RevisedPlan, in order to ensure the improvement of workers safety and health protection, including specific measures and actions, so thatthose working places comply with the norms and operate under normal conditions by the late 31 December 2013.This paper considers some outcomes of the Nucleu Program PN 07450226 funded by Romanian National Authority for Research(ANCS) and de...
Autori: Marius Kovacs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26404

AbstractMining industry, by underground coal exploitations allows the release of important methane quantities in the atmosphere.Methane can be found stored both in coal deposits, as well as in sterile rocks from the proximity of coal beds. By carrying out thedegassing process in advance of the exploitation, there can be obtained at least three benefits simultaneously: a new source offuel for heating devices, methane emissions reduction and ventilation costs reduction.With the help of computer, s...
Autori: Nicolae-Ioan Vlasin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26407

AbstractResearches aim to develop new knowledge in the metal cutting field, using a relatively new technique with a low number ofapplications nationwide, namely the flexible explosive charge with cumulative effect for fast and precise cutting of metals. Theprocedure of cutting with explosives is a process that involves using and handling materials in their solid phase.This procedure isespecially applied in cases where materials are mostly metals and it uses a directed and controlled cumulative e...
Autori: Ilie Ciprian Jitea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26410

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

AbstractAs the threat posed by global climate change becomes more acute, action must be taken to mitigate carbon emission. Carbonfootprint, as a widely used term and concept, is increasingly being recognized as a valuable indicator in the field of GHG andcarbon emissions management. However, few attempts have been made to investigate precise relationship between carbonfootprint and influential factors. In this paper, STIRPAT model was employed to reveal the dynamic relationships betweencarbon fo...
Autori: Xiangmei Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26414

AbstractPipeline crack-like defects are detected and localized through the monitoring of the transport parameters of the transmissionnetwork. Under SCADA monitoring, accidental gas loss is reduced and the negative environmental impact of the hydrocarbons isavoided. This paper presents a method for the localization of accidental gas leaks, the pressure gradient method combined with afuzzy analysis method, which operates simultaneously both numerical data and lexical arguments in order to accurate...
Autori: Adrian Bucur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26418

AbstractThe right individuation of the more convenient solution for final treatment and destination of sewage sludge deriving fromwastewater plants, normally after anaerobic digestion process, is a very interesting problem, in accounting of urgent needs foracceptable solutions. The produced sludge, primarily after thermal drying, can be sent to energetic valorization processes as, forexample, incineration, gasification and also pyrolysis. In this work we examined the thermal solutions (both dire...
Autori: Deborah Panepinto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26435

AbstractEvaluation of radon concentration is a very difficult task and a very important issue, in relation to the protection of human health.This is especially the case when there is an increase in concentration of radon on a deterministic basis, as is the case of nearbyphosphogypsum residues or geological characteristics. Radon gaseous that can be found in the environment occurs mainly fromnatural radioactive decay chains. The gamma ray spectroscopy is a powerful tool in order to monitor the en...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26441

AbstractIn order to diminish the climat changes due to greenhouse gases, the capture from the source, transport and storage of carbondioxide is one of the environmental priorities of the EU until 2050. Transportation of this gas through pipelines (one of thesolutions with most advantages in transport) can be done at ambient temperature only at high pressures, so the carbon dioxide toremain in the supercritical state. In case of underground pipelines, there is a risk of cracking at the wall of th...
Autori: Valentin Zichil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26447

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractCarbon monoxide (CO) is a gas obtained both from natural sources (bush fires, volcanic emissions and electric discharges) andby anthropogenic processes (incomplete combustion of fossil fuels). Together with particulate matter, nitrogen oxides andhydrocarbons, it is part of the air pollutants associated with the transport sector, which have a negative impact on human health,animals and vegetation. In this paper the authors propose a methodology for assessing CO emissions from road traffic...
Autori: Gabriela Mitran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26466

AbstractThis work presents an original method and an automated installation to recover by combustion the waste gas obtained in theignition process of xylites in rotary kiln. The flue gas resulting from the combustion of waste gas, with light fuel support areused in the technological processes of obtaining activated carbon, satisfying the conditions where the oxygen content does notexceed 0.3 % vol. and the temperature is above 1200°C, conditions imposed by the Project Manager of the European pro...
Autori: Aurel Gaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26461

AbstractThe present work is dealing with the identification of the mercury sources and the quantification of the mercury level in air andurban dust in the industrial area of Iasi municipality. A correlation between some meteorological indicators, atmospheric mercurycontent and the urban dust from the investigated area was pointed out, based on the real time measurements as well as spatialdistribution of other heavy metals in urban dust.The measurements of mercury level in air were carried out at...
Autori: Oana Maria Tucaliuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26479

AbstractIn this study a new generation of plate-type laboratory air treatment biofilter is applied for the removal of gaseous contaminantsfrom air. The packing material for the biofilter consists of porous plates arranged vertically one after the other to produce acapillary humidification effect. The porous plate is made of polymer to secure the stiffness of the plate. Birch fibre granulesthermally treated in a steam explosion reactor are fixed on both sides of the polymer board. The granules ar...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26480

AbstractThe conducted research has proved the dependence of gas flow rate in the separate channels of the two-level multichannel cycloneat a different inflow velocity and the number of channels. The carried out investigation demonstrates the dependence of changesin velocity in the channels under varying relations between peripheral and transitional flows. The work of a cyclone of the channelis based on centrifugal forces and an additionally occurring filtration process caused by the interaction ...
Autori: Pranas Baltrėnas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26488

AbstractThe purpose of the present study is the comparative investigation of the calcium cations removal from aqueous solutions usingtwo strong acid cationic resins recommended during the last years for water softening. The performances of the two resins wereevaluated by the means of the cationic exchange capacity and the retention degree of the calcium cations. The evaluation of thetwo resins behaviour in the ion exchange process was performed by the means of the FTIR spectra recorded on the re...
Autori: Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26489

AbstractEnhanced nitrogen inputs to both terrestrial and aquatic ecosystems affects biodiversity at all its levels. Grasslands provide acomplex range of functions, due to their wide representation throughout terrestrial ecosystems. Numerous studies demonstratesoil acidification, eutrophication and species richness reduction as a result of elevated reactive nitrogen availability. The presentstudy aims to assess soil nitrogen stocks and transformations for two Romanian grasslands during November 2...
Autori: Carmen Postolache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26497

AbstractConcentrations of seven heavy metals (Cd, Cr, Cu, Fe, Ni, Pb and Zn) in the discharged effluents of four wastewater treatmentplants located on the Romanian Black Seacoast, evaluated as average values for four seasons, during 2010-2011 are presented.Total and dissolved metals occurrence was investigated from seasonal samples, to assess the bioavailability of the heavy metalsin the discharged effluents. The analytical measurements were performed by flame atomic absorption spectrometry (FAA...
Autori: Elisabeta Chirilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26498

