AbstractIt was investigated the bioleaching of uranyl ions from uranium ores, in aquatic medium with algae: Scenedesmus quadricauda and Nostoc linkia under different experimental conditions. The oxidation of U(IV) to U(VI) species, like uranyl ions was done by means of the atomic oxygen generated through photosynthesis by the aquatic medium from solution above of uranium ores.After almost 10 days of direct contact with the given microorganisms, it was observed a bioleaching degree between 10% an...
Autori: Alexandru Cecal, Rodica Calmoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25107

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

AbstractElectrochemical impedance spectroscopy (EIS) measurements were used to characterize the electrochemical behaviour of the some commercial dental alloys: two PdAg based alloys (Paliag, PaliagMaestro), two NiCr based alloys (Wirolloy, VeraSoft), two CoCr based alloys (Vitallium, VeraPDI) and two CuAl based alloys (Gaudent, NPG+2) in artificial saliva. Impedance spectra were represented in the form of Bode plots and it was fitted using a commercial softwere package called Electrochemistry Po...
Autori: Daniel Mareci, Gina Ungureanu, Julia Claudia Mirza Rosca, Neculai Aelenei, Romeo Chelariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25143

Contain all the articles from this issueEnvironmental analysis by capillary electrophoresis. Atmospheric samplesCamelia Draghici, Gheorghe Coman, Mihaela Sica,Dana Perniu, Mihaela Badea   The ecological farms - A solution for sustainable agriculture. II. Position and perspectives of the ecofarms in the frame of the productive agricultural system Stela Axinte, Alina Stanciu, Lorica Axinte  The extraction and clean up of organochlorine pesticides and PCB's from water using solid phase ex...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25170

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

AbstractThe paper presents original results concerning concentrations of eight heavy metals in soils adjacent to two improperly built municipal waste deposits located in Eforie Sud and Techirghiol, Constanta County, Romania. Measurements have been done on surface and depth soils, during April-October 2006. The applied analytical technique for metal determination was flame atomic absorption spectrometry (FAAS). The mean measured values ranged as follows (in mg/kg dry weight): Cd: 0.09 - 0.15; Co:...
Autori: , Elisabeta Chirilă, Narcisa Elena Ilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25213

AbstractThe aim of this work was to obtain Ag - doped zeolite as antibacterial material using natural and sodium form of zeolite from Mirsid Romania with the dimensions ranged between 0.8-1.2 mm. The comparative structural characterization of natural and Ag - doped zeolite were performed using Laser Induced Breakdown Spectroscopy (LIBS), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), and Infrared Spectroscopy (IR). In addition, the ion exchange total ...
Autori: Aurel Iovi, Corina Orha, Cornelia Ratiu, Florica Manea, Georgeta Burtica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25220

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractSome industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the s...
Autori: Alina Soceanu, , Simona Dobrinas, Vasile Magearu, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25227

AbstractBased on the polarization curves and electrochemical impedance spectroscopy (EIS) in the case of three commercial alloys (Wirolloy, NicromalSoft and VeraSoft) maintained in artificial saliva, it was established the type and the intensity of the corrosion process by means of the corrosion currents value. The passivation of all the samples occurred spontaneously at the open circuit potential. The corrosion currents value decrease after the alloys maintenance in the corrosive medium due the...
Autori: Daniel Mareci, Gina Ungureanu, Julia Claudia Mirza Rosca, Neculai Aelenei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25235

AbstractPolycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector ...
Autori: Alina Soceanu, , Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25237

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractThe health effects caused by air pollutants may range from slight biochemical and physiological changes to difficulty breathing, wheezing, coughing and aggravation of existing respiratory and cardiac conditions. This paper presents an experimental study of air quality in the city of Tg. Jiu, Gorj County, by evaluating the air-floated powders of the PM10 fraction and lead from air. The analysis was performed by measurements in sampling points using the method presented in the European Nor...
Autori: Camelia Capatana, Claudia Maria Simonescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25247

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractThis paper deals with a statistical treatment applied to the determination of U(VI)/U(IV) ratio in some uranium ores, depending on the pH and humidity samples taken out directly from a uranium mine. The concentrations of different uranium species were determined spectrofotometrically. Some statistical parameters were calculated for a subsequent statistical interpretation of the experimental data....
Autori: Alexandru Cecal, Gabriel Barbir, Marian E. Răileanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25255

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractThe effective mass transfer area of a Mellapak 750 Y structured packing was measured in a bench-scale plant with a column having an internal diameter of 100mm, and a packing height of 518 mm, using a broad range of gas and liquid flow rates. The absorption of carbon dioxide into natrium hydroxide aqueous solutions of 0.5 and 1.0 mol/L has been employed as test reaction. The validity of data obtained was tested by checking the two conditions of fast pseudo first order irreversible reactio...
Autori: Anton Friedl, Ilie Siminiceanu, Michael Harasek, Mihaela Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25264

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractThe electrochemical behaviour of Ti6Al4V and Ti6Al4Zr alloys has been evaluated in Ringer's solution at 250C. The effect of the substitution of vanadium in Ti6Al4V alloy has been specifically addressed. The evaluation of the corrosion resistance was carried out through the analysis of the open circuit potential variation with time, potentiodynamic polarization curves, and electrochemical impedance spectroscopy (EIS) tests. Very low current densities were obtained (order of nA/cm2) from t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25334

AbstractThis study deals with the radiolytical decomposition of water molecules, in the presence of some catalysts, getting out hydrogen as unpolluting and cheaper energy vector. Instead of the spent nuclear fuel elements taken out from nuclear power plants, as irradiation source it was used the 60Co radionuclide having a specific activity of 1.1.105 Ci. It was observed that the radiolytic yield of resulted molecular hydrogen from water radiolysis in the presence of used catalysts decreased as:N...
Autori: Ada Macovei, Alexandru Cecal, Dumitru Ganju, , Oana R. Haută
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25354

AbstractTitanium alloys show attractive properties for biomedical applications where the most important factors are biocompatibility, corrosion resistance, low modulus of elasticity, very good strength-to-weight ratio, reasonable formability and osseointegration. The aim of present study was to evaluate the electrochemical behaviour of Ti6Al7Nb alloy in Ringer’s solution of different pH. This evaluation was carried out through the analysis of the potentiodynamic polarization curves, and electr...
Autori: Daniel Mareci, Julia Claudia Mirza Rosca, Marina Garcia Falcon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25363

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

AbstractThe quantification of heavy metals presence in the environment is a very important aspect regarding water quality control. The limits for those metals are very well established by Romanian laws and the essence of every validation report is to prove that the method, the apparatus and the operator can reach the established limits. In the present paper such a validation report is presented, proving the appropriate use of Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICP-AE...
Autori: Irina Dumitriu, , Ioana Raluca Bunghez, Rodica - Mariana Ion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25380

AbstractThis paper presents an analysis of the levels of electromagnetic fields caused by cellular base stations or mobile phones, measured in some residential areas. A statistical processing of the data has also been done in order to estimate both the short-term and the long-term variability of the fields caused by cellular base stations in some apartments and on the terraces of the apartment buildings at tens or hundreds of meters distance from the antenna systems. In some places, comparative ...
Autori: Alexandru Salceanu, Ionut Nica, Valeriu David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25381

Abstract Human exposure to heavy metals requires special surveillance measures on these elements in human body in order to detect a relation between heavy metal exposure and adverse health effects. The aim of this paper is focused on biomonitoring contamination with heavy metals in fish foodstuffs and in blood, and corroboration of contaminant levels with immunotoxicological effects on target groups of consumers. The final goal is to establish some recommendations on human diet with fish food...
Autori: Aurelia Meghea, Alina Murariu, Cristina Tanase, Eleonora Codorean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25398

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract Pollution with toxic metals is a serious concern, because once these elements enter in the soil they can be present for a long time, with the potential contamination of drinking water sources. Certain metals in soil may be taken up by plants which are subsequently harvest for human consumption. Our objective was to study the presence of heavy metals in soils, groundwater sources, some medicinal plants from areas of the water sources and in its watery extracts. All of the samples, af...
Autori: Diana Diaconu, Victor Nastase, Mara Mihaela Nanau, Ovidiu Nechifor, Elena Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25411

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract Textile industry is one of the most pollutant and water consuming industries. Large quantities of water are required in materials preparation and dyeing, so consumption and waste generation have become serious concerns for textile manufacturers and finishers. Textile effluents are characterized by high values of quality indicators such as BOD and COD, suspended solids and heavy metals. A serious environmental problem and also an aesthetic problem is the color of the effluent. Reactiv...
Autori: Daniela Cailean, George Barjoveanu, Corina - Petronela Musteret, Liliana Rozemarie Manea, Nicolae Sulitanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25420

Abstract The aim of this study is to investigate the electrochemical behavior of a three casting non-precious dental alloys: Vera PDI (Co-Cr based), Heraenium (Ni-Cr based) and NPG+2 (Cu-Al based) three test solutions: artificial saliva (AFNOR, pH = 8), acidified saliva (pH = 2.5) and fluoridated acidified saliva (1000 ppm F-, pH = 2.5). Open circuit potential (EOC) measurement; potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) are the electrochemical proce...
Autori: Daniel Mareci, Daniel Sutiman, Adrian Cailean, Julia Claudia Mirza Rosca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25435

Abstract It's well known the degradation of many Romanian (including Dobrogea) soils, both in hill and in plain environments, due to the increasing anthropic pressure on natural resources. Soil erosion and organic matter loss are recognized as the main processes responsible of such degradation and of the rising risk of desertification, to which land use changes and politics for agriculture not suitable for land specificities often contribute. The knowledge of land use impact on soil quality i...
Autori: Marioara Nicolaescu, Naliana Lupascu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25453

Abstract Arsenic (As)-contaminated drinking water is a major problem around the world. The removal efficiency depends strongly on the size of Fe3O4 sorbents.Fe3O4 prepared in laboratory is more efficient in the removal of As and is also more easily recovered from column of magnetic separator than the commercial materials. This would be beneficial in a water treatment system because the As-contaminated Fe3O4 could be flushed from the column permitting reuse of the separator system. The dispers...
Autori: Ionel Balcu, Adina Segneanu, Marius Mirica, Mirela Iorga, Catalin Badea, Iuliana Firuta Fitigau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25456

