Reviste: » Environmental Engineering and Management Journal» European Journal of Science and Theology» Sănătate Sport și Nutriție
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DECONTAMINATION OF SYNTHETIC WASTEWATER CONTAINING PHARMACEUTICAL CONTAMINANTS BY ANODIC OXIDATION WITH BORON- DOPED DIAMNOND (BDD) ELECTRODE Autori: Carmen Ionela BrînzilăData aparitiei: Septembrie / 2014 Revista: Environmental Engineering and Management Journal › Vol. 13 › Nr. 9 ISSN: 1843 - 3707 N.A.
Abstract
Tetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against a wide variety of organisms with application in human and veterinary medicine. The presence of TC in the environment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal body con. TC residues even in low concentration may produce serious toxic and other effects on humans and living organism. In this study are presented the applications of electrochemical advanced oxidation processes (EAOPs) for degradation of TC using de BDD electrode. The influence of experimental parameters (COD, TOC, nitrogen (total Kjeldhal, organic and inorganic), HPLC and UV-Vis spectrophotometry) on electrochemical degradation is evaluated. A pseudo-first kinetic order is obtained for electrochemical reactions with BDD. Model TC solutions is used and different experimental conditions, namely, initial concentration, initial pH, applied current density, type and concentration of the electrolyte, is also tested. To study the influence of the experimental conditions on the degradation of the antibiotic, assays was been running at experimental conditions that allow kinetic and/or diffusive control, in order to determine medium mass transfer coefficients that help to predict degradation rates at experimental conditions other than those tested. |