Include urmatoarele articole� Degradation of alcian blue 8 gx by heterogeneous and homogeneous photocatalytic processes� Evaluating the performance of solid waste management models� Bioreactors with stirred bed of immobilized cells 1. Studies on mixing efficiency� Fugitive emissions estimation from petroleum storage tanks� New Ni(II) coordination polymers with insulating and anticorrosive properties� Determination of water quality deterioration at pilgrimage centre along river netrav...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25196

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

This paper brings a review on the trends of arc plasma reactors, in the new millennium, as an alternative contribution to the reduction of carbon emission at global level. The development of technically and economically feasible plasma processes for the production of hydrogen is analyzed. Literature provides data on achievable intensification of the involved chemical processes comparing with those from the classic reactors. The hydrogen production is studied starting from hydrocarbons and alcoho...
Autori: Iulian Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25128

AbstractThis paper reviews some practical aspects of the application of algal biomass for the biosorption of heavy metals from wastewater. The ability of different algal species to remove metals varies with algal group and morphology, with the speciation of specific metals and their competition with others in wastewater, and with environmental or process factors. The scattered literature on the uptake of heavy metals by both living and dead algal biomass - both macroalgae and immobilized microal...
Autori: Loredana Branza, Maria Gavrilescu, Matthew J. Dring
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25133

In this work, the ability of Romanian peat for sorption of Pb (II) ions from aqueous solution has been determined using the batch experimental techniques. The sorption equilibrium has been studied at different pH values. The equilibrium adsorption level was determined to be dependent of the pH of solution and initial Pb(II) concentration.The equilibrium adsorption capacity of Romanian peat sorbent for lead has been described by seven types of mathematical model isotherms, namely: Freundlich, Lan...
Autori: Brindusa Robu, Corneliu Cojocaru, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25160

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� "Waste not, want not" a study of household attitude toward recycling of solid wastes� A kinetic model for the crystal violet mineralization in water by the electro- fenton process� Development of a coagulation/flocculation predictive model for turbidity removal from tehran water treatment plants� Removal of cadmium (II) from aqueous solutions by sphagnum moss peat: Equilibrium study� Environmental sustainability based on fuzzy models� Impact of dust emi...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25207

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractThis paper dealt with Cr(VI) sorption on isomorphic substituted Mg/Zn-Al - type hydrotalcites under proper working conditions. The prepared samples were named Mg3Al, Mg2ZnAl, Mg1.5Zn1.5Al, MgZn2Al and Zn3Al. The experimental data concerning sorption isotherms were modelled in accordance with four equilibrium equations: Langmuir (L), Freundlich (F), Langmuir-Freundlich (L-F) and Redlich-Peterson (R-P) by using two ways: (i) estimation of qmax, K and n; and (ii) estimation of K and n, for ...
Autori: Aurel Iovi, Eveline Popovici, Laura Cocheci, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25215

AbstractVolatile organic compounds (VOCs) constitutes an important class of environmental pollutants, which, together with other contaminants as NOx, SOx, CO, NH3, CO2 etc. participate in degradation of atmosphere and exhibit a potential risk for human health. VOC emissions may be generated in more than 25 percentages through the use of solvents in different industrial or house holding activities. For applying a certain plan concerning the pollution reduction, any user of organic solvents contai...
Autori: Florin Bandrabur, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25218

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractCadmium is listed by US-EPA as one of priority pollutant and as a known carcinogen, and therefore its removal from wastewaters of various industrial processes is a very important environmental problem. The paper analyzes the effectiveness of a Romanian sphagnum moss peat as available and cheaper sorbent in removal of Cd (II) from aqueous solutions. Batch sorption experiments were carried out in order to establish the influence of solution pH, peat dose, contact time and initial cadmium c...
Autori: Catalin Balan, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25231

AbstractThe comparative study on reactive extraction of p-hydroxybenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar s...
Autori: Anca-Irina Galaction, Dan Caşcaval, Maria Cămăruţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25250

AbstractThe synthesis of some grafted polysiloxane and azo-polysiloxanes with potential applications as rheology modifiers or surfactants for waterborne paints is reported. Nowadays it became very important to design environmentally friendly systems exhibiting the best end-uses properties. Due to their complex architecture and their sensitivity to UV radiation the studied polymeric systems exhibit very interesting rheological properties. All the polymers containing the azobenzenic groups in the ...
Autori: Constanta Ibanescu, Ioana Moleavin, Iulian Nor, Nicolae Hurduc, Viorel Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25252

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractAdvanced closing of paper machine circuits results in the accumulation of the dissolved and colloidal substances (DCS) in the process water. At a critical concentration, the DCS are destabilizing even by small variations in paper machine parameters, producing operational and product quality problems. This article presents results of lab experiments simulating the process water recycling in short circuit of paper machine, without and with addition of fixing agents. Tests were performing w...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25261

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

AbstractA new environmentally friendly lignosulfonate-based glue (LSG), which represents the lignin-containing interpolymer complex, has been developed for structuring sandy soils. It has been found that the changes in the LSG composition result in a change in its rheological properties, which are associated with the LSG binding ability and, thereby, have to influence the fractional composition and properties of the created soil aggregates. ...
Autori: Galia Shulga, Julia Brovkina, Juris Ozolinš, Olga Aniskevicha, Talrits Betkers
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25289

AbstractBiosorption an alternative process is the uptake of heavy metals from aqueous solutions by biological materials. The biosorption of nickel ions from aqueous solution was investigated by Nordmann fir (Abies nordmanniana (Stev.) Spach. subsp. nordmanniana) in a batch adsorption system as a function of pH, initial metal concentration, biomass dosage, contact time. The data showed that the maximum pH for efficient sorption of Ni(II) was 6.5. At the optimal conditions, Ni(II) ion biosorption ...
Autori: Handan Ucun, Ozkan Aksakal, Yusuf Kaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25295

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractWood-based epoxy resin was synthesized from resorcinol-liquefied wood. First, wood components were depolymerized and liquefied by reaction with resorcinol. The resorcinol-liquefied wood with plenty of hydroxyl groups could be considered as a precursor for synthesizing wood-based epoxy resin. Namely, the phenolic-OH groups of the liquefied wood reacted with epichlorohydrine under alkali condition. By the glycidyl etherification, epoxy functionality was introduced to the liquefied wood. Th...
Autori: Akira Fujita, Hajime Kishi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25310

AbstractThe sorption of Pb(II) and Hg(II) ions from aqueous solutions by moss peat (from Poiana Stampei, Romania) was studied in a batch system. The data obtained from experiments of a single-component sorption were analyzed using Langmuir and Freundlich models. The Langmuir equation describe sorption isotherm of Pb(II) and Hg(II) with high correlation coefficients, and better than Freundlich model. According to the Langmuir model, the maximum uptake capacities of moss peat for Pb(II) and Hg(II)...
Autori: Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu, Mioara Răţoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25311

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractThe paper is a short review on the soil decontamination applying ex-situ techniques. Some sources and pathways of soil  contamination are discussed. It was revealed that available techniques for soil decontamination can be divided in two parts, depending on where the action have place: in-situ or ex-situ. Also, depending on the nature of the process, these techniques can be biological, physical-chemical and thermal. In order to decontaminate soils properly, the primary contaminants ...
Autori: Lucian Vasile Pavel, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25318

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractThe use of adhesives for floor covering have been deeply modified for longtime, by formulations of polymer-based products in aqueous dispersion as an alternative to organic solvents. These advances envisaged ways for obtaining nonpolluting products. Developing these adhesives required the parallel development of methods for monitoring and analyzing the emissions over time. This paper shows the results of some research devoted to identify the indoor presence of volatile organic compounds ...
Autori: Irina Ioniţă, Domnica Ciobanu, Monica Tulbure, Iulian Tanţoş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25388

AbstractThe lead(II) ions sorption from aqueous solutions on three types of peat from Poiana Stampei (Romania) was studied. The peat was drawing from different deeps, such as 5-10 cm deep (peat 1), 0.5-1.0 m deep (peat 2) and from > 1.5 m deep (peat 3). The influence of several experimental parameters (initial lead concentration, contact time) was studied in batch experiments. The kinetics of sorption was followed based on the amount of lead(II) ions retained at various time intervals. The re...
Autori: Laura Bulgariu, Mioara Răţoi, Dumitru Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25389

AbstractThe adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated. The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed at 30, 40 and 50 ?C. Thermodynamic potentials ?H, ?S, and ?G and isosteric heats of adsorption were calculated from experiment performed at different temperatures (30-50?C...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25393

AbstractEquilibrium data of water vapor adsorption from wet air on several materials were experimentally determined at temperature values of 313 and 333 K and air relative humidity values ranged between 30 and 90 %. Experimental data were correlated with Langmuir and Freundlich models. The obtained results emphasize the significant difference between the water retained on the adsorbent materials impregnated with various salt solutions, and on classic adsorbents....
Autori: Ioan Mămăligă, Constantin Baciu, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25394

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract The European annual consumption of plastic materials has increased from 24.6 Mtons in 1993 to 39.7 M tons in 2003 and it is likely to keep growing. Europe is faced with the challenge of managing millions of tons of waste plastics. At the same time, polymer recyclers and manufacturing industries do not find enough secondary polymers of consistent quality. Plastics production and use has a range of environmental impacts because of the considerable quantity of resources needed as raw ma...
Autori: Peter Rem, Venga Solaria, Francesco Di Maio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25444

Abstract The synergistic combination of polymers and inorganic compounds via sol-gel process has attracted great attention, by manipulating structure at molecular level, for developing new materials with desired properties. These new hybrid materials could have a controllable combination of the benefits of polymers (flexibility, toughness, ease of processing) and those of ceramics or glasses (hardness, durability, thermal stability). The microstructures and the properties of hybrid materials...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25446

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract Wood has been used as an engineering material because it is low in cost, renewable and strong and it requires low processing energy. Wood has many excellent properties that result from its exceptional combination of microstructural, ultrastructural and molecular features. The main drawback is its dimensional instability in the presence of moisture, which can affects also the biological stability. Wood is susceptible to degradation in a number of ways, including rot or decay, insect a...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25473

Abstract A crucial stage which makes the other directions of development of membrane processes is getting new membrane materials, to meet increasingly stringent of selectivity and productivity. Polyetheretherketone shows high stability against chemical and physical agents but is poorly soluble in most common solvents. Present studies on obtaining the support of the polyetheretherketone membranes were limited by: solubility of polyetheretherketone in concentrated sulfuric acid and fast speed a...
Autori: Mihaela Emanuela Craciun, Aurelia Cristina Nechifor, Florin Aldea, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25475

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract Macro-Defect-Free (MDF) cements are polymer-cement composites characterized by high value of flexural strength. Due to their thermal and electrical insulating properties, MDF cements could replace other insulators obtained by environmental non-friendlier technologies or being themselves toxic and non-biodegradable. MDF cements obtained by the use of an ecologic polymer (poly(vinyl alcohol)) shows high mechanical resistance in the initial state but also it’s dramatic decrease after ...
Autori: , Georgeta Moise, Hulusi Ozkul, Ozgur Ekincioglu, Catalin Croitoru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25493