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract Highly dispersed nanoparticles of transition and noble metals are utilized for hydrocarbon reactions and rearrangements important to the chemical industry. The need to obtain 1 to 3 nm particles with narrow size distributions has prompted the development of alternative processing methods. Due to widespread speculation concerning the enhanced properties of nanoparticles over their bulk and atomic material equivalents, nanoparticle synthesis has become an active field of research withi...
Autori: , Irina Dumitriu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25482

Abstract Macro-Defect-Free (MDF) cements are polymer-cement composites characterized by high value of flexural strength. Due to their thermal and electrical insulating properties, MDF cements could replace other insulators obtained by environmental non-friendlier technologies or being themselves toxic and non-biodegradable. MDF cements obtained by the use of an ecologic polymer (poly(vinyl alcohol)) shows high mechanical resistance in the initial state but also it’s dramatic decrease after ...
Autori: , Georgeta Moise, Hulusi Ozkul, Ozgur Ekincioglu, Catalin Croitoru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25493

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract The recent results of technical development of low cost GPS systems, geographic information systems, equipment and sensors which are needed to identify the state of the crops and soils have shown a growing awareness in agriculture and related sciences. The actual demand for modern crop management is dominated by the economic pressure and by the social request to increase the transparency of environmental impact of agricultural land. Currently, worldwide there are the public policy a...
Autori: Vergil Marian Muraru, Cornelia Muraru-Ionel, Ion Pirna, Ion Tenu, Petru Cardei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25504

Abstract Preliminary investigation of contaminated soil in the surrounding area of a petroleum tank has been carried out based on fluorescence techniques: excitation emission matrix (EEM) and synchronous fluorescence scan (SFS). A fluorescence fingerprints library containing several EEM and SFS maps for various dilutions of Romanian crude oil in methanol, was used to confirm the identity of the soil contaminant. A calibration curve was created to estimate the contamination level of soil sampl...
Autori: Dan Savastru, Elfrida M. Carstea, Gabriela Pavelescu, Luminita Cristescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25505

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract In the textile finishing and dyeing industries, the total volume of water consumed is around 150 millions tons/year, and thus very large quantities of water are processed and produced as wastewater by textile plants. Quality indicators of textile wastewaters, like BOD and COD, have values which, in some cases, exceed 5 times the maximum concentration value (allowed by the national quality standards). One of the greatest concerns in wastewater treatment of a textile effluent is the co...
Autori: Daniela Cailean, , Florin Brinza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25538

Abstract The paper presents the surfactant-assisted solvo-thermal route to synthesize nanoparticles of cerium oxide with different shape and morphology. The precursor was calcined at 400°C for 4 h in order to obtain CeO2 nanoparticles. The obtained samples were characterized by means of thermal analysis and FTIR spectroscopy. The UV-Vis analysis was used to study the optical properties. The morphologies and nano-structures were characterized by scanning electron microscopy (SEM) and XRD. It...
Autori: Nicolae Apostolescu, Gabriela Carja, Gabriela Apostolescu, Elena Husanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25541

Abstract Starting from the disadvantages of the polystyrene system – the most important being that they are not biodegradable and their life cycle is relatively small, up to fifteen years – there were conceived several structures for outside walls made of perforated bricks vertically disposed and filled with granular materials. In this manner the thermal resistance is improved knowing that in gaps bigger than twenty millimeters there appear convective streams which substantially decrease ...
Autori: Răzvan Giuşcă, Vladimir Corobceanu, Raluca Giusca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25551

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract Organic matter is ubiquitous in every type of aquatic system and due to the influence that it has on their ecological health, can be used as a useful water quality indicator. Fluorescence spectroscopy has been efficiently used in the past decades to determine and characterize organic matter, and its link to function and chemical water quality. In this paper, fluorescence fingerprints are presented in order to evidence the anthropogenic influence on different aquatic systems. Using f...
Autori: Elfrida M. Carstea, Luminita Ghervase, Gabriela Pavelescu, Dan Savastru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25576

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract When plants are exposed to heavy metals influence, the processes of growth inhibition, ion leakage of all membrane, distribution of pigment and even more death of plants are produced. The physiological and biochemical changes in germinating seedling and cultivation in plastic pots experiments of different plant species (maize, bean, oat, and spinach) were investigated under the influence of copper ions as stress agent. Differences between tolerances against copper excess in the case ...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25578

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract In this work the method for the treatment of industrial waste waters effluents containing hexavalent chromium in three companies during process of treating metal surface with chromic acid is described. Industrial water polluted with hexavalent chromium is collected in separate sewage system. Polluted water is collected in precipitation tanks which are directly connected with neutralization reservoirs. The treatment process includes pre-neutralization by lime-milk, sedimentation, floc...
Autori: Igor Creţescu, Mirjana Cvijovic, Predrag Djurdjevic, Slavica Cvetkovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25596

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

PM10-2.5 and PM2.5 samples were collected from December 2007 to January 2008 at six sampling sites in Urumqi Xinjiang, China. The concentrations of seven kinds of water-soluble ions––SO4 2-, NO3-, Cl-, NH4 +, K+, Na+, and Ca2+––were analyzed using ion chromatography. The concentrations of heavy metal elements, Cr, Co, Cd, Pb, and Hg were measured using inductively coupled plasma mass spectrometry (ICP-MS). The results indicated that, in PM2.5 and PM10-2.5, the average mass concentration ...
Autori: Talip Dilnur, Tursun Yalkunjan, Manabu Igawa, Yimit Abulizihttp://www.ecozone.ro/reviste.php?RID=25683

A series of sodium bentonites as raw material were prepared to the modified inorganic iron-nickel montmorillonites and organic composite montmorillonites. The structural characterization and morphology of the iron-nickel crosslinked modified bentonites were observed by means of IR spectroscopy, X-ray diffraction, scanning electron microscopy. The effects of the amount of bentonites, adsorption time and pH change on the adsorption of Cr(VI) have also been studied. The results indicated that the a...
Autori: Shao Hong, Cao Ninghttp://www.ecozone.ro/reviste.php?RID=25695

The paper analyses the removal efficiency and fluorescence spectroscopic characterization of landfill leachate dissolved organic matter (DOM) fractions in the combined stripping, fenton oxidation, sequence batch reactor, and coagulation process. The high contents of DOM of landfill leachate in each process unit were fractionated into HA, FA, and HyI. The result was the combined process availability for effective removal of DOM fractions. The removal rates for DOM, HA, FA and HyI were 91.9%, 97.1...
Autori: Zhiping Liu, Jin-song Guo, Fang Fanghttp://www.ecozone.ro/reviste.php?RID=25702

Abstract:Under the circumstances of the deficit in total energetic resources of the Republic of Moldova, non-traditional sources as wind,solar and hydraulic energies are very opportune. Concurrently with the conventional energy resources (fossil fuels, atomic energyetc.), wind energy begins to regain its positions not only from ecological, but also from economical point of view. Also, the windenergy conversion systems could play a significant role in the production of mechanical, electrical ener...
Autori: Anatol Sochireanu, Ciupercă Rodion, Ion Bodnariuc, Ion Bostan, Ion Dicusară, Ion Sobor, Iulian Malcoci, Marin Guţu, Nicolae Trifan, Oleg Ciobanu, Radu Ciobanu, Radu Crudu, Valeriu Dulgheru, Viorel Bostan, Vitalie Gladîş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25717

Abstract:In this paper, the influence of two types of imidazolium-based ionic liquids (ILs) on the properties of sycamore maple (Acer pseudoplatanus) veneers, at 25 0C, 60 0C and 80 0C has been studied by using contact angle measurements and Fourier transform infrared spectroscopy analysis. The measurements showed that wood wettabillity is increased by IL treatment. It has been determined that the ILs decrease the crystallinity and improve the flexibility of the cellulose matrix. Also, it has be...
Autori: Attila Porzsolt, Catalin Croitoru, Christian Friedrich, Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25737

Abstract:The paper presents the influence of different WO3:TiO2 ratios on the photocatalytic and photoelectrolytic properties of the films.The investigations are focused on the morphological (Atomic Force Microscopy, Contact angle), compositional (X-raydiffraction), optoelectric (conductivity, photocurrent) and photocatalytic properties of titanium dioxide films mixed with tungstenoxide. The most important application of these layers is in wastewater purification and hydrogen production using ap...
Autori: Alexandru Enesca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25743

Abstract:This study aimed to assess the coagulation performance using simple aluminum sulfate (Alum) and pre-hydrolyzed polyaluminumchloride (PACl) coagulation agents by conventional global parameters, i.e., turbidity and organic matter expressed by totalorganic carbon (TOC) and chemical oxygen demand (COD), and non-conventional spectrophotometric parameters.Non-conventional spectrophotometric parameters, expressed as absorbance recorded at different wavelengths, i.e., A254, A280,A365, allowed d...
Autori: Florica Manea, Georgeta Burtică, Ilie Pisoi, Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25777

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

Pollutants transfer via the food chain was investigated in a wetland ecosystem from the Lower Prut Floodplain Natural Park in Romania. Trace elements (Cd, Cu, Pb and Zn) were determined by Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) from samples belonging to primary producers and primary and secondary consumers, and also from water and sediments samples. Non-essential trace elements as Cd and Pb exhibited low concentrations in molluscs and fish, but zinc had shown conc...
Autori: Alin Tudorache, Gabriel Chisamera, Gabriel Lucian Radu, Iulia Gabriela David, Laurentiu Rozylowicz, Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25855

This paper presents original studies about the influence of mineral and/or organic fertilization on the minerals contents (P, Na, K, Ca, Mg, Fe, Mn, Zn, Cu, Ni and Pb) in leguminous plants from permanent grassland situated in a hill area of Banat County. Determination of minerals in grassland is very important both for the nutritional or toxic effects of these elements and their compounds, in the plants, animals and environment. Phosphorous was analyzed colorimetric and all the others metals hav...
Autori: Alexandru Moisuc, Iosif Gergen, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25858

The aquatic species are permanently subjected to various stresses through the ecosystem and the food habit. Elucidating the impact at the cellular level allows us to understand the ways in which the polluting elements and their derivatives can disrupt the metabolism of aquatic organisms triggering apoptosis in individual cells or necrosis affecting groups of neighbouring cells. The aim of this preliminary study is to highlight the influence of the environmental factors on two fish population by ...
Autori: , Camelia Ureche, Dorel Ureche, Gabriel Lazar, Ileana Denisa Nistor, Irina Loredana Ifrim, Iuliana Mihaela Lazar, Marius Stamate, Valentin Nedeff
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25861