AbstractGreenhouse gases emissions represent a first-degree concern in power generation from fossil fuels combustion. Over the past twoand a half centuries, since the dawn of the industrial era, huge amounts of carbon dioxide have been released into the atmospherefrom combustion processes, most of it coming from fossil fuel-fired power plants. The effects of CO2 accumulation in theatmospheric environment become more and more apparent due to the increasingly strong greenhouse effect leading to gl...
Autori: Bogdan Horbaniuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26505

AbstractVegetables are an important part of a healthy diet because of their nutritional value. Contamination in vegetable may provehazardous for population. Polycyclic aromatic hydrocarbons (PAHs) are compounds widespread in the environment, many ofthem showing carcinogenic effects. These compounds can reach the food chain by different ways and, therefore, the analysis ofPAHs in food is a matter of concern.The present work provides data regarding levels of PAHs: acenaphthene (Ace), acenaphthylen...
Autori: Alina Soceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26510

AbstractThe mining waste facilities in the Baia Mare region, Romania, resulted from the extraction of poly-metallic ores (including Au,Ag). Metal sulphide minerals from the mining waste facilities have a potential to produce acid rock drainage (ARD) and togenerate risk for the environment, including for the water resources. Some of the mining waste deposits from the region arelocated near the town of Baia Mare, close to the residential areas, the agricultural lands and the surface water. The sho...
Autori: Oana-Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26512

AbstractThe alkylation of light hydrocarbons leads to produce the high octane number gasoline blending components. The homogeneouscatalytic alkylation reaction is usually carried out at low temperature in the presence of H2SO4 and HF. The use of heterogeneouscatalysis for this reaction is a promising solution for the replacement of hazardous acids to environmentally friendly zeolitecatalyst. The alkylation reaction of isobutane with 1-butene was studied on selected zeolite catalysts. The objecti...
Autori: Tatjána Juzsakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26514

AbstractAccurate quantification of gaseous emissions from livestock buildings to the atmosphere requires accurate determination of theventilation rate and the representative gas concentration in the exhaust air. But there is a lack in the investigation of reasons anduncertainties for selecting sampling points and locations in naturally ventilated dairy (NVD) buildings. The objective of thisstudy was to investigate uncertainties in calculating AER based on carbon dioxide (CO2) balance method. The...
Autori: Chayan K. Saha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26515

AbstractPetroleum tanker trucks are integral vehicles for delivering fuel and other petrochemical products from place to place and must becleaned regularly. Pressure washing with hot or cold water serving to remove oil and filth from the tanker truck container,produces oily waste water with an oil concentration of about 300-500 mg L-1 which, according to environmental standards andregulations worldwide, must be disposed of and treated properly. In the present paper an integrated electrochemical ...
Autori: Konstantinos Dermentzis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26520

AbstractAtomic absorption spectrophotometry (AAS) technique was applied in order to identify the occurrence of certain heavy metals insamples of pork products, such as bacon, ham, sausage and salami, taken from four commercial centers in Romania. Lead levelsin samples varied from 0.58 to 0.96 mg/kg, Cadmium values from 0.11 to 0.21 mg/ kg, Copper from 0.73 to 1.32 mg/kg, whileZinc levels were detected between 32.19 and 42.12 mg/kg. Lead, Copper and Zinc found in samples were lower than themaximu...
Autori: Gabriel Vasile Hoha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26522

AbstractThe primary objectives of this study were to identify the ecotypes of the ‘longicaulis’ giant reed (Arundo donax L.) that arewinter-frost and cold tolerant in temperate climates on marginal lands and to perform biotechnological research on theseecotypes. We searched for large ‘longicaulis’ giant reed ecotypes, which wintered successfully in spite of the 2012/2013 winterfrosts and sprouted from stem nodes in the spring of 2013 in three locations of the Balaton basin. Starting in vitro cul...
Autori: Gabriella Antal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26527

AbstractIn our study, we examined the annual carbon footprint and energy balance of a Hungarian biogas power plant with a poweroutput of 0.637 MW in 2013, with reference to the complete life cycle of the biogas production. The life cycle analysis (LCA)considered the emissions of greenhouse gases (GHG) during the production of feedstock and its transportation into the powerplant, during the operation of the factory and during the process of rendering the discarded waste materials harmless. Weesta...
Autori: György Szabó
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26548

AbstractAnaerobic degradation (AD) of municipal solid waste (MSW) depends on the moisture and nutrient distribution within thebioreactor; these factors are affected by leachate recirculation. In this work, the effects of leachate recirculation of 15 to 120 byvolume percentage (%V) on AD were studied. The ojectives of this study are as follows: a) to determine which recirculation rateprovides the best conditions for accelerated anaerobic degradation (AD) and b) to determine the optimal range of r...
Autori: Maria del Consuelo Hernández-Berriel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26557

AbstractThe distribution of mixing time for a split-cylinder gas-lift bioreactor has been investigated for simulated broths with apparentviscosities up to 26 cP. The results indicated important variation of mixing time on the height of riser or downcomer, as well asdifferent behavior of dispersion flows in the two regions. Thus, the highest mixing efficiency for the ascending circulation hasbeen recorded for the intermediary positions, placed above the sparger. Contrary, for the downcomer, the i...
Autori: Anca-Irina Galaction
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26560

AbstractEnvironmental and territorial compatibility of industrial activities can be evaluated by considering several criteria, usuallyformalized in the contest of a Strategic Environmental Assessment (SEA); the pipelines sector, however, is not as wellstandardized as others. In this paper, a new methodology to evaluate territorial compatibility of proposed pipelines is presented.This approach can be useful to assess proper development compatibility of oil and gas pipeline networks, and it could ...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26561

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractThe aim of this work is to study the valorisation of two regenerated low density polyethylene (LDPE) coming from dirty wastesby blending with polypropylene (PP) in presence of compatibilizer. The first step was the determination of the physico-chemicalproperties of the two regenerated samples (density, melt flow index, water absorption, melting temperature and oxidation index)and the mechanical properties (tensile and shore D hardness).The second step was the characterization of the phys...
Autori: Nabila Guerfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26565

AbstractThis study aims to understand the acid-leaching behavior of metals from 2 to 4 mm waste printed circuit boards (WPCBs)containing 22.0% ą 1.1 Cu, 6.7% ą 0.2 Ca, 0.68% ą 0.02 Sn, 0.59 ą 0.01 % Pb, 2.71% ą 0.08 Al, 0.22% ą 0.01 Fe, etc..Copper leaching was increased for sulfuric acid concentrations up to 1.2 mol/L and hydrogen peroxide concentrations of 10.0vol% for a pulp density of 100 g/L at 50°C over 4 h, whereas for the same concentrations of sulfuric acid and hydrogen peroxidecopper l...
Autori: Manoj Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26566

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

AbstractWe reported the results of an isotopic study aimed at evaluating the medium to long-term effects of different water qualities anddeficit irrigation strategies on the ecophysiology of grapefruit in a 7-year-old plantation in SE Spain. For a better understandingof the interaction between nitrogen and salts from reclaimed water, RW, an experiment using natural abundance (δ) of 15N wasconducted. This study showed that in grapefruit crop irrigated with RW leaf δ15N value increased. ...
Autori: Cristina Romero-Trigueros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26573