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract In the paper is analyzed the possibility of using some industrial wastes for obtaining new building materials. From the industry or from the power station a lot of by-products or wastes have resulted and their storage is a big problem for the environment. In the building material industry a part of these wastes can be used in different ways: for replacing the cement, as addition in concrete, as component of cements, in the mixture of polymer concrete, etc. In the present investigati...
Autori: Marinela Bărbuţă, Nicolae Taranu, Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25525

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract In the textile finishing and dyeing industries, the total volume of water consumed is around 150 millions tons/year, and thus very large quantities of water are processed and produced as wastewater by textile plants. Quality indicators of textile wastewaters, like BOD and COD, have values which, in some cases, exceed 5 times the maximum concentration value (allowed by the national quality standards). One of the greatest concerns in wastewater treatment of a textile effluent is the co...
Autori: Daniela Cailean, , Florin Brinza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25538

Abstract This paper is the investigation concerning the removal, from surface water, of humic acids and of some cations (Cu2+, Al3+) on activated carbons AG-3, BAU, CASO-16 from individual solutions as well as from their mixtures both in static and dynamic conditions. The conclusions of the paper are that, when humic acids are adsorbed from micellar solutions, semiassociates are formed on the surface of activated carbon BAU (in its porous structure), while humic acids adsorption on activated ...
Autori: Tudor Lupascu, Mihail Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25539

Abstract Geopolymerization is a continuous developing field of research for utilizing solid waste and by-products. It provides a solution to many problems where hazardous residue has to be treated and stored under critical environmental conditions. Consumption of fly ash in the manufacture of geopolymer is an important strategy in making materials more environmentally friendly. Fly ash has been chosen as a base material in order to utilize this industrial waste. Previous researches have show...
Autori: Maria Harja, Marinela Bărbuţă, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25542

Abstract Plasma is often called the fourth state of matter. It is distinct from other lower-energy states of matter, most commonly solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. Plasma technique may use any gas or gas mixture, within equipment limitations. Each gas or mixture of gases produces distinctive plasma, making possible a very diverse range of chemical environments. Besides the recombination mechanisms developed...
Autori: Marian I. Totolin, Ghiocel E. Ioanid, Iordana Neamtu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25550

Abstract White mustard (Sinapis white) is an annual plant of the Cruciferae family originating from the Mediterranean region and is cultivated in Europe and Asia, mainly for its seeds, but also for animal feed or crop rotation. White mustard seed is also an important source of vegetable oil that can be used as fuel. The chemical composition of mustard seed (Sinapis alba) includes glucosinolate (sinalbozida, sinapina free), essential oils, fatty oils (glycerides of oleic acid, linoleic, linole...
Autori: Camelia Ciubota-Rosie, Rodica Diaconescu, Irina Volf, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25561

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract This work describes the preparation of a hydroxyapatite/polyurethane composite membrane and their characteristics. The porous hydroxyapatite/polyurethane composite membranes were made via solvent casting process. The deposited hydroxyapatite layers were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The data suggest that the method utilized in this work can be applied to obtain deposition of coating of crystalline hydroxyapatite on porous polyurethane...
Autori: Gabriela Ciobanu, Dorina Ignat, Gabriela Carja, Constantin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25572

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract In this work, the behavior of n-hexane vapors in the adsorption-desorption cycles of non-functionalized polymeric adsorbents (MN 202 and MN 250) and granular activated carbon (AC 20) was studied. The adsorption experiments were performed in a fixed bed column, under dynamic conditions, at 30?C and atmospheric pressure. The inlet concentration of n-hexane in the air streams was 0.115 mg/cm3 (32500 ppm) and the space velocity was 2.75 s-1. Also, desorption experiments were performed in...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25584

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract Chromium (Cr) is one of the most common metal contaminants in soil because of its use in ore refining, production of steel and alloys, metal plating, tanneries, wood preservation, and pigmentation. In soil environment, the most stable oxidation states of chromium are Cr (III) and Cr (VI). While Cr (III) is considered an essential trace element for the functioning of living organisms, Cr (VI) is toxic and carcinogenic to humans via inhalation for long exposures, since it is easily sol...
Autori: Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu, Raluca Maria Hlihor, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25590

Abstract The use of biomaterials as biosorbents for treatment of wastewaters will provide as a potential alternate to the conventional treatment methods. The main advantages of biosorption are high selectivity , cost effectiveness and good removal performance. World wide numerous low cost bio materials have tried for biosorption of dyes. In this present investigation, the dead biomass of Penicillium sp. fungus and wood sawdust was used as biosorbents and their capacity to removed malachite gr...
Autori: Cornel Pohontu, Florin Luca, Igor Creţescu, Manea Liliana, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25593

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract The aim of this study was to assess nitrate removal using impregnated activated carbon (AC) with MgCl2. After impregnating of AC using heat treatment, the MgCl2 is converted to efficient MgO. The denitrification was conducted at pH 6.2, 25?C, and initial concentrations of 20 mg/L nitrate-N. The effects of the operating parameters including AC dosage, pH, and contact time have been investigated. Experimental data show that AC modified by MgCl2 was more effective than virgin AC for nit...
Autori: Abbas Rezaee, Hatam Godini, Sahand Jorfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25618

Abstract The adsorption behavior of bael tree (BT) leaf powder for cadmium ions from aqueous solutions has been investigated as a function of appropriate equilibrium time, adsorbent dose, adsorbate concentrations and pH using a batch system. Studies showed that the pH of aqueous solutions affected cadmium removal as a result of the fact that removal efficiency increased with increasing solution pH. The maximum adsorption was 93.56% at solution pH equal to 6.0, contact time of 30 min and initi...
Autori: Ponnusamy Senthilkumar, Rangasamy Gayathri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25621

Abstract Mathematical modeling of the ultrafiltration (UF) process is motivated by the complexity of retention phenomena that occur during the UF in conjunction with the complexity of wastewater matrices submitted to ultrafiltration, as well as by the need to predict the process behavior in extreme conditions, such as high pollution loads for UF-membrane cleaning cycles optimization or for automated control of the process. Thus, series of laboratory-scale ultrafiltration experiments were perf...
Autori: , George Barjoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25630

Abstract Equilibrium and kinetics of sorption of Zn (II) ions from aqueous solutions of pH 5 on indigene (Romanian) peat moss were investigated in batch system. The experimental equilibrium sorption data at three temperatures were analysed by Freundlich, Langmuir, Tempkin and Dubinin-Radushkevich sorption isotherm models. Results indicate the following order in to fit the isotherm equations: Langmuir > Tempkin > Dubinin-Radushkevich > Freundlich. The equilibrium sorption capacity determine...
Autori: Angelica Kicsi, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25632

? SUSTAINABLE CONCRETE HARDENING PROCESSES IN NORMAL CLIMATIC AND THERMAL TREATMENT CONDITIONS ? THE ENVIRONMENTAL DIMENSION ? AN INTERDISCIPLINARY RESEARCH AREA ? MENU PLANNING STRATEGY BASED ON ECOLOGICAL FOOTPRINT ? EVALUATING ENVIRONMENTAL IMPACT OF NIGERIAN COMPOSTED WASTES USING LABORATORY EXTRACTION TEST ? IN SITU RADIOFREQUENCY FIELD LEVEL ASSESSMENT IN TWO URBAN AREAS IN ROMANIA: OPEN QUESTIONS TO ELECTROMAGNETIC POLLUTION ? INNOVATIVE SOLUTION FOR WARNING ON HI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25657

? POST-DARCY FILTRATION THROUGH RIGID PERMEABLE MEDIA ? BIOSORPTION OF Cr(VI) FROM AQUEOUS SOLUTIONS ONTO Hydrilla verticillata WEED: EQUILIBRIUM, KINETICS AND THERMODYNAMIC STUDIES ? IMPACT OF BUILDING A TIDAL GATE ON THE YONGJIANG RIVER IN CHINA ? MONITORING OF THE HYDROTECHNICAL TORRENT CONTROL STRUCTURES: A STATISTICAL APPROACH ? RESEARCH ON SOIL PROPERTIES CONSERVATION DURING THE PREPARATION OF GERMINATION BEDS IN GREENHOUSES ? MANAGEMENT OF THE POTATO CROPS FOR MIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25664

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Biosorption of lead (II) onto the biosorbent, represented by untreated S. cerevisiae and NaOH-treated S. cerevisiae was examined and the effects of contact time were investigated. The lead (II) biosorption was fast and equilibrium was attained within 90 mins. The maximum removal ratios of lead (II) for untreated S. cerevisiae and NaOH-treated S. cerevisiae after 3 h were 48.6% and 92.5%, respectively, with initial lead (II) concentration of 40 mg/L and optimum pH of 5.0. Data obtained from batch...
Autori: Ying Zhang, Yingjie Dai, Baiyin Liu, Fang Ma, Ru Zheng, Limin Donghttp://www.ecozone.ro/reviste.php?RID=25670

It is a promising way for CO2 capture and sequestration by hydrates crystallization. In this study, the characteristics of CO2 hydrate formation are investigated in a small scale dynamic reactor under pressure conditions from 2.0-3.5 MPa and temperature varied between 0.5-4.0Â?C. The effects of supercooling degree and pressure on hydrates formation were discussed. Hydrates formation can be completely finished within 150 min and the final pressure-temperature points of system are just located on ...
Autori: Ni Liu, Xiaobo Xuan, Daoping Liu, Yingming Xiehttp://www.ecozone.ro/reviste.php?RID=25689

A submerged membrane bioreactor (MBR) was employed to treat wastewater containing different content of seawater in this work. During the process, the operating conditions were as follows: COD was 800-1000 mg/L, ammonium-N was 80-100 mg/L, pH was 7.5-8.5, mixed liquor suspended solids (MLSS) was around 7000 mg/L, dissolved oxygen (DO) was 2-4 mg/L. The results showed that the ammonium-N removal was better than COD removal. Sludge settling property was good in saline wastewater treatment, and the ...
Autori: Jin Li, Deshuang Yu, Dan Wanghttp://www.ecozone.ro/reviste.php?RID=25697

Abstract:Composite manufacturing from plastic wastes of polyethylene terephthalate (PET) type, sand-blasting represents a materialrecovery of the wastes. This process can be achieved, with the purpose of reducing the material consumption which is in deficit,production costs, and the duration of the technological processes.Thermoplastics composites obtained by a melting process at 170-200 oC, wastes incorporation and solidification in forms replacesuccessfully the thermo rigid composites obtained...
Autori: Ioan Ropotă, Marcela Muntean, Mihai Bratu, Ovidiu Dumitrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25741

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:In Romania, the small hydro power scheme (mini-, micro- and pico- hydro power) represents a potential renewable energy sourcefor electrical energy. Nevertheless, this small hydro potential must be used efficiently. The paper proposes an innovative e-methodof integrating design with manufacturing, for a small Pelton turbine. The first part presents the application of Rapid ProductDevelopment (RPD) with focus on Product Design (PD) of a new, very small customized hydropower turbine. This ...
Autori: Anisor Nedelcu, Bogdan Deaky, Razvan Udroiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25769

Abstract:This investigation focused on the adsorption of Pb (II) onto Lewatit FO 36 resin from aqueous solutions. The effects of initialmetal concentration, contact time, pH of solution were factors that affected the adsorption of Pb (II). Adsorption kinetic was betterexplained by the pseudo second order type 1 kinetic model that was confirmed by the values (R2>0.986). The Langmuir,Freundlich, Temkin and BET adsorption models were used for the equilibrium studies and Freundlich isotherm bette...
Autori: Alireza Asgari, Azra Setodeh, Mehdi Ahmadi, Mohamad Sedigh Mortazavi, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25791