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

In this study, we have tested the possibility of utilization of three types of natural low-cost sorbents: (Sphagnum moss peat, natural moss peat and alkaline treated moss peat) for the active biomonitoring of air quality from Căliman National Park area (Dorna Basin), during of two months (September – October 2010). The concentrations of some heavy metals (Pb, Cd, Cu, Mn and Fe) in the sorbent samples were used as an indicator of the level of air pollution in the studied region. After expo...
Autori: Iulian-Ovidiu Sandu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25868

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Herbicides industry is a large consumer of water, as well as a major wastewater generator, its effluents contain priority organic pollutants in very high concentrations which have severe effects on human health and on the environment due to their toxicity and bio-recalcitrant nature, persistence in the environment and bioaccumulation. A vast number of herbicides and other priority organic pollutants have been found in wastewater effluents, surface water, and drinking water around the world. The ...
Autori: Bianca Weinberg,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25874

Measurements of radium concentrations in water are important from the health protection point of view, so simple and reliable analytical methods must be available. In this paper we have determined the radium activity concentration in 24 spring waters which are used as potable water reservoirs. For this purpose we used radon emanation technique and also alpha spectrometry method. This work gives details of sample processing, Lucas cell and the methodology used in the emanation method. In the meas...
Autori: Alida Timar Gabor, Constantin Cosma, Oana Alexandra Rusu, Robert Csaba Begy, Simina Dreve
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25878

Fluorescence spectroscopy is a promising approach to the characterization of natural aquatic components and organic pollutants, due to its rapid analysis and high sensitivity. Petroleum products had been studied, using fluorescence technique, in numerous occasions, as seawater and soil contaminant or as raw sample. Nevertheless, no complex assessment has been made on fluorescence real–time spectra of freshwater diesel oil contamination. This study reports a 5–days experiment on an urban rive...
Autori: Elfrida M. Carstea, Gabriela Pavelescu, Luminita Ghervase, Marina Tautan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25882

Quantification of the floristic matrix is important both for animal’s nutrition and for the biodiversity monitoring of plants species under the influences of substance flow. Our researches have the main aim to study the possibilities offered by Infrared Spectroscopy in rapid, unpolluted and non-destructive analysis of floristic matrix modification from perennial grassland fertilized with organic and/or mineral fertilizers. It was performed three different FTIR models: for Poaceae (R2=0.949; RM...
Autori: Iosif Gergen, Moisuc Alexandru, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25892

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

AbstractIn this paper, we report a study on structural evolution, magnetic susceptibility and arsenic content of colloidal pyrite fromXinqiao deposits in Tongling, Anhui Province, China. The pyrite was treated under N2 atmosphere and charaterized with X-raypowder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), magnetic susceptibility analysis, and atomicfluorescence spectroscopy (AFS). We observed that heating of colloidal pyrite in N2 atomosphere did not change the crys...
Autori: Dong Chen, Ping Li, Tianhu Chen, Xiao Zhu, Yadan Shi, Yan Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25951

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

AbstractThe huge emission of greenhouse gases from fossil-fuelled power plants is emphasizing the need for efficient Carbon Captureand Storage (CCS) technologies. The biomimetic CO2 absorption in aqueous solutions has been recently investigated as apromising innovative alternative for post-combustion CCS. The carbonic anhydrase (CA) - a broad group of ubiquitous enzymes– may catalyse the CO2 hydration reaction and then to promote CO2 absorption rate into aqueous solutions. Nevertheless theresear...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Maria Elena Russo, Piero Salatino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25976

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractA comparative study regarding the shape, dimension and bactericidal activity of the undoped and Ag-doped TiO2 nanocrystalswas achieved. In this way, two hydrothermal methods, classical hydrothermal and microwave-assisted hydrothermal, was usedfor nanoparticles synthesis. The obtained materials were investigated by X-ray diffraction, DRUV-VIS spectroscopy, BET andSEM/EDX analysis. Antibacterial activity of undoped and Ag-doped TiO2 materials was tested on real water from Bega River.The be...
Autori: Carmen Lazau, Corina Misca, Corina Orha, Cornelia Bandas, Sorin Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26034

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

AbstractWater quality is an inportant concern for the ecosystem state from a particular region. Since the continuous urban and economicdevelopment induces a negative impact on entire hydrological cycle, this study investigates the water quality of a Romanian lake,located in the Surduc area - Timis County. This perimeter has undergone significant economic development in the past twodecades due to increased tourism potential and the number of holiday residences.We proposed hybrid materias for the ...
Autori: Adina-Elena Segneanu, Cornelia Bandas, Florentina Cziple, Ioan Grozescu, Paula Sfîrloagă, Titus Slavici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26040

AbstractThe paper intends to contribute to the stages of bioremediation technologies elaboration, by means of experiments and efficiencydemonstrations of adequate biological depollution and ecological reconstruction methods. During the 2009-2011 period, heavymetals and metalloids, etc phytoextraction tests were performed with Lolium perenne L, from tailing samples collected fromwaste heaps and tailings dams of the mining exploitations (Rodna, Bistriţa–Năsăud, Fundu-Moldovei, Sucea...
Autori: Alexandru Crihan, Alin Bolonyi, Bianca Malschi Florian, Cecilia Roman, Dana Malschi, Dorian Brăhaiţa, George Ghira, , Marin Şenilă, Mirela Miclean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26044

AbstractTraditionally, sanitary papers are obtained from virgin cellulosic fibers. Because the production of virgin fibers requires largequantity of wood it is an unsustainable process. In addition, virgin fiber pulp is expensive and deficient, being unattractive forpaper producers. Using of virgin fiber is a waste, because sanitary papers cannot be recovered. Due to the fact that the price ofsanitary papers must be as low as possible, the paper mills focused on the use of recovered fiber as raw...
Autori: Dan Gavrilescu, Iftimi Viorel, Roxana Vlase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26067

AbstractThe removal of residual oil from palm oil mill effluent (POME) using boiler fly ash was studied in this paper, with focus on theadsorption isotherms and kinetic studies by measuring the residual oil concentration using UV-spectrophotometer. The percentresidual oil adsorbed decreased from 80% to 5% as contact time was increased from 10 mins to 120 mins but increased from2.74% to 72.98% as initial concentration of residual oil increased from 0.04812 mg/L to 0.2406 mg/L. Pseudo-second order...
Autori: Jude C. Igwe, Stella N. Anioke, Uche Arukwe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26078

AbstractEight species of macromycetes which grow in phytocoenosis from “Călimani National Park” (Eastern Carpathians, Romania)have been analysed using Fourier Transform Infrared spectroscopy (FTIR). Among the analysed species, five species are beingconsidered edible (Clitopilus prunulus, Pleurotus eryngii, Macrolepiota rhacodes, Lacaria laccata and Suillus luteus) and threespecies are being considered toxic (Lyophyllum connatum, Paxillus involutus şi Gyromitra infula). The results of f...
Autori: Aurel Pui
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26091

AbstractThis paper presents the results of the research analyses and laboratory studies, aiming to develop design guidelines and suitabletechnologies for the construction of durable and environmental friendly rigid pavements by using recycled cement concrete,resulted from various demolition works. Various recycling principles and technologies, specific laboratory methods of improvedtechnical solutions to enhance wear coefficients, density homogeneity, mixture contamination and water absorption o...
Autori: Marius Muscalu
ISSN: 1843 - 3707Abstract This paper presents the results of the research analyses and laboratory studies, aiming to develop design guidelines and suitable technologies for the construction of durable and environmental friendly rigid pavements by using recycled
http://www.ecozone.ro/reviste.php?RID=26098

Abstract Being involved in the synthesis of precursors for amphetamine and amphetamine-like drugs, pyridine (Py) may be also regarded as a by-product found when these drugs are obtained via the Leuckart method. Also, pyridine is well known as a biomarker of microorganisms, when those are subjected to pyrolysis before analysis by various instrumental techniques. Consequently, since Py is not commonly found in the air, its presence as a contaminant at trace levels in a room could ind...
Autori: George-Bogdan Ghira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26109

Abstract Known as the most important byproducts of water disinfection with chlorigen chemicals, trihalomethanes (THMs) are incriminated in causing severe effects upon human health. The exposure pathways that can lead to potentially significant uptake of THMs include for adults ingestion of tap water and inhalation of THMs in vapor phase resulting from bathing, showering and washing. The purpose of this paper is the exposure assessment to THMs through ingestion, inhalation and derma...
Autori: Anca Elena Gurzău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26110

Abstract Poly(hydroxybutyrate) (PHB) is a biodegradable thermoplastic polyester with very high potential for industrial applications. The properties could be improved by mixing with another polymer, natural or synthetic, such as poly(vinyl alcohol) (PVA). The resulting polymer blends are potentially able to achieve the desired performance for different applications. Biodegradation modifies mechanical, physical and chemical properties of a given material. PHB are degraded by diverse...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26111

Abstract This study focuses on the local scale behavior of SO2 emissions resulting from lignite-combustion thermal power plants. The investigations aimed at monitoring the SO2 emissions and imissions over a two week period in September 2010. One of the largest power plants from Eastern Europe was chosen for monitoring using different optoelectronic techniques. Rovinari power plant (44o54’45”N – 23o09’44”E) is one of the largest electricity suppliers of Romania, having 4 groups of 3...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26113

Abstract This research has been performed during summer time at Iasi Atmosphere Optics, Spectroscopy and Lasers Laboratory site (LOA-SL), aerosol monitoring station (47.19N, 27.55E). In order to properly identify and characterize the aerosol types, Aerosol Robotic Network (AERONET) data and sun-photometer measurements were analysed using parameters such as: optical thickness, spectral dependence of Ĺngström exponent (α), spectral dependence of Single Scattering Albedo and the ...
Autori: Florin Unga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26116

Abstract Our researches have focused primarily on variations of different biophysical and biochemical effects on vegetal and animal material at macro, micro, and ultra-micro scale resulted from changes in environmental condition. Growth and spectral parameters of rapeseed seedlings from seeds exposed to UVA-VIS radiation with a high pressure lamp which emits incoherent continuously radiation for different time periods were examined 14 days after germination. These studied parameter...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26138