AbstractEnd-of-life tires are waste materials that pollute landscapes when they are disposed of in tire dumps. However, its life cycle is notfinished when they are scrapped. The rubber of end-of-life tires could be used for new purposes as construction material in roadrehabilitation. A gap-graded mix characterization was carried out in this work by means of laboratory and field performancetests. The mixture has a high content of crumb rubber (CR) by weight of bitumen. Crumb Rubber was added to t...
Autori: Victor F. Vázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26577

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract Wildfire emissions are a major contributor of atmospheric gaseous and particulate pollutants for local air pollution levels. With respect to wildfires, Turkey faces one of Europe’s most severe problems during summer. In this study, a database which holds data for wildfire emissions in Turkey for the last decade (between 2000 and 2009) was established in order to create a wildfire emissions inventory. The emissions of carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), n...
Autori: Faruk Dincer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26584

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract The present study was conducted to determine the heavy metals (Fe, Mn, Zn, Cu, Pb, and Cd) and essential oils content in the berries of Juniperus phoenicea L. grown in two different geographic origins; Dana conservation and Al-Hisha forest in Jordan. Atomic absorption and Hydrodistillation methods were used to determine heavy metals concentrations and oil contents in plant samples of J. phoenicea L., respectively. Results showed that, the oil yielded from J. phoenicea L. berries in ...
Autori: Mohammad Sanad Abu-darwish
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26595

Abstract This article covers the investigation of the catalyst waste (T.R.M 1 and T.R.M 2) produced in the reactor of oil catalytic cracking. The analysis of this waste was carried out. The properties of T.R.M 1 and T.R.M 2 were investigated and determined, the mineralogical analysis of catalyst waste was implemented, the analysis of thermal effects during the burning was performed. Catalyst waste materials investigated were used in a ceramic system (from 7  to 20  of the ove...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26600

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract In the Netherlands green gas is seen as a sustainable alternative to natural gas. However, green gas is still not competitive to natural gas in terms of pricing, and production volumes are remarkably low. Currently, there is a lot of attention to green gas which stems from upgraded biogas, which is produced by manure-based anaerobic co-digestion by livestock farmers. In this article the central question is to understand green gas demonstration projects from stakeholders’ persp...
Autori: Thomas Hoppe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26603

Abstract This article presents the results of investigations addressing the accumulation of heavy metals in different layers of the Lake Talkša, Lithuania. For the sampling from the ice of intact structure of the sediment the turf borer was used. Concentrations of these heavy metals in sapropel layers were determined in the extracts of sapropel. After the preparation of samples, the concentration of Pb, Ni, Cr, Zn and Cu were measured in the laboratory by means of atomic absorption sp...
Autori: Justyna Kozlovska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26615

Abstract The feasibility of catholyte-conditioning to enhance the electrokinetic (EK) remediation of cobalt and lead polluted soil has been investigated in this study. Electrokinetic experiments were conducted using an EK cell 10 cm in width, 10 cm in height, and 50 cm in length. Plate type electrode of graphite was used as electrode material. Two experiments were conducted under constant voltage condition (2 V/cm). The pH values of the soil significantly affect the removal of Co and Pb ions...
Autori: Mahdi Bahemmat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26623

Abstract Malathion is a toxic, wide-spectrum organophosphorus pesticide. The removal of this pesticide from water is one of the major environmental concerns. In this study, the biodegradation of malathion using batch activated sludge was studied. The effect of initial malathion concentration (5 to 140 mg/L) on the degradation process was investigated. The biokinetic parameters (rs max, Ks and Ki) were estimated. Identification of dominant bacterial flora was also achieved. In addition, two k...
Autori: Djaber Tazdaďt
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26625

Abstract The effects of nitrogen (N) and phosphorus (P) addition to peatland ecosystem on emissions of nitrous oxide (N2O) were measured using the closed chamber method during one growing season within a peatland on the Tibetan Plateau. The highest N2O fluxes occurred during late spring (May), while fluxes of N2O were lowest during early autumn (September). No significant correlations were found between N2O emissions and soil temperature. Because of the sites stable hydrological conditions n...
Autori: Yongheng Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26626

Abstract The degradation of polycyclic aromatic hydrocarbons (PAHs) including fluorene, phenanthrene, anthracene, fluoranthene and pyrene were investigated under thermophilic and mesophilic anaerobic-methanogenic conditions. By using central composite design, the impact of PAH concentration and soil to inocula ratio were systematically studied for their influence on PAH removal and biogas production. During the first 30 days, PAH concentration decreased in all samples indicating that the ino...
Autori: Tahseen Sayara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26629

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract 18F-FDG is a glucose analog in which the hydroxyl group on the second carbon is substituted with 18F, being used as an indicator of glucose uptake and cell viability. The aim of this work was to synthesize the 18F-FDG and to validate the methodology for the assessment of its both radiochemical and chemical purities, according to the European Pharmacopoeia. The proposed methodology encompasses three chromatographic methods: radio-HPLC, radio-TLC and HS/GC. Radiochemical impurities ...
Autori: Mirela Mihon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26640

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract The caraway (Carum carvi L.) samples were collected from little meadows situated in Harghita Mountain (Mădăraş Ciuc, Harghita Băi, Jigodin, Tuşnadu Nou), where a relatively small area was covered by a group of rich populations of wild cumin. The harvested plants are dried by: a) convective laboratory dryer in thick layer, b) static outdoors in sunshine, and (c) static in a warm indoor place in darkness. The hand-picked seeds were separated from debris by sie...
Autori: Csaba Dezső András
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26646

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Anaerobic digestion was analyzed as the biological process that converts the organic matter present in various types of wastes, activated sludge from the wastewater treatment facilities respectively, into biogas. Latest advancements in the mathematical modeling, simulation and control practices have helped in gaining a better insight of the process. In this paper, an energy efficiency and techno-economical investigation of anaerobic digestion technology for the CHP cogeneration unit...
Autori: Alexandrina Zuza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26648

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract Environmental contamination by antimony has been described as a critical issue in many articles. In this study, the Sb(III) removal by two brown algae, Sargassum muticum and Aschophylum nodosum, has been tested. Algae were collected in Viana do Castelo beach (Portugal). Preliminary tests were carried out and, based on the results, Sargassum muticum was chosen for subsequent experiments. Kinetic data were described by pseudo second order model. After about four hours contact time the...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26659

Abstract Sites contaminated with hazardous materials pose serious risks to human health and ecological environments. Quantitative health risk assessment is a site-specific complex procedure requiring evaluation of all possible pathways. Several studies have focused on the evaluation of heavy metals or organic pollutants; however, only few studies focused on the evaluation of diverse pollutants such as heavy metals and organics. In this study, the health risk of heavy metals and organic pollu...
Autori: Hou Wei
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26663