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Coconut coir pith, an agricultural solid waste was used for the sorption of Cd (II) from aqueous solution in batch mode. Parameters like contact time, adsorbent dosage and pH effect were studied. Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data and the system followed both the isotherms. Cd (II) adsorption capacity of coir pith was found to be 18.72 mg/g. Kinetic parameters of adsorption such as the Langergren pseudo-first-order, pseudo second order r...
Autori: Nagendra Badabhagni, Puthiya Veetil Nidheesh, Rajan Gandhimathi, Srikrishnaperumal Thanga Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25800

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

Abstract:The hereby article presents a part of the results of the research made by the author during his PhD degree preparation with respect to asbestos and plastics wastes recycling in the form of composite with polymeric matrix, respectively the toxicological tests performed on the new product. In this respect, three categories of tests were made based on complex and modern analysis methodologies, with high results accuracy: spectral analysis of the wear wastes, morphological analysis of the w...
Autori: Cristina Corpodean, Silvian Ionescu, Valeriu Deac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25812

An iron(Fe+3) oxide/hydroxide nanoparticles-based agglomerates (AggFe) suspension adsorbent was synthesized for efficient, cost-effective phosphate removal. A strong effect of AggFe concentration and pH level of water containing phosphate on removal efficiency was shown. It was found that phosphate adsorption onto the AggFe suspension may be described by pseudo-secondorder reaction kinetics and the Langmuir isotherm model. The unique adsorption properties of synthesized AggFe adsorbent are demon...
Autori: Grigori Zelmanov, Raphael Semiat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25829

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

The removal of Cr (VI) from aqueous solutions by sphagnum peat moss was investigated in batch experiments as a function of solution pH and initial Cr (VI) concentration. The highest removal percentage (R=99%) was obtained at pH = 1, in solutions of 20.8 mg Cr (VI)/L. In order to establish the mechanism of the removal process, Cr (VI) and total Cr (Cr (VI) + Cr (III)) in residual solutions was analyzed. The Cr (VI) removal by the peat moss at low pH is governed by two processes – electrostatic ...
Autori: Catalin Balan, Doina Bilba, Irina Volf, Matei Macoveanu, Petru Bulai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25849

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

Among the different types of waste products tested, the bark of different Pinus species have been identified as a promising class of low- cost sorbents for heavy metal binding. In this context, the potential of Romanian pine bark wastes as green and economical sorbent for cadmium (II) ions removal from aqueous solutions has been tested in batch conditions as function of initial pH, contact time, sorbent dose, metal ion concentration and temperature. The equilibrium data at three different temper...
Autori: Anca Miron, Brindusa Robu, Carmen Paduraru, Lavinia Tofan, Roxana Laura Mihailescu Amalinei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25871

This research investigates the influence of certain vitamins (A and D2) on the possibility of hydroxyapatite formation on polymer surfaces. A coating method based on biomimetic techniques was used to form a crystalline hydroxyapatite thin layer on porous polyurethane matrix. The method is based on a wet process of hydroxyapatite formation that involves porous polyurethane film soaking in a modified synthetic Simulated Body Fluid (SBF) solution. This modified SBF solution contains vitamin A and v...
Autori: Alina Costina Luca, Constantin Luca, Gabriela Ciobanu, Simona Ilisei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25884

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractThe huge emission of greenhouse gases from fossil-fuelled power plants is emphasizing the need for efficient Carbon Captureand Storage (CCS) technologies. The biomimetic CO2 absorption in aqueous solutions has been recently investigated as apromising innovative alternative for post-combustion CCS. The carbonic anhydrase (CA) - a broad group of ubiquitous enzymes– may catalyse the CO2 hydration reaction and then to promote CO2 absorption rate into aqueous solutions. Nevertheless theresear...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Maria Elena Russo, Piero Salatino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25976

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractWaste management includes all activities of collection, transport, treatment, recovery and disposal of waste, includingsupervising of such operations. The framework law that regulates waste management activities in Romania is Law no. 27/2007,approving Government Emergency Ordinance no. 61/2006, amending and supplementing Government Emergency Ordinance no.78/2000 on waste regime. This legislation sets the responsibilities for waste management from generation to disposal, thepriorities in ...
Autori: Constantin Mircea Orlescu, Ioana Alina Costescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26020

AbstractThe paper presents the research made on the FP7 project „Magnetic Sorting and Ultrasound Sensor Technologies for Productionof High Purity Secondary Polyolefins from Waste” in order to develop a magnetic fluid equipment for sorting of polypropylene(PP) and polyethylene (PE) from polymers mixed waste streams. Because both PP and PE float in water, it is difficult to separateone from the other. The paper presents the principles of inverse magnetic density separation process and the results ...
Autori: Bin Hu, Francesco Di Maio, Guillaume Houzeaux, Liana Baltes, Mircea Tierean, Peter Rem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26028

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe performance of two cation exchanger resins, Amberjet UP1400 and Amberlite IR120 in the process of Cs(I) ions removalfrom aqueous solutions was examined. Batch experiments were carried out to determine the influence of several parameters(resin dosage, contact time, temperature and initial concentration of Cs(I) ions) on the removal process. The equilibrium wasreached after 60 min for Amberlite IR120 and after 120 min for Amberjet UP1400, with an overall adsorption performance of~97% f...
Autori: Adina Negrea, Cornelia Muntean, Corneliu Mircea Davidescu, , Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26032

AbstractThe removal of residual oil from palm oil mill effluent (POME) using boiler fly ash was studied in this paper, with focus on theadsorption isotherms and kinetic studies by measuring the residual oil concentration using UV-spectrophotometer. The percentresidual oil adsorbed decreased from 80% to 5% as contact time was increased from 10 mins to 120 mins but increased from2.74% to 72.98% as initial concentration of residual oil increased from 0.04812 mg/L to 0.2406 mg/L. Pseudo-second order...
Autori: Jude C. Igwe, Stella N. Anioke, Uche Arukwe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26078

AbstractThe present study reports the efficiency of almond shell as a cheap and available material for the removal of Cu (II) fromcontaminated aqueous solutions. The equilibrium experiments indicated that Cu (II) sorption obeyed the Langmuir isotherm at26, 40 and 55oC. The highest value of the maximum uptake (Qo) from the Langmuir equation was found 6.783 mg g-1 at 40oC.The various thermodynamic parameters such as ΔGo, ΔHo and ΔSo were also calculated. The values of ΔGo varie...
Autori: Soheil Aber
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26080

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

Mother Earth Investments AG, is actively working onthe development 2nd generation bioenergy feedstocks.In this book, Mr. Jansen generously shares hisknowledge in the field, in particular, regarding thechallenges and opportunities in development ofbiomass-derived fuels. This essential guide toinvesting in bioenergy commodities details secondgeneration biofuels from a scientific, technical andeconomic perspective, and discusses their globalenvironmental, political and financial impact.The book is ...
Autori: Roland A. Jansen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26100

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Poly(hydroxybutyrate) (PHB) is a biodegradable thermoplastic polyester with very high potential for industrial applications. The properties could be improved by mixing with another polymer, natural or synthetic, such as poly(vinyl alcohol) (PVA). The resulting polymer blends are potentially able to achieve the desired performance for different applications. Biodegradation modifies mechanical, physical and chemical properties of a given material. PHB are degraded by diverse...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26111

Abstract The biosorption of Pb(II) and Cd(II) ions from aqueous solution on marine green algae biomass (Ulva lactuca sp.) was studied in batch systems, at initial solution pH of 5.0 and biomass dose of 8.0 g/L, considered as optimum experimental conditions. The obtained results from experiments of a single-component biosorption were analyzed using Langmuir, Freundlich and Dubinin- Radushkevich isotherm models. The Langmuir equation describe the biosorption isotherm of Pb(II) and Cd...
Autori: Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26152

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractExcess biomass produced in the degradation processes of organic pollutants is creating environmental challenges for wastewatertreatment plants. The A+OSA system, a modification of the anoxic / oxic (A/O) process via insertion of a sludge holding tankinto a sludge return line, has been demonstrated to be capable of achieving simultaneous nutrient removal and sludge reduction.Here we report the results of an investigation aimed at evaluating the impact of the sludge holding tank on the bio...
Autori: Li Jia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26207

AbstractPotential of unmodified Wheat Straw as an adsorbent for the removal of lead and copper was studied. Effect of pH, adsorbentdose, contact time and initial metal concentration on the removal of the metal ions were also investigated. Maximum removal oflead was found to be 43.55% by wheat straw under optimum conditions (pH=5, adsorbent dose=16g/L, contact time= 240minutes, metal concentration=100 mg/L). Unmodified Wheat straw removed 0.381 mg/g of lead. While 56.36% copper removalwas achieve...
Autori: Mehwish Anis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26209

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractGlobal warming is happening due to increasing level of carbon dioxide and other greenhouse gases into the atmosphere. In orderto reduce this rising level of CO2 emitted by human activities, carbon capture and storage technologies are being developed.The present paper investigates and compares, from a techno-economical point of view, two of the most used conceptual methods(post- and pre- combustion) for CO2 capture generated from the fossil fuel power generation sector. For post-combustio...
Autori: Anamaria Padurean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26217

AbstractThe purpose of the undertaken research work is to degrade the biopolymeric pigments present in the distillery spentwash. This isdone by direct electro-oxidation using iridium oxide coated titanium mesh as catalytic anode. The effects of current intensity,dilution, pH and time of electro-oxidation were studied. The combined effects were analyzed using Box-Behnken design foroptimization and statistical analysis. The rate constant for first order electrochemical kinetics relating the rate c...
Autori: R. Krishna Prasad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26253

AbstractThe extent of the problem of the excessive fluoride in drinking water remains an important health issue. In the present work,strong-base anion resins were investigated to assess their sorptive removal capacity of fluoride from water. It was found that theremoval of fluoride was high at natural pH (7) and was improved for increasing contact time and adsorbent dosage. Themaximum sorption of the resin was 13.7 mg/g according to the Langmuir model, namely higher than the values reported in t...
Autori: Mohammad Taghi Samadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26273

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractOceans have been proved to be an important resource due to their abundant reserves in oil and gas. However, because of the extent of oil exploration and development in recent years, the marine ecological environment has been increasingly affected. At present, the control and treatment of environmental pollution from offshore drilling both at home and abroad have focused on end-treatment after problems have already emerged. Nevertheless, preventative measures and appropriate control links...
Autori: Guancheng Jiang, Guangquan Liu, Hao Deng, Rongsha Wang, Shuixiang Xie, Yu Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26279

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractCosmetics, toiletry and household cleaning products are often based on different types of polymeric gels with specific rheologicalbehavior. Dynamic shear oscillation measurements were used for the monitoring of in situ polymerization process, and todetermine the viscoelastic properties of the hydrogels based on polyacrylamide and acetone-formaldehyde resin. Both storagemodulus G’ and loss modulus G” were measured in real time during the gelation process carried out directly between the p...
Autori: Andrei Rosu, Camelia Mihăilescu, Constanţa Ibănescu, Gabriela Halitchi, Maria Lungu, Maricel Danu, Simona Bistriceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26326