Abstract Avocado post-harvest losses and cultivar-oriented trade are relevant issues in Cameroon that affect producers and retailers incomes. Identifying specific chemical characteristics of avocado oils would give an added value to underutilized species. Five avocado varieties, Booth 7, Booth 8, Collinson, Hickson and Lula, were subjected to aqueous extraction and the Attenuated Total Reflectance-Fourier Transformed Infrared spectrometry coupled with chemometrics (ATR-FTIR) profil...
Autori: Brice Ulrich Saha Foudjo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26143

Abstract Large amount of radioactive sources generate gamma rays of various energies and intensities. Gamma-ray spectroscopy is applied for the quantitative study of the energy spectra of gamma-ray sources. In the present paper, a statistical analysis of the energy spectra of gamma-ray spectroscopy monitored during 4 years at the “Dosimetry and Radioprotection” Laboratory from ”Vasile Alecsandri” University of Bacău is provided. Several new mathematical parameters were calcula...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26144

Abstract Biogas can be used as a renewable and green energy source by upgrading to natural gas. Water scrubbing, which is one of the most widely-applied upgrading technologies, involves an accurate knowledge of the solubility of the main biogas components in water, which is essential to the design and optimization of the biogas upgrading process. In this work, we use several thermodynamic models available in the Aspen Plus software modeling environment to calculate the solubilit...
Autori: Petronela Cozma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26148

AbstractThe reuse of a wastewater treatment system was investigated using intermittent media infiltration (IMI) to evaluate the fecalcoliform (FC) removal efficiency with natural zeolite containing clinoptilolite from the state of San Luis Potosí, Mexico and itszinc-modified form (Zeo-Zn). The municipal wastewater, which was from Saltillo, Coahuila, Mexico, was treated for FC analysisfor four months. The physicochemical properties of zeolite were analyzed, and their behavior as filter media for ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26212

AbstractDespite the Moderate Resolution Imaging Spectrometer (MODIS/Aqua) presently collects data on operational basis, evaluationof its biogeochemical products from standard bio-optical algorithms is scare especially in Arctic waters. The present study isaimed to evaluate several MODIS/Aqua bio-optical algorithms and MODIS/Aqua remote sensing reflectance (Rrs) products inKongsfjorden waters on the western side of Svalbard, Arctic. Data sets consisting of in-situ measurements of radiometric quan...
Autori: Palanisamy Shanmugam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26220

AbstractIn an urban environment, visibility strongly reflects human safety and welfare. Generally, visibility is dependent on particlescattering and absorption. The former is influenced by light wavelength, atmospheric gaseous species and particle characteristics,especially number and size distribution. Therefore, it is necessary to establish the relationship between visibility and particlecharacteristics. Furthermore, it is important to understand the formation mechanism of secondary aerosols. ...
Autori: Chih-Ming Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26221

AbstractIn this study, changes induced in milk processed at ultra high temperature (UHT) were investigated following exposure to UVand white-light, by employing fluorescence spectroscopy. Two important indicators, namely Riboflavin (Rb) and vitamin A,were monitored to evaluate the light-induced damage in milk. It was noticed that the photo-degradation of Rb is due to thephotochemical decomposition and photosensitization. Moreover, it was found that the wavelength of the exposure light has agreat...
Autori: Maria Iliut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26241

AbstractThe intercalation of 2,6-dichlorobenzonitrile (DBN) into the NiMgAlLDH, CuMgAlLDH and MgAlLDH layered doublehydroxides was carried out using the calcination-rehydration reaction using NiMgAl, CuMgAl and MgAl oxide precursors,obtained by calcination at 550oC. X-ray diffraction (XRD), elemental analysis, infrared spectroscopy (FTIR) andthermogravimetric analysis (TG-DTG) confirmed that DBN molecules were successfully intercalated into the interlayer spaces ofLDHs. The resulting solid produ...
Autori: Mihaela Silion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26244

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractThe aim of this study is to elaborate a survey on the efficiency of three anti-aging cosmetic formulations by applying FourierTransform Infrared Spectroscopy (FTIR) with Attenuated Total Reflection (ATR) in order to characterize and identify thespecific recognition markers of the active ingredients. FTIR (ATR) spectrometry in specific regions was applied also to theingredients used in these products, depending on their role in the specific cream. Comparing the different composition of th...
Autori: Anca Maria Juncan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26261

AbstractThe main objective of this study is to investigate the utilization potential of oil well-derived drilling waste (DW) in the firedshale-brick production. Different mixtures were suggested for the experimental work with the DW content varying from 20% to40%. The prepared briquettes from different mixture were fired at a temperature ranging from 950°C to 1050°C for 1 h, with aheating rate of 2~3°C /min. Water absorption, apparent porosity, bulk density, weight loss by ignition, firing shrin...
Autori: XiangGuo Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26269

AbstractLithuania is planning to construct a new nuclear power plant nearby the closed one. The possible radioactive pollution can be one of the main problems in its surroundings. Results of investigations of the gamma radiation equivalent dose rate (EDR) at new nuclear power plant sites are presented. Main factors influencing the level of the EDR are identified and evaluated, and geological structure of alternative sites is discussed. The gamma spectrometry data showed that the dominant influen...
Autori: Raselė Girgždienė, Vigilija Cidzikienė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26277

AbstractLead (II) can bind with papain at its active site, destroying the enzymatic activity. Papain a sulfhydryl protease has beenimmobilized in calcium alginate bead for the purpose of removal of lead (II) from industrial waste water. Effect of lead (II) onthe enzyme activity of immobilized papain, has been observed. A detailed kinetic study has been carried out and the data arefitted to different kinetic models. EDS (Energy Dispersive X-Ray Spectrometry) and desorption study suggest that meta...
Autori: Aparupa Bhattacharyya, Parameswar De, Soumasree Chatterjee, Srabanti Basu, Susmita Dutta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26338

AbstractThis paper discussed the potential ecological risk, homologous relativity and spatial distribution of heavy metals in the waterlevel-fluctuating zone (WLFZ) of the Xiao River, a tributary of the Yangtze River. The Cd, Cu, Pb and Zn contents in the WLFZsoil were analyzed via atomic absorption spectroscopy. The potential ecological hazards of the heavy metals were also evaluatedusing the classical Lars Hakanson potential ecological risk index method. The average Cd, Cu, Pb and Zn contents ...
Autori: Chuan Fu, Dan Liu, Junjie Lin, Zhiguo Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26346

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractEvaluation of radon concentration is a very difficult task and a very important issue, in relation to the protection of human health.This is especially the case when there is an increase in concentration of radon on a deterministic basis, as is the case of nearbyphosphogypsum residues or geological characteristics. Radon gaseous that can be found in the environment occurs mainly fromnatural radioactive decay chains. The gamma ray spectroscopy is a powerful tool in order to monitor the en...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26441

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractFluorescence spectroscopy and parallel factor (PARAFAC) form a powerful tool in separating different fluorophores and maybe useful in detecting the fluorescent signature of dissolved organic matter (DOM). Despite the large number of studies onfluorescence and PARAFAC it is still uncertain if this combination is capable to separate DOM from different water types byanalyzing the presence of specific components and their spectral shape. This paper presents a preliminary study on thefluoresc...
Autori: Elfrida M. Carstea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26495

AbstractConcentrations of seven heavy metals (Cd, Cr, Cu, Fe, Ni, Pb and Zn) in the discharged effluents of four wastewater treatmentplants located on the Romanian Black Seacoast, evaluated as average values for four seasons, during 2010-2011 are presented.Total and dissolved metals occurrence was investigated from seasonal samples, to assess the bioavailability of the heavy metalsin the discharged effluents. The analytical measurements were performed by flame atomic absorption spectrometry (FAA...
Autori: Elisabeta Chirilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26498

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractAtomic absorption spectrophotometry (AAS) technique was applied in order to identify the occurrence of certain heavy metals insamples of pork products, such as bacon, ham, sausage and salami, taken from four commercial centers in Romania. Lead levelsin samples varied from 0.58 to 0.96 mg/kg, Cadmium values from 0.11 to 0.21 mg/ kg, Copper from 0.73 to 1.32 mg/kg, whileZinc levels were detected between 32.19 and 42.12 mg/kg. Lead, Copper and Zinc found in samples were lower than themaximu...
Autori: Gabriel Vasile Hoha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26522

AbstractGreywater (GW) has attracted global attention as an alternative water source over the last few decades. GW treatment andreliable reuse require the overall qualitative characterization of samples from different sources. This paper represents aninvestigation of household-generated GW in the Northern Great Plain Region of Hungary. Modern and reliable analyticaltechniques and instruments (ion chromatography, microwave plasma atomic emission spectrometry, Zetasizer Nano Z analysis,etc.) were ...
Autori: Ildiko Bodnar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26528

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractThe aim of this work is to study the valorisation of two regenerated low density polyethylene (LDPE) coming from dirty wastesby blending with polypropylene (PP) in presence of compatibilizer. The first step was the determination of the physico-chemicalproperties of the two regenerated samples (density, melt flow index, water absorption, melting temperature and oxidation index)and the mechanical properties (tensile and shore D hardness).The second step was the characterization of the phys...
Autori: Nabila Guerfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26565

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractEnd-of-life tires are waste materials that pollute landscapes when they are disposed of in tire dumps. However, its life cycle is notfinished when they are scrapped. The rubber of end-of-life tires could be used for new purposes as construction material in roadrehabilitation. A gap-graded mix characterization was carried out in this work by means of laboratory and field performancetests. The mixture has a high content of crumb rubber (CR) by weight of bitumen. Crumb Rubber was added to t...
Autori: Victor F. Vázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26577

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

Abstract The present study was conducted to determine the heavy metals (Fe, Mn, Zn, Cu, Pb, and Cd) and essential oils content in the berries of Juniperus phoenicea L. grown in two different geographic origins; Dana conservation and Al-Hisha forest in Jordan. Atomic absorption and Hydrodistillation methods were used to determine heavy metals concentrations and oil contents in plant samples of J. phoenicea L., respectively. Results showed that, the oil yielded from J. phoenicea L. berries in ...
Autori: Mohammad Sanad Abu-darwish
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26595