Abstract This study focused on the use of jet aeration to treat printing and dyeing wastewater. The related environmental factors influencing the dynamical efficiency of a jet aerator were investigated. Results showed that an ideal linear relation existed between dynamical efficiency and working pressure (R2 > 0.98), with dynamical efficiency decreasing gradually as the working pressure increased. When the gas–liquid ratio was approximately 0.6:1 to 1.4:1, more bubbles were formed b...
Autori: Chunsheng Le
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26664

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract Succinic acid is widely used in different industries, its demand increasing each year. Therefore, efficiently producing it (especially from bio-regenerable sources) is an aspect that researchers try to solve thorough different methods, one of the approaches consisting in using process models for generating predictions and improving production by process optimization. In this work, a combination of two bio-inspired algorithms represented by Artificial Neural Networks and Clonal Selec...
Autori: Elena-Niculina Drăgoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26669

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract The performance of electrocoagulation (EC) process, a non-specific electrochemical technology, was investigated for the removal of carbamazepine (CBZ), an antiepileptic drug, from water. Experiments were carried out in synthetic wastewater in a batch cell. The respective influences of some key process parameters were studied, such as mixing conditions, initial pH, and current on aluminium electrodes. Experimental results showed that a CBZ removal efficiency of 62% was observed under...
Autori: Tania Yehya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26683

Abstract In this research, a small-scale biogas plant using methane fermentation was developed. The electrical energy consumed by the heater/pump and the outside temperature of the small-scale biogas plant were logged from 1 July 2007 until 31 July 2009. The thermal efficiency of the small-scale biogas plant was calculated based on the electrical energy consumed by the heater/pump and the generated gas quantity. The results showed that a total thermal efficiency of 17.5% was obtained in the ...
Autori: Daisuke Tashima
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26694

Abstract Anaerobic processes have been successfully applied in the treatment of municipal and industrial wastewaters. Judicious use of nutrients in anaerobic treatment has not been systematically investigated. The optimal nutrient dosage for anaerobic wastewater treatment systems is largely unknown. In this paper, COD:N:P ratio used by various researchers in anaerobic wastewater treatment systems for treating different types of wastewaters are compiled and critically analyzed. In order to ha...
Autori: Athar Hussain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26697

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract Large quantities of snail and clam shells are left as waste material when their meat is used as food for people. It has been a big problem that how to treat these wastes and usually these are land filled as wastes. In the present paper, these shells are studied as recycling resource for phosphate removal from solutions. Laboratory-scale batch experiments were conducted to evaluate the efficiency of snail and clam shells in removing phosphate from aqueous solutions. Major factors inv...
Autori: Ji Bing Xiong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26727

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

`Abstract End of life tires require sound accounting of environmental performances to design sustainable procedures for material recovery. Their use in rubber modified asphalt provides could lead to the improvement of technical and environmental performances of asphalt roads, but the effectiveness of simplified procedures is to be proved. During LIFE+ project ROADTIRE, a rubber modified asphalt road prototype, with the upper surface layer containing 10% crumb rubber in the bituminous binder,...
Autori: Irene Bartolozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26741

Abstract The municipal waste landfills are known as important anthropogenic sources of methane and carbon dioxide being the most important greenhouse gases. The present study estimates the methane and carbon dioxide emission from the municipal open dump landfill of Cluj-Napoca (Romania). Two different methods were used: the first method was based on in situ measurements, using the closed chamber technique and the second one was based on the 2006 IPCC (Intergovernmental Panel on Climate Chan...
Autori: Gabriela-Emilia Popiţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26761

Abstract This paper presents the application of life cycle assessment (LCA) modelling used in the process of comparing the best technology for disposal municipal solid waste (MSW) in the Banjaluka region. Three scenarios were considered: unsanitary landfill, sanitary landfill with gas collection and burning on flare and sanitary landfill with energy recovery. The Banjaluka landfill is currently an unsanitary landfill because a system for collecting and treating gas has not yet been implement...
Autori: Draženko Bjelić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26767

Abstract This paper presents a toolset for the efficient control of the indoor air quality and thermal comfort in retrofitted buildings. The refurbishment of existing buildings, compliant to actual regulations, often leads to airtightness and the consequent poor conditions for the occupants that could cause low productivity and even sickness. For this reason, the CETIEB (Cost Effective Tools for Better Indoor Environment in Retrofitted Energy Efficient Buildings) project developed innovative...
Autori: Gian Marco Revel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26770

Abstract In the context of biogas sustainability assessment, a promising way to reach greenhouse gases (GHG) reduction and fossil energy savings is the anaerobic digestion (AD) of both animal manure and energy crops. Nowadays, more than 1,100 AD plants are working in Italy, mostly located in Northern Regions. To those plants with an electrical power lower than 1 MW, strong public incentives were given, therefore, several of them have been put into operation; this entailed increasing cereal ...
Autori: Jacopo Bacenetti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26771

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life (EoL) treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and at the aim of their exploitation as valuable sources of raw materials. Within this study an integrated approach for waste electrical and electronic equipment (WEEE) end of life treatment is proposed based on the integration of hydrometallur...
Autori: Claudia Brunori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26777

Abstract A VOC monitoring was carried out inside and outside a multi-storey car park in order to characterize the emission profile of vehicular traffic source in an indoor environment. BTEX, and in particular toluene, were the most abundant compounds in all monitored sites, with different compositions between indoor parking areas and outdoor sites. The motor vehicle exhaust and gasoline vapor emission in these enclosed parking garages were characterized by diffusion or degradation phenomena ...
Autori: Gianluigi de Gennaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26778

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract New and end of life tires have been pyrolyzed in an innovative pilot plant that processes whole tires, thus saving the energy costs of shredding while allowing energy and materials recovery. Furthermore, the presence of a hydraulic guard guarantees high process safety. Several tests at different temperatures have been performed and the collected solid, liquid and gaseous products have been quantified and characterized. The influence of the maximum process temperature on yields and c...
Autori: Loris Giorgini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26783

Abstract The Bio.Lea.R project aims to demonstrate the performance of a landfill for less reactive, biologically treated waste (pretreated organic wastes) compared to a conventionally managed landfill, with regard to both environmental (biogas and leachate production) and economic aspects. The objective is to control the pretreated biodegradable waste through a liquid injection in order to achieve the same biogas quantity in a shorter time than in conventional landfill. Laboratory and full ...
Autori: Alberto Godio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26784

Abstract The amount of collected Waste Electrical and Electronic Equipment (WEEE) in Europe is growing about 7 wt.-% per year (2007- 2012). It contains a number of economically relevant base, precious and high-tech metals. However, only a limited number of these metals can be recovered by currently applied recycling processes. Especially high-tech metals like gallium, germanium and tantalum get lost during the treatment of WEEE. The pyrolysis technology allows an accumulation of these metals...
Autori: Peter Hense
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26785