AbstractThe biosorption characteristics of Cd(II) ions using the NaCl-treated Ceratophyllum demersum were studied. The effect ofaltering the conditions, such as solution pH, the biosorbent dosage and contact time for the biosorption of Cd(II), and thebiosorption/desorption studies, were investigated. Langmuir, Freundlich, Dubinin-Radushkevich and Redlich–Peterson modelswere applied to describe the biosorption isotherms. Langmuir model fitted the equilibrium data better than the other isotherms(R...
Autori: Ali Akbar Babaei, Mehdi Ahmadi, Nadali Alavi, Nemat Jaafarzadeh, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26331

AbstractThe removal of phosphorus by strongly basic anion exchanger was investigated. Removal efficiency increased with contact time,resin mass and initial solute concentration, while temperature showed a reverse effect. Equilibrium data were best fitted ontoLangmuir isotherm model (R2>0.99). Maximum sorption capacity of the resin was 66.22 mg/g, namely significantly higher thevalues reported in the literature. The Freundlich parameter (n = 4.3) and the Langmuir separation factor (RL = 0.067-...
Autori: Abdeltif Amrane, Hamid Reza Ghaffari, Mansur Zarrabi, Mohammad Mahdi Soori, Mohammad Noori Sepehr, Saied Borji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26343

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractA deep understanding of the relationship between the solids deposition and head losses is vital to optimize the backwashing inbiological aerated filters (BAFs). In this article, the deposition solids were classified into four types: heterotrophic biomass,autotrophic biomass, inert biomass and extracellular polymeric substances (EPS). A concept model was developed to simulatethe solid deposition and the head loss development. The temporal and spatial distributions of the four types of sol...
Autori: Chengda He, Dongsu Bi, Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26347

AbstractBased on the improved C-D production function model, the relationship of China’s energy consumption, economic growth andcarbon emissions are comprehensively studied in this paper through the panel data in China from1991 to 2009. The researchshows that energy consumption and economic growth have a long-term equilibrium and a one-way causality relationship fromenergy consumption to economic growth. In both elasticity coefficients and contributive rate, energy consumption plays the mostimpo...
Autori: Huifeng Pan, Jian-Min Wang, Li Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26370

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

AbstractThe changes in fresh water quality are reflected, over time, in the structure of the biocenosis by adjusting the composition, theabundance and the spatial distribution of species, in an attempt to maintain a constant equilibrium. It is difficult to identify thisequilibrium just by analysing the physicochemical measurements because they represent water quality conditions of the moment,while the analysis based on biological indicators which are reflecting the composition of macrozoobenthos...
Autori: Roxana Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26431

AbstractIn the present work, the kinetics of amaranth dye biosorption onto the roots, stems, leaves and the whole plant of water hyacinth(Eichhornia crassipes) were studied for differential evaluation of the plant’s biosorptive potential to remove the toxic dye fromaqueous solutions. E. crassipes´ leaves showed the highest level of amaranth dye biosorption (43.1 mg/g), followed by the entireplant (31.18 mg/g), the roots (28.51 mg/g), and finally by the stems (23.97 mg/g). The same differential t...
Autori: Imelda Guerrero-Coronilla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26463

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

AbstractIn this study a new generation of plate-type laboratory air treatment biofilter is applied for the removal of gaseous contaminantsfrom air. The packing material for the biofilter consists of porous plates arranged vertically one after the other to produce acapillary humidification effect. The porous plate is made of polymer to secure the stiffness of the plate. Birch fibre granulesthermally treated in a steam explosion reactor are fixed on both sides of the polymer board. The granules ar...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26480

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

Abstract This study evaluates the potential of Crambe abyssinica press cake, a residue from crambe oil extraction and/or biodiesel production, as an adsorbent for removal of cationic dyes from wastewaters. Batch adsorption tests were performed at 30, 40 and 50oC. Adsorption kinetics and equilibrium were satisfactorily described by the pseudo second-order and Freundlich models, respectively. Adsorption was spontaneous and exothermic. Fixed bed adsorption (breakthrough curve) was satisfactoril...
Autori: Adriana S. Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26597

Abstract This study examined the characteristics of geopolymer with solar panel waste glass. After 28 days of curing, the compressive strengths of the geopolymer samples containing 10 mass % and 20 mass % solar panel waste glass were 63.3± 1.8 and 49.1 ± 2.2 MPa, respectively. The geopolymer sample with 10% solar panel waste glass exhibited a stronger reaction than that with 20% solar panel waste glass, and the strength decreased as the amount of solar panel waste glass increas...
Autori: HuiCong Hao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26621

Abstract A model of an irreversible combined thermionic-thermoelectric generator with internal and external irreversibilities is established in this paper. The performances of the combined generator, in which the heat transfers obey radiative heat transfer law, are analyzed and optimized by using the combination of finite time thermodynamics and non-equilibrium thermodynamics. The general expressions for power output and efficiency versus drop voltage are derived. The influence of finite rat...
Autori: Zemin Ding
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26624

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract The environmental impact assessment (EIA) is a compulsory evaluation instrument for environmental management and decision making processes and applies to different phases of activities (plans, programmes, projects and /or existing production or services), because it measures the natural and anthropogenic activities effects upon the environment. These impacts may affect the cultural richness, biodiversity, social-economic conditions and human health as well as the ecosystem equilibri...
Autori: Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26645

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract Environmental contamination by antimony has been described as a critical issue in many articles. In this study, the Sb(III) removal by two brown algae, Sargassum muticum and Aschophylum nodosum, has been tested. Algae were collected in Viana do Castelo beach (Portugal). Preliminary tests were carried out and, based on the results, Sargassum muticum was chosen for subsequent experiments. Kinetic data were described by pseudo second order model. After about four hours contact time the...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26659

Abstract Adsorption equilibrium and effective diffusion coefficients of water vapor, in cylindrical particles of activated alumina (A) and activated alumina impregnated with calcium chloride (MCA), are experimentally determined. The experiments were conducted at 303 K and 323 K using cylindrical particles with 2.5 mm in both length and diameter. Diffusion coefficients were determined from the kinetics of water sorption. The measurements were conducted in a constant pressure unit based on a m...
Autori: Eugenia Teodora Iacob Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26665

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract The deterioration of the natural polymers is a very complex process, and a problem that can be best addressed through modelling. The approach for modelling the rheological behaviour of different cellulose-based textile fibres (cotton, hemp, flax) when subjected to a hydrothermal treatment, followed by exposure to different doses of gamma-rays (5, 10, 15 and 25 kGy) is presented here. In order to predict the optimum radiation dose limit and hydrothermal aging time, the mathematical m...
Autori: Angelica Olaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26678

Abstract The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon material was found to adsorb vitamin B2 from aqueous solution at room temperature. The obtained ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26679

Abstract Supercritical fluid and ultrasound assisted extractions were applied as a first step in a complex processing of spruce bark in order to recover polyphenols compounds. The aim of the study was to compare the efficiency of these "green" processes with a conventional extraction technique (ethanolic extraction). Supercritical fluid extraction was carried out in two steps: (i) static extraction for 15 min at 1000 psi with pure CO2 and (ii) dynamic extraction for 45 min at 35, 4...
Autori: Adina Iulia Talmaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26680

Abstract In the present work, the removal of cadmium ions from aqueous solution using an agricultural waste as biosorbent, namely trunk palm fibers was investigated. The adsorption equilibrium and kinetics for this system were studied. Four adsorption models were applied to understand the nature of the adsorption process. Freundlich adsorption isotherm was found to best fit the experimental data. The maximum adsorption capacity was found to be 23.8 mg/g. The adsorption process was found to b...
Autori: Hosam Altaher
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26699

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract The aim of this paper is to determine the heat of combustion of plastic wastes resulted from municipal solid waste, automotive shredder facility waste and building and construction waste. The plastic wastes have been separated by flotation technique using as flotation media: water, ethanol, their mixtures and magnetic fluid. Resulted fractions have been analyzed aiming to determine the most effective fraction from the heat of combustion point of view. The obtained results have been ...
Autori: Liviu Costiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26750

Abstract Extensive use of plastics leads to the increase of non biodegradable wastes that have to be recycled due to both dramatically decrease of natural resources to producing them and to their increasing need as well as due to environmental issues. Most of goods made by materials based on wastes have to be commonly used by people. Antibacterial character of those is necessary to avoid epidemics. This paper deals with determination of antimicrobial character of materials based on polymeric...
Autori: Florica Silvia Cristina Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26751

Abstract Every day, millions of people are exposed to noise at work and to all the associated risks. It is a clear fact that the noise is an important problem in the industrial areas and moreover it becomes a significant issue in a wide range of other non-industrial environments as well. The current trend in the construction of gearboxes, regarding the speed increasing, favors the increase of the dynamic loads, which are accompanying the operation of equipments. The dynamic contact phenomen...
Autori: Zoltan Iosif Korka
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26765

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract A two-stage game model is proposed in this paper to study how China can best respond to the European Union (EU) Aviation Carbon Tax Scheme. Four possible strategies of China can be chosen, including “non-resistance”, “refusal of pay”, “retaliatory duties” and “credible threat”. The analytic result shows that the strategy “refusal of pay” makes a consensus with the Chinese policy as an optimal strategy for China. The main co...
Autori: Qiao Han
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26801

Abstract One of the imperative concerns in river water quality management is to develop pollution control strategies, which are satisfactory for all pollution load dischargers. The game theory can be applied for modeling the natural process of decision making among dischargers under the condition of having just one water quality checkpoint in a river reach, which receives pollution loads of several dischargers who would be penalized for any water quality violation from the standards. In this...
Autori: Armaghan Abed-Elmdoust
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26834

Abstract This study concentrates on the reactive biosorption of dyes such as Reactive Red 3:1 (RR3:1), Reactive Orange 13 (RO13), Reactive Blue 13 (RB13), Reactive Blue 72 (RB72). The modified fungal biosorbent, Paecilomyces sp., had a higher dye biosorption yield in our study. 100% of biosorption yield observed on RR3:1 and RB13 and 94.09% of color removal of RO13 with the chemically modified biosorbent were great. Also, such modified biosorbent exhibited remarkable performance in simulate...
Autori: Ahmet Çabuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26860

Abstract In the present study, several selected formulations based on recycled (rPP) or virgin polyolefins (vPP) and lignocelluloses were prepared and subjected to microorganism attack. Biodegradation tests were performed with microbial strains belonging to fungal genera, like Aspergillus, Penicillium and Fusarium. The initiation of biodegradation was demonstrated by Scanning Electron Microscope (SEM) micrographs showing the colonization of surface samples by microbial strains. The crystalli...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26879

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The results of batch tests of anaerobic dechlorination on groundwater samples collected downgradient from an industrial site in Northern Italy are presented and discussed. The experiments were carried out using sucrose as electron donor at equimolar concentration and at selected excess with respect to the total reducible species. The purpose of the study was to investigate the effectiveness of sucrose to achieve a complete chlorinated solvents degradations at the specific site, and ...
Autori: Luca Di Palma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26895

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

Abstract The objective of this study is to manufacture a geopolymer by replacing part of the metakaolinite by calcined oil-contaminated clay (OCC) and investigate its properties. The effects of the calcination temperature, the mix design of the alkali activator, and the degree of calcined OCC replacement on the properties of the geopolymer were studied. Evaluation of pozzolanic activity and compressive strength as well as micro structure observation by SEM and XRD were performed in this stud...
Autori: Huan-Lin Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26905