Abstract This article covers the investigation of the catalyst waste (T.R.M 1 and T.R.M 2) produced in the reactor of oil catalytic cracking. The analysis of this waste was carried out. The properties of T.R.M 1 and T.R.M 2 were investigated and determined, the mineralogical analysis of catalyst waste was implemented, the analysis of thermal effects during the burning was performed. Catalyst waste materials investigated were used in a ceramic system (from 7  to 20  of the ove...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26600

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract Heavy metals, such as Cr (chromium), have received attention during recent years due to their disposal in soil and water. Brave peanut (Pterogyne nitens Tul.), a tropical tree, was cultivated in 500 mol L-1 Cr+6 to observe how this species responds to this stress, with a view to its possible application in the restoration of degraded areas. In the present study, we report the use of a new method, photoacoustic spectroscopy, to evaluate the emission of CO2 and ethylene and th...
Autori: Luisa Brito Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26602

Abstract This article presents the results of investigations addressing the accumulation of heavy metals in different layers of the Lake Talkša, Lithuania. For the sampling from the ice of intact structure of the sediment the turf borer was used. Concentrations of these heavy metals in sapropel layers were determined in the extracts of sapropel. After the preparation of samples, the concentration of Pb, Ni, Cr, Zn and Cu were measured in the laboratory by means of atomic absorption sp...
Autori: Justyna Kozlovska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26615

Abstract This study examined the characteristics of geopolymer with solar panel waste glass. After 28 days of curing, the compressive strengths of the geopolymer samples containing 10 mass % and 20 mass % solar panel waste glass were 63.3± 1.8 and 49.1 ± 2.2 MPa, respectively. The geopolymer sample with 10% solar panel waste glass exhibited a stronger reaction than that with 20% solar panel waste glass, and the strength decreased as the amount of solar panel waste glass increas...
Autori: HuiCong Hao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26621

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon material was found to adsorb vitamin B2 from aqueous solution at room temperature. The obtained ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26679

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract Recently several innovative suggestions on how industrial wastes can be utilised in new products have been presented in literature, e.g. as filler or additives in concrete, incorporated in ceramic materials to produce glass-ceramics and pavement construction. In this work, metallurgical materials from secondary aluminium scrap processing and glass waste derived from treatments of packaging and fluorescent lamps were considered for fabrication of new ceramic materials using powder te...
Autori: Rosa Taurino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26794

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract The feasibility of treating tannery wastewater having high organic loads was studied using ceramic membrane based microfiltration process. The common effluent treatment plant (CETP) of a centralized leather complex was selected for the study which accommodates about 450 tanneries in the city, processing hides from raw to finished products. Effluent sample was collected from different locations of the CETP, i.e. untreated composite effluent, effluent from primary clarifier and from ...
Autori: Priyankari Bhattacharya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26837

Abstract Flame atomic absorption spectrometry (FAAS) and X-ray fluorescence spectrometry (XRF) were used as investigation techniques in the assessment of soils contaminated with metals such as Pb, Cu and Zn. The investigation focused on the comparability of the concentrations determined by the two methods, in order to identify the most suitable approach for Pb, Cu and Zn quantification, with respect to metal monitoring in brownfields. Generally, the concentrations obtained through FAAS were...
Autori: Maria Lucia Bizo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26875

Abstract The aim of this study was to determine the content of the main essential trace (Co, Cr, Cu, Mn, Se and Zn) and toxic (As, Cd, Hg and Pb) elements in milk by inductively coupled plasma-mass spectrometry (ICP-MS) and cold vapor atomic fluorescence spectrometer (CV-AFS) following priory microwave-assisted digestion with HNO3-H2O2. The milk samples were collected from local small-scale producers of different parts of Rodnei Mountains, Eastern Carpathians, Romania. Mean concentrations in...
Autori: Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26876

Abstract In the present study, several selected formulations based on recycled (rPP) or virgin polyolefins (vPP) and lignocelluloses were prepared and subjected to microorganism attack. Biodegradation tests were performed with microbial strains belonging to fungal genera, like Aspergillus, Penicillium and Fusarium. The initiation of biodegradation was demonstrated by Scanning Electron Microscope (SEM) micrographs showing the colonization of surface samples by microbial strains. The crystalli...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26879

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract Ash resulting from wood combustion constitutes a waste disposal problem to facility owners. The use of ash fertilizer or soil amendment could provide nutrients for agriculture if its nutrient content is adequate and it does not contain harmful amounts of heavy metals. The recycling of nutrients bound in ash would provide an inexpensive solution to waste problem. In our study, we aimed to characterize ash and clinker resulted from incineration of oak waste resulted from wood industry...
Autori: Ioan Oroian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26885

Abstract The CoCrMo alloys have been widely used in artificial knee or hip joints. It is well known that these materials have a good corrosion resistance and acceptable biocompatibility properties. Zirconia as a ceramic biomaterial facilitates the osteoconductivity and tissue osteogenetic capacity in new bone formation around implant. Linear polarization and electrochemical impedance spectroscopy (EIS) were employed to characterize the electrochemical behavior of plasma sprayed yttrium oxid...
Autori: Manuela Romaş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26896

Abstract The design, the realization of the prototype and the acoustic standardization process of a novel periodic system made up of multiphysical phenomena scatterers as a road traffic noise reducing device are reported in this work. The structure analysed here, inspired by Sonic Crystals, has been designed following the guidelines established in recent works according to the concept of tunability. Thus, the acoustic barrier proposed here includes several mechanisms of noise control, such a...
Autori: Sergio Castińeira-Ibáńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26900

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Abstract The possibility to use release controlled fertilizers in the agriculture of the tropical countries is more important than in the agriculture of the countries of the cold regions. In this context, the purpose of this work is the characterization of an encapsulated commercial Fertilizer of Controlled Release named FERLENT®, which was covered with a polymeric material, obtained in situ, under controlled conditions, which allowed to corroborate the fairly well adjustment of the synt...
Autori: Mayra González Hurtado
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26916

In this work biodegradation of basic fuchsin and methyl red by the blue green algae Hydrocoleum oligotrichum and Oscillatoria limnetica was investigated. The degradation of basic fuschin after 7 days by H. oligotrichum and O. limnetica was 92.44% and 90.23%, respectively. On the other hand, the degradation of methyl red by H. oligotrichum and O. limnetica after 7 days was 53.23% and 50.18%, respectively. The degradation of these dyes by algae seems to be related to the molecular structures of...
Autori: Ghada W. Abou-El-Souod
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26949

Various plants were investigated here as bioindicators for control of the environment. Grass, moss and leaves of maple, birch and oak from different locations, i.e., mining, chemical industrial sites and open green area in a small industrial town in the southwestern Poland (Zloty Stok) were examined. Concentrations of As, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Se, Sr, Ti, V and Zn were measured by the ICP-OES and CVG-ICP-OES techniques. Infrared spectroscopy (FT-IR) was used to inves...
Autori: Lukasz Zarebski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26951

The influence of the Black Sea on the continental climate is generally limited, comparatively with other maritime basins. Nevertheless, the influence is important for local scale environment, with several applications in the economy, i.e. building industry, agriculture, forestry. The extension of the Black Sea influence inside the Dobroudja Plateau has been tackled constantly by the Romanian climatologists, the main methodological problem being the low number of meteorological stations in Do...
Autori: Sorin Constantin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26963

Cameroon's coast that is located in the Guinea Gulf oil region was exposed to hydrocarbon pollution due to oil exploitations and other petroleum activities. The intrinsic biodegradation of hydrocarbons is essential for the depollution methods of the marine environment. Nevertheless, these do not represent a common practice in Cameroon. This study aimed to assess the capacity of bacteria of Cameroon’s waters coast to degrade gasoline and diesel. The kinetic degradation of gasoline an...
Autori: Lucie Leme Banock
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26983

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

Biomass is a very important source for the production of biofuels. During the hydrolysis step of the process for obtaining biofuels the rate of decomposition of biomass is strictly related to its organic matter content and the operating mode of the facilities. This paper highlights the effect of different pretreatments on the composition of biomass at the molecular level using Fourier Transform Infrared Spectroscopy (FTIR) and Principal Component Analysis (PCA). For this experiment, a mixture...
Autori: Andreea Cocarcea Rusei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26986

This paper reports the distribution of natural uranium in different underground water sources and health risk evaluation around Narora Atomic Power Station, Narora, India. The uranium concentration at studied locations ranged from BDL (<0.2 μg/L) to 32.37 μg/L with geometric mean (GM) of 6.4 μg/L and geometric standard deviation of 7.85. The life time average daily dose of uranium in drinking water was 0.64 μg kg-1 day-1. The cancer morbidity and mortality risk were also calcul...
Autori: Manbir Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27001

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

Fly ash is the major residue produced during the combustion of coal. Research has been carried out to recover silica and alumina from fly ashes collected from different thermal power plants in India. Silica and alumina from the fly ash were recovered and the recovered products were subjected to X-ray diffraction, X-ray fluorescence and Inductively Coupled Plasma-Optical Emission Spectroscopy analyses to estimate the silica and alumina content. Total recovered silica content in the samples was...
Autori: Ruth Sherly Endluri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27007

This paper presents the results of measurements related to the activity concentrations of 226Ra, 232Th and 40K in autoclaved aerated concrete (AAC) used as building materials for various constructions in Romania. Radiation index (I) and the hazard index (HI) were estimated to assess the risk arising from the usage of AAC materials. Our study considered various AAC samples produced by different companies, in 2015. The activity concentrations of 226Ra, 232Th and 40K were measured using by a gam...
Autori: Dorina Nicolina Isopescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27018

Zirconia (ZrO2) as a ceramic biomaterial facilitates the osteoconductivity in new bone formation around implant. Surface characterization before and after electrochemical testing was performed used scanning electron microscopy (SEM). The electrochemical properties of the yttrium oxide stabilized zirconium oxide (YSZ) coated and uncoated MgCa sample with the open circuit potential at different immersion time in Ringer’s solution were studied by electrochemical impedance spectroscopy (EI...
Autori: Bogdan Istrate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27021