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract Solid digestate (SD) represents an environmental problem due to the continuous increase of biogas production. In the present study four white-rot fungal strains were screened for their ability to grow on two different SD samples, obtained from industrial biogas plants, using wheat straw (WS) as a control medium. Results show that i) the feedstock used in the biogas plant influences the time required for the colonization of the corresponding SD and ii) different fungal strains have d...
Autori: Guglielmo Santi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26792

Abstract Recently several innovative suggestions on how industrial wastes can be utilised in new products have been presented in literature, e.g. as filler or additives in concrete, incorporated in ceramic materials to produce glass-ceramics and pavement construction. In this work, metallurgical materials from secondary aluminium scrap processing and glass waste derived from treatments of packaging and fluorescent lamps were considered for fabrication of new ceramic materials using powder te...
Autori: Rosa Taurino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26794

Abstract This study carried out for the first time a comparison among ligninolytic (white-rot) and cellulosolytic or xylanolytic (Trichoderma) pre-treated wheat straw, for biogas production, potential, without or with pig slurry in co-digestion. Methane (CH4) production from wheat straw pre-treated for 4 and 10 weeks with seven different fungal isolates was preliminarily measured. Then, the effects on biogas yield of the co-digestion with pig slurry were checked on straw pre-treated with 3 s...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26796

Abstract Chinese political winds encourage unconventional resource exploitation. However, replication of “shale gas miracle” outside North America seems impossible because of things like problematical accumulation in geological conditions. There are many obstacles and difficulties China faced in this context. The accuracy of resource assessment and technology progress are key aspect to lower investment risk. Based on these, this paper provides integrate ways to make resource esti...
Autori: Shubin Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26800

Abstract The feasibility of humidification-dehumidification utilizing waste heat from exhaust gas was investigated. The exhaust gas below 100°C was used as the heat resource and to evaporate the salt water. The effect of operation conditions on the fresh water productivity and thermal efficiency was studied, including the salt water flow rate, exhaust gas flow rate and temperature. The performance of this process was discussed from the view of temperature field, and the temperature field...
Autori: Huaigang Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26812

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract Drying wood requires a significant amount of energy. This includes both thermal energy, necessary to heat-up wood, evaporate the water inside it and cover the insulation and vent losses, as well as electric energy consumed to force air circulation through the stacks. When wood is frozen, both energy consumptions increase; on one hand because frozen water requires a supplementary heat for transformation into liquid and then into gaseous state, and on the other hand, because of the lo...
Autori: Maria Bernadett Szmutku
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26841

Abstract An experimental study on the hydrodynamics of fixed, fluidized and spouted granular bed was performed. With this aim two commercial adsorbent materials and a composite material obtained by impregnation with a hygroscopic inorganic salt were employed. The fluid phase consisted in dry air. The obtained results highlight the influence of grain size, material density and roughness over pressure drop and gas velocity. Increasing grain size leads to decreasing pressure drop and increasing...
Autori: Ioan Solomon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26854

Abstract Energy costs not included in consumer utility invoices include human health problems triggered by air pollution from burning fossil fuels, and environmental degradation caused by global warming, acid rain, and water pollution. Such costs, peripheral to energy pricing, are called externalities because electricity producers and users do not pay for them directly. Society as a whole must pay. This pricing system masks the true costs of fossil-based electricity generation plants, result...
Autori: Hasan Karimzadegan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26862

Abstract Flame atomic absorption spectrometry (FAAS) and X-ray fluorescence spectrometry (XRF) were used as investigation techniques in the assessment of soils contaminated with metals such as Pb, Cu and Zn. The investigation focused on the comparability of the concentrations determined by the two methods, in order to identify the most suitable approach for Pb, Cu and Zn quantification, with respect to metal monitoring in brownfields. Generally, the concentrations obtained through FAAS were...
Autori: Maria Lucia Bizo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26875

Abstract This paper analyses mass and energy balances of some Integrated Municipal Solid Waste Systems (IMSWS) focusing on MSW sorting, treatment and energy recovery conversion chains suitable for the last entries into the European Union (EU). In particular the Romanian case-study has been developed as reference scenario. In this context the actions timelines for the case-study are immediate (S1A), midterm (S1B) and long term (S2). In the scenarios S1A, S1B a poor selective collection (SC) i...
Autori: Gabriela Ionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26878

Abstract To assess the pollutants input of acid mine drainage (AMD) and domestic activities in Aries River, the water was monitored monthly, during one year, in 15 sampling points along the River. The dissolved metals (Ca, Mg, Na, K, Fe, Cu, Zn, Mn), anions (SO42-, NO3- and Cl-), pH and electrical conductivity were analyzed. The obtained data were assessed against the water quality standards, Principal Component Analysis (PCA) and Hierarchical Cluster Analysis. The results revealed the water...
Autori: Erika Andrea Levei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26881

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

Abstract The design, the realization of the prototype and the acoustic standardization process of a novel periodic system made up of multiphysical phenomena scatterers as a road traffic noise reducing device are reported in this work. The structure analysed here, inspired by Sonic Crystals, has been designed following the guidelines established in recent works according to the concept of tunability. Thus, the acoustic barrier proposed here includes several mechanisms of noise control, such a...
Autori: Sergio Castińeira-Ibáńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26900

Abstract Trace metal elements commonly exist in drinking water. Excessive exposing on them may result in lots of health problems. This paper mainly focuses on the accumulations of Cu2+, Cd2+, and Pb2+ in drinking water supply networks with amorphous Al(OH)3 formation. The effects of pH, water flow rate, and metal element contents were investigated at laboratory bench scale. It was found that chemical adsorption mainly occurred at pH > 7.0. Suspended Al(OH)3 showed a strong adsorption capa...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26906

Abstract Much attention is paid to removing formaldehyde from indoor air to decrease the health risk for urban inhabitants since formaldehyde is a main indoor pollutant causing various symptoms. In this study, formaldehyde removal by the shoots of potted Chlorphytum comosum (spider plant), Epipremnum aureum (golden pothos) and Aloe vera (aloe) was investigated with a dynamic chamber technique. The results indicated that the order of formaldehyde removal capacities for the plant shoots was C....
Autori: Haiping Hou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26908

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Abstract The ethanol-gasoline blends have brought new challenges to the in-cylinder mixture air-fuel ratio control for the variable fuel characteristics especially in the traditional PFI (Port Fuel Injection) SI (Spark Ignition) engines. This paper studied all the dynamic links in the intake fuel transfer process from the fuel injectors to cylinders, including the wall-wetting effect and injector fuel flow characteristics. A wall-wetting fuel film evaporation model and an injector fuel flow ...
Autori: Dongwei Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26918

Abstract The present study was designed to determine the sound effects of ultrasonic treatment and the biologically mediated extraction of uranium from low grade black shale. Low grade uranium was subjected to fungal treatments assisted by sonication by conventional methods. In situ fungal leaching of black shale with different fungal strains in the presence of molasses as growth substrate resulted in highest leaching yield of uranium by Phoma tropica (57.73%) compared to Penicillium chrysog...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26919