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Abstract The possibility to use release controlled fertilizers in the agriculture of the tropical countries is more important than in the agriculture of the countries of the cold regions. In this context, the purpose of this work is the characterization of an encapsulated commercial Fertilizer of Controlled Release named FERLENT®, which was covered with a polymeric material, obtained in situ, under controlled conditions, which allowed to corroborate the fairly well adjustment of the synt...
Autori: Mayra González Hurtado
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26916

Abstract This paper is an environmental approach of land cover in rural areas, based on a case study of Eastern Romania: Studineţ catchment (9669 hectares). The information necessary to shape the profile of the research area is obtained through diachronic and comparative analysis of different land cover categories. For this purpose, three distinct aspects were analyzed: weight and fragmentation of arable land; evolution and current weight of forests; expansion of xerotermophilous shrubs...
Autori: Iulian Cătălin Stângă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26924

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

Adsorptive removal of dibutyl phthalate (DBP) by bamboo biochar (BC) was investigated under various experimental conditions. BC demonstrated excellent sorptive ability to remove DBP from the aqueous solutions. The removal of DBP by BC increased as the contacting time increased and reached an equilibrium value after 240 min. The presence of natural organic matter decreased the removal efficiency while increased the time to reach sorption equilibrium. The adsorption of DBP on BC could be well ...
Autori: Junliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26934

Because of their toxic effects on the food chain and sources of water, antibiotics are potential pollutants that represent an important environmental problem. The objective of this research was to study the adsorption of penicillin G (PEN G) onto chestnut shell using a batch adsorption system. Maximum adsorption was achieved at pH 3.0. The equilibrium uptake capacity (mg/g) increased with increasing levels of initial penicillin G concentration. The uptake capacity of penicillin G onto chestnu...
Autori: Amir Sheikh Mohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26940

The grafted polymer of P(MMA-MAh)- PEGME synthesized was used as adsorbent to remove phenol in aqueous solution. Through the adsorption research of phenol, it was found the removal percentage (%) of phenol was promising when pH was less than 6. With the adsorbent dose increasing, the removal percentage increased, meanwhile the adsorption amount qe (mg·g-1) correspondingly decreased. It was taken 35h for the phenol adsorption with the grafted polymer to reach the equilibrium. The study...
Autori: Yun Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26966

The flocculation process is applied in wastewater treatment to separate the destabilized colloid particles (or the particles formed during the coagulation phase) by forming flocs. The scope of this research was to identify the predictability of the synthetic organic flocculants use for industrial wastewater treatment. The research was performed at small scale, in laboratory, but also at industrial scale, by applying the synthetic organic flocculants in a real industrial wastewater treatment p...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26975

The renewable sources of energy represent a viable alternative for satisfying the energetic needs of humanity in case the fossil fuels reserves are exhausted, which is estimated to occur in maximum 25 years if the current rate of exploitation is maintained. Nowadays, there are several concerns about the valorization of the energetic potential of these resources (wind, water flows, solar, geothermal energy etc.), but also a series of extremely beneficial practical uses (i.e. wind parks, photov...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26989

Environmental threats posed in the environment by plastic production and plastic wastes continue to be a major problem today, closely connected with the increase of plastics consumption by the population. Moreover, little efforts are involved in some parts of the world associated to plastic waste collection, recycling and reuse. Considering all these prerequisites, the identification and discussion of risks generated by plastic production and waste in the environment are performed in this pap...
Autori: Elena - Diana Comăniță
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26990

The adsorption characteristics of nitrate ions from aqueous solution using Lewatit FO 36 was investigated as a function of pH, biomass dosage and contact time. Results showed that optimum conditions were obtained at pH 8, adsorbent dosage of 160 mg/L and contact time of 60 min. At the optimized experimental parameters, the maximum nitrate adsorption capacity of Lewatit FO 36 was 200 mg/g and nitrate adsorption followed Freundlich model. Among seven kinetic models used in this study, the adso...
Autori: Mehdi Ahmadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26996

The release of nitrogen compounds into the environment is a major concern worldwide. Different studies howed that recycled materials have a high removal capacity for pollutants. Bentonite and its major clay minerals, smectites clays are common bleaching agents used for oil refinery bleaching and known as bleaching earth (BE). In this study regeneration of spent bleaching earth (SBE) acquired from the vegetable oil industry was surveyed via different methods and the regenerated spent bleaching...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27000

Adsorption studies of cadmium(II) were conducted on 623oK or 723oK carbonized banana peels named as BP623 and respectively BP723 as well as on the dried ones (BP). Carbonization enhances the quality of organic by-product used as adsorbent, reduces the equilibrium time and improves the quality of the final product (water). Evaluation of the effects of pH, contact time and solution temperature showed that the uptake of cadmium(II) ions was highly dependent on these factors, and increased with ...
Autori: Josiane Ponou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27009

Removal of Cd(II) from aqueous streams is of special concern because of its very high toxicity and persistent nature. The sorbents based on natural and waste materials have very promising performances in the treatment of Cd(II) contaminated waters. Very few reviews are available that provide valuable information on the various aspects of the utilization of natural and waste materials for Cd(II) metal ions removal. In this context, this review examines a wide range of materials as green sorben...
Autori: Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27033

Renewable resources, biopolymers and bio-based materials are keywords of the sustainable development and environmental sustainability concepts. Biopolymers, the green alternatives to fossil fuel based polymers, have already found different feasible applications, from consumer goods to regenerative medicine. Keratin is the biopolymer contained in the skin derivatives and appendages and is one of the the proteins with the most sophisticated architecture nature could produce. It is found in huge...
Autori: Hossein Rajabinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27043

This study highlights the potential use of yellow Zea mays seed chaff (YZMSC) biomass as a biosorbent for the removal of Cr3+, Cd2+ and Pb2+ ions from aqueous solutions. Fourier transformed Infrared analysis of the biomass suggests that YZMSC biomass is basically composed of cellulose and methyl cellulose. The biosorption capacities, qmax, of YZMSC biomass for Cr3+, Cd2+ and Pb2+ are 14.68, 121.95 and 384.62 mg/g respectively. Biosorption equilibrium was achieved at 20, 30 and 60 min for Cr3+...
Autori: Jonathan Oyebamiji Babalola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27083

This work evaluates the potential of Phyllanthus debilis for the adsorption of Zn2+ and Ni2+ ions using synthetic solutions. Adsorption experiments were performed in order to examine the effect of pH, contact time, biomass concentration and initial metal ion concentration in the removal process, in a batch mode. The results revealed that the adsorption is highly pH dependent. The adsorption of Zn2+ and Ni2+ ions were concentration dependent and increased from 2.446 to 8.688 mg/g for Zn2+ and ...
Autori: Mohammad Aslam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27084

Iron humate (IH) produced as a waste by-product during the industrial manufacture of humic substances from young brown coal was tested as a new cost-effective sorbent for the removal of inorganic arsenic from waters. Its removal efficiency was compared with that of two other non-conventional sorbents – magnetite and oxihumolite (weathered brown coal). Magnetite and IH have been found to be effective in removing both forms of inorganic arsenic (arsenite and arsenate) from aqueous solutio...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27098

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

The Project “Green - Industrial Symbiosis” (G-IS), in Emilia Romagna region (IT), took place in two phases: phase I, 05.2013 – 03.2014; phase II, 10. 2014 – 10.2015. During the first phase, it was completed the first part of the pilot project of industrial symbiosis (IS) in Emilia-Romagna, which involved 13 companies in the agro-industrial sector, 7 laboratories of the High Technology Network, with Unioncamere and Aster (promoters) and ENEA (technical and scientific co...
Autori: Laura Cutaia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27124

Waste frying oil (WFO) is a complex and heterogeneous waste collected mainly from restaurants and, to a lesser extent, from food processors and households. In the last decades, interest for this waste has deeply grown and a strong competition in grabbing this raw material has begun. About 90% of WFOs collected in Europe is recycled for biodiesel production, being the high free fatty acids (FFAs) concentration in WFOs one of the main drawback limiting the yield of the conversion process. In th...
Autori: Cinzia Pezzella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27130

In this study, the potential for biogas production from biodegradable bioplastics was evaluated. Mater-Bi® (a family of maizestarch based flexible films) and PLA (PolyLactic Acid; a rigid, polylactide-based, polymer) bioplastics were digested in laboratory batch reactors, alone or in co-digestion with pig slurry or scotta (partially deproteinized cheese whey), at 35°C or 55°C. Methane (CH4) and hydrogen (H2) production were monitored during the incubation period. Maximum CH4 (Mmax...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27134

The production process of wine and distilled generates several by-products (20-30% of total production). Currently, most of the solid by-products (pomace, stalks, lees and seeds) obtained as downstream of the vinery industry, are conferred to the distillery or, less frequently, used in agriculture and for energy production. As a consequence, much of the antioxidant compounds contained in the grape is unused in the products of processing and is lost. These substances (among which the most impo...
Autori: Paola Zitella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27135

Dried Typha angustifolia (TA) leavesor commonly known as the common cattail were evaluated as an adsorbent for the adsorption of lead in synthetic aqueous solutions. Equilibrium studies were conducted in a batch mode and the selected sorption isotherms were then applied. Equilibrium was achieved after 8 hours. The selected sorption isotherms were the Langmuir, Freundlich, D-R and Temkin model. Data fitting was done based on linear regression analysis. The adsorption system fitted the Langmui...
Autori: Yen Ling Sharain-Liew
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27166

A new material containing 2-(2′ thiazolylazo) p-cresol (TAC) grafted poly acrylamide (PAA) was prepared and its adsorption ability was studied for the removal of inorganic mercury from aqueous media. Adsorption of Mercury (II) ions from aqueous solution was investigated in detail as a function of mercury concentration, pH, ionic strength, and temperature. The adsorption data were analyzed by using the Langmuir, Freundlich and Dubinin-Radushkevich (DR) models. The adsorption of Mercury (...
Autori: Selçuk Şimşek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27170

Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by local low-cost agricultural by-products – peanut hulls, soybean shells and grapefruit peels were compared to develop high-efficient and low-cost biosorbents for removal of lead(II) from wastewater. Batch kinetics showed adsorption equilibrium at about 90 min and the adsorption process for the three biosorbents was better represented by the pseudo-second-order model than the pseudo-first-order model. Batch equilib...
Autori: Rui Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27176

The discovery of entropy in thermodynamics has set fundamental premises for the study and analysis of the relationship between the entropy law and economic processes, as one of the main objectives of such endeavours was to separate the qualitative aspects from the realm of economics. The law we have chosen to focus on in the present paper states that, in the universe or in isolated structures, entropy increases constantly and irreversibly, thus causing a continuous and unidirectional degradat...
Autori: Ionel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27179

The adsorption of tartrazine from aqueous solution was evaluated using an iron (III) modified zeolitic tuff. The adsorbent was characterized by scanning electron microscopy and X-ray power diffraction; the modification process does not affect the crystalline structure of the zeolitic tuff. Sorption kinetic, isotherms, dose and pH effects were determined and the adsorption behavior was analyzed. The sorption equilibrium was reached in 72 hours, the adsorption capacity determined by the Langmuir m...
Autori: Adrián Alcántara-Cobos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27182