Air quality became a concern of highest priority in cities and town agglomerations, worldwide. Professional environmental monitoring strategies are prerequisites for supplying appropriate programmes destined to maintain air quality. Due to their capacity of bioaccumulation, tree species may be used as biomonitoring agents within programmes of monitoring air quality in urban spaces. The present study aims to emphasize the ability of A. hippocastanum L., and T. cordata Mill. leaves to be used a...
Autori: Ilie Covrig
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27026

The aim of this study was to determine the impact of mercury pollution on soil, surface water, and sediment ecosystems in the area of old mercury mines. The study was performed in the touristic area of Sântimbru Băi and Sâncrăieni villages from the Harghita County, Romania. More than twenty years ago, a mine for the extraction of mercury operated in Sântimbru Băi. The area was decontaminated, but no monitoring studies have been made for over 15 years. During t...
Autori: Luisa Roxana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27038

This paper presents a research on ways to reduce waste and to diminish sound pollution by recovery of fir sawdust and recycled rubber granules and use in making sound absorbing composite materials. Four materials were prepared using raw materials (fir sawdust and recycled rubber granules) in various percentages, and polyurethane binder. Materials mechanical and acoustic properties were characterized, proving these materials have useful properties. Materials acoustic performance was compared w...
Autori: Ancuţa Elena Tiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27039

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

The aim of the present study was to prepare environmentally friendly silver-based materials using Cornus mas L. fruits extract. For this purpose, silver nanoparticles (Cornus mas-AgNPs) were green synthesized using this plant extract. The bioreduction of silver ions was analyzed by UV–VIS and ATR-FTIR spectroscopic studies. Scanning Electron Microscopy (SEM) analysis revealed the formation of spherical phyto-nanosilver particles with size ranging between 12 and 40 nm. Different amounts ...
Autori: Ioana-Raluca Suica-Bunghez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27139

In this study, the impact of silicate admixture in 2-line ferrihydrite on its sorption properties is presented. Synthetic ferrihydrites with broad Si content in the range of 0 to 1.5 Si/Fe molar ratios were prepared and characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDS). With an increase in the Si/Fe ratio, a typical XRD peak at 2.5Å broadens and shifts toward 3 Å; the position of Si-O stretchi...
Autori: Gabriela Pieczara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27140

The adsorbent gels utilized in this research project were synthesized from non-commercially available chitosan, obtained by deacetylation of chitin, which was isolated from fermented shrimp waste by a major local industrial food biopolymer. Chitosan-based adsorbent gels were used for the removal of a tris-azo dye (Direct Blue 71) from aqueous solutions. Sorption experiments focused on the chemical modification of chitosan using two cross-linking agents, sodium tripolyphosphate (TPP) and glutaral...
Autori: Reyna G. Sánchez-Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27184

Waste from a cola beverage industry containing high concentration of phosphorus (P) was treated by the struvite precipitation method. The influence of excess of ammonia and order of reagent addition were evaluated as independent variables on the removal and recovery of phosphorus from cola beverage waste. It was removed about 95% of P of the sample in a short reaction time. The precipitated crystals were identified and analyzed by X-ray Diffraction (XRD), infra-red spectroscopy (IR) and surface ...
Autori: Wilson Roberto Barreto dos Santos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27188

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

In this paper low power microwave radiation impact on Zea mays root meristeme tissues was investigated. Seeds with uniform genophond were exposed for 3 hours at 10 W incident power level in controlled condition to continuous wave at three different frequencies (0.6 GHz, 1 GHz and 2.5 GHz) and let to germinate after electromagnetic exposure. Dosimetric assessment made experimentally and computationally allowed the proper energetic characterization of the interaction between vegetal tissue and rad...
Autori: Mihaela Răcuciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27196

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

In this article we present the results of the study concerning the relationship between the concentration of trace elements (lead, chromium, cadmium, cobalt, copper, zinc and nickel) in soil and in the leaves and bark of Populus nigra L. The samples were collected in the period May 2010 – October 2010 in two areas from the Romanian North Littoral of Black Sea. The concentrations of the trace elements in soil, leaves and bark were determined using Flame Atomic Absorption Spectrometry (F...
Autori: Lucica Barbeş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27239

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

Different bioleaching processes were applied to mining wastes deposited in the highly polluted post-industrial region - Lower Silesia in Poland. The chemical characterization of the wastes before and after bioleaching processes was performed. The characterisation was based on the distribution of selected elements (Fe, Mn, As, Co, Cr, Cu and Ni) between operationally-defined phases. The phases were defined using a six-step extraction procedure optimised according to the properties of the studie...
Autori: Joanna Pałdyna
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27259

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

This study presents the results obtained in tailoring thin films of alumina, deposited onto aluminium substrates by spray pyrolysis, at 250°C, using AlCl3 solutions (0.15M) in a water:ethanol (1:1) solvent mixture. As morphology controlling agents, acetylacetone and maleic acid based copolymers are added in the precursors’ solutions. The precursors’ systems are analyzed by FTIR spectroscopy and the surface morphology of alumina thin films is investigated by atomic force microscop...
Autori: Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27291

Paintings signed by Nicolae Grigorescu and Stefan Luchian, exponents of Romanian Modern Art were selected for a technical study on easel painting canvases. Both the physical integrity and the appearance of the artefacts derive mainly from the strength of the canvas and the physical and chemical characteristics of the fibres imparting their response to deterioration. In order to determine a deterioration pattern for canvases subjected to environmental stress, a simulation on flax fibres samples w...
Autori: Maria Geba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27292

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

Considering the actual environmental issues, the waste management has become a major challenge in Europe and worldwide. Recycling the waste into sustainable products can be an alternative to landfill with positive effects on the costs and environmental pollution. In this respect, in the last years numerous studies and research emphasize the utilization of different type of waste to obtain materials for building applications. The aim of this paper is to assess the effect of using sewage sludge ge...
Autori: Petronela Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27315

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

In the current context of industrialization, chemical and radioactive pollution is a concern for environmental protection and interference with human health. Care for environmental protection also includes vegetation that grows spontaneously in potentially contaminated places, thus avoiding illness among the population if consumed. The study area is located at 4.5km SSE from downtown Bacău City, Romania and is the result of the manufacture of H3PO4 through the wet method. In this study, t...
Autori: Mioara Săndulache Rachieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27331

The objective of this study was to develop a naturally dyeing process of 70% wool /30% Angora mohair blended yarns by using bio-mordants as an environmentally friendly alternative for the conventional metallic salts. Bio-mordanting operation was achieved by using of condensed tannin extract from quebracho bark trees. Conventional mordanting has been performed using the conventional mordants like copper sulphate and tin chloride. Another specific objective of this study was to investigate the pos...
Autori: Ioana Stanculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27337

Acetone-Butanol-Ethanol (ABE) industrial production by fermentation is strongly affected by the low concentration of solvent (<25 g/L) that affects the cost of the recovery process. To decrease the overall cost of the butanol production, alternative routes for the recovery have proposed in literature. This paper presents a techno-economic analysis of an innovative butanol recovery process from ABE fermentation broth based on gas stripping technique. The comparison with a recovery process bas...
Autori: Lucia Salemme
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27346

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

This study presents mercury (Hg) assessment in water from tailing dumps collected form NW Romania by using commercial Diffusive Gradients in Thin-films (DGT) devices and Thermal Desorption - Atomic Absorption Spectrometry method (TD-AAS) technique. Additional aim of this study is to present Hg method validation and measurement uncertainty estimation for selected samples. An atomic absorption spectrometer based on thermal desorption for mercury vapor generation and DGT devices specific for Hg (c...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27383

A comparative study of humic substances (HS) extracted from raw sludge and its digested product was carried out in order to analyze HS evolution during sludge anaerobic digestion. HS content, elemental composition, functional groups, infrared spectra and ultraviolet absorbances were analyzed by means of chemical and spectrographic methods. The extracted HS were also fractionated by ultrafiltration in order to obtain their molecular weight (MW) distribution. The results showed that humic acids (...
Autori: Huan Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27390

This research was focused on the valorization of agro industrial waste/by products available in the local industry with the kilometer zero (km 0) concept, as a replacement of virgin raw materials (clay) to elaborate lightweight aggregates (LWAS). The alternative raw materials were employed as pore forming agent, in order to reduce sintering temperature and energy consumption of the furnace. The three technical nutrients studied were provided for local food industries: sludge from wastewater trea...
Autori: Romina D. Farias
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27405

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

This study analyses the relationship between the scattering properties and the chemical compounds internal mixture of the aerosols near Bucharest, Romania. Several cases of local aerosols influenced by heating sources, like wood or fossil fuel, are characterized in order to retrieve the winter period specificity. Correlation between organic and inorganic aerosols composition from mass spectrometry measurements made with Compact Time (CT) of Flight Aerosol Mass Spectrometer (AMS) and scatteri...
Autori: Luminita Marmureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27444

Considering that glass containers are generally highly transparent they are good candidates for spectroscopic measurements and application of a transmittance for glass separation. The selection of glass container samples directly from municipal waste disposal bins, characterized by different colors, thicknesses, and shapes was done. Transmittance spectra of clear, green, amber and black clean glass containers were recorded, along with spectra of the usual bottled liquids. Positions of the absorp...
Autori: Dragana D. Strbac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27452

In many laboratories, offices and home rooms exists devices and equipment working in the radio frequency (RF) and microwave (MW) bands. People working with these equipments may be exposed to electromagnetic fields of high density that can produce adverse effects on human health. It is suitable to perform measurements on the scattered fields, especially in the near-field regions (Fresnel’ radiating and reactive regions), where the incident power density can reach dangerous levels for occ...
Autori: Sorin-Bogdan Balmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27466

The paper presents results obtained by analysis of some soil and wastes samples in order to establish the heavy metal (HM) content from these samples. The analyzed wastes were sewage sludge from municipal waste treatment and hydrotechnical basin sludge. These types of wastes were mixed with soil from Oltenia Sub-Carpathian area, obtaining the substrates useful for different types of plants. It was studied the migration potential of the metals from substrate to apple trees, the results being comp...
Autori: Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27476

Chemical composition variations of aerosols during summer and winter seasons have been investigated using an Aerosol Mass Spectrometer (AMS) at Magurele, a city near Bucharest, Romania. Proportions of chemical species, concentration time series, mass range distribution and aerodynamic size distribution of aerosols have been analyzed. AMS measurements proved that the organics, nitrate, sulphate and ammonium, with small amounts of chloride were the main species at ground level during the investig...
Autori: Jeni Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27479