Abstract Establishing a management system for collecting and disposing the solid waste materials is of great importance in urban areas. Belgrade, the capital city of Serbia, is at its initial phase of managing this problem. Currently, landfill disposal is the main option for dealing with rapidly growing amounts of waste. This paper’s research goal is to estimate the landfill gas quantity at Belgrade’s only landfill site Vinca, and to estimate the potential for collection and util...
Autori: Vesna Alivojvodic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26923

As the serious effect of climate change and global warming is recognized, nitrous oxide (N2O) emission during wastewater treatment is receiving lots of attention due to its high potential to greenhouse effect. In this study, nitrifiers were acclimated in sequencing batch reactors with influent ammonium nitrogen (NH4-N) concentrations of 60 mg/L (SBR60) and 180 mg/L (SBR180), respectively. Nitrous oxide emission during nitrification was examined in both typical cycles and batch experiments. T...
Autori: Enge Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26926

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

The pickling liquor used in the stainless steel manufacturing process is a mixture of nitric and hydrofluoric acid which generates wastewater with nitrate concentrations ranging between 500 and 6000 mgNO3--N/L. In the present study, laboratory-scale anoxic Sequencing Batch Reactors (SBRs) were used to treat high nitrate wastewaters. Two different sludge inocula were tested: one from a Municipal Solid Waste Leachate Treatment Plant (LTP), and the other from a Sewage Treatment Plant (STP). Meth...
Autori: Ana Isabel Pelaez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26933

In this paper, the classical adiabatic model was chosen. The assumption of perfect gas working fluid was replaced by that of a real gas working fluid. This last assumption was defined by the van der Waals state equation. A Gamma type Stirling engine functioning with a maximum filling pressure of 10 bars was used to carry out experiments. Both theoretical models: the Perfect Gas Adiabatic Model (PGAM) and the Real Gas Adiabatic Model (RGAM) were applied to the Gamma Stirling engine. The influ...
Autori: Ramla Gheith
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26937

Eco-efficiency is a key concept which brings together two essential aspects for economic progress and ecological aspect. Ecoefficiency indicators are very relevant and play an important role for environmental cost management. For a thermal power plant, which has a great impact on the environment, these indicators involve lower costs and efficient use of energy, water and fuel. The paper proposes a number of eco-efficiency indicators applicable to a thermal power plant, according with specific...
Autori: Roxana Grigore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26938

The influence of key process parameters of homogenous catalytic ozonation using ferrous or manganese catalysts on the mineralization rate of salicylic acid (SA), model pharmaceutical pollutant, in water was investigated. In order to assess the combined influence and interactions of studied process parameters as well, the empirical/statistical approach applying Box- Behnken experimental design (BBD) combined with response surface methodology (RSM) was applied. Three numerical and one categori...
Autori: Kresimir Koricic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26939

Treatment of agrochemical industry wastewater is difficult to carry out unless integration with some advanced oxidation process (AOP) is used. The present study deals with treatment of an agrochemical industry wastewater, first using activated sludge and then with sulfuric acid treated activated carbon (SAAC) in presence of Fenton reagent. During the activated sludge treatment the food-to-microorganisms (F/M) ratio is varied from 0.1 to 0.2 mg chemical oxygen demand (COD) per mg mixed liquor ...
Autori: Makarand Vasant Karkare
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26957

Waste recycling in steel industry by turning grain-size and powdery waste into pellets is a must now more than ever for economical motivation, in order to save raw materials and also for ecological reasons, as it leads to a cut down in the quantity of dumped waste. Industrial practice offers processors various technologies of waste recycling (agglomeration, briquetting, pelleting, mechanical mixture). The optimal variant should be chosen according to waste type, its content of useful elements...
Autori: Ana Virgina Socalici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26968

Ranunculus rionii and Ceratophyllum demersum develop aquatic dense stands, which lately started to represent a major ecological concern for all the ponds and/or lakes in Romania. The potential relationships between the phytochemical compounds detected in these plant extracts (acids, phenols, heterocycles, alcohols, hydrocarbures) and the allelopathic properties against Gram positive and Gram negative bacterial strains and microalgal cultures were investigated and discussed in the current stud...
Autori: Mariana Lupoae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26971

Cameroon's coast that is located in the Guinea Gulf oil region was exposed to hydrocarbon pollution due to oil exploitations and other petroleum activities. The intrinsic biodegradation of hydrocarbons is essential for the depollution methods of the marine environment. Nevertheless, these do not represent a common practice in Cameroon. This study aimed to assess the capacity of bacteria of Cameroon’s waters coast to degrade gasoline and diesel. The kinetic degradation of gasoline an...
Autori: Lucie Leme Banock
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26983

The study aims to identify important challenges that the practitioners and researchers in wastewater collection systems are facing in order to reduce the emissions of hydrogen sulphide and greenhouse gas emissions. Based on literature review, it identifies the main technologies used for avoiding and removing odorous compounds from wastewater gas streams. The paper also highlights issues pertaining to the emission and biofiltration of hydrogen sulphide, methane and nitrous oxide from sewage co...
Autori: Iulia Carmen Ciobotici Terryn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26984

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

Biomass is a very important source for the production of biofuels. During the hydrolysis step of the process for obtaining biofuels the rate of decomposition of biomass is strictly related to its organic matter content and the operating mode of the facilities. This paper highlights the effect of different pretreatments on the composition of biomass at the molecular level using Fourier Transform Infrared Spectroscopy (FTIR) and Principal Component Analysis (PCA). For this experiment, a mixture...
Autori: Andreea Cocarcea Rusei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26986

Air pollution has a significant impact on human health and natural ecosystems. The principal gaseous pollutants compounds result from different types of combustion processes. In this category there are included carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), dust and hydrocarbons. Nitrogen oxides are a group of highly reactive gases, which contain nitrogen and oxygen in varying amounts. Most of the nitrogen oxides are colorless and odorless gas. This paper highlights the c...
Autori: Doina Capşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26988

The renewable sources of energy represent a viable alternative for satisfying the energetic needs of humanity in case the fossil fuels reserves are exhausted, which is estimated to occur in maximum 25 years if the current rate of exploitation is maintained. Nowadays, there are several concerns about the valorization of the energetic potential of these resources (wind, water flows, solar, geothermal energy etc.), but also a series of extremely beneficial practical uses (i.e. wind parks, photov...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26989

Our study aims to analyse soil quality based on the concentrations of potentially toxic elements (PTEs) in natural or slightly modified anthropogenic soils, technosols and landfill deposits in Iasi. The pollution level analysis based on lognormal distribution plot allows the differentiation of elements coming from the parent material (Mo, Cd, Ni and As) of those with anthropogenic origin (Pb, Zn and Cu). The enrichment factor (EF) calculated based on manganese (Mn) as reference in the parent ...
Autori: Cristian Vasilica Secu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26991