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

The adsorbent gels utilized in this research project were synthesized from non-commercially available chitosan, obtained by deacetylation of chitin, which was isolated from fermented shrimp waste by a major local industrial food biopolymer. Chitosan-based adsorbent gels were used for the removal of a tris-azo dye (Direct Blue 71) from aqueous solutions. Sorption experiments focused on the chemical modification of chitosan using two cross-linking agents, sodium tripolyphosphate (TPP) and glutaral...
Autori: Reyna G. Sánchez-Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27184

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

In this study, the biosorption of zinc(II) ions from the aqueous solutions by the lichen biomass of Xanthoria parietina (L.) Th. Fr. was studied as a function of contact time, initial pH of metal solution, biosorbent concentration, initial metal ion concentration and stirring speed in a batch system. The optimum pH value for maximum zinc biosorption was found to be 5.5. Concentrations intervals from 50 mg/L to 250 mg/L were tested and it was observed that the biosorption efficiency depends on th...
Autori: Zuleyha Bingul
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27213

Banana stalk (BS) waste is used to remove Pb2+ from aqueous solution. Equilibrium data were analyzed with Langmuir and Freundlich adsorption models, which fit better in the former equation. The qmax (maximum metal uptake capacity) for Pb2+ adsorption was 105.14 mg/g of BS at pH 5.0, which followed pseudo-second order kinetics model. IR spectra confirmed the participation of hydroxyl, amino, and acidic functional moieties in the removal of Pb2+. The major mechanism involved in the biosorption of ...
Autori: Kashif Iqbal Sahibzada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27214

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

Composted livestock waste (CLW) was studied as one low-cost material to remove Pb(II), Cu(II), Cd(II) and Zn(II) from simulated acid mine drainage (AMD) by batch and column experiments. The adsorption isotherm data were well fitted by the Langmuir model. The maximum monolayer adsorption capacities were 0.5485 mmol/g for Pb(II), 0.4092 mmol/g for Cu(II), 0.2246 mmol/g for Cd(II), and 0.1879 mmol/g for Zn(II) at pH 4.0. Due to the competition effect, the adsorption capacity of the single metal ion...
Autori: Mingliang Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27262

This study investigates the adsorption of several metals in aqueous solution, by hemp materials (loose fibre and felted fibre). After characterization of the fibre, an extensive study was conducted on the adsorption properties of this material. The experiments were carried out in poly-metallic aqueous solutions containing Al, Co, Cr, Cu, Ni and Zn at a concentration of 1 mg L-1 and 10 mg L-1 each. The pH effect was found to lead to an optimum between pH 4 and 4.5. The kinetics of the adsorption ...
Autori: Justine Bugnet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27272

The Romanian peat was used as low-cost adsorbent to remove Cd(II) ions from aqueous solutions. The cadmium adsorption capacity of the peat was studied as a function of the solution pH (3-5.5) and temperature (293 – 333 K). Adsorption capacity was found to increase with the pH increasing and temperature decreasing and attained a maximum value of 27.9 mg/g at pH = 5±0.1 (acetate buffer) and 293 K. In addition, various thermodynamic parameters such as free energy change (ΔG0), en...
Autori: Catalin Balan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27276

This study presents the results obtained in tailoring thin films of alumina, deposited onto aluminium substrates by spray pyrolysis, at 250°C, using AlCl3 solutions (0.15M) in a water:ethanol (1:1) solvent mixture. As morphology controlling agents, acetylacetone and maleic acid based copolymers are added in the precursors’ solutions. The precursors’ systems are analyzed by FTIR spectroscopy and the surface morphology of alumina thin films is investigated by atomic force microscop...
Autori: Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27291

Construction industry uses a huge quantity of traditional and modern building materials which generally are produced to satisfy different demands, such as: resistant and safety requirements, friendly with the environment, architectural aspects etc. Researches must solve any requirements related to materials properties and offer a large diversity from which the proper solution must be considered. For improving the mechanical properties of polymer concrete, the use of fibers of different types is ...
Autori: Vasilică Ciocan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27306

The paper aims to present the sorption properties of two sorbent substrates (composts) prepared by aerobic fermentation from vegetables waste composted with beech sawdust (BR2) and beech ash (BC1) to be used for Cu2+ removal from wastewaters. The composts structures and surface properties were characterised in terms of active groups (FTIR), crystallinity (XRD), morphology (SEM), topography (AFM) and specific surface and pores analysis (BET), and the changes in properties after Cu2+ sorption were...
Autori: Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27323

Acetone-Butanol-Ethanol (ABE) industrial production by fermentation is strongly affected by the low concentration of solvent (<25 g/L) that affects the cost of the recovery process. To decrease the overall cost of the butanol production, alternative routes for the recovery have proposed in literature. This paper presents a techno-economic analysis of an innovative butanol recovery process from ABE fermentation broth based on gas stripping technique. The comparison with a recovery process bas...
Autori: Lucia Salemme
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27346

The monomer with ketimine side group, 2-(1-(benzylimino)ethyl)phenol (2-BEP), was synthesized from the condensation of 2- hydroxyacetophenone and benzyl amine. The enzymatic oxidative polymerization of 2-BEP was performed in the presence of hydrogen peroxide using horseradish peroxidase (HRP) as catalyst. The oxidation reaction was carried out in various solvents and phosphate buffers at room temperature. These studies have shown that a dark brown polymer was successfully synthesized by utilizin...
Autori: Senem Tapan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27377

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

The objectives of this study were to investigate the composition of activated sludge biofilms and flocs in a sequential batch reactor (SBR) and in a sequential biofilm batch reactor (SBBR), and to evaluate the role of the extracellular polymeric substances produced in the reactors in comparison with the respective treatment efficiency of domestic wastewater, containing 1 to 40 mg/L phenol. Both reactors showed variable removal efficiencies. The SBR was found to contain more protistan species ...
Autori: Chrysi A. Papadimitriou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27422

A light-driven dissipative engine, which must necessarily operates at a nonzero rate and far from equilibrium to be capable of providing power and work, is investigated in this paper. On the basis of the assumptions that the heat exchange between the working fluid and the environment obeys the linear phenomenological heat transfer law [ q  (T 1) ], the piston trajectories minimizing the entropy generation are determined. Furthermore, numerical examples are provided for...
Autori: Lingen Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27432

Removal of the heavy metal ions from water disposals remains a widespread problem due to their adverse influence on public health. The most harmful materials are the products of nuclear fission called radioisotopes such as cerium ions. Cerium barely interacts with adsorbent materials, therefore the new substances capable to bind cerium are of great interest. Ca and Na alginate samples were incubated in Ce3+ solutions; adsorption capacity was measured and the results were evaluated using Langm...
Autori: Maxim Khotimchenko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27435

The negative effects of acid mine drainage (AMD) on the natural and human environments are well understood in South Africa, yet a robust and economic AMD treatment technology has not been developed. The current study aimed at exploring the performance of synthetic zeolite F9 in AMD treatment with specific focus on iron and manganese removal. For this, batch adsorption mode was adopted for which the effects of adsorbent dosage, initial pH and temperature were investigated. As a result, it was fou...
Autori: Mike Masukume
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27454

Three modified bentonites, hydroxy-aluminum pillared bentonite (Al(OH)-Bent), cetyl trimethylammonium bromide modified bentonite (CTAB-Bent), and both cetyl trimethylammonium bromide and hydroxy-aluminum modified bentonite (Al(OH)-CTAB-Bent) were prepared and characterized by Fourier transform infrared spectroscopy (FTIR) analysis. Batch experiments were conducted on the adsorption of phenol at different temperatures, pH and initial concentration. The results indicated that adsorption capacity o...
Autori: Xiping Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27481

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

Nowadays, the polyolefins (polyethylene, polypropylene) are increasingly consumed in large amounts for many applications. This issue causes a concern regarding the environmental impact of the waste materials generated after the first use. Mechanical recycling of polyolefin wastes helps to conserve oil and gas resources and reduce the polymeric waste accumulation in environment. In this paper, the modification of some post-consumer polypropylene (rPP) properties coming from packaging processi...
Autori: Maria Râpă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27493

This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multi-active blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than ...
Autori: Jacob Kitinya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27505

This paper introduces basic information on the biodegradation of polymers as well as the mechanisms of degradation and factors influencing this process. This paper describes prodegradant additives that induce decomposition of polymers to biodegradable compounds with regard to additives causing oxo-biodegradation. Based on the results of experiments conducted for molded pieces made of polypropylene and extrudates made of low density polyethylene with a d2w prodegradant additive, dependences betwe...
Autori: Tomasz Jachowicz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27519

This work describes the variations in nitrogen (N) and phosphorus (P) removal performances and bacterial population dynamics in response to different influent C/N and C/P ratios in a novel BNR-IC process combining biological nutrients removal (BNR) with induced crystallization (IC). A good nutrients removal performance was achieved at 7.8 of C/N ratio and 23.3 of C/P ratio, where P and TN removal efficiencies were 94.0±2.4% and 90.5±4.3%, respectively. Moreover, significant changes...
Autori: Haiming Zou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27523

This paper investigates the macrophyte Azolla pinnata modified with sodium hydroxide, as a bioadsorbent for Cu2+ and Pb2+ ions in synthetic solutions. Biomaterial characterization was performed using Scanning Electronic Microscopy (SEM); Energy- Dispersive X-Ray Spectroscopy (EDX); Fourier Transform Infra-red (FTIR) spectroscopy techniques and through the blocking of carboxylic and sulfonic functional groups. Kinetics of the process has highlighted a quick and efficient adsorption, even in low ...
Autori: Arielle Barros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27532

A series of column experiments were conducted to study volatile contaminant (benzene) removal and process principles using soil vapor extraction (SVE) under different thermal conditions. Compared with the normal SVE method, two thermal methodssteam injection and electrical resistance heating effectively increased the benzene vapor diffusion and removal rates. The removal efficiency of benzene with the electrical resistance heating method was 96.5%, which was significantly higher than that with t...
Autori: Peng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27534

The potential use of a novel low-cost adsorbent, Eupatorium adenophorum Spreng, as a solution to remove Cr(VI) ions from aqueous was reported. Effects of various regulating parameters, such as pH value of reaction, adsorbent dosage and temperature, were investigated. To fit the adsorption equilibrium data, Langmuir isotherm and Freundlich isotherm were invoked. Additionally, thermodynamic parameters of the adsorption process, such as ΔG, ΔS and ΔH, were also calculated. The res...
Autori: Chen Jin-fa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27535

The aim of this study was to examine the adsorption of malachite green dye from aqueous solutions on the waste foundry sand. The effects of contact time, adsorbent amount, pH and initial dye concentration were investigated. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin adsorption isotherm models. The adsorption capacity of waste foundry sand for the removal of malachite green dye was determined with the Langmuir and found to be 23.29 mg/g. The adsorption isothe...
Autori: Elif Hatice Gürkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27536

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

It is acknowledged that organic fertilizers and wastes, such as animal slurries/manure from intensive farm enterprise, sewage sludge, poultry litter are and will continue to be spread on agricultural land and provide beneficial nutrients to crops. However, many of these materials which are also potentially polluting if not properly managed can pose a risk to groundwater and surface water quality. Generally, their distribution on the soil is performed with specialized machines to reduce the risk...
Autori: Vasilica Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27545

Among the organic pollutants, the chlorinated phenols represent an important class of compounds having a stable world market of ca. 100 kt per year. Due to their aryl structure and presence of the chlorine atom, chlorinated phenols are exceptionally recalcitrant toward chemical reactions aimed at their reduction. Adsorption from liquid phase has received special interest due to its flexibility and simplicity in operation. Especially adsorption using activated carbon (AC) has been recognized by t...
Autori: Marius Sebastian Secula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27552