Three modified bentonites, hydroxy-aluminum pillared bentonite (Al(OH)-Bent), cetyl trimethylammonium bromide modified bentonite (CTAB-Bent), and both cetyl trimethylammonium bromide and hydroxy-aluminum modified bentonite (Al(OH)-CTAB-Bent) were prepared and characterized by Fourier transform infrared spectroscopy (FTIR) analysis. Batch experiments were conducted on the adsorption of phenol at different temperatures, pH and initial concentration. The results indicated that adsorption capacity o...
Autori: Xiping Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27481

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

Thessaloniki’s suburban forest is environmentally protected by law and also characterized as a high-fire-risk forest. It has a high road density due to its proximity to a city of 1.3 million. Following the disastrous fire of 1997, a number of rehabilitation works were conducted in the 2005- 2009 period along existing road routes. The existing environmental protection laws are not sufficient to assess the environmental impacts of these works within the forest environment. A method has been ...
Autori: Thomas Psilovikos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27510

This paper investigates the macrophyte Azolla pinnata modified with sodium hydroxide, as a bioadsorbent for Cu2+ and Pb2+ ions in synthetic solutions. Biomaterial characterization was performed using Scanning Electronic Microscopy (SEM); Energy- Dispersive X-Ray Spectroscopy (EDX); Fourier Transform Infra-red (FTIR) spectroscopy techniques and through the blocking of carboxylic and sulfonic functional groups. Kinetics of the process has highlighted a quick and efficient adsorption, even in low ...
Autori: Arielle Barros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27532

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Dielectric measurements were carried out on a series of bent-core liquid crystals based on resorcinol and 2, 7-dihydroxinaphtalene cores and presenting B mesophase in between 30-160°C. The dielectric constants in the liquid crystalline phase were measured as a function of frequency and temperature. The dielectric relaxation of bent-core compounds has been analyzed by dielectric constants/frequency curves. The variation of the dielectric strength with temperature has been determined as well. ...
Autori: Irina Carlescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27568

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

In order to investigate the influence of coal macerals on biomethane production, two types of coal samples were collected respectively from Malan mine in Gujiao and Shaqu mine in Liulin, Shanxi. The vitrinite, inertinite and liptinite were separated by the methods of hand picking and float-and-sink test. Meanwhile, biomethane production experiments using the raw coal samples, vitrinite-rich coal samples, inertinite-rich coal samples as substrates were carried out in the laboratory. Finally, the ...
Autori: Hongyu Guo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27620

Tobacco is one of the most important agricultural products in the Republic of Macedonia. Elemental composition of tobacco and soil from different agricultural areas was studied for monitoring purposes. The main purpose was to determine the intensity of accumulation of various elements in tobacco plants and to determine possible relationships between certain chemical and physical properties of soils (pH, clay, cation exchange capacity - CEC, organic matters - OM and total organic carbon - TOC). T...
Autori: Biljana Jordanoska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27625

In this paper the results of the aerosol flux measurements in near water boundary layer are presented. Measurements were conducted using two micrometeorological methods in the southern Baltic Sea region. The preliminary results of comparisons of two methods are discussed. The eddy covariance (EC) method is shown as a method for the calibration of the gradient method (GM). The reason for proceeding with such calibration is to show that the GM, which is an indirect measuring method, is comparable ...
Autori: Piotr Markuszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27630

Thin-film transistor liquid-crystal display (TFT-LCD) waste glass can be used as a raw material for producing geopolymers, because it contains large amounts of silicon and aluminum in its amorphous structure. The setting time and compressive strength were evaluated to determine the quality of the geopolymer product with various amounts of nano-SiO2 (0%–3%) and TFT-LCD waste glass replacement (0% - 40%). The microstructures of the samples were characterized using mercury intrusion porosimet...
Autori: Kang Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27634

Magnesium wastes are among the gradually ascending and therefore challenging metal wastes, which are produced by many industrial activities. The purpose of this study is the usage of magnesium waste, a raw material in magnesium borate production by hydrothermal synthesis. Boron sources (boric acid (H3BO3) and boron oxide (B2O3)) react with magnesium wastes in order to synthesize the magnesium borate mineral of admontite (MgO(B2O3)3ꞏ7(H2O)). In addition to the synthesis from waste magne...
Autori: Azmi Seyhun Kipcak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27657

Porous membranes as gas-liquid contactors are widely used in carbon dioxide (CO2) absorption systems. It provides larger mass transfer area and excellent operational flexibility. Membrane contactors have been considered as alternative to conventional approaches in removing CO2. In spite of its advantages over conventional technologies, membrane wetting is a major problem which reduces performance of CO2 absorption. This paper explains the concept of membrane wetting phenomenon and its influen...
Autori: Abdul Latif Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27676

Adsorption, desorption, and kinetics behavior of Gd(III) ion on chelating resin were investigated in this paper. Batch adsorption studies were carried out with different pH, contact time, and temperature. The adsorption of Gd(III) follows the Langmuir model better than the Freundlich model. The apparent activation energy Ea and adsorption rate constant are k308 4.16 kJ/mol and 6.01×10-5 s-1, respectively. Thermodynamic parameters such as ΔH, ΔS and ΔG indicated that Gd(II...
Autori: Leilei Pi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27688

The aim of this study was to evaluate the content of Zn, Mn, Cu and Ni in the aboveground and underground shouts of Glyceria maxima and in the bottom sediments of the Słupia River. These studies allow for assessment of the existing and potential hazards resulting from toxic influence of heavy metals on water environment and human health. The concentration of research elements was determined by atomic absorption spectrometry (AAS). Results indicate that the concentration of heavy metals in t...
Autori: Agnieszka Parzych
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27701

Salt tolerance was studied in eight upland cotton cultivars (CIM-446, CIM-473, CIM-496, CIM-499, CIM-506, CIM-554, CIM-707 and SLH-284) under four NaCl salinity concentrations (50, 100, 150 and 200 mM) and control. Significant (p≤0.01) variations were observed among cultivars, salinity concentrations, and cultivar by salinity interactions for various growth traits and ions (K+ and Na+) accumulation in dry shoot and root tissues. As compared to control, the growth variables were decreased by i...
Autori: Zarina Bibi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27778

The quantification of heavy metals in dry and wet weather derived (runoff and snowfall) sediment from roads, under three different environmental conditions, has indeed the potential to allow improved understanding on urban diffuse pollution. With that aim, the reported study determined the concentrations of Cd, Cu, Pb, Ni, Cr and Zn in road sediment, which are reported to be found in elevated level in the road-traffic environment, and associated pollution levels at four different sites, represen...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27776

The present paper focuses upon the analysis of 226Ra, 232Th and 40K radionuclides, making use of high-resolution HPGe γ-spectrometry devices. By means of this technique, the radiological risk is investigated in the case of various sand samples. The natural concentrations for 226Ra, 232Th and 40K, from sand samples, ranged from (9.3-20.0 Bqkg-1), (9.1-23.7 Bqkg-1) and (203.5-403.3 Bqkg-1), respectively. The radium equivalent activity of sands under investigation was also analyzed and ranged...
Autori: Dorin Vasile Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27775

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

This study investigated the spatial variability of heavy metal emission patterns and associated measures of contamination on Riccarton Campus at Heriot-Watt University in Edinburgh, Scotland. Road deposited sediments were collected from 12-different sites representing typical urban/sub-urban road layout over a 10 month period covering seasonal variations. The heavy metal concentrations of the road sediments collected from different sites of a road were determined by strong nitric acid digestion ...
Autori: Sudip K. Pal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27738

Capillary gas chromatography coupled with mass spectrometry technique was used for the assessment of low concentration of dinitrophenol pesticide, Dinocap in different spiked samples. For this purpose it has been spiked with Dinocap (15- 200 μg/mL) five environmental matrices (a soil sample and two each samples of wine and grapes). The Dinocap degradation grade in these samples was also monitored. The extraction was performed in dichloromethane. The assessment of the Dinocap in the samples we...
Autori: Nicoleta Grigoriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27746

A study was conducted to determine the composition and concentration of trace metals in suspended particulate matter (PM10) and indoor dust in two academic buildings of Universiti KebangsaanMalaysia. One building was in the final phases of renovation (UR) and the other building had just finished renovation (AR). PM10 sampling of air was performed using a low volume sampler (LVS), and samples of indoor dust were obtained using a brush and a small plastic bag. The compositions of trace metals in b...
Autori: Mohd Talib Latif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27758

In this study, the effect of raw material formulation used in the core layer on the water resistance and mechanical properties of particleboard made from a mixture of rice husk and wood particles was investigated. For this aim, four series of particleboard core layer were produced from different proportions of rice husk/wood particles, different amounts of urea-formaldehyde (UF) adhesive, low density polyethylene (LDPE), and maleic anhydride grafted polyethylene (MAPE), respectively. The amounts...
Autori: Jin Heon Kwon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27871

Heavy metals are inorganic persistent pollutants with adverse health and environmental effects. In our study, self-synthesized iron oxide magnetic nanoparticles were encapsulated in the Phanerochaete chrysosporium (P. chrysosporium) hyphae. The prepared biosorbents possessed high efficiency for Pb(II) biosorption from single and binary metal systems. The maximum biosorption capacity was found to be 50.05 mg g–1 at pH 5.0. Environmental scanning electron microscope accompanied with energy d...
Autori: Danlian Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27864

The analysis by numerical simulations can be applied to building materials subjected to different climatic conditions to envisage the influence of environmental factors in terms of drying time, water absorption and thermal performance of materials. Currently there is a wide variety of new building materials used for insulation, waterproofing and rehabilitation, each contributing in a specific way to constructions improvement during their service life. In time, every building is subjected to degr...
Autori: Alexandra Alisa Găină
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27863

This paper presents the results of experimental researches regarding the optimization of a decontamination process through thermal desorption of soils contaminated with crude oil. The optimization was performed for the following desorption parameters: heating temperature of the soil and the treatment duration, by increasing the temperature from 300°C to 350°C and decreasing the treatment duration from 10, 15 and 20 minutes to 5, 10 and 15 minutes. The economic calculation of the decontam...
Autori: Dorina Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27846