High contents of colloidal and organic materials in municipal wastewater sludge cause problems in the process of dewatering. The filtering efficiency can be improved by chemical conditioning, but the effectiveness of mechanical dewatering is limited because flocculated sludge is highly compressible. Physical conditioners such as bagasse can be used to facilitate mechanical dewatering. This paper describes the use of bagasse pith (cane sugar waste fiber) to improve the dewatering process of mu...
Autori: Nematallah Jaafarzadeh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26995

A pure strain of Pseudomonas chlororaphis DJ-4 capable of anaerobic biodegradation of o-xylene, m-xylene and p-xylene was isolated from gasoline contaminated soil. In batch cultures, growth of the strain and biodegradation of xylene isomers led to stoichiometric reduction of nitrate. P. chlororaphis DJ-4 could degrade 150 mg L-1 of m-xylene completely within 12 days and without a lag period. However, higher initial concentrations of o-xylene and p-xylene were toxic to the bacterium of P. chl...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27005

A mine ventilation system provides a fresh air flow to the underground workings in a coal mine. Such sufficient air volume can dilute and remove noxious gases (typically NOx, SO2, CH4, CO2 and CO) and maintain a suitable working environment for coal miners. On the other hand, a poor ventilation system often leads to serious consequences such as mine gas explosions, production loss or higher operational costs. Hence, the functions of mine ventilation system are very important for an undergroun...
Autori: Jianwei Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27008

Adsorption studies of cadmium(II) were conducted on 623oK or 723oK carbonized banana peels named as BP623 and respectively BP723 as well as on the dried ones (BP). Carbonization enhances the quality of organic by-product used as adsorbent, reduces the equilibrium time and improves the quality of the final product (water). Evaluation of the effects of pH, contact time and solution temperature showed that the uptake of cadmium(II) ions was highly dependent on these factors, and increased with ...
Autori: Josiane Ponou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27009

Emission from the combustion processes can cause adverse effect to the environment. The formation of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), carbon dioxide (CO2) and oxides of sulphur (SOx) are hazardous and harmful to the ecosystem. Due to these pollutants and also depletion of fossil fuel, several steps should be taken in order to mitigate this problem. Biofuel is known as the potential replacement for fossil fuel. Envo Diesel is one form of biofuel that can be us...
Autori: Mohammad Nazri Mohd Ja’afar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27011

The diversity of life cycle impact assessment (LCIA) methods may create barriers to life cycle assessment (LCA) since the focus and outcomes generated could be quite different. Furthermore, these could lead to different interpretations and hence affect the robustness of LCA. While previous studies have attempted to compare various LCIA methods, their results are limited to the cases that were used in their respective studies. To assist LCA participants in selecting a suitable LCIA method to a...
Autori: Ya Hong Dong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27012

Air quality became a concern of highest priority in cities and town agglomerations, worldwide. Professional environmental monitoring strategies are prerequisites for supplying appropriate programmes destined to maintain air quality. Due to their capacity of bioaccumulation, tree species may be used as biomonitoring agents within programmes of monitoring air quality in urban spaces. The present study aims to emphasize the ability of A. hippocastanum L., and T. cordata Mill. leaves to be used a...
Autori: Ilie Covrig
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27026

Maghemite nanoparticles (γ-Fe2O3) were synthesized in order to be used as magnetic adsorbent for two heavy metals, Pb(II) and Zn(II), from aqueous solutions. γ-Fe2O3 was prepared from magnetite nanoparticles and was tested for single and binary aqueous solutions. Efficiency removal (%) for single solutions appears only after 10 minutes and was higher than 80%. In case of binary solutions, same results regarding efficiency removal were registered after 60 minutes, being almost 90% ...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27029

The aim of this study was to determine the impact of mercury pollution on soil, surface water, and sediment ecosystems in the area of old mercury mines. The study was performed in the touristic area of Sântimbru Băi and Sâncrăieni villages from the Harghita County, Romania. More than twenty years ago, a mine for the extraction of mercury operated in Sântimbru Băi. The area was decontaminated, but no monitoring studies have been made for over 15 years. During t...
Autori: Luisa Roxana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27038

This paper presents a research on ways to reduce waste and to diminish sound pollution by recovery of fir sawdust and recycled rubber granules and use in making sound absorbing composite materials. Four materials were prepared using raw materials (fir sawdust and recycled rubber granules) in various percentages, and polyurethane binder. Materials mechanical and acoustic properties were characterized, proving these materials have useful properties. Materials acoustic performance was compared w...
Autori: Ancuţa Elena Tiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27039

In studies of biochemical methane production (BMP) researchers often collate a large number of samples at the same time for a sample archive. The samples are often frozen to avoid microbial transformation, further homogenized by grinding. We studied the influence of subfreezing/thawing and drying/milling of energy crop on BMP and anaerobic biodegradability (BD). Relative standard deviation (RSD, %) between the BMP of controls and of the subfrozen was in the range 2.1–9.0%, and of the d...
Autori: Jin Mi Triolo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27079

Membrane technology has become a fundamental unit operation in the industry and society of nowadays and fouling is, probably, the most important concern related with this technology. Fouling is a complex process that can limit the performances of facilities using membranes. Many research efforts have been done in order to reduce fouling tendency. Ceramic membranes can play a major role in fouling mitigation due to its high hydrophilic nature. This paper describes the characterization of a new...
Autori: Mihaela-Elena Dascalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27089

The release of low molecular weight (LMW) organic acids under lead (Pb) and zinc (Zn) stresses in Typha latifolia (T. Latifolia) and Vetiver zizanioides (V. zizanioides) were investigated. In addition, changes in antioxidative enzymes: superoxide dismutase (SOD) and peroxidase (POD) in the leaves of T. Latifolia under Pb stress were also examined. Amongst the eight types of LMW organic acids detected in the present study, oxalic acid was found to be the most dominant during Pb and Zn treatmen...
Autori: Yu Bon Man
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27092

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

The concentrations of isopropyl alcohol were monitored during the working time (8 hours) in three different printing plants (two sheet-fed offset and one digital) in Novi Sad, Serbia, using portable gas chromatograph. The concentration levels were below the recommended limits by the U.S. National Institute for Occupational Safety and Health. Unequal presence of isopropyl alcohol in printing plants involved a multiple linear regression analysis of microclimate parameters using program ORIGIN 5...
Autori: Jelena Kiurski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27096

Iron humate (IH) produced as a waste by-product during the industrial manufacture of humic substances from young brown coal was tested as a new cost-effective sorbent for the removal of inorganic arsenic from waters. Its removal efficiency was compared with that of two other non-conventional sorbents – magnetite and oxihumolite (weathered brown coal). Magnetite and IH have been found to be effective in removing both forms of inorganic arsenic (arsenite and arsenate) from aqueous solutio...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27098

The research presented in this paper aimed to investigate the relationship between sludge anaerobic biodegradability and degree of sludge disintegration based on COD (DDCOD) in a wide range from 0 to 66.7%. Sonication as an advanced sludge pretreatment was used to disintegrate sludge. Meanwhile, biogas production in the anaerobic digestion process was used to present the sludge biodegradability. The performances of anaerobic digestion for pretreated sludge at different degrees of disintegrati...
Autori: Shuyu Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27100