Two multiple linear regression (MLR) models were developed with the aim to estimate the decomposition temperature of a series of polyimides. Two parameters, Tni and Tai, corresponding to the temperature of 10 % weight loss of the sample, determined by dynamic thermogravimetric analysis under conditions of N2 inert atmosphere and air, respectively, were used as a criterion for thermal stability. The obtained MLR models correlate thermostability with a series of characteristics of the studied poly...
Autori: Catalin Lisa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27556

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Fusarium Head Blight is caused by several Fusarium species. Infections can result in mycotoxin contamination on cereals and associated foods. Harvested products are contaminated due to its secondary metabolites. The aim was to analyse the occurrence of spike Fusarium and Alternaria spp. in hulled Triticum spelta L. wheat species via polymerase chain reaction (PCR) method and the deoxynivalenol (DON) content analysis. Three varieties of spelt were used (Ceralio and Rubiota – winter and one ...
Autori: Karel Suchý
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27562

The potential of Sphagnum moss peat to adsorb oxyanions (As(III), As(V), Sb(III), Sb(V) and Se(VI)) from aqueous solution was studied in batch mode. For arsenic (both species) and selenium, the results were negative: moss peat is not able to retain these oxyanion. For antimony, the hydroxyl and carboxyl groups from the Sphagnum moss peat surface seems to be responsible for Sb uptake. Kinetic studies were conducted for both Sb(III) and Sb(V) and a fast uptake process was observed, equilibrium bei...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27565

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

In this research, the capability of uranium biosorption by dried biomass of the red algae was investigated in a batch system. For the screening of the most appropriate biosorbent, they were placed in 0.5 mmol/L uranium solution with different pH for 3hrs of contact times. The obtained results showed that the species of the Gracilaria corticata (J. Agardh) are having the maximum rate of the biosorption. Sorption equilibrium was reached within 3hrs of contact time (at pH 4.5), and the results of t...
Autori: Reza Dabbagh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27596

This paper presents the results of experimental tests on polymer concrete prepared with different wastes. Two types of polymer concrete mixes were compared. The control polymer concrete was obtained with epoxy resin, natural aggregates in two sorts (0-4 mm and 4-8 mm) and fly ash waste used as filler. To the control mix, both sorts of natural aggregate were replaced in different dosages by polystyrene granules waste. The influence of polystyrene granules as substitution of aggregate on density, ...
Autori: Andrei Burlacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27599

A new low-cost activated carbon was developed from kiwi peel for removing Pb(II) from aqueous solution. The adsorbent characteristics were determined by different analyses such as BET, FTIR and SEM. The adsorbent demonstrated remarkable characteristics such as high surface area (306.18 m2.g-1) and large total pore volume (0.4810 cm3.g-1). The effect of pH, contact time, initial concentration, shaking rate and adsorbent dosage on the Pb removal efficiency was investigated. It was found that the o...
Autori: Mostafa Rahimnejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27605

The present work aimed to optimize a new economic medium for biopolymers production by Rhizobium leguminosarum. Biopolymers were poly-β-hydroxybutyrate and exopolysaccharide (EPS and PHB). They were extensively used in various industrial sectors. Statistical experimental designs and Response Surface Methodology were employed to optimize the medium components. A central composite design was applied to increase the production yield and predict the optimal values of the selected factors. An op...
Autori: Mohamed Sellami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27609

The study of binary biosorption of Pb(II) and Cu(II) was performed by pine nuts shell. Results were compared with the single biosorption of Pb(II) and the single biosorption of the Cu(II). Experiments were performed in batch stirred and in a continuous system. The presence of lead caused a slightly decrease of the copper biosorption yield and can be related to the copper equilibrium uptake. This antagonistic action can be related to competition phenomena between metal ions in solution for active...
Autori: Gabriel Blázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27611

FLUCTUATION OF RIVER NETWORK WATER ENVIRONMENTAL CARRYING CAPACITY IN A COMPLICATED RIVER-LAKE SYSTEM    • MINERALOGY AND GEOCHEMICAL DISTRIBUTION OF HEAVY METALS FOR THE FAGUL CETĂȚII TAILINGS, ROMANIA    • ACCUMULATION AND AVAILABILITY OF TRACE ELEMENTS FROM SOIL INTO ORIENTAL TOBACCO GROWN IN MACEDONIA    • OLFACTORY EFFECT ON LANDSCAPE PREFERENCE    • EFFECT OF MOLASSES ADDITION AS BIODEGRADABLE MATERIAL ON PHENOL REMO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27628

Thin-film transistor liquid-crystal display (TFT-LCD) waste glass can be used as a raw material for producing geopolymers, because it contains large amounts of silicon and aluminum in its amorphous structure. The setting time and compressive strength were evaluated to determine the quality of the geopolymer product with various amounts of nano-SiO2 (0%–3%) and TFT-LCD waste glass replacement (0% - 40%). The microstructures of the samples were characterized using mercury intrusion porosimet...
Autori: Kang Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27634

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

Recycling of solid plastic waste composed of post-consumer mixed polyolefines (polypropylene and polyethylene) was carried out by injection moulding of secondary material streams. The materials have been characterized by melt flow index (MFI), tensile, bending and impact measurements, density and differential scanning calorimetry (DSC). The sink-float technique was used to separate the polyethylene fraction, which was then blended into virgin polyethylene at different ratios and processed anew. ...
Autori: Laurens Delva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27646

Copper pollution is common across the world and has caused serious public health problems recently. Among the conventional methods, adsorption has proved effective, economic, versatile and simple for the removal of aqueous Cu(II) contaminants. Deposits of natural Kaolin are abundant around the world, and are regarded as valueless due to its limited usage in industry. In this study, the adsorption behavior of natural Kaolin towards Cu(II) was evaluated. According to the results, the isothermal ad...
Autori: Qiang Tang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27651

Bacillus thuringiensis (Bt) is a spore-forming bacterium which produces insecticidal crystal protein in the sporulation phase. Polymerase chain reaction (PCR)-based identification of Bacillus thuringiensis toxin genes has become a routine step in most B. thuringiensis isolation and characterization initiatives. In the present study, eighteen native Bt isolates from diverse habitats of North India were taken for the presence of cry1 type genes. The distribution of cry1 gene families in native ...
Autori: Shiv Shankar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27666

Hexavalent chromium Cr(VI), a constituent of wastewater from many industries, is regulated by the Environmental Protection Agency (EPA) as one of the priority pollutants. Adsorption is an important technique that can be used for Cr(VI) removal from wastewater. The challenge in adsorption techniques is to find a cheap, widely available adsorbent that has a high adsorption capacity to Cr(VI). Dates stones (DS) and palm fiber (PF) are two agricultural wastes that are produced from palm trees. These...
Autori: Reda Abubeah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27689

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27782

In the present study, Dowex HCR-S/H, cationic resin was used as a resin for the removal of cadmium from aqueous solutions. The experiments were carried out in a batch vessel. Subsequent experiments were performed as a function of initial solution pH, resin dosage, agitation time, initial Cd2+ concentration, solution temperature and agitation speed. Ion exchange rate increased with the increase in initial cadmium concentration, stirring speed and temperature. The Langmuir, Freundlich, Elovich,...
Autori: Baybars Ali Fil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27777

Bare zero-valent iron nanoparticles (bare-ZVIN) have a great tendency to aggregate, which drops their reactivity with pollutants. To address this issue, polyvinylpyrrolidone stabilized-ZVIN (PVP-ZVIN) was synthesized and used for the removal of Cd2+ from aqueous solution in a batch system. The effects of operation conditions such as the pH of aqueous solution (2-8), reaction time (0-120), adsorbent concentration (1-6 g L-1) and the initial Cd2+ concentration (10-60 mg L-1) on the removal efficie...
Autori: Amirhosein Ramazanpour Esfahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27764

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27729

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27730

In this study, the removal of Cu(II) from real industrial wastewater, being taken from galvanotechnic industry, by means of manganese ferrite (MnFe2O4) nanoparticles (NPs) was investigated. The effects of pH, adsorbent dosage, and contact time on Cu(II) removal from wastewater were monitored using the real wastewater while the effect of initial concentration was studied on synthetic aqueous solutions. Optimal conditions were found for copper removal in this study. Cu(II) removal and adsorption c...
Autori: Naim Sezgin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27743

Debris from deciduous trees in the form of park green waste was investigated as a potential biosorbent for the removal of chlorinated solvents from water. The sorption properties of beech leaves and cupules, oak leaves and acorns, birch leaves and lime leaves (all tree species common for a moderate climate) in a non-modified form were investigated with regard to the removal of perchloroethylene, 1,1,2-trichloroethane and 1,1,1,2-tetrachlorothane. The preliminary results showed that these biosorb...
Autori: Marek Tobiszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27760

The research has been focused on concretes in which the continuous phase is some kind of polymeric resin and the discrete phase is some type of mineral aggregate. Such composite materials are known as Polymer concretes (PC) and boast several advantages such as lower weights, higher resistance to corrosive environments and chemical attacks, faster curing and lower permeabilities. In PC the inorganic fraction can reach up to 90% of the total and is made up of aggregates such as sand and gravel. Th...
Autori: Paolo Pozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27799

Environmental pollution has become a major global problem. However, despite increased environmental investment, studies have not clarified whether environmental pollution has been effectively controlled. On the basis of 1998-2014 panel data on three types of industrial waste from 31 mainland China provinces, a stochastic frontier analysis (SFA) model was used to estimate the input efficiency of environmental governance in China, explore the overall characteristics of input efficiency, and explor...
Autori: Ye Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27862

The study performs an approach to the "environment - life quality - biotechnological molecular gastronomy" direction, an axis with consistent theoretic and practical potential in offering attractive and pleasant culinary products for the consumers, with the same effect on health as supplementary under pharmaceutics format. The paper proposes a change of paradigm, in order to develop certain excellence gastronomic preparations, based on incorporating functional and/or nutraceutic foo...
Autori: Romulus Gruia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27855

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

The macrophyte Pistia stratiote was used as biosorbent for the removal of Black Krom KJR (BK-KJR) dye in synthetic aqueous solution. Initially, some tests were performed to verify the best operational conditions such as pH, biosorbent particle size, sorption temperature and stirring speed, which were later used in the kinetic and equilibrium tests. All tests were performed in duplicate. The highest removal rates of the pollutant were achieved at the process conditions of initial pH 2, granulo...
Autori: Aparecido Nivaldo Módenes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27843

The aim of this paper is to determine the influence of desulphurization on process efficiency and monoethanolamine (MEA) absorption capacity. The experiment was conducted on a circulating fluidized bed combustion (CFBC) which uses indigenous coal from Jiu Valley. We determined the absorption capacity of MEA considering three values of concentrations in the solution: 20%, 30% and 40%. It was noticed that the higher the concentration of MEA is in the solution, the greater is the influence in th...
Autori: Cristian Dincă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27879

The main topic of this study is the photo-optical and electrochemical behavior of a series of fluorinated copolyimides containing both oxadiazole and perylene moieties in the main chain. The polymers prove a strong photo-optical stability on a large temperature domain and display different types of photoluminescent behavior in solution and in solid state, with emission maxima in the bluish and green–yellow domains. Cyclic voltammetry investigations suggest that the polymers can be easil...
Autori: Radu-Dan Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27883