The aim of this paper is to determine the influence of desulphurization on process efficiency and monoethanolamine (MEA) absorption capacity. The experiment was conducted on a circulating fluidized bed combustion (CFBC) which uses indigenous coal from Jiu Valley. We determined the absorption capacity of MEA considering three values of concentrations in the solution: 20%, 30% and 40%. It was noticed that the higher the concentration of MEA is in the solution, the greater is the influence in th...
Autori: Cristian Dincă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27879

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

In the mineral matter of coal there are microelements chemically bounded to organic matter or mineral impurities in various combinations that catalyzes the evolution / involution of a spontaneous combustion phenomenon as an accelerator in the oxidation reaction or which slows down these processes. Specialised literature analyzes the phenomenon of coal self-heating based on several theories of which we exemplify the theory of coal oxidation, the theory of pyrite and the theory of the microele...
Autori: Cristian Tomescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27966

In order to highlight the impact of environmental pollution for Romanian nursing mothers we evaluated the concentration of heavy metals and trace elements in their blood and breast milk. The evaluation was done taking into account the pollution level of mother’s residence: Bucharest (an industrial and heavy transited town, identified as the highly polluted area) and a small town (without industrial plants, identified as less polluted area). The determination of heavy metals and trace eleme...
Autori: Larisa Prioteasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27973

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

The paper reports on the preparation of polysiloxane hydrophobized viscose-maghemite/goethite magnetic composite with properties appropriate for uses in oil spill sorption from polluted aqueous media. A multi-step procedure was employed to obtain the polymeric composite. The structures of the prepared samples and precursors were analyzed by Fourier transform infrared spectroscopy (FTIR), whereas their morphology was investigated by means of scanning electron microscopy (SEM). The hydrophobic...
Autori: Răzvan Rotaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28008

This paper discussed the results of studies regarding metal ions distribution in water, sediments, aquatic plants and different tissues of fish from Snagov Lake, Romania, a natural lake situated 25-30 kilometers north from Bucharest, the capital of Romania. The concentration of several metal ions (Li, Ba, Al, Pb, As, Se) was measured in three points of the lake, namely receiving-input, middle and discharging-output ponds. The samples were collected during spring time from water, sediments, Ce...
Autori: Daniela Simina Ștefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28010

Inorganic thermal insulators are commonly used to improve energy efficiency. However, environmental and health aspects of their production until the end of life have been increasingly concerned. Agricultural wastes including rice straw, rice husk and corn cobs are abundant in Thailand and converted into value-added products such as thermal insulation materials offers a viable recycling opportunity as the ecological burden of a product has now become a widely-discussed issue. In this paper, gl...
Autori: Phairat Usubharatana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28033

Aspergillus fumigatus has been selected to bioleach the metals ion from brown shale. Process parameters like pH (5.0, 5.5, 5.8, 6.0, and 6.5), substrate concentration (2, 4, 6, 8, and 10%), pulp density (1, 5, 10, 15, and 20%), temperature (30, 35, 40, 45, 50oC) and agitation (100, 150, 200, 250, 300 rpm) were optimized according to L25 Taguchi orthogonal experimental array design that resulted in the twenty five batch bio recovery experiments. After biorecovery experiments, optimum value of ...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28035

The development of green eco-friendly inhibitors for the corrosion of metallic surfaces in acid media is still considered as a major challenge and target for corrosion-mitigation engineers. We have prepared in this work 4 different extracts from the plant Ruta Chalepensis using methanol, chloroform, ethyl acetate, and aqueous ethyl acetate solvent systems. The flavonoids content, as well as the other oxygenated compounds, in the 4 extracts was carefully screened using the gas chromatographic&nda...
Autori: Meryem Amal Benghalia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28063

Leather processing is one of the highly polluting industries, due to generation of significant quantities of tanned and untanned wastes. Untanned wastes are less contaminated with chemicals and a better source of high value products such as collagen rather than tanned or finished leather wastes. In the present study, collagen dissolution substances (CDS) were prepared from bovine limed split wastes as value added products, by treating leather wastes with sodium hydroxide and fermented dairy b...
Autori: Gökhan Zengin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28095

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

In the present research, the intensity of contamination with heavy elements Vanadium (V) and Arsenic (As) in the coastal sediments of Bandar Abbas is gauged and rated using the method of Atomic Absorption Spectroscopy. All processes of sampling and assimilation of sediments are performed according to the guideline of the Manual of Oceanographic Observations and Pollutant Analyses Methods (MOOPAM) Standard issued by the Regional Organization for the Protection of the Marine Environment (RAPMI).T...
Autori: Akbar Elsagh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28105

Wastewater generated from industrial activities has delivered elevated heavy metal concentrations into fresh and salted aqueous systems. Herein, the migrated trace metals were studied from their initial location through a coastal aquifer up to the seawater. The experiments were carried out at lab scale using a sandbox with glass beads and two attached chambers containing natural groundwater and seawater. The study focused on the transport behaviour of heavy metals such as copper, zinc and lead i...
Autori: Abdelkader Tawfeek Ahmed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28111

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

In this work, the removal of methyl orange (MO) and Cd2+ by simultaneous adsorption on adsorbent obtained from modified charcoal (BCBH) coated with TiO2 has been studied. The synthesized materials obtained from wood branches were characterized using atomic force microscopy (AFM) for the roughness and SEM to determine the morphology of the surface. EDX spectroscopy indicates the presence of C, N, O, Na, K, P and Ti on the surface of the adsorbent materials. The micro-porosity and BET specific sur...
Autori: Nicoleta Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28157

Apart of new equipment’s development such as absorption columns with higher efficiency, for chemical industry, there is a strong need for greenhouse gases reduction in order to assure the environmental protection and, consequently, many studies regarding the purification methods of exhausted gases have been performed. There are several types of reactors used for gases purification, such as: bubbling jet reactor, combined packed and spray tower absorber, cable wet scrubber and packed column...
Autori: Elisabeta Droniuc Hultuana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28160

The contamination of aquatic and terrestrial environments by pesticides is highlighted by their possible toxic properties and poor biodegradability on the environment. The development of low cost by products from agricultural sectors as a suitable solution for contaminated areas remediation is of great environmental interest. Straw wastes can be considered as a promising alternative to remove different chemical compound that are environmentally toxic. In this study, some materials derived from ...
Autori: Irina Gabriela Cara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28161

The paper covers the results of a study, carried out during 2005 and 2018, regarding the impact of sludge dump of a wastewater treatment plant from Iasi city, Romania, on the soil characteristics. Experimental research was conducted to highlight the evolution of the heavy metal content of both the material in the storage site and the soil in its proximity. The following heavy metal concentrations were analyzed with atomic adsorption spectrometry method: Zn, Ni, Cr, Pb, Co, Cu and Cd. Research ha...
Autori: Georgiana Cezarina Bartic Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28164

Inorganic ceramic materials is receiving more attention in recent times due to their unique characteristics which include different pore structures, hydrophilic surfaces, high chemical, thermal and mechanical stabilities that offer avenues for application in water treatment. In the present work, cost-effective clay ceramic water filters of different designs were developed from clay (50, 60, and 70) %, sawdust (15, 20, 25, and 35) %, grog (5, 10 and 15)% ratios plus 5% bone char by volume and ...
Autori: Enyew Amare Zereffa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28196

The paper analyses the possibilities of recycling tannery sludge (TS) in clay brick manufacture. The physico-mechanical properties and microstructure of clay brick and cement mortars vary depending on TS content in the mix. 2.5 %–15.0  TS (by weight) was added to clay bricks fired at 1000 C temperature and maintained at maximum heat for 1 hour. The tests revealed that 2.5  TS addition had a positive effect on physical and mechanical properties of clay brick: reduce drying and mfi...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28209

Cultural heritage objects represent valuable testimonies of the past, which must be kept in the right condition to transmit to future generations. Together with the spectacular progress recorded by humankind regarding technology, opportunities to obtain valuable data on heritage objects so as to preserve them have started to emerge. The current researchers aimed to determine the internal composition of the colors and materials used in some paintings from a historic wooden church monument, from ...
Autori: Elena Demenchuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28230

Nutrients have been considered the main factor affecting microorganisms responsible for methane gas production during anaerobic digestion processes. In this study, the nutritional composition of some fruit wastes; mango (M), watermelon (W), pawpaw (P), their effects on methane gas production, and resulting energy values were assessed. Substrate samples for anaerobic digestion where prepared into various slurry treatments; M, W, P, WM, PW, MP, MWP and CONTROL. Proximate compositions of the subst...
Autori: Ogemdi Chinwendu Anika
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28233

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

The work is devoted to the search and investigation of the properties of the effective environmentally friendly phytoremediation activators. An integrated approach was used to evaluate the effect of the compositions of thiosulfonates with rhamnolipid biosurfactant on remediation plants. The biochemical and biophysical analysis of the rapeseed and ryegrass plants grown in the oil polluted soil - photosynthetic pigments, indicators of oxidative reactions and electrical impedance characteristics we...
Autori: Olena Yaremkevych
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28319

The concentrations of Copper (Cu), cadmium (Cd), manganese (Mn) and lead (Pb) in liver, kidneys and red meat of cattle slaughtered in selected abattoirs in Owerri metropolis, Nigeria were studied using atomic absorption spectroscopy (AAS). This was performed in relation to their concentrations in a forage grass, Panicum maximum randomly harvested from roadsides of Owerri- Onitsha and Owerri-Aba expressways. Results obtained showed that cattle meat samples contained all heavy metals studied. Thei...
Autori: Henry Uzoma Anuforo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28320

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

This research applied passive air pollution samplers to monitor the concentration of the pollutants nitrogen dioxide (NO2) and ozone (O3) in order to investigate the relationships between pollutant concentrations and meteorological variables. The study was carried out in three strategic sites in the municipality of Erechim, Brazil, which provide intense traffic of small and large vehicles. The pollutant analyses were performed using the method of UV/VIS spectrophotometry. NO2 concentrations vari...
Autori: Eduardo Pavan Korf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28326

Road dust from atmospheric deposition is considered as one of the significant environmental pollutants for containing toxic heavy metals. In this connection, to explore the present scenario of urban contamination and potential health risk of heavy metals present in road dust; this study was carried out in Tangail Municipality Area of Bangladesh. Road dust samples were collected seasonally from five different sampling sites encompassing different traffic homogeneity. Collected samples were proces...
Autori: Mir Talas Mahammad Diganta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28334

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349