In order to improve the soil fertility, several eco-friendly alternatives to traditional cultivation practices have been proposed. The use of biofertilizers, such as rhizobacteria with different plant growth promoting properties is an environmentally-friendly option to achieve sustainability in agriculture. In this context, two bacterial strains (Bacillus pumilus R3 and Pseudomonas lini R7) isolated from the rhizosphere of runner bean plants were assessed for their plant growth promoting abil...
Autori: Gabriela Mihalache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27108

Intensive agriculture has become an indispensable practice because it has to meet the needs of increasingly large yields to feed the population of the planet. In recent years, tough challenges to increase the efficiency of bioconversion were performed, since the conventional system has negative impacts on the environment, especially on health products by low intake in nutrients. In this context, the aim of this study is to show the effects of fertilization measures, which improve the quality ...
Autori: Daniela Cristina Dimitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27110

The aim of this study is to investigate an innovative way to utilize the char obtained from tyres pyrolysis, in order to realize lightweight materials for building. Pyrolysis residue, mixed with three types of waste glass, has been used as raw material to obtain lightweight materials, exploiting its capability to behave as foaming agent. The results demonstrate that the pyrolysis char is a good foaming agent for the mixtures 50/50 with glassy sand and packaging glass waste, thermal treated at...
Autori: Fernanda Andreola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27119

In Palestine, the energy situation is unique compared to other Middle Eastern Countries, as there are technical and political challenges for transporting, storing, importing and exporting energy. Actually, energy import from Israel meets the major share of Palestinian energy needs. Palestinian reliance on Israel concerning its energy supply is an issue due to the political situation. Furthermore, from an environmental point of view, Israel predominantly relies on fossil fuels for its own elec...
Autori: Jacopo Bacenetti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27120

This work focuses on treatment of lead polluted waste glass from urban collection (Pb≈5% wt) for its valorization as support in the immobilization of lipase, because soda-lime glasses are used in enzymatic catalysis. First of all, an extraction process of surface Pb was performed. The process is based on nitrilotriacetic acid (NTA) chelating agent. The operating conditions are: T=80°C, t=1h, pH 10, solid/liquid weight ratio=1/10, reagent concentration=0.1 M. Leaching tests at contr...
Autori: Luisa Barbieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27122

Waste frying oil (WFO) is a complex and heterogeneous waste collected mainly from restaurants and, to a lesser extent, from food processors and households. In the last decades, interest for this waste has deeply grown and a strong competition in grabbing this raw material has begun. About 90% of WFOs collected in Europe is recycled for biodiesel production, being the high free fatty acids (FFAs) concentration in WFOs one of the main drawback limiting the yield of the conversion process. In th...
Autori: Cinzia Pezzella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27130

In this study, the potential for biogas production from biodegradable bioplastics was evaluated. Mater-Bi® (a family of maizestarch based flexible films) and PLA (PolyLactic Acid; a rigid, polylactide-based, polymer) bioplastics were digested in laboratory batch reactors, alone or in co-digestion with pig slurry or scotta (partially deproteinized cheese whey), at 35°C or 55°C. Methane (CH4) and hydrogen (H2) production were monitored during the incubation period. Maximum CH4 (Mmax...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27134

The removal of phthalic acid diesters PAEs, specifically di-n-butyl phthalate (DBP) and di(2-ethylhexyl) phthalate (DEHP), from leachates of a municipal solid waste incineration plant treatment process was studied. The leachates originated from the adjusting unit, the biochemical unit, the ultrafiltration membrane unit, and the reverse osmosis membrane unit. The initial concentrations of DBP and DEHP were 250.5 and 332.3 μg/L, respectively, which were correspondingly reduced to 4.2 and 2.2...
Autori: Hongyuan Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27143

This special issue of Environmental Engineering and Management Journal (EEMJ) contains papers that were delivered at the LivestockWaste 2013 conference, which took place in Jiaxing City, Zhejiang Province, China in 25-26 October, 2013. The topic of the conference was on recent advances in resource recovery and pollution control for livestock waste management. The papers included in this special issue focus on the following areas: (1) policies and regulations on management of animal waste; (2) te...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27144

Greenhouse gas (GHG) emissions from vegetable land are of great concern because agricultural land is one of major sources contributing to global GHG emissions. In this study, the emission of GHG (methane, CH4; nitrous oxide, N2O; and ammonia, NH3), as well as the factors affecting GHG and NH3 emission were investigated in land planted with Lactuca sativa L. and treated with different animal manure composts in a greenhouse located in Beijing. Methane emission flux was significantly affected by so...
Autori: Zhen Ge
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27153

It is of great concern to reduce greenhouse gases (GHG) and ammonia (NH3) emissions from animal manure composting in China. The purpose of this study was to investigate effects of adding red mud on emissions of GHG (methane (CH4), nitrous oxide (N2O)) and NH3 in full-scale swine manure windrow composting. Two full-scale swine manure windrow composting experiments were carried out to compare emission of GHG and NH3 with and without addition of red mud. Results showed that the addition of modified...
Autori: Chenyang Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27158

A combined system of up-flow cyclic sludge bed (UCSB) and aerobic nitrification reactor (ANR) was designed for organic matter and ammonia nitrogen (NH4-N) removals of swine wastewater. The UCSB had one acidogenic zone for hydrolytic acidification to solve the problem of poor carbon source in swine wastewater, and the other zone for denitrification. Results showed that average removals of the chemical oxygen demand (COD) and NH4-N were 92% and 95%, respectively, under the following conditions...
Autori: Jie Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27160

In this study, a mathematical model was introduced to calculate the collection efficiency of dust particles in a wire-pipe single-stage electrostatic precipitator (ESP). The aerodynamic diameters of these particles are less than 10 μm (PM10). The mathematical model, using combined Deutsch-Anderson Equation, considers coupling effects among gas flow field, electric field and particle field. A simplified 2-D ESP model was established using GAMBIT and a software application (FLUENT) was used to ...
Autori: Jian-Ping Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27172

The need for ensuring safety of energy supply, as well as the tendency to reduce greenhouse gas emissions has led to greater use of energy efficient technologies and renewable energy sources. Cogeneration (combined production of heat and electricity) is one of high-efficiency technologies, because the losses of primary energy are less than losses from the separate generation of heat and power. Consequently, in 27 EU member-states 70% of the district heating is based on cogeneration plants. Us...
Autori: Vladimir Vukašinović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27177

In this study, chitosan-iron(III) was used as adsorbent of the dye acid red 29. The effect of pH, temperature and concentration of the dye on the adsorption capacity were evaluated. The maximum adsorption capacity was calculated from the adsorption isotherms which were well fitted by Sips isotherm model. The process followed the kinetic model of pseudo-second-order. The activation parameters showed that the adsorption process is spontaneous and favorable. A decrease in adsorption capacity was ob...
Autori: Carla Albertina Demarchi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27181

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183