A study on the biodegradability of several formulations based on poly[vinyl alcohol] (PVA) and wood flour has been carried out. Basically, all formulations are based on PVA and wood flour, and the influence of starch, glycerol and/or polyvinyl chloride (PVC) incorporated in some of them was investigated. Biodegradation was performed by incubation of the composites with a selected Aspergillus niger strain able to act as an polymer biodegrading agent. The composites biodegradation was evaluated...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27886

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

The influence of initial metal ion concentration and temperature on the adsorption of Zn(II) from aqueous solution onto amino ethyl cellulose (AEC) functionalized with Orange 16 reactive dye, was examined. Batch experiments were performed at pH of 4.0 and adsorbent dose of 8.0 g/L previously established as optimum, ranging the initial Zn(II) concentration between 22.74-181.92 mg/L and temperature between 2 and 60 C. Three isotherm models (Langmuir, Freundlich and Dubinin – Radus...
Autori: Gabriela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27904

Biosorption of copper(II) by lyophilized and thermally treated bacterial biomass of Pseudomonas aeruginosa PAO1 and Pseudomonas fluorescens BME in aqueous suspension was studied. The cell surface properties were characterized and the experimental conditions, e.g., pH, adsorption time, and initial metal concentration were optimized for efficient biosorption. The surface charge was negative at pH above 2.5 for P. aeruginosa, and above pH 4 for P. fluorescens. The highest copper(II) uptake was ...
Autori: Anikó Kőnig-Péter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27917

In this study we investigated the possibilities of using recyclable fine and coarse grain waste obtained by grinding Polyethylene Terephthalate (PET) containers, as light filling materials for different applications (clay dams, highway embankments, and backfills behind retaining structures. Various geotechnical tests were performed on clayey soil and soil-PET mixtures using recycled fine and coarse granules of Polyethylene Terephthalate bottles. The results indicated that the use of the recyc...
Autori: Osman Gunaydin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27920

Agro-industrial waste are seen as potential precursors in the development of adsorbents for the removal of phenolic compounds, which exhibit a harmful effect to human health due to their high toxicity. This work evaluated the use of coal prepared from coconut tree agro-industrial waste, for the adsorption of phenol in aqueous solutions. Three coal samples were prepared as follows: carbonized only (Cb), activated with synthetic air (Cair) and activated with CO2 (CCO2). Based on the results of ...
Autori: Marta Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27937

The present study explores the potential use of plant waste i.e. spotted golden thistle (Scolymus maculatus L.) stalks, as an inexpensive sorbent for the removal of methylene blue from synthetic aqueous solutions. Firstly, the waste material was characterized using different analysis methods, then kinetics and equilibrium of dye sorption were investigated using a batch sorption technique. The influence of contact time, initial dye concentration, sorbent dose, particle size and agitation speed...
Autori: Zoubida Senouci Bereksi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27941

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27946

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27947

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27968

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

This study evaluates the environmental impacts of four types of frozen food packages throughout their lifecycle and suggests strategies for reducing their related environmental impacts. The four most widely used frozen food packaging materials were chosen for this study: (1) pouches composed of low-density polyethylene (LDPE) film; (2) pouches composed of polyethylene terephthalate (PET) and LDPE film laminate; (3) cardboard boxes coated with LDPE; and (4) multipackage composed of cardboard boxe...
Autori: Daina Kliaugaite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27979

In this study, Coal Fly Ash (CFA), a byproduct of coal combustion power plants, was used as an adsorbent to remove color from locally-obtained pulp mill effluent (PME). Batch adsorption studies were conducted to determine the adsorption parameters that would result in the maximum color removal from PME at the lowest CFA dosage and process cost. The effects of operating variables on color removal were studied by varying: 1) CFA dosage, 2) initial PME pH, and 3) contact time. The findings indic...
Autori: Christopher Willett
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27986

In this paper, several image analysis techniques have been applied aiming to obtain useful information regarding the processing of municipal solid waste polymers. An automated color extraction method has been applied in order to quantize the color distribution in the polymer wastes aiming their resource and time-efficient separation according to their color. Also, by processing different density fractions from the polymer waste the color of the final material has been predicted, as well as th...
Autori: Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27994

Water retention capacity and hydraulic conductivity are major soil hydraulic properties that influence soil quality and the environment. The objective of this work was to assess major soil hydraulic characteristics in response to the effect of soil management and tillage practices. Eight soil treatments were considered: conventional tillage, reduced tillage, no-tillage, fallow notillage, abandoned soil, compacted soil, plough on compacted soil, and application of super absorbent polymers. The...
Autori: Fereshte Haghighi Fashi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27996

With the rapid development of electric vehicles (EV), more and more EV batteries will intensively face the retirement. If they are treated improperly, EV batteries might pose a serious threat to human health and environment. Therefore, recycling spent EV battery is full of significance. However, the recycling system and specific policies have not be well established in China. This paper aims to evaluate several recycling subsidy policies being considered and tested in China for their influenc...
Autori: Xin Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28002

The paper reports on the preparation of polysiloxane hydrophobized viscose-maghemite/goethite magnetic composite with properties appropriate for uses in oil spill sorption from polluted aqueous media. A multi-step procedure was employed to obtain the polymeric composite. The structures of the prepared samples and precursors were analyzed by Fourier transform infrared spectroscopy (FTIR), whereas their morphology was investigated by means of scanning electron microscopy (SEM). The hydrophobic...
Autori: Răzvan Rotaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28008

Sustainability and renewability in constructional materials and also utilization of such materials for various engineering purpose is the need of the hour. Green retrofitting with the aid of green fibre reinforced polymer (FRP) materials, made up of natural bio fibres like sisal would contribute to sustainable development. Non fossil-fuel carbon precursor organic fibres, i.e. sisal FRP composites were used for retrofitting of reinforced concrete (RC) beams, designed to undergo shear failure. ...
Autori: Tara Sen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28025

Since the middle of the past century, when the synthetic fibers began their rise, wool has steadily lost importance in the textile sector, and now is a marginal fiber on the textiles market. Great amounts of non-marketed raw wool have turned from an income source for sheep farmers into a problematic waste, which is, at best, burn or landfill. With increasing interest for sustainable use of natural resources, wool was reconsider as an underrated, underused renewable resource, worthy of a bette...
Autori: Hossein Rajabinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28031

Extracts of Bifurcaria bifurcata seaweed were obtained by diverse conditions. Different extraction techniques, such as hydrothermal and ultrasounds, and three different solvents (water, ethanol and water/ethanol (50:50)) depending on technique were used. Moreover, supercritical CO2 (SC-CO2) with 10% of ethanol as co-solvent using different extraction times (30, 45 and 60 min) was also used as extraction technique. Extraction yield, phenolic content and antioxidant activity were measured for e...
Autori: Rubén Agregán
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28039

The development of green eco-friendly inhibitors for the corrosion of metallic surfaces in acid media is still considered as a major challenge and target for corrosion-mitigation engineers. We have prepared in this work 4 different extracts from the plant Ruta Chalepensis using methanol, chloroform, ethyl acetate, and aqueous ethyl acetate solvent systems. The flavonoids content, as well as the other oxygenated compounds, in the 4 extracts was carefully screened using the gas chromatographic&nda...
Autori: Meryem Amal Benghalia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28063

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

The maintenance of flexible roads or roads at end of life service generates high quantities of reclaimed asphalt pavement every year. The reuse of these materials, considered for a long time as waste, allows a substantial saving in transport, energy, and maintains dwindling natural resources. Recycling of asphalt also helps to reduce inert waste storage volumes, and conserve valuable landfill space. The applicability of recycled asphalt was tested in laboratory, and asphalt mixtures containing 2...
Autori: Mehena Oualit
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28117

There are considerable environmental and health and safety concerns regarding liquid crystal display (LCD) waste glass because of the waste electrical and electronic equipment (e-waste) that is deposited in landfills. In current study, the effect of variation in LCD waste glass on the deconvoluted fractions of silicon centers of metakaolin geopolymers has been comprehensively investigated to discover the underlying mechanisms governing the performance. Solid/liquid ratio affects the kinetics of ...
Autori: Kang-Wei Lo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28146

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

This present study, investigates the performance of activated sardine scale powder (ASSP)/ Cellulose acetate (CA)/Polyvinylpyrrolidone (PVP) and powdered activated carbon (PAC)/ Cellulose acetate (CA) / Polyvinylpyrrolidone (PVP) composites membranes prepared by phase inversion for the elimination of humic substances (HS) from aqueous solutions. The materials and composites membranes were characterized by FTIR, XRD, SEM analyses. Overall, the results exhibit the higher performance of ASSP /CA/ P...
Autori: Naziha Sid-Sahtout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28199

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

Printed circuit boards are the most important component of any electrical and electronic device. The average metal content in waste printed circuit boards is ~30-35% whereas the rest of the material is a non-metal fraction (NMF). Metals in the waste printed circuit boards are recycled for their value whereas the NMF is mostly sent to landfills or incinerators for disposal. The circuit board laminates contain flame retardant chemicals that pose potential hazards to the environment and to public h...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28216

The textile industry has been contributing to the generation of wastewater containing dyes during the dyeing process. In this sector, Reactive Blue BB is a dye used on a large scale. One method widely applied to dyes wastewater treatment is adsorption. This technique is inexpensive since it can apply industrial by-products as adsorbents. In this work, the adsorption of Reactive Blue BB dye by the sugarcane bagasse, a by-product from the sugar and alcohol industry, was evaluated in batch syste...
Autori: Handria Hariane Piffer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28226

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

Impregnation of aluminium ion onto silica gel (SG) surface (Al/SG) is to increase the adsorption capacity of an anionic dye such as Indigo carmine (IC). The impregnation was carried out using wetness impregnation. The change of the functional group was evaluated by FTIR, crystallinity was determined using XRD, surface morphology were studied by SEM-EDX, while surface area and pore size using N2 gas adsorption-desorption analyzer. Meanwhile, the best of IC adsorption condition onto SG and Al/SG ...
Autori: Yudi Aris Sulistiyo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28253

Due to the environmental deterioration because of pollution and excessive consumption of natural resources, governments are driving efforts to limit pollution emissions and to encourage cleaner manufacturing. The most common interventions governments adopted are providing subsidy to green products and taxing non-green products. With the green consciousness improving gradually, consumers prefer to buy products based on greenness of products with price and quality level together. In order to inve...
Autori: Yitong Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28258

TDue to the environmental deterioration because of pollution and excessive consumption of natural resources, governments are driving efforts to limit pollution emissions and to encourage cleaner manufacturing. The most common interventions governments adopted are providing subsidy to green products and taxing non-green products. With the green consciousness improving gradually, consumers prefer to buy products based on greenness of products with price and quality level together. In order to i...
Autori: Yitong Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28259

Groundwater at an abandoned industrial area near Bergamo, Italy, was historically contaminated by tetrachloroethylene (PCE) (>100 μg/L) and, to a lesser extent, by trichlorethylene (TCE), dichloropropane (DP) and 1,1,2,2-tetrachloroethane (R-130). A liquid reagent (EHC® Liquid) was selected for remediation of groundwater at the site. The reagent is provided in two parts: EHC® Liquid Mix (a soluble organo-iron salt), and ELS® Microemulsion (a lecithin-based carbon substrate), a...
Autori: Alberto Leombruni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28300